EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

phenethyl anthranilate
2-aminobenzoic acid 2-phenyl ethyl ester

Supplier Sponsors

Name:2-phenylethyl 2-aminobenzoate
CAS Number: 133-18-6Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:205-098-0
FDA UNII:8HBK71OD81
Nikkaji Web:J10.045E
MDL:MFCD00025190
CoE Number:258
XlogP3:4.20 (est)
Molecular Weight:241.28995000
Formula:C15 H15 N O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:1543 phenylethyl anthranilate
FLAVIS Number:09.723 (Old)
DG SANTE Food Flavourings:09.723 phenethyl anthranilate
FEMA Number:2859 phenethyl anthranilate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):133-18-6 ; PHENETHYL ANTHRANILATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid to solid (est)
Assay: 98.00 to 100.00
Food Chemicals Codex Listed: Yes
Melting Point: 39.00 to 44.00 °C. @ 760.00 mm Hg
Boiling Point: 226.00 °C. @ 760.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.000001 mmHg @ 25.00 °C. (est)
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 4.158 (est)
Soluble in:
 alcohol
 water, 4.073 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:medium
sweet floral rose grape orange orris honey
Odor Description:at 100.00 %. sweet floral rose grape orange iris honey
Luebke, William tgsc, (1990)
Odor sample from: Givaudan Corporation
Flavor Type: floral
floral fruity orangeflower grape narcissus
Taste Description: floral fruity orangeflower grape narcissus
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
PHENETHYL ANTHRANILATE ≥98.0%, Kosher
Odor Description:Fruity, floral (rose), honey-like
For a long lasting warm honey, rose topnote with permanence.
Taste Description:sweet
Useful in honey and cocoa flavors.
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Bedoukian Research
PHENETHYL ANTHRANILATE
≥98.0%, Kosher
Flavor: sweet
Useful in honey and cocoa flavors.
BOC Sciences
For experimental / research use only.
Phenethyl Anthranilate
CJ Latta & Associates
PHENYL ETHYL ANTHRANILATE
Inoue Perfumery
PHENETHYL ANTHRANILATE
Jiangyin Healthway
Phenethyl Anthranilate
New functional food ingredients
Penta International
PHENYLETHYL ANTHRANILATE
Reincke & Fichtner
Phenethyl Anthranilate
Synerzine
Phenethyl Anthranilate
 
Safety Information:
European information :
Most important hazard(s):
Xi N - Irritant, Dangerous for the environment.
R 36/38 - Irritating to skin and eyes.
R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
S 60 - This material and its container must be disposed of as hazardous waste.
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
10 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Useful in honey and cocoa flavors.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Useful in honey and cocoa flavors.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for phenethyl anthranilate usage levels up to:
  6.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 1.70 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 7.00 (μg/capita/day)
Threshold of Concern:1800 (μg/person/day)
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
 average usual ppmaverage maximum ppm
baked goods: -5.80000
beverages(nonalcoholic): -1.40000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -1.90000
fruit ices: -1.90000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -6.20000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 84, (FGE.84)[1] - Consideration of Anthranilate derivatives evaluated by JECFA (65th meeting) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf

EPI System: View
Chemical Carcinogenesis Research Information System:Search
Env. Mutagen Info. Center:Search
EPA Substance Registry Services (TSCA):133-18-6
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :8615
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 3077
WGK Germany:2
2-phenylethyl 2-aminobenzoate
Chemidplus:0000133186
EPA/NOAA CAMEO:hazardous materials
RTECS:CB3720000 for cas# 133-18-6
 
References:
 2-phenylethyl 2-aminobenzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:133-18-6
Pubchem (cid):8615
Pubchem (sid):134974583
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB37696
FooDB:FDB016824
Export Tariff Code:2922.49.3800
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
6,7,8-
decen-1-ol
FR
nonanal diethyl acetal
FL/FR
balsamic
benzyl cinnamate
FL/FR
callitropsis araucarioides wood oil
FR
phenethyl cinnamate
FL/FR
3-
phenyl propyl acetate
FL/FR
chocolate
iso
amyl phenyl acetate
FL/FR
cocoa pentenal
FL/FR
citrus
abronia fragrance
FR
citronella fragrance
FR
citronitrile (Symrise)
FR
curacao peel oil
FL/FR
2-
dodecanone
FL/FR
lime oil distilled terpeneless
FL/FR
methyl indole-1-carboxylate
FR
floral
allyl anthranilate
FL/FR
amyl anthranilate
FL/FR
iso
amyl undecylenate
FL/FR
benzyl alcohol
FL/FR
butyl benzyl ether
FL/FR
citronellal
FL/FR
laevo-
citronellol
FL/FR
citronellyl anthranilate
FL/FR
citronellyl propionate
FL/FR
damascate
FR
gamma-
damascone
FR
(Z)-alpha-
damascone
FL/FR
(Z)-4-
decen-1-yl acetate
FL/FR
decyl anthranilate
FR
dihydrocarvyl acetate
FL/FR
ethyl anthranilate
FL/FR
ethyl phenoxyacetate
FR
ethyl phenyl acetate
FL/FR
farnesyl acetate
FL/FR
floral pyran
FR
gelsone (IFF)
FL/FR
geranium oil egypt
FL/FR
geranium oil egypt fractions
FR
geranium oil terpeneless
FL/FR
geranium petiole oil india
FL/FR
geranium rose oil
FL/FR
geranium rose-scented oil cuba
FR
geranyl acetate
FL/FR
geranyl acetone
FL/FR
(E)-
geranyl acetone
FL/FR
geranyl hexanoate
FL/FR
(E)-
geranyl linalool
FL/FR
glycoacetal
FR
hawthorn ethanol
FR
hyacinth acetals
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
iso
jasmone
FL/FR
iso
jasmone
FL/FR
para-
methyl benzyl acetate
FL/FR
(Z)-
methyl epi-jasmonate
FL/FR
N-
methyl ionone
FR
alpha-iso
methyl ionone (70% min.)
FL/FR
alpha-iso
methyl ionone (80% min.)
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
methyl jasmonate
FL/FR
2-
methyl octanal
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
cis-
muguet shiseol
FL/FR
musk acetate
FR
(E)-
nerolidol
FL/FR
nerolin fragarol
FL/FR
neryl acetate
FL/FR
neryl isovalerate
FL/FR
nonanol
FL/FR
octanal / methyl anthranilate schiff's base
FR
octyl isovalerate
FL/FR
bitter
orangeflower absolute morocco
FL/FR
orris rhizome absolute (iris pallida)
FL/FR
osmanthus concrete
FL/FR
papaya isobutyrate
FL/FR
peony alcohol
FR
petitgrain mandarin oil
FL/FR
petitgrain mandarin oil terpeneless
FL/FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
phenethyl butyrate
FL/FR
phenethyl heptanoate
FL/FR
phenethyl hexanoate
FL/FR
phenethyl lactate
FL/FR
phenethyl phenyl acetate
FL/FR
phenethyl salicylate
FL/FR
phenyl acetaldehyde digeranyl acetal
FR
3-
phenyl propyl formate
FL/FR
primrose fragrance
FR
rhodinol substitues
FL/FR
rhodinyl acetate substitutes
FL/FR
rhodinyl benzoate
FR
rhodinyl phenyl acetate
FL/FR
rosa alba flower oil CO2 extract
FR
rose absolute (rosa centifolia)
FL/FR
rose absolute (rosa centifolia) morocco
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
rose absolute (rosa damascena) turkey
FL/FR
rose absolute pentanol
FR
rose acetate
FR
rose blossom pentanol
FR
rose butanoate
FL/FR
rose concrete (rosa centifolia)
FR
rose concrete (rosa damascena)
FR
rose oil (rosa centifolia) egypt
FL/FR
rose oil (rosa damascena) bulgaria
FL/FR
rose oil (rosa damascena) iran
FL/FR
