EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

(E)-tiglaldehyde
(E)-2-methyl-2-butenal

Sponsors

Name:(E)-2-methylbut-2-enal
CAS Number: 497-03-0Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:207-833-0
FDA UNII:27ZVE2K81C
Nikkaji Web:J102.093E
Beilstein Number:1698207
MDL:MFCD00006977
XlogP3-AA:0.90 (est)
Molecular Weight:84.11796000
Formula:C5 H8 O
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
FLAVIS Number:05.095 (Old)
DG SANTE Food Flavourings:05.095 (E)-2-methylcrotonaldehyde
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 99.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.86800 to 0.87300 @ 20.00 °C.
Pounds per Gallon - (est).: 7.231 to 7.273
Refractive Index:1.44500 to 1.45000 @ 20.00 °C.
Boiling Point: 117.00 to 118.00 °C. @ 760.00 mm Hg
Acid Value: 3.00 max. KOH/g
Vapor Pressure:17.107000 mm/Hg @ 25.00 °C. (est)
Flash Point: 70.00 °F. TCC ( 21.11 °C. )
logP (o/w): 1.065 (est)
Soluble in:
 alcohol
 water, 2.50E+04 mg/L @ 25 °C (exp)
Insoluble in:
 water
Similar Items:note
tiglaldehyde
(Z)-tiglaldehyde
 
Organoleptic Properties:
Odor Strength:high ,
recommend smelling in a 0.10 % solution or less
Odor Description:at 0.10 % in dipropylene glycol. strong green fruit
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Tiglic aldehyde 95%
Parchem
(E)-tiglaldehyde
Santa Cruz Biotechnology
For experimental / research use only.
Tiglic aldehyde
Sigma-Aldrich: Aldrich
For experimental / research use only.
Tiglic aldehyde ≥96%
Synerzine
2-Methyl-2-butenal
TCI AMERICA
For experimental / research use only.
trans-2-Methyl-2-butenal >95.0%(GC)
Chemical Sources Association
Need This Item for Flavor/Food?: You can contact the Chemical Sources Association
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 11 - Highly flammable.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 16 - Keep away from sources of ignition - No Smoking.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for (E)-tiglaldehyde usage levels up to:
  0.0500 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.61 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.20 (μg/capita/day)
Structure Class: I
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Flavouring Group Evaluation 201: 2-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.2 of FGE.19[1]
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 201 Revision 1 (FGE.201Rev1): 2-Alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19.
View page or View pdf
EPI System: View
Chemical Carcinogenesis Research Information System:Search
EPA Substance Registry Services (TSCA):497-03-0
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5321950
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 1989
WGK Germany:3
(E)-2-methylbut-2-enal
Chemidplus:0000497030
 
References:
 (E)-2-methylbut-2-enal
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:497-03-0
Pubchem (cid):5321950
Pubchem (sid):134977393
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB31512
Export Tariff Code:2912.19.5000
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
acidic
iso
butyric acid
FL/FR
cyclohexyl acetic acid
FL/FR
2-
methyl butyric acid
FL/FR
alliaceous
dibutyl sulfide
FL/FR
methyl furfuryl disulfide
FL/FR
balsamic
2-
acetyl furan
FL/FR
benzophenone
FL/FR
buttery
acetyl propionyl
FL/FR
butyl butyryl lactate
FL/FR
2,3-
heptane dione
FL/FR
caramellic
coffee dione
FL/FR
cyclotene
FL/FR
cheesy
butyric acid
FL/FR
2-
methyl hexanoic acid
FL/FR
S-(
methyl thio) butyrate
FL/FR
2-
methyl valeric acid
FL/FR
2-
methyl-2-hexenoic acid
FR
chocolate
cocoa hexenal
FL/FR
2,6-
dimethyl pyrazine
FL/FR
2-
methyl butyraldehyde
FL/FR
2,4,5-
trimethyl thiazole
FL/FR
coffee
coffee difuran
FL/FR
furfuryl mercaptan
FL/FR
1-
hydroxy-2-butanone
FL/FR
2-
methyl-3-,5 or 6-(furfuryl thio) pyrazine
FL/FR
ethereal
ethyl formate
FL/FR
propyl formate
FL/FR
fatty
hexanoic acid
FL/FR
floral
laevo-
citronellol
FL/FR
citronellyl acetate
FL/FR
(E)-
citronellyl tiglate
FL/FR
cyclohexyl propanol
FR
dihydrorose oxide
FR
6,8-
dimethyl-2-nonanol
FR
floral pyran
FR
geranium dihydropyran
FR
geranium nitrile
FR
geranium pyran
FR
geranyl hexanoate
FL/FR
geranyl nonanoate
CS
geranyl tiglate
FL/FR
methyl citronellate
FL/FR
musk acetate
FR
peony acetonitrile
FR
phenethyl pivalate
FL/FR
phenyl acetaldehyde digeranyl acetal
FR
rhodinyl propionate
FL/FR
(Z)-
rose oxide
FL/FR
laevo-
rose oxide
FL/FR
fruity
acetaldehyde diisoamyl acetal
FL/FR
iso
amyl propionate
FL/FR
citronellyl isobutyrate
FL/FR
cyclohexyl carboxylic acid
FL/FR
filbert hexenone
FL/FR
4-
heptanone
FL/FR
methyl 4-methyl valerate
FL/FR
2-
methyl butyl isovalerate
FL/FR
prenyl hexanoate
FL/FR
sorbyl butyrate
FL/FR
tropical indene
FR
tropical ionone
FL/FR
tropical thiazole
FL/FR
green
2-iso
butyl thiazole
FL/FR
diphenyl methane
FL/FR
diphenyl oxide
FL/FR
geranium thiazole
FL/FR
1-
hepten-3-ol
FL/FR
(Z)-4-
hexen-1-ol
FL/FR
(E)-2-
hexenal
FL/FR
3-
hexenal
FL/FR
1-
penten-3-ol
FL/FR
(E)-2-
pentenal
FL/FR
herbal
geranium cyclohexane
FR
meaty
meaty dithiane
FL/FR
4-
methyl nonanoic acid
FL/FR
medicinal
2,6-
xylenol
FL/FR
musty
menthofuran
FL/FR
nutty
3,5-
cocoa pyrazine
FL/FR
2,3-
dimethyl pyrazine
FL/FR
4,5-
dimethyl-2-ethyl-3-thiazoline
FL/FR
filbert heptenone
FL/FR
5-
methyl quinoxaline
FL/FR
2-
methyl thio-3,5 or 6-methyl pyrazine
FL/FR
nutty quinoxaline
FL/FR
2,3,5,6-
tetramethyl pyrazine
FL/FR
popcorn
2-
acetyl pyrazine
FL/FR
sulfurous
benzothiazole
FL/FR
dimethyl sulfide
FL/FR
ethyl methyl mercaptopropionate
FL/FR
fish thiol
FL/FR
furfuryl thioacetate
FL/FR
S-
furfuryl thioformate
FL/FR
methyl 3-(methyl thio) propionate
FL/FR
2-
methyl 5-(methyl thio) furan
FL/FR
tropical
tropical 3-thiobutyrate
FL/FR
vegetable
1-
furfuryl pyrrole
FL/FR
methional
FL/FR
waxy
2-
methyl heptanoic acid
FL/FR
nonanoic acid
FL/FR
2-
nonanol
FL/FR
undecanoic acid
FL/FR
yeasty
2-
octen-4-one
FL/FR
For Flavor
No flavor group found for these
acetaldehyde 1,3-octane diol acetal
FL
acetaldehyde diisoamyl acetal
FL/FR
iso
amyl 3-methyl thiopropionate
FL
benzyl methyl sulfide
FL
2,5-
dimethyl-3-thiofuroyl furan
FL
ethyl 3-octenoate
FL
ethyl cyclohexyl carboxylate
FL
(E,E)-2,4-
heptadien-1-ol
FL
(Z)-3-
hexenoic acid
FL
5-
methyl hexanoic acid
FL
4-
methyl valeric acid
FL
2-
methyl-3-,5 or 6-(furfuryl thio) pyrazine
FL/FR
phenethyl pivalate
FL/FR
prenyl hexanoate
FL/FR
acidic
acidic
iso
butyric acid
FL/FR
alliaceous
benzyl mercaptan
FL
dicyclohexyl disulfide
FL
tropical thiazole
FL/FR
brown
1-
hydroxy-2-butanone
FL/FR
burnt
furfuryl alcohol
FL
2-
methyl quinoxaline
FL
2,6-
xylenol
FL/FR
buttery
2,3-
heptane dione
FL/FR
2-
methyl valeric acid
FL/FR
(E)-2-
pentenoic acid
FL
caramellic
caramel furanone
FL
cyclotene
FL/FR
cheesy
hexanoic acid
FL/FR
cocoa
cocoa hexenal
FL/FR
coffee
coffee difuran
FL/FR
coffee dione
FL/FR
coffee pyrazine
FL
difurfuryl ether
FL
diisoamyl thiomalate
FL
2,4-
dimethyl thiazole
FL
furfuryl mercaptan
FL/FR
methyl furfuryl disulfide
FL/FR
2-
thiophene thiol
FL
corn chip
2-
acetyl-2-thiazoline
FL
creamy
acetoin butyrate
FL
butyl butyryl lactate
FL/FR
2-
methyl-4-pentenoic acid
FL
dairy
4-
pentenoic acid
FL
earthy
difurfuryl sulfide
FL
eggy
iso
propyl mercaptan
FL
ethereal
ethyl formate
FL/FR
fatty
dimethyl sulfoxide
FL
4-
methyl nonanoic acid
FL/FR
nonanoic acid
FL/FR
2,4-
octadien-1-ol
FL
(E)-2-
octenoic acid
FL
fermented
methyl thio isovalerate
FL
floral
laevo-
citronellol
FL/FR
citronellyl acetate
FL/FR
geranyl tiglate
FL/FR
methyl citronellate
FL/FR
laevo-
rose oxide
FL/FR
tropical ionone
FL/FR
fruity
iso
amyl propionate
FL/FR
citronellyl isobutyrate
FL/FR
cyclohexyl carboxylic acid
FL/FR
filbert hexenone
FL/FR
furfuryl propionate
FL
geranyl hexanoate
FL/FR
4-
heptanone
FL/FR
methyl 4-methyl valerate
FL/FR
2-
methyl butyl isovalerate
FL/FR
2-
methyl butyric acid
FL/FR
propyl formate
FL/FR
rhodinyl propionate
FL/FR
sorbyl butyrate
FL/FR
fusel
2-
methyl butyraldehyde
FL/FR
geranium
benzophenone
FL/FR
green
2-iso
butyl thiazole
FL/FR
(E)-
citronellyl tiglate
FL/FR
dibutyl sulfide
FL/FR
diphenyl methane
FL/FR
diphenyl oxide
FL/FR
2-
ethyl butyraldehyde
FL
geranium thiazole
FL/FR
1-
hepten-3-ol
FL/FR
(Z)-4-
hexen-1-ol
FL/FR
(E)-2-
hexenal
FL/FR
3-
hexenal
FL/FR
2-
methyl-5-isopropyl pyrazine
FL
1-
penten-3-ol
FL/FR
(E)-2-
pentenal
FL/FR
(Z)-
rose oxide
FL/FR
meaty
benzothiazole
FL/FR
meaty dithiane
FL/FR
2-
methyl 3-(methyl thio) furan
FL
2-
methyl-3-tetrahydrofuran thiol
FL
metallic
2,5-
dihydroxy-1,4-dithiane
FL
mustard
furfuryl methyl ether
FL
musty
menthofuran
FL/FR
2-
methyl 5-(methyl thio) furan
FL/FR
S-(
methyl thio) butyrate
FL/FR
nutty
2-
acetyl furan
FL/FR
3,5(6)-
cocoa pyrazine
FL
3,5-
cocoa pyrazine
FL/FR
2,3-
dimethyl pyrazine
FL/FR
2,6-
dimethyl pyrazine
FL/FR
4,5-
dimethyl-2-ethyl-3-thiazoline
FL/FR
filbert heptenone
FL/FR
5-
methyl quinoxaline
FL/FR
2-
methyl thio-3,5 or 6-methyl pyrazine
FL/FR
nutty quinoxaline
FL/FR
2,3,5,6-
tetramethyl pyrazine
FL/FR
2,4,5-
trimethyl thiazole
FL/FR
oily
2-
methyl hexanoic acid
FL/FR
onion
furfuryl isopropyl sulfide
FL
methyl propyl disulfide
FL
roasted
2-
acetyl pyrazine
FL/FR
ethyl 3-(furfuryl thio) propionate
FL
furfuryl thioacetate
FL/FR
sour
butyric acid
FL/FR
2,4-
dimethyl-2-pentenoic acid
FL
3-
methyl valeric acid
FL
sulfurous
butyl mercaptan
FL
dimethyl sulfide
FL/FR
ethyl methyl mercaptopropionate
FL/FR
ethyl methyl sulfide
FL
S-
ethyl thioacetate
FL
fish thiol
FL/FR
S-
furfuryl thioformate
FL/FR
furfuryl thiopropionate
FL
methyl 4-(methyl thio) butyrate
FL
potato butanone
FL
2-
thienyl mercaptan
FL
tropical 3-thiobutyrate
FL/FR
sweet
cyclohexyl acetic acid
FL/FR
toasted
acetyl propionyl
FL/FR
tomato
methional
FL/FR
vegetable
1-
furfuryl pyrrole
FL/FR
methyl 3-(methyl thio) propionate
FL/FR
2-
octen-4-one
FL/FR
waxy
2-
methyl heptanoic acid
FL/FR
2-
nonanol
FL/FR
undecanoic acid
FL/FR
 
