benzaldehyde / methyl anthranilate schiff's base
methyl N-benzylidene-2-aminobenzoate
 
Notes:
None found
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methyl 2-(benzylideneamino)benzoate (Click)
CAS Number: 37837-44-8Picture of molecule
ECHA EINECS - REACH Pre-Reg: 253-685-5
Nikkaji Web: J261.316F
XlogP3-AA: 3.10 (est)
Molecular Weight: 239.27401000
Formula: C15 H13 N O2
NMR Predictor: Predict (works with chrome or firefox)
Category: cosmetic and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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Physical Properties:
Appearance: yellow solid (est)
Assay: 98.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 1.10100 to 1.10750 @  25.00 °C.
Pounds per Gallon - (est).: 9.161 to  9.216
Refractive Index: 1.56150 to 1.56900 @  20.00 °C.
Boiling Point: 405.00 to  406.00 °C. @ 760.00 mm Hg
Flash Point: 371.00 °F. TCC ( 188.33 °C. )
logP (o/w): 3.316 (est)
Soluble in:
 alcohol
 water, 69.14 mg/L @ 25 °C (est)
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Organoleptic Properties:
Odor Type: fruity
Odor Strength: medium ,
recommend smelling in a 10.00 % solution or less
 sweet  almond bitter almond  cherry  fruity  floral  
Odor Description:
at 10.00 % in dipropylene glycol. 
sweet benzaldehyde cherry fruity floral
Luebke, William tgsc, (1988)
Substantivity: 400 Hour(s)
  
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
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Suppliers:
BOC Sciences
For experimental / research use only.
Methyl Anthranilate / Benzaldehyde Schiff Base 50% In Dep
fnfsurplus.com
Benzaldehyde Schiffs Base
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: cosmetic and fragrance agents
Recommendation for benzaldehyde / methyl anthranilate schiff's base usage levels up to:
  8.0000 % in the fragrance concentrate.
 
Recommendation for benzaldehyde / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 37837-44-8
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 162275
National Institute of Allergy and Infectious Diseases: Data
 methyl 2-(benzylideneamino)benzoate
Chemidplus: 0037837448
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References:
 methyl 2-(benzylideneamino)benzoate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 37837-44-8
Pubchem (cid): 162275
Pubchem (sid): 135118372
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 citronitrile (Symrise)FR
(E+Z)-4,8-dimethyl-3,7-nonadien-2-oneFL/FR
aldehydic
3-methyl-4-hexyl oxybutyraldehydeFR
anisic
ortho-acetanisoleFL/FR
ortho-anisaldehydeFL/FR
balsamic
2-acetyl furanFL/FR
 benzyl cinnamateFL/FR
(E)-benzyl tiglateFL/FR
 cinnamyl formateFL/FR
 methyl (E)-cinnamateFL/FR
 methyl cinnamateFL/FR
bready
 furfuralFL/FR
buttery
3,4-hexane dioneFL/FR
camphoreous
 butyrophenoneFL/FR
caramellic
 geranyl crotonateFR
chocolate
 chocolate pyrazine AFL/FR
2-methoxy-3-methyl pyrazineFL/FR
citrus
(R)-citronellyl nitrileFR
2-heptanolFL/FR
earthy
 dibenzyl etherFL/FR
ethereal
 cyclohexyl formateFL/FR
fatty
 butyl undecylenateFL/FR
4-ethyl octanoic acidFL/FR
fermented
 methyl decanoateFL/FR
floral
 acetal 318FR
 acetophenoneFL/FR
isoamyl angelateFL/FR
alpha-amyl cinnamaldehydeFL/FR
 benzyl acetateFL/FR
 benzyl acetoacetateFL/FR
 benzyl formateFL/FR
 benzyl isobutyrateFL/FR
 blue lagoon fragranceFR
(S)-citronellyl acetateFL/FR
 citronellyl butyrateFL/FR
 citronellyl hexanoateFL/FR
 citronellyl propionateFL/FR
(E)-citronellyl tiglateFL/FR
3-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl esterFR
 cymbopogon validus leaf oilFR
 dihydrojasmoneFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
3,6-dimethyl-3-octyl acetateFR
 ethyl anthranilateFL/FR
 ethyl ethyl anthranilateFL/FR
 eucalyptus macarthurii oilFR
 geraniolFL/FR
 geranyl isobutyrateFL/FR
 hibiscus fragranceFR
 ionone mixed isomersFL/FR
 jasmin cyclopentanoneFR
isojasmoneFL/FR
 linalyl butyrateFL/FR
 magnolia specialtyFR
 menthadienyl formateFR
ortho-methoxybenzyl ethyl etherFR
 methoxymelonalFL/FR
1-(2-methyl allyl oxy)-3-methoxy-3-methyl-1-butaneFR
para-methyl benzyl acetateFL/FR
 methyl benzyl acetate (mixed ortho-,meta-,para-)FL/FR
alpha-isomethyl ionone (90% min.)FL/FR
 methyl ionyl acetateFL/FR
(±)-3-methyl-gamma-decalactoneFL/FR
white nelumbo nucifera flower absoluteFR
pink nelumbo nucifera flower absoluteFR
white nelumbo nucifera flower concreteFR
3-nonanon-1-yl acetateFL/FR
 orris rhizome concrete butter (iris pallida)FL/FR
 osmanthus absolute replacerFR
 osmanthus concreteFL/FR
 petitgrain mandarin oilFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl isovalerateFL/FR
 phenyl acetaldehyde diisobutyl acetalFL/FR
1-phenyl propyl butyrateFL/FR
2-phenyl propyl isobutyrateFL/FR
4-phenyl-3-buten-2-olFL/FR
isopropyl benzoateFL/FR
 rhodinyl butyrateFL/FR
 rose undeceneFR
 souroubea specialtyFR
 star fruit oil cubaFL/FR
 styralyl propionateFL/FR
 terpinyl valerateFL/FR
 tetrahydroionyl acetateFR
para-tolualdehyde propylene glycol acetalFL/FR
fruity
 allyl 2-ethyl butyrateFL/FR
 allyl benzoateFR
 allyl isovalerateFL/FR
 almond fragranceFR
bitter almond oilFL/FR
 almond specialtyFR
isoamyl 2-methyl butyrateFL/FR
 amyl butyrateFL/FR
para-anisyl propionateFL/FR
 apricot essenceFL/FR
 benzaldehydeFL/FR
 benzaldehyde glycrol acetalFL/FR
2-benzofuran carboxaldehydeFL/FR
 benzyl propionateFL/FR
 benzyl valerateFL/FR
 berry hexanoateFR
 bread thiopheneFL/FR
 butyl 2-naphthyl etherFL/FR
isobutyl anthranilateFL/FR
isobutyl furyl propionateFL/FR
 cherry oxyacetateFL/FR
 cherry pentenoateFL/FR
 cherry propanolFL/FR
 citronellyl isobutyrateFL/FR
 cyclohexyl cinnamateFL/FR
(Z)-beta-damasconeFL/FR
(E)-beta-damasconeFL/FR
beta-damasconeFL/FR
(R)-gamma-dodecalactoneFL/FR
 eriocephalus punctulatus flower oilFR
4-ethyl benzaldehydeFL/FR
 ethyl benzoyl acetateFL/FR
 ethyl levulinateFL/FR
 ethyl methyl-para-tolyl glycidateFL/FR
 ginseneFR
 heptyl isobutyrateFL/FR
 linalool oxide acetatesFL/FR
3-mercaptohexyl acetateFL/FR
 methyl (Z)-3-hexenoateFL/FR
 methyl bicycloheptenyl methyloxirane carboxylateFR
 methyl isobutyrateFL/FR
3-methyl-2-butenalFL/FR
(E)-7-methyl-3-octen-2-oneFL/FR
 myrasconeFR
2-nonanone propylene glycol acetalFL/FR
alpha-ocimeneFL/FR
 peach nitrileFR
 plum damascone (high alpha)FR
 prunus amygdalus amara seed extractFL/FR
 raspberry ketone methyl etherFL/FR
 rhubarb pyranFR
 sambucus canadensis fruit absoluteFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
(R)-styralyl acetateFL/FR
para-tolualdehydeFL/FR
meta-tolualdehydeFL/FR
 tolualdehyde glyceryl acetalFL/FR
 tolualdehydes (mixed o,m,p)FL/FR
4-(para-tolyl)-2-butanoneFL/FR
 tropical iononeFL/FR
cis-woody acetateFR
green
isoamyl 3-(2-furan) propionateFL/FR
 benzaldehyde dimethyl acetalFL/FR
(Z)-3-hexen-1-yl isovalerateFL/FR
 hexoxyacetaldehyde dimethyl acetalFR
 magnolia flower oil CO2 extractFL/FR
(Z)-2-penten-1-olFL/FR
 phenyl acetaldehyde diethyl acetalFL/FR
1-[(3aS,7aR)-3a,4,7,7a-tetrahydro-1H-inden-6-yl]ethanoneFR
herbal
 chamomile isobutyrateFR
 chamomile propionateFR
 chamomile valerateFR
 clary propyl acetateFR
 geranium cyclohexaneFR
 methyl cyclogeranateFR
laevo-perillaldehydeFL/FR
 tagete oil madagascarFL/FR
honey
 methyl phenyl acetateFL/FR
 phenyl pyruvic acidFL/FR
medicinal
ortho-cresyl acetateFL/FR
minty
 methyl 5-methyl salicylateFR
naphthyl
2,4-dimethyl benzaldehydeFL/FR
3,5-cocoa pyrazineFL/FR
2-methyl-3-(methyl thio) pyrazineFL/FR
2-methyl-3-ethoxypyrazineFL/FR
 nutty cyclohexenoneFL/FR
phenolic
2'-hydroxyacetophenoneFL/FR
 methyl benzoateFL/FR
powdery
para-anisyl acetateFL/FR
 dibenzyl ketoneFL/FR
alpha-methyl iononeFL/FR
(E)-alpha-methyl ionone (74-80%)FL/FR
spicy
para-anisyl formateFL/FR
 cinnamyl isovalerateFL/FR
 cinnamyl propionateFL/FR
para-methoxycinnamaldehydeFL/FR
(E)-para-methoxycinnamaldehydeFL/FR
 spicy acetoacetateFL/FR
tropical
 triflaige AFR
waxy
 dihydrocitronellyl acetateFL/FR
(E)-methyl geranateFL/FR
 phytyl acetateFL/FR
woody
2-decalinyl acetateFR
 melozol acetateFR
 rhubarb oxiraneFR
 
For Flavor
 
No flavor group found for these
1-acetyl cyclohexyl acetateFL
 allyl 2-ethyl butyrateFL/FR
isoamyl angelateFL/FR
para-anisyl propionateFL/FR
 benzyl valerateFL/FR
 butyl 2-naphthyl etherFL/FR
2-butyl thiopheneFL
 butyrophenoneFL/FR
 chocolate pyrazine AFL/FR
 chocolate pyrazine BFL
ortho-cresyl acetateFL/FR
 cyclohexyl cinnamateFL/FR
(Z)-beta-damasconeFL/FR
2,4-difurfuryl furanFL
 dihydrocitronellyl acetateFL/FR
S-(2,5-dimethyl-3-furyl) ethane thioateFL
(E+Z)-4,8-dimethyl-3,7-nonadien-2-oneFL/FR
(R)-gamma-dodecalactoneFL/FR
 ethyl 2-phenyl-3-furoateFL
 ethyl anthranilateFL/FR
4-ethyl benzaldehydeFL/FR
 ethyl ethyl anthranilateFL/FR
5-ethyl-2-thiophene carboxaldehydeFL
2-hexenalFL
 ionone mixed isomersFL/FR
 linalool oxide acetatesFL/FR
 magnolia flower oil CO2 extractFL/FR
(E)-para-methoxycinnamaldehydeFL/FR
 methyl (E)-cinnamateFL/FR
para-methyl benzyl acetateFL/FR
 methyl benzyl acetate (mixed ortho-,meta-,para-)FL/FR
 methyl furfuracrylateFL
(E)-methyl geranateFL/FR
alpha-isomethyl ionone (90% min.)FL/FR
4-methyl salicylaldehydeFL
2-methyl-3-(methyl thio) pyrazineFL/FR
2-methyl-3-ethoxypyrazineFL/FR
(±)-3-methyl-gamma-decalactoneFL/FR
2-nonanone propylene glycol acetalFL/FR
alpha-ocimeneFL/FR
 phenyl acetaldehyde diethyl acetalFL/FR
1-phenyl propyl butyrateFL/FR
2-phenyl propyl isobutyrateFL/FR
 phytyl acetateFL/FR
isopropyl benzoateFL/FR
(R)-styralyl acetateFL/FR
meta-tolualdehydeFL/FR
 tolualdehyde glyceryl acetalFL/FR
para-tolualdehyde propylene glycol acetalFL/FR
isoamyl 3-(2-furan) propionateFL/FR
 benzyl acetoacetateFL/FR
isobutyl furyl propionateFL/FR
beta-damasconeFL/FR
anisic
ortho-anisaldehydeFL/FR
aromatic
 dimethyl benzyl carbinyl acetateFL/FR
laevo-perillaldehydeFL/FR
balsamic
(E)-benzyl tiglateFL/FR
berry
 heptyl isobutyrateFL/FR
 raspberry ketone methyl etherFL/FR
bitter
 dibenzyl ketoneFL/FR
brown
 furfuralFL/FR
burnt
 ethyl 2-furoateFL
buttery
3,4-hexane dioneFL/FR
cherry
para-methoxycinnamaldehydeFL/FR
citrus
 petitgrain mandarin oilFL/FR
 styralyl propionateFL/FR
ethereal
 methyl isobutyrateFL/FR
fatty
 butyl undecylenateFL/FR
4-ethyl octanoic acidFL/FR
 methyl decanoateFL/FR
(E)-7-methyl-3-octen-2-oneFL/FR
floral
 cinnamyl propionateFL/FR
(S)-citronellyl acetateFL/FR
 citronellyl hexanoateFL/FR
 citronellyl propionateFL/FR
 dihydrojasmoneFL/FR
 geraniolFL/FR
 geranyl isobutyrateFL/FR
 linalyl butyrateFL/FR
 methyl phenyl acetateFL/FR
 orris rhizome concrete butter (iris pallida)FL/FR
 rhodinyl butyrateFL/FR
 tropical iononeFL/FR
 allyl isovalerateFL/FR
bitter almond oilFL/FR
isoamyl 2-methyl butyrateFL/FR
 amyl butyrateFL/FR
para-anisyl acetateFL/FR
 apricot essenceFL/FR
 benzaldehydeFL/FR
 benzaldehyde glycrol acetalFL/FR
 benzyl acetateFL/FR
 benzyl formateFL/FR
 benzyl isobutyrateFL/FR
 benzyl propionateFL/FR
 bread thiopheneFL/FR
isobutyl anthranilateFL/FR
 cherry laurel oilFL
 cherry oxyacetateFL/FR
 cherry pentenoateFL/FR
 cherry propanolFL/FR
 cinnamyl isovalerateFL/FR
 citronellyl butyrateFL/FR
 citronellyl isobutyrateFL/FR
 dibenzyl etherFL/FR
 ethyl benzoyl acetateFL/FR
 ethyl levulinateFL/FR
 ethyl methyl-para-tolyl glycidateFL/FR
2-heptanolFL/FR
2,4-hexadien-1-olFL
2-hexyl-4-acetoxytetrahydrofuranFL
 methoxymelonalFL/FR
 methyl (Z)-3-hexenoateFL/FR
 methyl 4-phenyl butyrateFL
(E)-alpha-methyl ionone (74-80%)FL/FR
3-methyl-2-butenalFL/FR
3-nonanon-1-yl acetateFL/FR
 osmanthus concreteFL/FR
 phenethyl isovalerateFL/FR
2-phenyl-4-pentenalFL
 sambucus canadensis fruit absoluteFL/FR
 star fruit oil cubaFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
 tagete oil madagascarFL/FR
 terpinyl valerateFL/FR
 tolualdehydes (mixed o,m,p)FL/FR
4-(para-tolyl)-2-butanoneFL/FR
green
 benzaldehyde dimethyl acetalFL/FR
 cyclohexyl formateFL/FR
(E)-beta-damasconeFL/FR
(Z)-3-hexen-1-yl isovalerateFL/FR
isojasmoneFL/FR
(Z)-2-penten-1-olFL/FR
honey
 phenethyl isobutyrateFL/FR
 phenyl acetaldehyde diisobutyl acetalFL/FR
leafy
(E)-citronellyl tiglateFL/FR
naphthyl
2,4-dimethyl benzaldehydeFL/FR
2'-hydroxyacetophenoneFL/FR
nutty
2-acetyl furanFL/FR
2-benzofuran carboxaldehydeFL/FR
3,5-cocoa pyrazineFL/FR
3,5(6)-cocoa pyrazineFL
2-methoxy-3-methyl pyrazineFL/FR
 nutty cyclohexenoneFL/FR
 prunus amygdalus amara seed extractFL/FR
phenolic
 methyl benzoateFL/FR
 phenyl pyruvic acidFL/FR
powdery
ortho-acetanisoleFL/FR
 acetophenoneFL/FR
 powdery ketoneFL
spicy
para-anisyl formateFL/FR
 benzyl cinnamateFL/FR
 cinnamyl formateFL/FR
 methyl cinnamateFL/FR
 spicy acetoacetateFL/FR
para-tolualdehydeFL/FR
tropical
alpha-amyl cinnamaldehydeFL/FR
3-mercaptohexyl acetateFL/FR
waxy
alpha-methyl iononeFL/FR
4-phenyl-3-buten-2-olFL/FR
woody
 methyl ionyl acetateFL/FR
 
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Potential Uses:
 bubble gumFR
 cherryFR
 cherry blossomFR
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 amandolene liquid 21060
 benzaldehyde / methyl anthranilate schiff's base
 benzoic acid, ((phenylmethylene)amino)-, methyl ester
 methyl ((phenyl methylene)amino) benzoate
 methyl ((phenylmethylene)amino)benzoate
 methyl (benzylidene amino) benzoate
 methyl (phenylmethylideneamino)benzoate
 methyl 2-((phenylmethylene)amino)benzoate
 methyl 2-(benzylideneamino)benzoate
 methyl anthranilate / benzaldehyde schiff base 50% in DEP
 methyl anthranilate / benzaldehyde schiff's base
 methyl N-benzylidene-2-aminobenzoate
 methyl phenyl methylene aminobenzoate
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Articles:
 None found yet.
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