methyl cyclogeranate (Firmenich)
2,6,6-trimethyl-2-cyclohexene-1-carboxylic acid, methyl ester

Sponsors

Fragrance Demo Formulas
Name: methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate
CAS Number: 28043-10-9Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 248-792-9
Nikkaji Web: J250.635A
XlogP3-AA: 2.60 (est)
Molecular Weight: 182.26286000
Formula: C11 H18 O2
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
 
Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 0.95790 to 0.96820 25.00 °C.
Pounds per Gallon - (est).: 7.971 to 8.056
Refractive Index: 1.49100 to 1.49900 @ 20.00 °C.
Boiling Point: 212.00 to 214.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.151000 mm/Hg @ 25.00 °C. (est)
Vapor Density: 6.3 ( Air = 1 )
Flash Point: 171.00 °F. TCC ( 77.22 °C. )
logP (o/w): 3.372 (est)
Soluble in:
 alcohol
 water, 27.88 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items: note
isoamyl geranate
ethyl geranate
(E)-methyl geranate
 
Organoleptic Properties:
Odor Type: herbal
Odor Strength: medium
Substantivity: 1 hour(s) at 100.00 %
 natural herbal floral fruity woody camphoreous
Odor Description:
at 100.00 %.
natural herbal floral fruity woody camphor
Luebke, William tgsc, (1985)
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Azelis UK
METHYL CYCLO GERANIATE
Services
Ernesto Ventós
METHYL CYCLOGERANIATE FIRMENICH 936915
Odor: FLORAL,HERBAL,FRUITY,AROMATIC
Firmenich
METHYL CYCLOGERANATE
Odor: METHYL CYCLOGERANATE is a floral, rose, fruity note that also brings an earthy, camphor and damascone like character to fragrances.
Use: Mild intensity ingredient that can be used in most fragrances bringing rosy, fresh and fruity tonalities.
Lluch Essence
METHYL CYCLOGERANATE
Odor: FRUITY, FLORAL, HERBACEOUS
Moellhausen
METHYL CYCLO GERANATE
Organica Aromatics
METHYL CYCLO GERANATE
Vigon International
Methyl Cyclogeranate
Odor: Natural herbal floral fruity woody camphor
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 4150 mg/kg
Luebke, William tgsc, (1985)

Dermal Toxicity:
skin-rabbit LD50 > 2000 mg/kg
Luebke, William tgsc, (1985)

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for methyl cyclogeranate (Firmenich) usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for methyl cyclogeranate (Firmenich) flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 28043-10-9
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 119800
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate
Chemidplus: 0028043109
 
References:
 methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 28043-10-9
Pubchem (cid): 119800
Pubchem (sid): 135077844
 
Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
ChemSpider: View
 
Potential Blenders and core components note
For Odor
aldehydic
3-
methyl-4-hexyl oxybutyraldehyde
FR
balsamic
fir carboxylate
FR
scotch
pine wood/needles resinoid
FR
camphoreous
2,6-
dimethyl-3-oxatricyclo(4.2.1.0*2,4*)nonane
FR
citrus
acetaldehyde citronellyl methyl acetal
FR
(R)-
citronellyl nitrile
FR
citronitrile (Symrise)
FR
fatty
hexyl pivalate
FR
floral
acetal 318
FR
anise indene
FR
blue lagoon fragrance
FR
4-tert-
butyl cyclohexane carboxaldehyde
FR
butyl tiglate
FR
cassis cyclohexene
FR
3-
cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester
FR
cymbopogon validus leaf oil
FR
dihydromyrcene
FR
2,4-
dimethyl cyclohexyl methyl acetate
FR
2,4-
dimethyl-3-cyclohexene-1-methanol
FR
3,6-
dimethyl-3-octyl acetate
FR
eau de brouts absolute
FR
ethyl linalool
FR
ethyl linalyl acetal
FR
eucalyptus macarthurii oil
FR
floral pyranol
FR
heather fragrance
FR
heliotrope absolute
FR
herbal pyran
FR
hibiscus fragrance
FR
ho leaf oil
FR
jasmin cyclopentanone
FR
karo karounde absolute
FR
lavandin concrete decolorized
FR
lavender absolute replacer
FR
lavender oil replacer
FR
magnolia specialty
FR
menthadienyl formate
FR
ortho-
methoxybenzyl ethyl ether
FR
1-(2-
methyl allyl oxy)-3-methoxy-3-methyl-1-butane
FR
N-
methyl ionone
FR
pink
nelumbo nucifera flower absolute
FR
white
nelumbo nucifera flower absolute
FR
white
nelumbo nucifera flower concrete
FR
nonisyl propionate
FR
bitter
orangeflower concrete morocco
FR
osmanthus absolute replacer
FR
pelargonium graveolens flower water
FR
rose carboxylate
FR
rose undecene
FR
sambucus nigra flower oil CO2 extract
FR
souroubea specialty
FR
tetrahydroionyl acetate
FR
tetrahydrolinalyl acetate
FR
vetiver pentanone
FR
fruity
allyl benzoate
FR
3-
allyl oxy-1,4-dimethyl bicyclo(3.2.1)octane
FR
benzaldehyde / methyl anthranilate schiff's base
FR
berry hexanoate
FR
1-(3,3-
dimethyl bicyclo(2.2.1)hept-2-yl)-2-methyl cyclohex-3-ene carbaldehyde
FR
1,4-
dimethyl bicyclo(3.2.1)oct-3-yl acetate
FR
1,2-
dimethyl butyl 2-butenoate
FR
eriocephalus punctulatus flower oil
FR
ginsene
FR
green acetate
FR
methyl bicycloheptenyl methyloxirane carboxylate
FR
myrascone
FR
peach nitrile
FR
plum damascone (high alpha)
FR
rhubarb pyran
FR
cis-
woody acetate
FR
green
(Z)-3-
hexen-1-yl angelate
FR
hexoxyacetaldehyde dimethyl acetal
FR
1-[(3aS,7aR)-3a,4,7,7a-
tetrahydro-1H-inden-6-yl]ethanone
FR
herbal
1-
allyl-2,2,7,7-tetramethyl cycloheptanol
FR
calendula officinalis flower oil CO2 extract
FR
cananga fruit oil
FR
carrot seed oil (daucus carota ssp. gummifer hook. fil.) spain
FR
chamomile isobutyrate
FR
chamomile propionate
FR
chamomile valerate
FR
chrysanthemum ketone
FR
clary propyl acetate
FR
dimethyl cyclormol (IFF)
FR
geranium cyclohexane
FR
herbal dioxane
FR
herbal specialty
FR
herbal undecanone
FR
inula root oil
FR
lavandin flower water
FR
lavender stem oil lithuania
FR
nonisyl acetate
FR
tricyclodecenyl propionate
FR
spicy
carnation absolute
FR
N,N-
diethyl octanamide
FR
green oxane
FR
thujonic
cedarleaf oil terpeneless
FR
tropical
triflaige A
FR
woody
2-tert-
butyl cyclohexanone
FR
2-
decalinyl acetate
FR
hinoki root oil
FR
juniper berry oil terpenes
FR
melozol acetate
FR
rhubarb oxirane
FR
sandal octanol
FR
1-(5',5',6'-
trimethyl bicyclo(2.2.1)hept-2'-ylidene) propan-2-one
FR
zdravetz absolute
FR
For Flavor
No flavor group found for these
8,9-
dehydrotheaspirone
FL
2,4-
difurfuryl furan
FL
acidic
acidic
(E)-2-
hexenoic acid
FL
fruity
2-
hexyl-4-acetoxytetrahydrofuran
FL
 
Potential Uses:
 basilFL/FR
 chamomileFR
 chypreFR
 flower shopFR
 fruitFR
 greenFR
 herbalFR
 rosemaryFR
 woodyFR
 
Occurrence (nature, food, other): note
 not found in nature
 
Synonyms:
2-cyclohexene-1-carboxylic acid 2,6,6,-trimethyl methyl ester
2-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester
 methyl 2,6,6-trimethyl cyclohex-2-ene carboxylate
 methyl 2,6,6-trimethyl cyclohex-2-ene-1-carboxylate
 methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate
 methyl cyclo geranate
 methyl cyclogeranate (Firmenich)
 methylcyclogeranate
2,6,6-trimethyl-2-cyclohexene-1-carboxylic acid, methyl ester
 
 
Notes:
Blends well with damascones. Gives good body.
 
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2018 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy