(Z)-4-hexen-1-ol
cis-4-hexen-1-ol
 
Notes:
Green topnotes. Constit. of bananas
  • Bedoukian Research
    • Bedoukian Research, Inc.
      Constantly Improving
      Working closely with our customers to meet their requirements.
      Paul Bedoukian founded the company to fill a niche as a supplier of high quality specialty aroma and flavor ingredients. In 1975 the company began manufacturing insect pheromones which are chemically similar to flavor and fragrance ingredients. Today, Bedoukian Research offers more than 450 Aroma Chemicals and 50 Insect Pheromones, while also providing custom manufacturing services to the pharmaceutical, agrochemical, and specialty chemical industries.
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      Product(s):
      135 cis-4-HEXEN-1-OL ≥96.5%, Kosher
      SDS
      Lends an intense green topnote to heavier fragrances.
      Green, notes for heavy cream, metallic notes for potato, pineapple, and tomato.
       
       
  • CTC Organics
    • CTC Organics
      For More Than 40 Year
      Your source for rare aroma chemicals for the flavor and fragrance industy.
      “The world is run by middle men.” The number of times I have heard Dr. Liu utter those words are innumerable. He loved reciting and recording famous quotes and had many of his own. Among his many talents, Dr. Liu had a unique genius in the area of chemistry. He had an uncanny understanding of the pulse of the chemical industry and was a superb salesman.
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      Product(s):
      W01701 cis-4-hexen-1-ol
       
  • Lluch Essence
    • Lluch Essence S.L.
      A family company dedicated to sales and distribution
      Flexibility, availability, price and quality.
      Flexibility, availability, price and quality make LLUCH ESSENCE S.L. one of Europe’s references when it comes to essential oils and aroma chemicals, and it is now well known all around the world.
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      Product(s):
      cis-4-HEXENOL 96,5%
       
  • Penta International
    • Penta International Corporation
      Chemistry innovation
      At Penta, our products and services help businesses do business better.
      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      Product(s):
      08-28810 cis-4-HEXENOL, Kosher
       
  • TCI AMERICA
    • TCI AMERICA
      Moving Your Chemistry Forward
      We continuously strive to advance our technology.
      Tokyo Chemical Industry Co., Ltd. (TCI) is a leading worldwide manufacturer of specialty organic chemicals founded in 1946. TCI provides organic laboratory chemicals as well as pharmaceutical, cosmetic and functional materials. More than 60 years of synthesis experience and multi-purpose plants enable TCI to offer more than 27,000 products as well as custom synthesis. TCI established overseas facilities in North America, Europe, China and India to serve customers worldwide.
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      Product(s):
      H0754 cis-4-Hexen-1-ol >95.0%(GC)
       
Synonyms   Articles   Notes   Search
(Z)-hex-4-en-1-ol (Click)
CAS Number: 928-91-6Picture of molecule
% from: 92.00% to 98.00%
ECHA EINECS - REACH Pre-Reg: 213-187-0
FDA UNII: 780WMA6J84
Nikkaji Web: J126.475C
Beilstein Number: 1720136
MDL: MFCD00148974
XlogP3-AA: 1.20 (est)
Molecular Weight: 100.16084000
Formula: C6 H12 O
NMR Predictor: Predict (works with chrome or firefox)
Also(can) Contains: (E)-4-hexen-1-ol 0.10% to 8.00%
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
Flavis Number: 02.160 (Old)
FEMA Number: 3430  cis-4-hexen-1-ol
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Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 96.00 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 0.85400 to 0.85800 @  25.00 °C.
Pounds per Gallon - (est).: 7.106 to  7.139
Refractive Index: 1.44200 to 1.44600 @  20.00 °C.
Boiling Point: 159.00 to  160.00 °C. @ 760.00 mm Hg
Boiling Point: 80.00 °C. @ 30.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure: 0.929000 mm/Hg @ 25.00 °C. (est)
Vapor Density: >1 ( Air = 1 )
Flash Point: 142.00 °F. TCC ( 61.11 °C. )
logP (o/w): 1.541 (est)
Soluble in:
 alcohol
 water, 1.6e+004 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
Odor Type: green
Odor Strength: high ,
recommend smelling in a 1.00 % solution or less
 green  vegetable  tomato  turnup  brothy  gassy  
Odor Description:
at 1.00 % in dipropylene glycol. 
green cooked vegetable tomato cooked turnup brothy gassy
Luebke, William tgsc, (2009)
 green  herbal  musty  tomato  metallic  vegetable  
Odor Description:
Green, herbal, musty, tomato, with metallic and vegetable nuances
Mosciano, Gerard P&F 15, No. 4, 59, (1990)
 green  tomato  fresh  herbal  vegetable  
Taste Description:
at 20.00 ppm.  
Green, tomato, fresh with herbal vegetable nuances
Mosciano, Gerard P&F 15, No. 4, 59, (1990)
Substantivity: 6 hour(s) at 100.00 %
  
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Cosmetic Information:
None found
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Suppliers:
Bedoukian Research
cis-4-HEXEN-1-OL
≥96.5%, Kosher
Odor: Very powerful, pungent, green vegetable
Use: Lends an intense green topnote to heavier fragrances.
Flavor: Metallic, earthy notes similar to potato and cooked pineapple
Green, notes for heavy cream, metallic notes for potato, pineapple, and tomato.
Carbosynth
For experimental / research use only.
cis-4-Hexen-1-ol
CTC Organics
cis-4-hexen-1-ol
Lluch Essence
cis-4-HEXENOL 96,5%
Penta International
cis-4-HEXENOL, Kosher
Santa Cruz Biotechnology
For experimental / research use only.
cis-4-Hexen-1-ol
Sigma-Aldrich
For experimental / research use only.
cis-4-Hexen-1-ol ≥95.0% (GC)
TCI AMERICA
For experimental / research use only.
cis-4-Hexen-1-ol >95.0%(GC)
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for (Z)-4-hexen-1-ol usage levels up to:
  0.8000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 2.40 (μg/capita/day)
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 8
Click here to view publication 8
 average usual ppmaverage maximum ppm
baked goods: -4.00000
beverages(nonalcoholic): -2.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: -4.00000
egg products: --
fats / oils: --
fish products: --
frozen dairy: -2.00000
fruit ices: -2.00000
gelatins / puddings: -2.00000
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: -2.00000
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
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Safety References:
European Food Safety Athority(efsa): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
EPI System: View
EPA Substance Registry Services (TSCA): 928-91-6
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 5365589
National Institute of Allergy and Infectious Diseases: Data
WISER: UN 1993
WGK Germany: 3
 (Z)-hex-4-en-1-ol
Chemidplus: 0000928916
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References:
 (Z)-hex-4-en-1-ol
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 928-91-6
Pubchem (cid): 5365589
Pubchem (sid): 135028155
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): HMDB31502
FooDB: FDB011532
Export Tariff Code: 2905.29.9000
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
Read: Under the conditions of intended use - New developments in the FEMA GRAS program and the safety assessment of flavor ingredients
Read: A GRAS assessment program for flavor ingredients
Read: Sensory testing for flavorings with modifying properties. Food Technology
Read: Criteria for the safety evaluation of flavoring substances
Read: A procedure for the safety evaluation of natural flavor complexes used as ingredients in food: essential oils
Read: FEMA Expert Panel: 30 Years of safety evaluation for the flavor industry
Read: Consumption ratio and food predominance of flavoring materials
Synonyms   Articles   Notes   Search   Top
Potential Blenders and core components note
 
For Odor
aldehydic
aldehydic
 fresh carbaldehydeFR
amber
 amber furanFR
animal
isobutyl quinolineFR
balsamic
 cinnamyl formateFL/FR
citrus
 aldehydic nitrileFR
 citronellyl nitrileFR
 dodecane nitrileFR
 geranyl nitrileCS
homogeranyl nitrileFR
4-methyl-2-(1-methyl propyl)-1,3-oxathiane 
ethereal
 ethyl 4-pentenoateFL/FR
2-methyl valeraldehydeFL/FR
 propyl valerateFL/FR
fatty
 neryl acetoneFL/FR
(E)-2-octenalFL/FR
floral
isoamyl salicylateFL/FR
 dihydrorose oxideFR
 dimethyl benzyl carbinyl butyrateFL/FR
2,4-dimethyl-3-cyclohexene-1-methanolFR
 floral pyranFR
 geranium oil africaFL/FR
 geranium oil egyptFL/FR
 heliotropyl acetateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
 hexyl nonanoateFL/FR
 hyacinth etherFR
 muguet nitrileFR
 neryl formateFL/FR
2-pentyl cyclopentanoneFR
isophytolFL/FR
laevo-rose oxideFL/FR
(Z)-rose oxideFL/FR
 rose pyranFR
 tuberolideFL/FR
fruity
 cyclohexyl carboxylic acidFL/FR
gamma-dodecalactoneFL/FR
 ethyl 3-hexenoateFL/FR
2-heptyl butyrateFL/FR
2-pentyl furanFL/FR
 tropical indeneFR
 tropical thiazoleFL/FR
green
isobutyl heptanoateFL/FR
isobutyl methyl ketoneFL/FR
2-isoBUTYL PYRAZINEFL/FR
2-isobutyl thiazoleFL/FR
2-sec-butyl thiazoleFL/FR
 chrysanthemum oxideFL/FR
 cognac heptanoneFL/FR
 cortex pyridineFL/FR
 cucumber essenceFL/FR
 geranium thiazoleFL/FR
 green etherFL/FR
 heptanal (aldehyde C-7)FL/FR
1-heptanolFL/FR
1-hepten-3-olFL/FR
 heptyl benzoateFL/FR
(E)-4-hexen-1-ol 
(Z)-2-hexen-1-olFL/FR
(Z)-3-hexen-1-yl butyrateFL/FR
(Z)-3-hexen-1-yl octanoateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
3-hexenalFL/FR
4-hexenolFL/FR
3-hexenyl 2-methyl butyrateFL/FR
english ivy leaf absoluteFR
2-octen-1-olFL/FR
1-penten-3-olFL/FR
(E)-2-pentenalFL/FR
 phenethyl isopropyl etherFR
isopropyl decanoateFL/FR
4-isopropyl quinolineFL/FR
isopropyl quinolineFR
 seaweed absolute (fucus vesiculosus et serratus)FL/FR
herbal
6-acetoxydihydrotheaspiraneFL/FR
alpha-amyl cinnamyl formateFL/FR
 anethum graveolens herb oilFL/FR
 anthemis nobilis flower oil romanFL/FR
sweet basil absoluteFL/FR
3-butylidene phthalideFL/FR
(+)-alpha-campholenic aldehydeFL/FR
 dimethyl benzyl carbinyl formateFL/FR
cis-herbal cyclohexaneFR
 herbal dioxaneFR
 herbal heptaneFR
 hop absoluteFL/FR
 hop oilFL/FR
 linalyl formateFL/FR
 linalyl octanoateFL/FR
(E)-6-methyl-3-hepten-2-oneFL/FR
 mistletoe absolute 
 nonisyl formateFR
 ocimene oxiraneFR
1-octen-3-yl acetateFL/FR
 origanum oil greeceFL/FR
curled parsley seed oilFL/FR
 perillaldehydeFL/FR
3-propylidene phthalideFL/FR
 reseda absoluteFR
 safranalFL/FR
 tagete oil CO2 extractFL/FR
 tagete oil rwandaFL/FR
 tagete oil south africaFL/FR
 theaspiraneFL/FR
 thyme absoluteFL/FR
 viridiflorolFL/FR
 wormwood oil americaFL/FR
malty
S-methyl methioninium chloride 
minty
 carvyl acetateFL/FR
isopropyl tiglateFL/FR
(-)-isopulegolFL/FR
mossy
 treemoss absoluteFR
musk
(E)-12-musk decenoneFR
pine
 dipentene terpene hydrocarbon byproductsFR
spicy
isobutyl angelateFL/FR
(-)-cubenolFL/FR
 cuminaldehydeFL/FR
isocyclogeraniol (IFF)FR
 cassis pentanoneFL/FR
 dimethyl sulfideFL/FR
 ethyl methyl mercaptopropionateFL/FR
 fish thiolFL/FR
 methyl 3-(methyl thio) propionateFL/FR
 passiflora acetateFL/FR
tropical
delta-dodecalactoneFL/FR
vegetable
 methionalFL/FR
endo-1,2,3,3-tetramethyl bicyclo(2.2.1)heptan-2-olFR
 propyl decanoateFL/FR
woody
alpha-thujene 
 verdoxanFR
yeasty
2-octen-4-oneFL/FR
 