rose oil (rosa damascena) turkey
FL/FR
rose oil replacer
FR
laevo-
rose oxide
FL/FR
rose pyran
FR
rose specialty
FR
styralyl propionate
FL/FR
2-
undecen-1-ol
FL/FR
(E)-2-
undecen-1-ol
FL/FR
fruity
acetyl methyl anthranilate
FL/FR
apple crotonate
FR
bisabolene
FL/FR
butyl anthranilate
FL/FR
iso
butyl anthranilate
FL/FR
iso
butyl isobutyrate
FL/FR
(E)-alpha-
damascone
FL/FR
ethyl 3-hydroxyhexanoate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
ethyl para-methyl-beta-phenyl glycidate
FR
ethyl propionate
FL/FR
fig crotonate
FR
grape butyrate
FL/FR
3-
hexanone
FL/FR
(Z)-3-
hexen-1-yl anthranilate
FL/FR
linalyl isobutyrate
FL/FR
methyl anthranilate
FL/FR
methyl formyl anthranilate
FL/FR
neryl propionate
FL/FR
plum crotonate
FR
iso
propenyl acetate
FL/FR
propyl heptanoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
strawberry glycidate 2
FL/FR
vanilla carboxylate
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
iso
decanal
FL/FR
green carboxylate
FR
2-
heptyl tetrahydrofuran
FR
(E)-2-
hexen-1-yl isovalerate
FL/FR
hexyl isobutyrate
FL/FR
leafy acetal
FL/FR
[(4E,4Z)-5-
methoxy-3-methyl-4-penten-1-yl] benzene
FR
4-
methyl-4-phenyl pentanone
FR
neryl butyrate
FL/FR
phenyl acetaldehyde
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
herbal
chamomile valerate
FR
white
cognac oil
FL/FR
hop oil
FL/FR
laevo-
menthyl propionate
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
nonisyl acetate
FR
rose oil (rosa centifolia) morocco
FL/FR
honey
methyl phenyl acetate
FL/FR
phenyl acetic acid
FL/FR
musty
cocoa butenal
FL/FR
naphthyl
beta-
naphthyl ethyl ether
FL/FR
powdery
para-
anisyl alcohol
FL/FR
spicy
cinnamyl propionate
FL/FR
iso
eugenyl phenyl acetate
FL/FR
maja fragrance
FR
pepper hexanone
FR
waxy
ethyl decanoate
FL/FR
woody
cycloionone
FL/FR
For Flavor
No flavor group found for these
1-
acetyl cyclohexyl acetate
FL
allyl anthranilate
FL/FR
amyl anthranilate
FL/FR
iso
amyl undecylenate
FL/FR
butyl benzyl ether
FL/FR
curacao peel oil
FL/FR
(Z)-alpha-
damascone
FL/FR
iso
decanal
FL/FR
(Z)-4-
decen-1-yl acetate
FL/FR
(E)-
geranyl linalool
FL/FR
3-
heptyl acetate
FL
laevo-
menthyl propionate
FL/FR
methyl formyl anthranilate
FL/FR
2-
methyl octanal
FL/FR
nonanal diethyl acetal
FL/FR
octyl isovalerate
FL/FR
phenethyl heptanoate
FL/FR
phenethyl lactate
FL/FR
3-
phenyl propyl formate
FL/FR
rhodinyl acetate substitutes
FL/FR
(E)-2-
undecen-1-ol
FL/FR
2-
undecen-1-ol
FL/FR
apple
apple
red
apple concentrate
FL
aromatic
hyacinth acetals
FL/FR
leafy acetal
FL/FR
balsamic
phenethyl cinnamate
FL/FR
3-
phenyl propyl acetate
FL/FR
berry
gooseberry flavor
FL
rhodinol substitues
FL/FR
citrus
bisabolene
FL/FR
lime oil distilled terpeneless
FL/FR
blood
orange flavor
FL
petitgrain mandarin oil
FL/FR
styralyl propionate
FL/FR
ethereal
iso
propenyl acetate
FL/FR
fatty
2-
dodecanone
FL/FR
floral
iso
amyl phenyl acetate
FL/FR
cinnamyl propionate
FL/FR
citronellal
FL/FR
laevo-
citronellol
FL/FR
citronellyl propionate
FL/FR
cocoa pentenal
FL/FR
dihydrocarvyl acetate
FL/FR
farnesyl acetate
FL/FR
geranium oil egypt
FL/FR
geranium oil terpeneless
FL/FR
geranium petiole oil india
FL/FR
geranium rose oil
FL/FR
geranyl acetone
FL/FR
(E)-
geranyl acetone
FL/FR
(Z)-3-
hexen-1-yl anthranilate
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
jasmin flavor
FL
linalyl isobutyrate
FL/FR
(Z)-
methyl epi-jasmonate
FL/FR
alpha-iso
methyl ionone (70% min.)
FL/FR
alpha-iso
methyl ionone (80% min.)
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
methyl jasmonate
FL/FR
methyl phenyl acetate
FL/FR
mimosa flavor
FL
cis-
muguet shiseol
FL/FR
neryl acetate
FL/FR
bitter
orangeflower absolute morocco
FL/FR
phenethyl alcohol
FL/FR
phenyl acetic acid
FL/FR
rose absolute (rosa centifolia)
FL/FR
rose absolute (rosa centifolia) morocco
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
rose absolute (rosa damascena) turkey
FL/FR
rose oil (rosa centifolia) egypt
FL/FR
rose oil (rosa damascena) bulgaria
FL/FR
rose oil (rosa damascena) iran
FL/FR
rose oil (rosa damascena) turkey
FL/FR
laevo-
rose oxide
FL/FR
fruity
acetyl methyl anthranilate
FL/FR
para-
anisyl alcohol
FL/FR
red
apple flavor
FL
benzyl alcohol
FL/FR
butyl anthranilate
FL/FR
iso
butyl anthranilate
FL/FR
iso
butyl isobutyrate
FL/FR
citronellyl anthranilate
FL/FR
(E)-alpha-
damascone
FL/FR
ethyl 3-hydroxyhexanoate
FL/FR
ethyl anthranilate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
ethyl propionate
FL/FR
furfuryl butyrate
FL
geranyl hexanoate
FL/FR
3-
hexanone
FL/FR
methyl anthranilate
FL/FR
para-
methyl benzyl acetate
FL/FR
nerolin fragarol
FL/FR
neryl isovalerate
FL/FR
osmanthus concrete
FL/FR
petitgrain mandarin oil terpeneless
FL/FR
phenethyl butyrate
FL/FR
rose butanoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
strawberry glycidate 2
FL/FR
vanilla carboxylate
FL/FR
fusel
white
cognac oil
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
cocoa butenal
FL/FR
gelsone (IFF)
FL/FR
geranyl acetate
FL/FR
grape butyrate
FL/FR
(E)-2-
hexen-1-yl isovalerate
FL/FR
hexyl isobutyrate
FL/FR
iso
jasmone
FL/FR
iso
jasmone
FL/FR
(E)-
nerolidol
FL/FR
neryl butyrate
FL/FR
neryl propionate
FL/FR
papaya isobutyrate
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
herbal
hop oil
FL/FR
rose oil (rosa centifolia) morocco
FL/FR
honey
ethyl phenyl acetate
FL/FR
phenethyl acetate
FL/FR
phenethyl phenyl acetate
FL/FR
phenyl acetaldehyde
FL/FR
medicinal,
phenethyl salicylate
FL/FR
melon
melon flavor
FL
nutty
2-
acetyl-1-methyl pyrrole
FL
powdery
beta-
naphthyl ethyl ether
FL/FR
spicy
benzyl cinnamate
FL/FR
iso
eugenyl phenyl acetate
FL/FR
sweet
orris rhizome absolute (iris pallida)
FL/FR
waxy
ethyl decanoate
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
nonanol
FL/FR
phenethyl hexanoate
FL/FR
propyl heptanoate
FL/FR
rhodinyl phenyl acetate
FL/FR
woody
cycloionone
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
 
Potential Uses:
FRcarnation
 fixer
FRgardenia
FRgenet
FRgrape
FRhoneysuckle
FRjasmin
FRorange blossom
FRoriental
 origan
FRorris
FRrose white rose
FRscented stock
FRsweet pea
FRtobacco flower
FRviolet
 
Occurrence (nature, food, other):note
 murraya exotica
Search Trop Picture
 
Synonyms:
2-aminobenzoic acid 2-phenyl ethyl ester
 anthranilic acid phenethyl ester
 anthranilic acid, phenethyl ester
 benzoic acid, 2-amino-, 2-phenylethyl ester
 benzyl carbinyl anthranilate
 benzylcarbinyl anthranilate
2-phenethyl 2-aminobenzoate
beta-phenethyl o-aminobenzoate
beta-phenethyl ortho-aminobenzoate
2-phenyl ethyl anthranilate
2-phenyl ethyl ortho-aminobenzoate
2-phenylethyl 2-aminobenzoate
 phenylethyl anthranilate
2-phenylethyl anthranilate
2-phenylethyl o-aminobenzoate
 
 
Notes:
Flavouring ingredient
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