EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

gamma-damascone

Sponsors

Name:(E)-1-(2,2-dimethyl-6-methylidenecyclohexyl)but-2-en-1-one
CAS Number: 35087-49-1Picture of molecule3D/inchi
Nikkaji Web:J2.513.699C
XlogP3-AA:3.50 (est)
Molecular Weight:192.30160000
Formula:C13 H20 O
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 94.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.92800 to 0.93400 @ 20.00 °C.
Pounds per Gallon - (est).: 7.731 to 7.781
Refractive Index:1.49300 to 1.49700 @ 20.00 °C.
Boiling Point: 267.76 °C. @ 760.00 mm Hg (est)
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.008000 mm/Hg @ 25.00 °C. (est)
Vapor Density:6.7 ( Air = 1 )
Flash Point: 208.00 °F. TCC ( 97.78 °C. )
logP (o/w): 3.400
Soluble in:
 alcohol
 water, 8.831 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:high ,
recommend smelling in a 10.00 % solution or less
Substantivity:64 hour(s) at 100.00 %
fruity floral rose green apple cooked apple plum thujonic tobacco
Odor Description:at 10.00 % in dipropylene glycol. fruity floral rose green cooked apple plum thujonic tobacco
Odor sample from: Vigon International, Inc.
Odor and/or flavor descriptions from others (if found).
Firmenich
DAMASCONE GAMMA
Odor Description:A diffusive fruity, floral and thuyone-like note, with slight tobacco undertones
DAMSCONE GAMMA gives unique effects. Excellent results can be obtained with aldehydic, floral, woody, herbal, citrus and fruity notes.
 
Cosmetic Information:
None found
 
Suppliers:
Azelis UK
DAMASCONE GAMMA
Services
Ernesto Ventós
DAMASCONE GAMMA FIRMENICH 944580
Odor: FLORAL,ROSE,GREEN,FRUITY,THUJONE
Firmenich
DAMASCONE GAMMA
Odor: A diffusive fruity, floral and thuyone-like note, with slight tobacco undertones
Use: DAMSCONE GAMMA gives unique effects. Excellent results can be obtained with aldehydic, floral, woody, herbal, citrus and fruity notes.
Penta International
DAMASCONE GAMMA, Kosher
Vigon International
Damascone Gamma
Odor: A diffusive fruity, floral and thuyone-like note, with slight tobacco undertones
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 > 2000 mg/kg
DAMSCONE GAMMA gives unique effects. Excellent results can be obtained with aldehydic, floral, woody, herbal, citrus and fruity notes.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
IFRA Critical Effect: Sensitization
IFRA: View Standard
Fragrance usage is IFRA RESTRICTED. View Standard for complete information.
Please review all IFRA documents for complete information.
IFRA categories: limits in the finished product: (For a description of the categories, refer to the IFRA QRA Information Booklet.)
Category 1:
See Note (1)
0.003 % (1)
Category 2:  0.004 %
Category 3:  0.02 %
Category 4:  0.02 %
Category 5:  0.02 %
Category 6:  0.07 % (1)
Category 7:  0.008 %
Category 8:  0.02 %
Category 9:  0.02 %
Category 10:  0.02 %
Category 11: See Note (2)
 Notes:
 

For this material, for pragmatic reasons, restrictive levels allowed by the QRA for certain categories but actually being higher than those already in place before applying the QRA, will temporarily not be implemented until the end of a 5 year monitoring phase. At the end of the 5 years the position will be reevaluated again.

 

(1) IFRA would recommend that any material used to impart perfume or flavour in products intended for human ingestion should consist of ingredients that are in compliance with appropriate regulations for foods and food flavourings in the countries of planned distribution and, where these are lacking, with the recommendations laid down in the Code of Practice of IOFI (International Organisation of the Flavor Industry). Further information about IOFI can be found on its website (www.iofi.org).

 

(2) Category 11 includes all non-skin contact or incidental skin contact products. Due to the negligible skin contact from these types of products there is no justification for a restriction of the concentration of this fragrance ingredient in the finished product.

use level in formulae for use in cosmetics:
  0.0200 %
Dermal Systemic Exposure in Cosmetic Products:
 0.0005 mg/kg/day (IFRA, 2002)
 
Recommendation for gamma-damascone flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):35087-49-1
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :9837013
National Institute of Allergy and Infectious Diseases:Data
SCCNFP:opinion
WGK Germany:2
(E)-1-(2,2-dimethyl-6-methylidenecyclohexyl)but-2-en-1-one
Chemidplus:0035087491
 
References:
Leffingwell:Chirality or Article
 (E)-1-(2,2-dimethyl-6-methylidenecyclohexyl)but-2-en-1-one
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:35087-49-1
Pubchem (cid):9837013
Pubchem (sid):135265260
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
6,7,8-
decen-1-ol
FR
3-
methyl-4-hexyl oxybutyraldehyde
FR
balsamic
fir carboxylate
FR
hexyl cinnamate
FR
citrus
abronia fragrance
FR
(R)-
citronellyl nitrile
FR
citronitrile (Symrise)
FR
citrus specialty
FR
fatty
hexyl pivalate
FR
floral
acetal 318
FR
alpha-
amyl cinnamaldehyde diethyl acetal
FR
blue lagoon fragrance
FR
boronia specialty
FR
cassis cyclohexene
FR
iso
cyclodimethyl octanol
FR
3-
cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester
FR
cymbopogon validus leaf oil
FR
6,8-
dimethyl-2-nonanol
FR
3,6-
dimethyl-3-octyl acetate
FR
ethyl phenoxyacetate
FR
eucalyptus macarthurii oil
FR
floral pyran
FR
geranium oil egypt fractions
FR
geranium rose-scented oil cuba
FR
glycoacetal
FR
hawthorn ethanol
FR
hibiscus fragrance
FR
jasmin cyclopentanol
FR
jasmin cyclopentanone
FR
lily propanol
FR
southern
magnolia leaf oil fractions
FR
magnolia specialty
FR
menthadienyl formate
FR
(2-
methoxy-1-methyl propyl) benzene
FR
(3-
methoxy-2-methyl propyl) benzene
FR
ortho-
methoxybenzyl ethyl ether
FR
1-(2-
methyl allyl oxy)-3-methoxy-3-methyl-1-butane
FR
muguet butanol
FR
musk acetate
FR
pink
nelumbo nucifera flower absolute
FR
white
nelumbo nucifera flower absolute
FR
white
nelumbo nucifera flower concrete
FR
osmanthus absolute replacer
FR
osmanthus specialty
FR
peony alcohol
FR
phenyl acetaldehyde digeranyl acetal
FR
phenyl propyl phenyl acetate
FR
pomarose
FR
primrose fragrance
FR
rhodinyl benzoate
FR
rosa alba flower oil CO2 extract
FR
rose absolute pentanol
FR
rose acetate
FR
rose blossom pentanol
FR
rose concrete (rosa centifolia)
FR
rose concrete (rosa damascena)
FR
rose oil replacer
FR
rose pyran
FR
rose specialty
FR
rose undecene
FR
souroubea specialty
FR
tetrahydroionyl acetate
FR
tilia cordata flower oil CO2 extract
FR
fruity
allyl amyl glycolate
FR
allyl benzoate
FR
3-
allyl oxy-1,4-dimethyl bicyclo(3.2.1)octane
FR
benzaldehyde / methyl anthranilate schiff's base
FR
berry hexanoate
FR
3-
butyl bicyclo[3.2.1]-6-octen-2-one
FR
1,4-
dibutyl-6,8-dioxabicyclo(3.2.1)octane
FR
eriocephalus punctulatus flower oil
FR
ethyl 2-cyclohexyl propionate
FR
ethyl 3,5,5-trimethyl hexanoate
FR
endo-
ethyl bicyclo(2.2.1)-5-heptene-2-carboxylate
FR
ethyl para-methyl-beta-phenyl glycidate
FR
fig crotonate
FR
fruity butanate
FR
ginsene
FR
heptanal cyclic ethylene acetal
FR
heptyl valerate
FR
(Z)-3-
hexen-1-yl 2-methyl-2-pentenoate
FR
methyl bicycloheptenyl methyloxirane carboxylate
FR
myrascone
FR
nerolidyl isobutyrate
FR
(Z)-6-
nonen-1-al dimethyl acetal
FR
peach nitrile
FR
plum crotonate
FR
plum damascone (high alpha)
FR
rhubarb undecane
FR
(E,E)-5,6,7,7-
tetramethyl-2,5-octadien-4-one
FR
tropical indene
FR
tropical specialty
FR
cis-
woody acetate
FR
green
acetaldehyde methyl hexyl acetal
FR
actinidia chinensis fruit water
FR
allyl phenethyl ether
FR
benzhydrol
FR
galbanum specialty
FR
green dioxolane
FR
2-
heptyl tetrahydrofuran
FR
herbal cyclohexane
FR
(Z)-3-
hexenyl methyl ether
FR
[(4E,4Z)-5-
methoxy-3-methyl-4-penten-1-yl] benzene
FR
neogall
FR
phenethyl isopropyl ether
FR
phenethyl oxyacetaldehyde
FR
1-[(3aS,7aR)-3a,4,7,7a-
tetrahydro-1H-inden-6-yl]ethanone
FR
violet dienyne
FR
herbal
chamomile isobutyrate
FR
chamomile propionate
FR
chamomile valerate
FR
geranium cyclohexane
FR
6-
methoxy-2,6-dimethyl octanal
FR
methyl cyclogeranate (Firmenich)
FR
tricyclodecyl acetate
FR
4,4,6-
trimethyl-2-phenyl-1,3-dioxane
FR
spicy
2,5-
dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate + 1,4-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate
FR
maja fragrance
FR
pepper hexanone
FR
tropical
triflaige A
FR
woody
2-
decalinyl acetate
FR
(E)-
ethyl geranate
FR
melozol acetate
FR
lariciu
pine needle oil
FR
rhubarb oxirane
FR
verdoxan
FR
woody acetate
FR
For Flavor
 
Potential Uses:
FRaldehydic
FRcitrus
FRfloral
FRfruit
FRherbal
FRwoody
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 damascone gamma
1-(2,2-dimethyl-6-methylene cyclohexyl)-2-buten-1-one
(E)-1-(2,2-dimethyl-6-methylidenecyclohexyl)but-2-en-1-one
 
 
Notes:
None found
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2018 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy