EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
BT
 

theaspirane
2,6,6,10-tetramethyl-1-oxaspiro[4.5]dec-9-ene

Sponsors

Name: 2,6,6,10-tetramethyl-1-oxaspiro[4.5]dec-9-ene
CAS Number: 36431-72-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 253-031-9
FDA UNII: 7371A7GT6E
Nikkaji Web: J52.337B
Beilstein Number: 1424383
MDL: MFCD00085214
CoE Number: 10515
XlogP3-AA: 3.00 (est)
Molecular Weight: 194.31754000
Formula: C13 H22 O
NMR Predictor: Predict (works with chrome or firefox)
EFSA/JECFA Comments:
Racemate, and mixture of (Z)-isomer (55-58%), (E)-isomer (42-45%) and 5 other secondary components 8-13.5% (EFFA, 2010a).
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 1238 theaspirane
Flavis Number: 13.098 (Old)
DG SANTE Food Flavourings: 13.098 theaspirane
FEMA Number: 3774 theaspirane
FDA Mainterm: THEASPIRANE
 
Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 96.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 0.93100 25.00 °C.
Boiling Point: 68.00 to 72.00 °C. @ 3.00 mm Hg
Boiling Point: 274.00 to 275.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.028000 mm/Hg @ 25.00 °C. (est)
Vapor Density: 6.6 ( Air = 1 )
Flash Point: 149.00 °F. TCC ( 65.00 °C. )
logP (o/w): 4.057 (est)
Soluble in:
 alcohol
 water, 3.796 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: herbal
Odor Strength: high ,
recommend smelling in a 1.00 % solution or less
 tea herbal green wet tobacco leafy metallic woody spicy
Odor Description:
at 1.00 % in dipropylene glycol.
tea herbal green wet tobacco leaf metallic woody spicy
Luebke, William tgsc, (1991)
 woody cooling minty camphoreous fresh green herbal
Odor Description:
Woody, cooling, minty and camphoreous, with a fresh green herbal nuance
Mosciano, Gerard P&F 15, No. 6, 35, (1990)
Flavor Type: cooling
 cooling minty camphoreous herbal pine
Taste Description:
at 10.00 ppm.
Cooling minty, camphoraceous, with an herbal and piney nuance
Mosciano, Gerard P&F 15, No. 6, 35, (1990)
Odor and/or flavor descriptions from others (if found).
Frutarom
THEASPIRAN ≥85.00% (sum of isomers), NI, Kosher
Odor Description: Green, Herbal, Metallic, Spicy, Woody
Suggested Uses: Blackberry, Citrus Fruits, Herbal Flavours, Raspberry, Soft Fruits, Tea, Vanilla
Taste Description: cooling mint camphor herbal pine
Givaudan
Spiroxide ≥85%, NI, Kosher
Odor Description: Green,Fruity,Woody,Champhorated
This strong chemical demonstrates camphoraceous fresh fruity notes.
Indukern F&F
THEASPIRANE
Odor Description: GREEN, FRUITY, WOODY, CAMPHORATED
Pell Wall Perfumes
Theaspirane
Odor Description: Fresh, tea-like, tobacco, woody, fruity-berry. Powerful
A very interesting material of great power, here in pure form.
 
Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Apple Flavor & Fragrance
Theaspirane,2,6,10,10-Tetramethyl-1-oxaspiro[4,5]dec-6-one
Beijing Lys Chemicals
Theaspirane
Berjé
Theaspirin
Happening at Berje
BOC Sciences
For experimental / research use only.
(±)-Theaspirane
Charkit Chemical
THEASPIRAN FEMA 3774
DeLong Chemicals America
Theaspirane, Kosher
Ernesto Ventós
THEASPIRANE
Odor: FRUITY,WOODY,SWEET,TEA,TOBACCO
Flavor: WOODY, GREEN
Frutarom
THEASPIRAN
≥85.00% (sum of isomers), NI, Kosher
Odor: Green, Herbal, Metallic, Spicy, Woody
Use: Suggested Uses: Blackberry, Citrus Fruits, Herbal Flavours, Raspberry, Soft Fruits, Tea, Vanilla
Givaudan
Spiroxide
≥85%, NI, Kosher
Odor: Green,Fruity,Woody,Champhorated
Use: This strong chemical demonstrates camphoraceous fresh fruity notes.
Indukern F&F
THEASPIRANE
Odor: GREEN, FRUITY, WOODY, CAMPHORATED
M&U International
THEASPIRANE
Organica Aromatics
ORSPIRANE
Pell Wall Perfumes
Theaspirane 10%
Odor: Fresh, tea-like, tobacco, woody, fruity-berry
Use: In 1985 Arcadi Boix Camps writes that “Theaspirane is one of those singular chemicals that seldom emerge from research. It might even be considered one of the 10 best chemicals on the market. It is present in natural tea, and its fragrance is extraordinarily complex: herbal, greeen tea, moist and recently cut tobacco leaves, with metalic, woody, floral and spicy backnotes. Its blends with vanilla notes, [tabanon], formyl tricide decane, the macrocyclic musks, Oxo-Edulane, 4-oxo ionyl acetate, Oxo-Damascone or beta-Damascone are unique. Its radiant and unequalled beauty places this chemical among the exalted ranks of products such as the Damascones and Damascenone, Hedione and Exaltolide, without implying of course, that all these aromatic chemicals can be grouped in the same family.” In 2009 he adds “Theaspirane is a jewel that will be used more and more in the future”.
Pell Wall Perfumes
Theaspirane
Odor: Fresh, tea-like, tobacco, woody, fruity-berry. Powerful
Use: A very interesting material of great power, here in pure form.
Penta International
THEASPIRANE, Kosher
Perfumery Laboratory
TIASPIRAN 10% in SP Ventós (THEASPIRANE Ventós)
Odor: Powerful, tea, herbal, spicy aroma with a hint of metallic leaf tobacco
Reincke & Fichtner
Theaspirane
Riverside Aromatics
THEASPIRAN
Shanghai Vigen Fine Chemical
Theaspirane
Shijiazhuang Donglian Nankai Aroma Chemicals
Theaspirane
Odor: Wood, fruity, black tea and fuller herb
Sigma-Aldrich
Theaspirane, mixture of cis and trans, ≥85%
Odor: berry; green; woody; minty; vanilla; wine-like
Certified Food Grade Products
Synerzine
Theaspirane
Taytonn
Theaspirane
Odor: Green, Herbal/ Herbaceous, Metallic/ Metal, Spicy, Woody
WEN International
THEASPIRANE
Synthetic
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/39 - Wear suitable clothing and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for theaspirane usage levels up to:
  0.5000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 1.70 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.10 (μg/capita/day)
Structure Class: II
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 15
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): -0.50000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: -20.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -2.50000
fruit ices: -1.80000
gelatins / puddings: -3.00000
granulated sugar: --
gravies: --
hard candy: -3.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: -2.50000
meat products: --
milk products: -1.50000
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Flavouring Group Evaluation 59 (FGE.59): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 (2006) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf
Flavouring Group Evaluation 33 (FGE.33)[1] - Six Tetrahydrofuran Derivatives from Chemical Groups 13, 14, 16 and 26 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010)
View page or View pdf
EPI System: View
EPA Substance Registry Services (TSCA): 36431-72-8
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 61953
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 2,6,6,10-tetramethyl-1-oxaspiro[4.5]dec-9-ene
Chemidplus: 0036431728
 
References:
Leffingwell: Chirality or Article
 2,6,6,10-tetramethyl-1-oxaspiro[4.5]dec-9-ene
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 36431-72-8
Pubchem (cid): 61953
Pubchem (sid): 135018915
Pherobase: View
 
Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS): View
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB36823
FooDB: FDB015771
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
Wikipedia: View
RSC Learn Chemistry: View
 
Potential Blenders and core components note
For Odor
aldehydic
agrumen nitrile
FR
decanal (aldehyde C-10)
FL/FR
9-
decenal
FL/FR
dodecanal (aldehyde C-12 lauric)
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
amber
ambrette seed absolute
FL/FR
angelica archangelica root oil CO2 extract
FL/FR
angelica root oil
FL/FR
animal
iso
butyl quinoline
FR
para-
cresyl caprylate
FL/FR
6-
methyl quinoline
FL/FR
anisic
ambrette seed oil
FL/FR
para-
anisaldehyde
FL/FR
estragole
FL/FR
ocimum basilicum leaf oil america
FL/FR
balsamic
2-
acetyl furan
FL/FR
amyl phenyl acetate
FL/FR
siam
benzoin resinoid
FL/FR
benzophenone
FL/FR
benzyl salicylate
FL/FR
laevo-
bornyl acetate
FL/FR
iso
bornyl acetate
FL/FR
iso
bornyl formate
FL/FR
iso
bornyl propionate
FL/FR
iso
butyl cinnamate
FL/FR
cinnamyl alcohol
FL/FR
cinnamyl formate
FL/FR
clover nitrile
FR
ethyl cinnamate
FL/FR
fir balsam absolute
FR
fir needle oil siberia
FL/FR
methyl cinnamate
FL/FR
3-
phenyl propyl alcohol
FL/FR
christmas
pine fragrance
FR
verbenol
FL/FR
berry
raspberry ketone
FL/FR
raspberry ketone acetate
FL/FR
raspberry ketone methyl ether
FL/FR
camphoreous
laevo-
fenchone
FL/FR
caramellic
2-iso
butyl-3-methyl pyrazine
FL/FR
cereal
bran absolute
FR
citrus
bergamot oil
FL/FR
iso
decyl acetate
FR
grapefruit oil c.p. california
FL/FR
grapefruit pentanol
FR
ocimene quintoxide
FL/FR
verbena absolute france
FL/FR
waxy nitrile
FR
clean
clean nitrile
FR
earthy
geosmin
FL/FR
(S)-1-
octen-3-ol
FL/FR
ethereal
ethyl 4-pentenoate
FL/FR
fatty
decanol
FL/FR
(E)-2-
octenal
FL/FR
2-
octenal
FL/FR
floral
alpha-
amyl cinnamaldehyde
FL/FR
iso
amyl salicylate
FL/FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
bois de rose oil brazil
FL/FR
boronia butenal
FR
iso
butyl salicylate
FL/FR
cassis oxime 10%
FR
champaca absolute
FR
cilantro herb oil egypt
FL/FR
citronellol
FL/FR
citronellyl acetate
FL/FR
coriander seed oil
FL/FR
cyclamen aldehyde
FL/FR
cymbopogon validus leaf oil
FR
beta-
damascenone
FL/FR
alpha-
damascone
FL/FR
delta-
damascone
FL/FR
9-
decen-1-ol
FL/FR
dictamnus hispanicus oil
FR
dihydrocarvyl acetate
FL/FR
dihydrocitronellyl ethyl ether
FR
dihydrorose oxide
FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
dimethyl benzyl carbinyl propionate
FR
2,4-
dimethyl-3-cyclohexene-1-methanol
FR
ethyl linalool
FR
ethyl phenyl acetate
FL/FR
floral pyranol
FR
gardenia oxide
FR
geraniol
FL/FR
geranium oil africa
FL/FR
geranium oil egypt
FL/FR
geranyl acetate
FL/FR
geranyl formate
FL/FR
heliotropin
FL/FR
heliotropyl acetone
FL/FR
heliotropyl diethyl acetal
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
ho leaf oil
FR
hyacinth ether
FR
leerall
FR
lilyall
FR
laevo-
linalool
FL/FR
linalool
FL/FR
linalool oxide
FL/FR
linden flower absolute
FR
melaleuca ericifolia leaf oil
FR
para-
methyl acetophenone
FL/FR
para-
methyl benzyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
(Z)-
methyl epi-jasmonate
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
muguet carboxaldehyde
FR
nerol
FL/FR
neryl formate
FL/FR
3-
nonanone
FL/FR
ocean propanal
FL/FR
orris pyridine 25% IPM
FR
2-
pentyl cyclopentanone
FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
phenethyl isobutyrate
FL/FR
phenethyl phenyl acetate
FL/FR
phenethyl salicylate
FL/FR
iso
phytol
FL/FR
prenyl salicylate
FL/FR
rhodinol
FL/FR
rose butanoate
FL/FR
rose pyran
FR
tea acetate
FR
tetrahydrolinalool
FL/FR
tobacco flower absolute
FR
5-
tricyclodecenyl acetate
FR
fruity
allyl amyl glycolate
FR
allyl hexanoate
FL/FR
alpha-
amyl cinnamyl isovalerate
FL/FR
benzyl propionate
FL/FR
3-
butyl bicyclo[3.2.1]-6-octen-2-one
FR
cyclohexanone diethyl acetal
FL/FR
(E)-beta-
damascone
FL/FR
(Z)-beta-
damascone
FL/FR
beta-
damascone
FL/FR
1,4-
diethyl-6,8-dioxabicyclo(3.2.1)octane
FR
dimethyl benzyl carbinyl isobutyrate
FR
ethyl 2-ethyl acetoacetate
FL/FR
ethyl 3-hydroxyhexanoate
FL/FR
ethyl levulinate
FL/FR
green acetate
FR
heptyl butyrate
FL/FR
tropical indene
FR
fungal
methyl 2-furoate
FL/FR
green
agrumen aldehyde
FR
birch leaf specialty
FR
iso
butyl heptanoate
FL/FR
iso
butyl methyl ketone
FL/FR
2-sec-
butyl thiazole
FL/FR
S-sec-
butyl thioisovalerate
FL/FR
carrot leaf oil (daucus carota ssp.maximus)
FR
chrysanthemum carbaldehyde
FR
diphenyl methane
FL/FR
diphenyl oxide
FL/FR
galbanum oil
FL/FR
heptanal (aldehyde C-7)
FL/FR
1-
heptanol
FL/FR
heptyl benzoate
FL/FR
(Z)-4-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
3-
hexenyl 2-methyl butyrate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
english
ivy leaf absolute
FR
(Z)-
leaf acetal
FL/FR
magnolia flower oil
FL/FR
marigold pot absolute
FL/FR
melon nonenoate
FL/FR
6-
methyl-3-hepten-2-one
FL/FR
phenyl acetaldehyde
FL/FR
3-
propyl bicyclo(3.2.1)-6-octen-2-one
FR
seaweed absolute (fucus vesiculosus et serratus)
FL/FR
terpinyl propionate
FL/FR
triplal / ethyl anthranilate schiff's base
FR
hay
beeswax absolute
FL/FR
tobacco leaf absolute
FL/FR
woodruff absolute
FR
herbal
alpha-
amyl cinnamyl formate
FL/FR
anethum graveolens herb oil
FL/FR
anethum graveolens herb tincture
FL/FR
anthemis nobilis flower extract
FL/FR
anthemis nobilis flower oil roman
FL/FR
apium graveolens seed oil
FL/FR
apium graveolens seed oil india
FL/FR
arnica flower absolute
FR
arnica montana flower oil CO2 extract
FR
artemisia alba oil
FR
sweet
basil absolute
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
chrysanthemum ketone
FR
1,4-
cineole
FL/FR
clary sage absolute
FL/FR
clary sage oil france
FL/FR
coriander oleoresin
FL/FR
daucus carota fruit oil
FL/FR
dill weed oil cuba
FL/FR
dill weed oil reunion
FL/FR
dimethyl benzyl carbinyl formate
FL/FR
2-(2,4-
dimethyl-3-cyclohexene-1-yl)-4,4-dimethyl-1,3-oxathiane
FR
hay oil
FR
cis-
herbal cyclohexane
FR
herbal dioxane
FR
herbal heptane
FR
herbal undecanone
FR
hop absolute
FL/FR
hop oil
FL/FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
hyssopus officinalis extract
FL/FR
hyssopus officinalis leaf tincture
FL/FR
lantana camara flower oil
FR
lavender absolute bulgaria
FL/FR
linalyl acetate
FL/FR
linalyl formate
FL/FR
linalyl octanoate
FL/FR
marigold oil mexico
FL/FR
matricaria chamomilla flower oil
FL/FR
melaleuca leucadendron var. cajuputi leaf oil
FL/FR
1-(2-
methyl allyl oxy) heptane
FR
methyl nicotinate
FL/FR
(E)-6-
methyl-3-hepten-2-one
FL/FR
monarda fistulosa oil
FR
myrtenol
FL/FR
nonisyl formate
FR
nopyl acetate
FR
1-
octen-3-yl acetate
FL/FR
oregano specialty
FR
origanum oil
FL/FR
origanum oil greece
FL/FR
perilla leaf oil
FL/FR
perillaldehyde
FL/FR
petroselinum crispum seed oil CO2 extract
FL/FR
phenyl acetaldehyde diisoamyl acetal
FR
beta-
pinene
FL/FR
alpha-
pinene
FL/FR
prenyl senecioate
FL/FR
reseda absolute
FR
rosmarinus officinalis extract
FL/FR
rosmarinus officinalis tincture
FL/FR
sabinene hydrate
FL/FR
saffron indenone
FL/FR
safranal
FL/FR
salvia sclarea oil
FL/FR
tagete oil CO2 extract
FL/FR
tagete oil rwanda
FL/FR
tagete oil south africa
FL/FR
thyme absolute
FL/FR
tricyclodecyl acetate
FR
viridiflorol
FL/FR
wormwood oil america
FL/FR
wormwood oil italy
FL/FR
wormwood oil poland
FL/FR
yerba mate absolute
FL/FR
honey
methyl phenyl acetate
FL/FR
phenyl acetic acid
FL/FR
licorice
sweet
basil oleoresin
FL/FR
marine
marine pyridine
FR
mentholic
cornmint oil china
FL/FR
laevo-
menthol
FL/FR
(±)-iso
menthone
FL/FR
peppermint cyclohexanone
FL/FR
minty
(-)-
menthone
FL/FR
pennyroyal oil fractions
FL/FR
peppermint absolute
FL/FR
(-)-iso
pulegol
FL/FR
iso
pulegol
FL/FR
mossy
oakmoss absolute
FL/FR
treemoss absolute
FR
musty
ketoiso
phorone
FL/FR
phenolic
2'-
hydroxyacetophenone
FL/FR
pine
dipentene terpene hydrocarbon byproducts
FR
popcorn
2-
acetyl pyridine
FL/FR
powdery
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
soapy
methyl anthranilate / hexyl cinnamaldehyde schiff's base
FR
spicy
benzyl isoeugenol
FL/FR
iso
butyl angelate
FL/FR
clove bud oil
FL/FR
(-)-
cubenol
FL/FR
cuminaldehyde
FL/FR
iso
cyclogeraniol (IFF)
FR
N,N-
diethyl octanamide
FR
alpha-
methyl cinnamaldehyde
FL/FR
methyl isoeugenol
FL/FR
origanum majorana oil
FL/FR
outdoors specialty
FR
black
pepper oil
FL/FR
spicy carbonate
FR
terpenic
frankincense oil
FL/FR
pine needle oil dwarf
FL/FR
alpha-
terpineol
FL/FR
thujonic
armoise oil
FR
tobacco
para-
cresyl isovalerate
FL/FR
3-
ethyl pyridine
FL/FR
methyl benzoxole
FL/FR
tobacco concrete
FR
(E,E/E,Z)-
tobacco cyclohexenone
FL/FR
veltonal (Bedoukian)
FR
tonka
gamma-
hexalactone
FL/FR
mint lactone
FL/FR
saffron resinoid
FL/FR
tonka bean absolute
FR
tonka undecanone
FR
vanilla
ethyl vanillin
FL/FR
propenyl guaethol
FL/FR
vanillyl acetate
FL/FR
waxy
decyl acetate
FL/FR
1-
dodecanol
FL/FR
ethyl laurate
FL/FR
1-
undecanol
FL/FR
woody
amber carbinol
FR
amber decatriene
FR
angelica archangelica root extract
FL/FR
angelica archangelica root tincture
FL/FR
angelica archangelica root water
FL/FR
(+)-
camphene
FL/FR
camphene
FL/FR
cedarwood oil virginia
FR
alpha-
cedrene epoxide
FR
cinnamyl tiglate
FL/FR
cistus twig/leaf oil
FL/FR
cyperus root oil (cyperus rotundus)
FR
dalbergia sissoo leaf oil
FR
alpha-
farnesene
FL/FR
alpha-
farnesene isomer
FL/FR
longifolene
FL/FR
iso
longifolene ketone
FR
methyl cedryl ketone
FL/FR
patchouli ethanone
FR
patchouli oil
FL/FR
sandalwood oil
FL/FR
santall
FR
spruce needle oil canada
FL/FR
tobacarol (IFF)
FR
tobacco nonene
FR
verdoxan
FR
woody acetate
FR
(Z)-
woody amylene
FR
woody dioxolane
FR
woody ether
FR
woody propanol
FR
For Flavor
No flavor group found for these
4-
acetyl-2-isopropenyl pyridine
FL
ambrette seed oil
FL/FR
alpha-
amyl cinnamyl formate
FL/FR
amyl phenyl acetate
FL/FR
angelica archangelica root extract
FL/FR
angelica archangelica root oil CO2 extract
FL/FR
angelica archangelica root tincture
FL/FR
angelica archangelica root water
FL/FR
iso
butyl heptanoate
FL/FR
2-sec-
butyl thiazole
FL/FR
4-
butyl thiazole
FL
S-sec-
butyl thioisovalerate
FL/FR
(+)-
camphene
FL/FR
cinnamyl tiglate
FL/FR
cistus twig/leaf oil
FL/FR
cyclohexanone diethyl acetal
FL/FR
9-
decenal
FL/FR
dimethyl benzyl carbinyl formate
FL/FR
ethyl 4-pentenoate
FL/FR
fig leaf absolute
FL
heptyl benzoate
FL/FR
(E,E)-2,4-
hexadien-1-ol
FL
linalyl formate
FL/FR
magnolia flower oil
FL/FR
melaleuca leucadendron var. cajuputi leaf oil
FL/FR
methyl nicotinate
FL/FR
(E)-6-
methyl-3-hepten-2-one
FL/FR
6-
methyl-3-hepten-2-one
FL/FR
(S)-1-
octen-3-ol
FL/FR
2-
octenal
FL/FR
3-
octyl butyrate
FL
perilla leaf oil
FL/FR
prenyl senecioate
FL/FR
2-
propyl pyridine
FL
2-
propyl thiazole
FL
seaweed absolute (fucus vesiculosus et serratus)
FL/FR
ortho-
vinyl anisole
FL
viridiflorol
FL/FR
althaea officinalis root tincture
FL
beta-
damascone
FL/FR
aldehydic
aldehydic
1-
undecanol
FL/FR
animal
para-
cresyl caprylate
FL/FR
6-
methyl quinoline
FL/FR
balsamic
siam
benzoin resinoid
FL/FR
benzyl salicylate
FL/FR
laevo-
bornyl acetate
FL/FR
iso
bornyl propionate
FL/FR
iso
butyl cinnamate
FL/FR
ethyl cinnamate
FL/FR
fir needle oil siberia
FL/FR
berry
heliotropyl acetone
FL/FR
raspberry ketone
FL/FR
raspberry ketone acetate
FL/FR
raspberry ketone methyl ether
FL/FR
brown
beeswax absolute
FL/FR
camphoreous
camphene
FL/FR
laevo-
fenchone
FL/FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
caramellic
3-
ethyl pyridine
FL/FR
methyl 2-furoate
FL/FR
cherry
heliotropin
FL/FR
citrus
bergamot oil
FL/FR
grapefruit oil c.p. california
FL/FR
linalool
FL/FR
laevo-
linalool
FL/FR
nerol
FL/FR
ketoiso
phorone
FL/FR
alpha-
terpineol
FL/FR
verbena absolute france
FL/FR
coffee
2,4-
dimethyl thiazole
FL
cooling
iso
butyl salicylate
FL/FR
1,4-
cineole
FL/FR
laevo-
menthol
FL/FR
sabinene hydrate
FL/FR
WS-3
FL
corn
2-
acetyl pyridine
FL/FR
creamy
althaea officinalis root extract
FL
para-
anisaldehyde
FL/FR
gamma-
hexalactone
FL/FR
para-
methyl acetophenone
FL/FR
mint lactone
FL/FR
earthy
geosmin
FL/FR
fatty
(Z)-3-
hexen-1-yl benzoate
FL/FR
(E)-2-
octenal
FL/FR
floral
bois de rose oil brazil
FL/FR
citronellol
FL/FR
citronellyl acetate
FL/FR
dihydrocarvyl acetate
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
geraniol
FL/FR
geranium oil africa
FL/FR
geranium oil egypt
FL/FR
linalyl acetate
FL/FR
2-
methyl butyl 3-methyl butenoate
FL
methyl dihydrojasmonate
FL/FR
(Z)-
methyl epi-jasmonate
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
methyl phenyl acetate
FL/FR
ocean propanal
FL/FR
phenethyl alcohol
FL/FR
phenyl acetic acid
FL/FR
rhodinol
FL/FR
tetrahydrolinalool
FL/FR
fruity
allyl hexanoate
FL/FR
alpha-
amyl cinnamyl isovalerate
FL/FR
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
benzyl propionate
FL/FR
alpha-
damascone
FL/FR
(Z)-beta-
damascone
FL/FR
(E)-beta-
damascone
FL/FR
ethyl 2-ethyl acetoacetate
FL/FR
ethyl 3-hydroxyhexanoate
FL/FR
ethyl levulinate
FL/FR
linalyl octanoate
FL/FR
para-
methyl benzyl acetate
FL/FR
neryl formate
FL/FR
rose butanoate
FL/FR
tagete oil CO2 extract
FL/FR
tagete oil rwanda
FL/FR
tagete oil south africa
FL/FR
geranium
benzophenone
FL/FR
grassy
tobacco leaf absolute
FL/FR
green
iso
amyl salicylate
FL/FR
anethum graveolens herb tincture
FL/FR
angelica root oil
FL/FR
iso
butyl angelate
FL/FR
iso
butyl methyl ketone
FL/FR
2-iso
butyl-3-methyl pyrazine
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
celery distillates
FL
cinnamyl alcohol
FL/FR
clary sage absolute
FL/FR
coriander oleoresin
FL/FR
cyclamen aldehyde
FL/FR
diphenyl methane
FL/FR
diphenyl oxide
FL/FR
alpha-
farnesene
FL/FR
alpha-
farnesene isomer
FL/FR
galbanum oil
FL/FR
geranyl acetate
FL/FR
geranyl formate
FL/FR
heptanal (aldehyde C-7)
FL/FR
heptyl butyrate
FL/FR
(Z)-4-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
3-
hexenyl 2-methyl butyrate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
(Z)-
leaf acetal
FL/FR
linalool oxide
FL/FR
marigold pot absolute
FL/FR
melon nonenoate
FL/FR
3-
nonanone
FL/FR
oakmoss absolute
FL/FR
ocimene quintoxide
FL/FR
1-
octen-3-yl acetate
FL/FR
terpinyl propionate
FL/FR
herbal
anethum graveolens herb oil
FL/FR
anthemis nobilis flower extract
FL/FR
anthemis nobilis flower oil roman
FL/FR
apium graveolens seed oil
FL/FR
apium graveolens seed oil india
FL/FR
sweet
basil absolute
FL/FR
celery seed oleoresin
FL
cilantro herb oil egypt
FL/FR
clary sage oil france
FL/FR
coriander seed oil
FL/FR
daucus carota fruit oil
FL/FR
dill weed oil cuba
FL/FR
dill weed oil reunion
FL/FR
hop absolute
FL/FR
hop oil
FL/FR
hyssopus officinalis extract
FL/FR
hyssopus officinalis leaf tincture
FL/FR
lavender absolute bulgaria
FL/FR
marigold oil mexico
FL/FR
matricaria chamomilla flower oil
FL/FR
ocimum basilicum leaf oil america
FL/FR
origanum majorana oil
FL/FR
origanum oil
FL/FR
origanum oil greece
FL/FR
petroselinum crispum seed oil CO2 extract
FL/FR
prenyl salicylate
FL/FR
rosmarinus officinalis extract
FL/FR
rosmarinus officinalis tincture
FL/FR
saffron indenone
FL/FR
salvia sclarea oil
FL/FR
thyme absolute
FL/FR
verbenol
FL/FR
wormwood oil america
FL/FR
wormwood oil italy
FL/FR
wormwood oil poland
FL/FR
yerba mate absolute
FL/FR
honey
ethyl phenyl acetate
FL/FR
phenethyl acetate
FL/FR
phenethyl isobutyrate
FL/FR
phenethyl phenyl acetate
FL/FR
phenyl acetaldehyde
FL/FR
licorice
sweet
basil oleoresin
FL/FR
estragole
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
phenethyl salicylate
FL/FR
mentholic
peppermint cyclohexanone
FL/FR
minty
cornmint oil china
FL/FR
(-)-
menthone
FL/FR
(±)-iso
menthone
FL/FR
myrtenol
FL/FR
pennyroyal oil fractions
FL/FR
peppermint absolute
FL/FR
(-)-iso
pulegol
FL/FR
iso
pulegol
FL/FR
naphthyl
2'-
hydroxyacetophenone
FL/FR
nutty
2-
acetyl furan
FL/FR
methyl benzoxole
FL/FR
(E,E/E,Z)-
tobacco cyclohexenone
FL/FR
oily
iso
phytol
FL/FR
orris
costus root oil
FL
phenolic
para-
cresyl isovalerate
FL/FR
pine
pine needle oil dwarf
FL/FR
beta-
pinene
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
1-
dodecanol
FL/FR
solvent
1-
heptanol
FL/FR
spicy
benzyl isoeugenol
FL/FR
cinnamyl formate
FL/FR
clove bud oil
FL/FR
(-)-
cubenol
FL/FR
cuminaldehyde
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
methyl cinnamate
FL/FR
methyl isoeugenol
FL/FR
paprika oleoresin
FL
black
pepper oil
FL/FR
perillaldehyde
FL/FR
3-
phenyl propyl alcohol
FL/FR
sweet
saffron resinoid
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
vanilla
ethyl vanillin
FL/FR
propenyl guaethol
FL/FR
vanillyl acetate
FL/FR
waxy
decanal (aldehyde C-10)
FL/FR
decanol
FL/FR
9-
decen-1-ol
FL/FR
decyl acetate
FL/FR
ethyl laurate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
woody
ambrette seed absolute
FL/FR
iso
bornyl acetate
FL/FR
iso
bornyl formate
FL/FR
beta-
damascenone
FL/FR
delta-
damascone
FL/FR
frankincense oil
FL/FR
longifolene
FL/FR
methyl cedryl ketone
FL/FR
patchouli oil
FL/FR
alpha-
pinene
FL/FR
safranal
FL/FR
sandalwood oil
FL/FR
spruce needle oil canada
FL/FR
 
Potential Uses:
 berryFR
 blackberryFR
 citrusFR
 fruit tropical fruit 
 grapeFR
 grapefruitFR
 greenFR
 guavaFR
 herbalFR
 mintFR
 neroliFR
 passion fruitFR
 quinceFR
 raspberryFR
 spiceFR
 tea 
 tobacco leafFL/FR
 vanillaFR
 woodyFR
 
Occurrence (nature, food, other): note
 blackberry fruit
Search PMC Picture
 grape
Search Trop Picture
 guava fruit
Search Trop Picture
 passion fruit
Search Trop Picture
 raspberry red raspberry plant
Search Trop Picture
 tea leaf
Search Trop Picture
 
Synonyms:
6,9-epoxy-4-megastigmene
1-oxaspiro-2,6,10,10-tetramethyl(4.5)dec-6-ene
1-oxaspiro(4.5)dec-6-ene, 2,6,10,10-tetramethyl-
1-oxaspiro[4.5]dec-6-ene, 2,6,10,10-tetramethyl-
 spiroxide (Givaudan)
2,6,10,10-tetramethyl-1-oxa-spiro[4.5]dec-6-ene
 tetramethyl-1-oxaspiro-6-decene
2,6,10,10-tetramethyl-1-oxaspiro(4.5)dec-6-ene
2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene
2,6,6,10-tetramethyl-1-oxaspiro[4.5]dec-9-ene
 theaspirane
(±)-theaspirane
 

Articles:

US Patents: 4,014,905 - Esters of certain tetramethyl and pentamethyl-1-oxa-spiro [4-5] decan-6-ols with certain alkanoic acids
PubMed: Main odorants in Jura flor-sherry wines. Relative contributions of sotolon, abhexon, and theaspirane-derived compounds.
PubMed: Fate of key odorants in Sauternes wines through aging.
PubMed: Assessment of the volatile composition of juices of apricot, peach, and pear according to two pectolytic treatments.
PubMed: Hydrolysis of glycosidically bound volatiles from apple leaves (Cv. Anna) by Aspergillus niger beta-glucosidase affects the behavior of codling moth (Cydia pomonella L.).
PubMed: Fate of key odorants in Sauternes wines through aging.
PubMed: Hydrolysis of glycosidically bound volatiles from apple leaves (Cv. Anna) by Aspergillus niger beta-glucosidase affects the behavior of codling moth (Cydia pomonella L.).
 
Notes:
Blends well with vanilla notes. Constit. of raspberry, yellow passion fruit, tea, wine grape, white wine, quince, cherimoya and black chokeberry. Flavouring ingredient [DFC]
 
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