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(Z)-4-hexen-1-ol
cis-4-hexen-1-ol

Sponsors

Name:(Z)-hex-4-en-1-ol
CAS Number: 928-91-6Picture of molecule3D/inchi
% from:92.00% to 98.00%
ECHA EINECS - REACH Pre-Reg:213-187-0
FDA UNII:780WMA6J84
Nikkaji Web:J126.475C
Beilstein Number:1720136
MDL:MFCD00148974
XlogP3-AA:1.20 (est)
Molecular Weight:100.16084000
Formula:C6 H12 O
NMR Predictor:Predict (works with chrome or firefox)
Also(can) Contains:(E)-4-hexen-1-ol 0.10% to 8.00%
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
FLAVIS Number:02.160 (Old)
FEMA Number:3430 cis-4-hexen-1-ol
FDA:No longer provide for the use of these seven synthetic flavoring substances
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 96.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:0.85400 to 0.85800 @ 25.00 °C.
Pounds per Gallon - (est).: 7.106 to 7.139
Refractive Index:1.44200 to 1.44600 @ 20.00 °C.
Boiling Point: 159.00 to 160.00 °C. @ 760.00 mm Hg
Boiling Point: 80.00 °C. @ 30.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.929000 mm/Hg @ 25.00 °C. (est)
Vapor Density:>1 ( Air = 1 )
Flash Point: 142.00 °F. TCC ( 61.11 °C. )
logP (o/w): 1.541 (est)
Soluble in:
 alcohol
 water, 1.6e+004 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: green
Odor Strength:high ,
recommend smelling in a 1.00 % solution or less
Substantivity:6 hour(s) at 100.00 %
green vegetable tomato turnup brothy gassy
Odor Description:at 1.00 % in dipropylene glycol. green cooked vegetable tomato cooked turnup brothy gassy
Luebke, William tgsc, (2009)
Odor sample from: Bedoukian Research, Inc.
green herbal musty tomato metallic vegetable
Odor Description:Green, herbal, musty, tomato, with metallic and vegetable nuances
Mosciano, Gerard P&F 15, No. 4, 59, (1990)
Flavor Type: green
green tomato fresh herbal vegetable
Taste Description: at 20.00 ppm. Green, tomato, fresh with herbal vegetable nuances
Mosciano, Gerard P&F 15, No. 4, 59, (1990)
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
cis-4-HEXEN-1-OL ≥96.5%, Kosher
Odor Description:Very powerful, pungent, green vegetable
Lends an intense green topnote to heavier fragrances.
Taste Description:Metallic, earthy notes similar to potato and cooked pineapple
Green, notes for heavy cream, metallic notes for potato, pineapple, and tomato.
 
Cosmetic Information:
None found
 
Suppliers:
Bedoukian Research
cis-4-HEXEN-1-OL
≥96.5%, Kosher
Odor: Very powerful, pungent, green vegetable
Use: Lends an intense green topnote to heavier fragrances.
Flavor: Metallic, earthy notes similar to potato and cooked pineapple
Green, notes for heavy cream, metallic notes for potato, pineapple, and tomato.
BOC Sciences
For experimental / research use only.
cis-4-HEXEN-1-OL 96.5%
Carbosynth
For experimental / research use only.
cis-4-Hexen-1-ol
Lluch Essence
cis-4-HEXENOL 96,5%
Penta International
cis-4-HEXENOL, Kosher
Santa Cruz Biotechnology
For experimental / research use only.
cis-4-Hexen-1-ol
Sigma-Aldrich
For experimental / research use only.
cis-4-Hexen-1-ol ≥95.0% (GC)
Synerzine
cis-4-Hexen-1-ol
TCI AMERICA
For experimental / research use only.
cis-4-Hexen-1-ol >95.0%(GC)
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for (Z)-4-hexen-1-ol usage levels up to:
  0.8000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 2.40 (μg/capita/day)
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 8
 average usual ppmaverage maximum ppm
baked goods: -4.00000
beverages(nonalcoholic): -2.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: -4.00000
egg products: --
fats / oils: --
fish products: --
frozen dairy: -2.00000
fruit ices: -2.00000
gelatins / puddings: -2.00000
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: -2.00000
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

EPI System: View
EPA Substance Registry Services (TSCA):928-91-6
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5365589
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 1993
WGK Germany:3
(Z)-hex-4-en-1-ol
Chemidplus:0000928916
 
References:
 (Z)-hex-4-en-1-ol
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:928-91-6
Pubchem (cid):5365589
Pubchem (sid):135028155
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):HMDB31502
FooDB:FDB011532
Export Tariff Code:2905.29.9000
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
fresh carbaldehyde
FR
amber
amber furan
FR
animal
iso
butyl quinoline
FR
balsamic
cinnamyl formate
FL/FR
citrus
aldehydic nitrile
FR
citronellyl nitrile
FR
dodecane nitrile
FR
geranyl nitrile
CS
homo
geranyl nitrile
FR
ethereal
ethyl 4-pentenoate
FL/FR
2-
methyl valeraldehyde
FL/FR
propyl valerate
FL/FR
fatty
neryl acetone
FL/FR
(E)-2-
octenal
FL/FR
floral
iso
amyl salicylate
FL/FR
dihydrorose oxide
FR
dimethyl benzyl carbinyl butyrate
FL/FR
2,4-
dimethyl-3-cyclohexene-1-methanol
FR
floral pyran
FR
geranium oil africa
FL/FR
geranium oil egypt
FL/FR
heliotropyl acetate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
hexyl nonanoate
FL/FR
hyacinth ether
FR
muguet nitrile
FR
neryl formate
FL/FR
2-
pentyl cyclopentanone
FR
iso
phytol
FL/FR
laevo-
rose oxide
FL/FR
(Z)-
rose oxide
FL/FR
rose pyran
FR
tuberolide
FL/FR
fruity
cyclohexyl carboxylic acid
FL/FR
gamma-
dodecalactone
FL/FR
ethyl 3-hexenoate
FL/FR
2-
heptyl butyrate
FL/FR
2-
pentyl furan
FL/FR
tropical indene
FR
tropical thiazole
FL/FR
green
iso
butyl heptanoate
FL/FR
iso
butyl methyl ketone
FL/FR
2-iso
butyl pyrazine
FL/FR
2-sec-
butyl thiazole
FL/FR
2-iso
butyl thiazole
FL/FR
chrysanthemum oxide
FL/FR
cognac heptanone
FL/FR
cortex pyridine
FL/FR
cucumber essence
FL/FR
geranium thiazole
FL/FR
green ether
FL/FR
heptanal (aldehyde C-7)
FL/FR
1-
heptanol
FL/FR
1-
hepten-3-ol
FL/FR
heptyl benzoate
FL/FR
(Z)-2-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl butyrate
FL/FR
(Z)-3-
hexen-1-yl octanoate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
3-
hexenal
FL/FR
4-
hexenol
FL/FR
3-
hexenyl 2-methyl butyrate
FL/FR
english
ivy leaf absolute
FR
2-
octen-1-ol
FL/FR
1-
penten-3-ol
FL/FR
(E)-2-
pentenal
FL/FR
phenethyl isopropyl ether
FR
iso
propyl decanoate
FL/FR
4-iso
propyl quinoline
FL/FR
iso
propyl quinoline
FR
seaweed absolute (fucus vesiculosus et serratus)
FL/FR
herbal
6-
acetoxydihydrotheaspirane
FL/FR
alpha-
amyl cinnamyl formate
FL/FR
anethum graveolens herb oil
FL/FR
anthemis nobilis flower oil roman
FL/FR
sweet
basil absolute
FL/FR
3-
butylidene phthalide
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
dimethyl benzyl carbinyl formate
FL/FR
cis-
herbal cyclohexane
FR
herbal dioxane
FR
herbal heptane
FR
hop absolute
FL/FR
hop oil
FL/FR
linalyl formate
FL/FR
linalyl octanoate
FL/FR
(E)-6-
methyl-3-hepten-2-one
FL/FR
nonisyl formate
FR
ocimene oxirane
FR
1-
octen-3-yl acetate
FL/FR
origanum oil greece
FL/FR
curled
parsley seed oil
FL/FR
perillaldehyde
FL/FR
3-
propylidene phthalide
FL/FR
reseda absolute
FR
safranal
FL/FR
tagete oil CO2 extract
FL/FR
tagete oil rwanda
FL/FR
tagete oil south africa
FL/FR
theaspirane
FL/FR
thyme absolute
FL/FR
viridiflorol
FL/FR
wormwood oil america
FL/FR
minty
carvyl acetate
FL/FR
iso
propyl tiglate
FL/FR
(-)-iso
pulegol
FL/FR
mossy
treemoss absolute
FR
musk
(E)-12-
musk decenone
FR
pine
dipentene terpene hydrocarbon byproducts
FR
spicy
iso
butyl angelate
FL/FR
(-)-
cubenol
FL/FR
cuminaldehyde
FL/FR
iso
cyclogeraniol (IFF)
FR
sulfurous
cassis pentanone
FL/FR
dimethyl sulfide
FL/FR
ethyl methyl mercaptopropionate
FL/FR
fish thiol
FL/FR
methyl 3-(methyl thio) propionate
FL/FR
passiflora acetate
FL/FR
tropical
delta-
dodecalactone
FL/FR
vegetable
methional
FL/FR
endo-1,2,3,3-
tetramethyl bicyclo(2.2.1)heptan-2-ol
FR
waxy
propyl decanoate
FL/FR
woody
verdoxan
FR
yeasty
2-
octen-4-one
FL/FR
For Flavor
No flavor group found for these
6-
acetoxydihydrotheaspirane
FL/FR
alpha-
amyl cinnamyl formate
FL/FR
iso
butyl heptanoate
FL/FR
2-iso
butyl pyrazine
FL/FR
4-
butyl thiazole
FL
2-sec-
butyl thiazole
FL/FR
dimethyl benzyl carbinyl formate
FL/FR
epoxy-2-decenal
FL
ethyl 4-pentenoate
FL/FR
fig leaf absolute
FL
heptyl benzoate
FL/FR
2-
heptyl butyrate
FL/FR
(E,E)-2,4-
hexadien-1-ol
FL
hexyl nonanoate
FL/FR
linalyl formate
FL/FR
4-(
methyl thio) butanol
FL
(E)-6-
methyl-3-hepten-2-one
FL/FR
2-
methyl-6-propoxypyrazine
FL
neryl acetone
FL/FR
iso
propyl decanoate
FL/FR
propyl decanoate
FL/FR
2-iso
propyl pyridine
FL
4-iso
propyl quinoline
FL/FR
2-
propyl thiazole
FL
propyl valerate
FL/FR
2-iso
propyl-3-(methyl thio) pyrazine
FL
seaweed absolute (fucus vesiculosus et serratus)
FL/FR
viridiflorol
FL/FR
alliaceous
alliaceous
allyl disulfide
FL
benzyl mercaptan
FL
3-
mercapto-2-pentanone
FL
3-
tetrahydrothiophenone
FL
tropical thiazole
FL/FR
celery
3-
butylidene phthalide
FL/FR
citrus
cognac heptanone
FL/FR
cooling
theaspirane
FL/FR
creamy
delta-
dodecalactone
FL/FR
ethereal
4-
hexen-3-one
FL
fatty
2-
octen-1-ol
FL/FR
(E)-2-
octenal
FL/FR
fermented
methyl thio isovalerate
FL
floral
dimethyl benzyl carbinyl butyrate
FL/FR
geranium oil africa
FL/FR
geranium oil egypt
FL/FR
heliotropyl acetate
FL/FR
laevo-
rose oxide
FL/FR
fruity
cyclohexyl carboxylic acid
FL/FR
gamma-
dodecalactone
FL/FR
ethyl 3-hexenoate
FL/FR
linalyl octanoate
FL/FR
neryl formate
FL/FR
tagete oil CO2 extract
FL/FR
tagete oil rwanda
FL/FR
tagete oil south africa
FL/FR
green
iso
amyl salicylate
FL/FR
iso
butyl angelate
FL/FR
iso
butyl methyl ketone
FL/FR
2-iso
butyl thiazole
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
cassis pentanone
FL/FR
chrysanthemum oxide
FL/FR
cortex pyridine
FL/FR
cucumber essence
FL/FR
dihydroxyacetophenone (mixed isomers)
FL
geranium thiazole
FL/FR
green ether
FL/FR
heptanal (aldehyde C-7)
FL/FR
1-
hepten-3-ol
FL/FR
(Z)-2-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl butyrate
FL/FR
(Z)-3-
hexen-1-yl octanoate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
3-
hexenal
FL/FR
3-
hexenyl 2-methyl butyrate
FL/FR
4-
methyl thiazole
FL
3-(5-
methyl-2-furyl) butanal
FL
1-
octen-3-yl acetate
FL/FR
4-
penten-1-yl acetate
FL
1-
penten-3-ol
FL/FR
(E)-2-
pentenal
FL/FR
2-
pentyl furan
FL/FR
2-
propyl pyrazine
FL
iso
propyl tiglate
FL/FR
propylene glycol acetone ketal
FL
3-
propylidene phthalide
FL/FR
(Z)-
rose oxide
FL/FR
herbal
anethum graveolens herb oil
FL/FR
anthemis nobilis flower oil roman
FL/FR
sweet
basil absolute
FL/FR
hop absolute
FL/FR
hop oil
FL/FR
origanum oil greece
FL/FR
curled
parsley seed oil
FL/FR
thyme absolute
FL/FR
wormwood oil america
FL/FR
meaty
2,6-
dimethyl thiophenol
FL
metallic
2,5-
dihydroxy-1,4-dithiane
FL
4-
hexenol
FL/FR
minty
carvyl acetate
FL/FR
(-)-iso
pulegol
FL/FR
oily
iso
phytol
FL/FR
onion
methyl propyl disulfide
FL
methyl propyl trisulfide
FL
solvent
1-
heptanol
FL/FR
spicy
cinnamyl formate
FL/FR
(-)-
cubenol
FL/FR
cuminaldehyde
FL/FR
perillaldehyde
FL/FR
sulfurous
allyl sulfide
FL
dimethyl sulfide
FL/FR
ethyl methyl mercaptopropionate
FL/FR
ethyl methyl sulfide
FL
fish thiol
FL/FR
methyl benzyl disulfide
FL
methyl thiomethyl butyrate
FL
potato butanone
FL
tomato
methional
FL/FR
tropical
passiflora acetate
FL/FR
vegetable
methyl 3-(methyl thio) propionate
FL/FR
2-
methyl valeraldehyde
FL/FR
2-
octen-4-one
FL/FR
waxy
furfuryl octanoate
FL
tuberolide
FL/FR
woody
safranal
FL/FR
 
Potential Uses:
FRbanana
FRgreen
FRhay new mown hay
FLmilk
FLonion
FRpassion fruit
FLpotato
FLtomato
 
Occurrence (nature, food, other):note
 banana fruit
Search Trop Picture
 butter
Search PMC Picture
 olive
Search Trop Picture
 passion fruit
Search Trop Picture
 tomato
Search Trop Picture
 
Synonyms:
(4Z)-hex-4-en-1-ol
(Z)-hex-4-en-1-ol
cis-hex-4-en-1-ol
cis-4-hexen-1-ol
4-hexen-1-ol, (4Z)-
4-hexen-1-ol, (Z)-
(Z)-4-hexenol
cis-4-hexenol
cis-1-hydroxy-4-hexene
 
 
Notes:
Green topnotes. Constit. of bananas
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