For Flavor
 
No flavor group found for these
6-acetoxydihydrotheaspiraneFL/FR
alpha-amyl cinnamyl formateFL/FR
isobutyl heptanoateFL/FR
2-isoBUTYL PYRAZINEFL/FR
4-butyl thiazoleFL
2-sec-butyl thiazoleFL/FR
(+)-alpha-campholenic aldehydeFL/FR
 chrysanthemum oxideFL/FR
 dimethyl benzyl carbinyl formateFL/FR
 epoxy-2-decenalFL
 ethyl 4-pentenoateFL/FR
 fig leaf absoluteFL
 green etherFL/FR
 heptyl benzoateFL/FR
2-heptyl butyrateFL/FR
(E,E)-2,4-hexadien-1-olFL
 hexyl nonanoateFL/FR
 linalyl formateFL/FR
4-(methyl thio) butanolFL
4-methyl-2-(1-methyl propyl)-1,3-oxathiane 
(E)-6-methyl-3-hepten-2-oneFL/FR
2-methyl-6-propoxypyrazineFL
 mistletoe absolute 
 neryl acetoneFL/FR
 propyl decanoateFL/FR
isopropyl decanoateFL/FR
2-isopropyl pyridineFL
4-isopropyl quinolineFL/FR
2-propyl thiazoleFL
 propyl valerateFL/FR
2-isopropyl-3-(methyl thio) pyrazineFL
(-)-isopulegolFL/FR
 seaweed absolute (fucus vesiculosus et serratus)FL/FR
alpha-thujene 
 tuberolideFL/FR
 viridiflorolFL/FR
alliaceous
 allyl disulfideFL
 benzyl mercaptanFL
3-mercapto-2-pentanoneFL
3-tetrahydrothiophenoneFL
 tropical thiazoleFL/FR
celery
3-butylidene phthalideFL/FR
citrus
 cognac heptanoneFL/FR
cooling
 theaspiraneFL/FR
creamy
delta-dodecalactoneFL/FR
ethereal
4-hexen-3-oneFL
fatty
2-octen-1-olFL/FR
(E)-2-octenalFL/FR
fermented
 methyl thio isovalerateFL
floral
 dimethyl benzyl carbinyl butyrateFL/FR
 geranium oil africaFL/FR
 geranium oil egyptFL/FR
 heliotropyl acetateFL/FR
laevo-rose oxideFL/FR
fruity
 cyclohexyl carboxylic acidFL/FR
gamma-dodecalactoneFL/FR
 ethyl 3-hexenoateFL/FR
 linalyl octanoateFL/FR
 neryl formateFL/FR
 tagete oil CO2 extractFL/FR
 tagete oil rwandaFL/FR
 tagete oil south africaFL/FR
green
isoamyl salicylateFL/FR
isobutyl angelateFL/FR
isobutyl methyl ketoneFL/FR
2-isobutyl thiazoleFL/FR
 cassis pentanoneFL/FR
 cortex pyridineFL/FR
 cucumber essenceFL/FR
 dihydroxyacetophenone (mixed isomers)FL
 geranium thiazoleFL/FR
 heptanal (aldehyde C-7)FL/FR
1-hepten-3-olFL/FR
(Z)-2-hexen-1-olFL/FR
(E)-4-hexen-1-ol 
(Z)-3-hexen-1-yl butyrateFL/FR
(Z)-3-hexen-1-yl octanoateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
3-hexenalFL/FR
3-hexenyl 2-methyl butyrateFL/FR
4-methyl thiazoleFL
3-(5-methyl-2-furyl) butanalFL
1-octen-3-yl acetateFL/FR
4-penten-1-yl acetateFL
1-penten-3-olFL/FR
(E)-2-pentenalFL/FR
2-pentyl furanFL/FR
2-propyl pyrazineFL
isopropyl tiglateFL/FR
 propylene glycol acetone ketalFL
3-propylidene phthalideFL/FR
(Z)-rose oxideFL/FR
herbal
 anethum graveolens herb oilFL/FR
 anthemis nobilis flower oil romanFL/FR
sweet basil absoluteFL/FR
 hop absoluteFL/FR
 hop oilFL/FR
 origanum oil greeceFL/FR
curled parsley seed oilFL/FR
 thyme absoluteFL/FR
 wormwood oil americaFL/FR
meaty
2,6-dimethyl thiophenolFL
metallic
2,5-dihydroxy-1,4-dithianeFL
4-hexenolFL/FR
minty
 carvyl acetateFL/FR
oily
isophytolFL/FR
onion
 methyl propyl disulfideFL
 methyl propyl trisulfideFL
solvent
1-heptanolFL/FR
spicy
 cinnamyl formateFL/FR
(-)-cubenolFL/FR
 cuminaldehydeFL/FR
 perillaldehydeFL/FR
sulfurous
 allyl sulfideFL
 dimethyl sulfideFL/FR
 ethyl methyl mercaptopropionateFL/FR
 ethyl methyl sulfideFL
 fish thiolFL/FR
 methyl benzyl disulfideFL
S-methyl methioninium chloride 
 methyl thiomethyl butyrateFL
 potato butanoneFL
tomato
 methionalFL/FR
tropical
 passiflora acetateFL/FR
vegetable
 methyl 3-(methyl thio) propionateFL/FR
2-methyl valeraldehydeFL/FR
2-octen-4-oneFL/FR
waxy
 furfuryl octanoateFL
woody
 safranalFL/FR
 
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Potential Uses:
 bananaFR
 greenFR
 hay new mown hay foin coupeFR
 milkFL
 onionFL
 passion fruitFR
 potatoFL
 tomatoFL
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 banana fruit
Search  Picture
 butter
Search  Picture
 olive
Search Trop  Picture
 passion fruit
Search Trop  Picture
 tomato
Search  Picture
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Synonyms:
(4Z)-hex-4-en-1-ol
(Z)-hex-4-en-1-ol
cis-hex-4-en-1-ol
cis-4-hexen-1-ol
4-hexen-1-ol, (4Z)-
4-hexen-1-ol, (Z)-
(Z)-4-hexenol
cis-4-hexenol
cis-1-hydroxy-4-hexene
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