Potential Uses:
FRalmond
FLcheese
FRcherry
FLchicken
FRcoffee
 fruit tropical fruit
FRgrape
FRgreen
FLtomato
FRvanilla
 
Occurrence (nature, food, other):note
 hyacinthus orientalis absolute @ 0.01%
Data GC Search Trop Picture
 lavender oil spike spain @ 0.002%
Data GC Search Trop Picture
 
Synonyms:
 but-2-enal, (E)-2-methyl-
2-butenal, 2-methyl-, (2E)-
2-butenal, 2-methyl-, (E)-
 crotonaldehyde, 2-methyl-, (E)-
(E)-alpha,beta-dimethyl acrolein
trans-2,3-dimethyl acrolein
trans-alpha,beta-dimethyl acrolein
(E)-2,3-dimethylacrolein
trans-2,3-dimethylacrolein
2-methyl (E)-2-butenal
(E)-alpha-methyl crotonaldehyde
trans-2-methyl crotonaldehyde
trans-alpha-methyl crotonaldehyde
(2E)-2-methyl-2-butenal
(E)-methyl-2-butenal
(E)-2-methyl-2-butenal
trans-methyl-2-butenal
trans-2-methyl-2-butenal
2-methyl-2-butenal, (E)-
2-methyl-2-butenal, trans-
(E)-2-methyl-but-2-enal
2-methylbut-2-en-1-al, (E)-
(2E)-2-methylbut-2-enal
(E)-2-methylbut-2-enal
trans-2-methylbut-2-enal
(E)-2-methylcrotonaldehyde
2-methylcrotonaldehyde, (E)-
 tigaldehyde, trans-
trans-tiglaldehyde
trans-tiglic aldehyde
 
 
Notes:
None found
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2018 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy