geranium cyclohexane
geranodyle (Givaudan)
 
Notes:
derived from the leaves of the lemon eucalyptus, corymbia citriodora; a leech repellent. Constit. of the roots of Litsea cubeba (mountain pepper) p-Menthane-3,8-diol, also known as para-menthane-3,8-diol and PMD, is an active ingredient used in insect repellents. It smells similar to menthol and acts as a coolant. PMD is found in the oil within leaves of the Eucalyptus citriodora tree. This tree is native to Australia, but is now cultivated in many warm places around the world. This oil, when refined for use in insect repellents, is known as Oil of Lemon Eucalyptus or, more commonly, Citriodiol. Typically, Citriodiol contains 64% PMD (a mixture of the cis and trans isomers of p-menthane-3,8-diol). Citriodiol has been notified under the European Biocidal Products Directive (BPD) 98/8/EC and is currently proceeding through the registration process with the Heath and Safety Executive in the UK. It is the only natural ingredient that can now be used as an insect repellent.
  • Azelis
    • Azelis UK Life Sciences
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      GERANODYLE
       
  • Vigon International
    • Vigon International, Inc.
      Passion for Simplicity
      Manufacturer and supplier of high quality flavor and fragrance ingredients.
      The growth and success of Vigon is due in large part to a unique corporate concept that Vigon has developed and established within the industry: Creative Partnerships. This partnership concept has been and continues to be the foundation and guiding principle for all of Vigon's activities.
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      501881 Geranodyle
       
Synonyms   Articles   Notes   Search
Fragrance Demo Formulas
2-(2-hydroxypropan-2-yl)-5-methylcyclohexan-1-ol (Click)
CAS Number: 42822-86-6Picture of molecule
ECHA EINECS - REACH Pre-Reg: 255-953-7
FDA UNII: 6T6Z1Z1NC4
Nikkaji Web: J309.978D
Beilstein Number: 2552262
MDL: MFCD00191551
XlogP3-AA: 2.20 (est)
Molecular Weight: 172.26780000
Formula: C10 H20 O2
NMR Predictor: Predict (works with chrome or firefox)
(1R,2S,5R)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-ol (Click)
CAS Number: 50373-36-9Picture of molecule
Other: 59905-53-2
ECHA EINECS - REACH Pre-Reg: 256-557-7
FDA UNII: 3TH92O3BXN
Nikkaji Web: J3.215H
XlogP3-AA: 3.00 (est)
Molecular Weight: 154.25266000
Formula: C10 H18 O
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
IBM Patents: Obtain
Pubchem Patents: Search
PubMed: Search
NCBI: Search
FDA Mainterm: P-MENTHANE-3,8-DIOL
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Physical Properties:
Appearance: yellow to orange clear liquid (est)
Assay: 80.00 to 100.00 % 
Food Chemicals Codex Listed: No
Boiling Point: 267.58 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 0.001000 mm/Hg @ 25.00 °C. (est)
Flash Point: 75.00 °F. TCC ( 23.89 °C. )
logP (o/w): 1.374 (est)
Soluble in:
 alcohol
 water, 670.7 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
Odor Type: herbal
Odor Strength: medium
 geranium  rose  fruity  
Odor Description:
at 100.00 %. 
geranium rose fruity
 floral  rose  geranium  herbal  green  lavender  tea  
Odor Description:
at 1.00 %.  
floral, rose , geraniol with herbal, green lavender and tea like nuances
Mosciano, Gerard, (2009)
 floral  rose  geranium  herbal  green  lavender  tea  
Taste Description:
at 10.00 ppm.  
Floral, rose , geraniol with herbal, green lavender and tea like nuances
Mosciano, Gerard, (2009)
Substantivity: 20 Hour(s)
  
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: hair conditioning
oral care agents
skin conditioning
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Suppliers:
Azelis
GERANODYLE
Services
CG Herbals
Geranodyle
Odor: Geranium, Rosy, Fruity
Use: Geranodyle is a complex mixture with a fresh, geranium odour. A top note ingredient, it has good diffusivity and increases the fruity character of compositions.
Givaudan
Geranodyle
Odor: Geranium, Rosy, Fruity
Use: Geranodyle is a complex mixture with a fresh,geranium odour. A top note ingredient, it has good diffusivity and increases the fruity character of compositions.
Perfumery Laboratory
GERANODIL Givaudan (GERANODYLE Givaudan)
Odor: fresh, complex, rich odor with a deep note of geranium
The Perfumers Apprentice
Geranodyle (G)
Odor: fresh,geranium odor with good diffusivity
Use: increases the fruity character of compositions
Vigon International
Geranodyle
Odor: Geranium, Rosy, Fruity
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Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 10 - Flammable.
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: fragrance agents
maximum skin levels for fine fragrances:
  0.0200 %  and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey).
Recommendation for geranium cyclohexane usage levels up to:
  5.0000 % in the fragrance concentrate.
use level in formulae for use in cosmetics:
  0.0200 %
Dermal Systemic Exposure in Cosmetic Products:
 0.0005 mg/kg/day
 
Recommendation for geranium cyclohexane flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
ClinicalTrials.gov: search
Cancer Citations: Search
Toxicology Citations: Search
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 556998
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 2-(2-hydroxypropan-2-yl)-5-methylcyclohexan-1-ol
Chemidplus: 0042822866
 (1R,2S,5R)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-ol
Chemidplus: 050373369
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References:
 2-(2-hydroxypropan-2-yl)-5-methylcyclohexan-1-ol
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 556998
Pubchem (sid): 135251241
 (1R,2S,5R)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-ol
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 170833
Pubchem (sid): 748355
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS): View
CHEBI: View
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB36145
FooDB: FDB014996
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
Wikipedia: View
RSC Learn Chemistry: View
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Potential Blenders and core components note
 
For Odor
alliaceous
 dibutyl sulfideFL/FR
floral
 benzyl isobutyrateFL/FR
 cassis buteneoneFR
 citronellal diisotridecyl acetalFR
laevo-citronellolFL/FR
 citronellyl acetateFL/FR
(S)-citronellyl acetateFL/FR
 citronellyl anthranilateFL/FR
 citronellyl hexanoateFL/FR
(E)-citronellyl tiglateFL/FR
beta-damascenoneFL/FR
delta-damasconeFL/FR
 dihydrorose oxideFR
 dimethyl benzyl carbinyl acetateFL/FR
 ethyl linalyl acetateFR
 ethyl ortho-anisateFL/FR
 floral pyranFR
 geraniolFL/FR
 geranium nitrileFR
 geranium oil egyptFL/FR
 geranyl hexanoateFL/FR
 geranyl isobutyrateFL/FR
 geranyl propionateFL/FR
 geranyl tiglateFL/FR
 geranyl valerateFL/FR
 musk acetateFR
 phenethyl isobutyrateFL/FR
 phenethyl isovalerateFL/FR
 phenethyl propionateFL/FR
2-phenethyl valerateFL/FR
 rhodinyl butyrateFL/FR
 rhodinyl propionateFL/FR
fruity
 allyl isononylateFR
(E)-ethyl tiglateFL/FR
 geranyl butyrateFL/FR
 octyl formateFL/FR
green
 hexyl phenyl acetateFL/FR
herbal
 geranyl octanoateFL/FR
 linalyl formateFL/FR
waxy
 dihydrocitronellyl acetateFL/FR
 ethyl nonanoateFL/FR
winey
 butyl angelateFL/FR
woody
 santalyl butyrateFL/FR
 
For Flavor
 
No flavor group found for these
 butyl angelateFL/FR
laevo-citronellolFL/FR
 citronellyl anthranilateFL/FR
 dihydrocitronellyl acetateFL/FR
 ethyl ortho-anisateFL/FR
 geranyl hexanoateFL/FR
 geranyl octanoateFL/FR
 geranyl valerateFL/FR
 linalyl formateFL/FR
 octyl formateFL/FR
2-phenethyl valerateFL/FR
 santalyl butyrateFL/FR
aromatic
 dimethyl benzyl carbinyl acetateFL/FR
floral
(S)-citronellyl acetateFL/FR
 citronellyl acetateFL/FR
 citronellyl hexanoateFL/FR
 geraniolFL/FR
 geranium oil egyptFL/FR
 geranyl isobutyrateFL/FR
 geranyl tiglateFL/FR
fruity
 benzyl isobutyrateFL/FR
(E)-ethyl tiglateFL/FR
 geranyl butyrateFL/FR
 hexyl phenyl acetateFL/FR
 phenethyl isovalerateFL/FR
 phenethyl propionateFL/FR
 rhodinyl butyrateFL/FR
 rhodinyl propionateFL/FR
green
 dibutyl sulfideFL/FR
honey
 phenethyl isobutyrateFL/FR
leafy
(E)-citronellyl tiglateFL/FR
waxy
 ethyl nonanoateFL/FR
 geranyl propionateFL/FR
beta-damascenoneFL/FR
delta-damasconeFL/FR
 
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Potential Uses:
 berryFR
 cherryFR
 floralFR
 fruitFR
 geraniumFR
 hair conditioning 
 herbalFR
 melonFR
 mintFR
 oral care agents 
 roseFR
 skin conditioning 
 tea 
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Occurrence (nature, food, other): note
 found in nature
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Synonyms:
 cyclohexanemethanol, 2-hydroxy-a,a,4-trimethyl- (mixture)
 cyclohexanol, 2-(2-hydroxy-2-propyl)-5-methyl- (mixture)
 geranium cyclohexane
 geranodyle (Givaudan)
2-(1-hydroxy-1-methylethyl)-5-methylcyclohexanol (mixture)
1-hydroxy-2-(1-methyl-1-hydroxyethyl)-5-methyl cyclohexane reaction mixture
2-hydroxy-a,a,4-trimethylcyclohexane methanol (mixture)
2-hydroxy-alpha,alpha,4-trimethyl cyclohexane methanol
2-(2-hydroxypropan-2-yl)-5-methylcyclohexan-1-ol (mixture)
2-(2-hydroxypropan-2-yl)-5-methylcyclohexanol (mixture)
p-menthan-3,8-diol (mixture)
p-menthane-3,8-diol (mixture)
(±)-(1alpha,2beta,5alpha)-5-methyl-2-(1-methyl vinyl) cyclohexan-1-ol (mixture)
 reaction mixture containing 1-hydroxy-2-(1-methyl-1-hydroxyethyl)-5-methyl cyclohexane
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