heliotropyl diethyl acetal
piperonyl diethyl acetal
 
Notes:
Blends well with almost anything.
  • Hermitage Oils
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      Heliotropine Diethyl Acetal
      Arctander tells us that it has a “very mild floral, sweet odour of mildly green spicy type, remotely reminiscent of Heliotrope and Hawthorne – but much weaker.” Interestingly he goes on to say : “The author finds that this material is of very little value and could not possibly arouse much interest among other perfumers even if the material were made commercially available.” Little did he know that 50 years on it would be a widely used material.
       
       
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    • Pell Wall Perfumes
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      Heliotropine Diethyl Acetal
       
  • Penta International
    • Penta International Corporation
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      Product(s):
      08-03700 HELOITROPIN DIETHYL ACETAL
       
  • Ernesto Ventós
Synonyms   Articles   Notes   Search
5-(diethoxymethyl)-1,3-benzodioxole (Click)
CAS Number: 40527-42-2Picture of molecule
ECHA EINECS - REACH Pre-Reg: 254-956-0
Nikkaji Web: J50.700H
Beilstein Number: 0085612
XlogP3: 2.30 (est)
Molecular Weight: 224.25632000
Formula: C12 H16 O4
BioActivity Summary: listing
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
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Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 1.11300 to 1.12100 @  20.00 °C.
Pounds per Gallon - est.: 9.272 to 9.339
Boiling Point: 276.00 to  277.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.008000 mm/Hg @ 25.00 °C. (est)
Flash Point: 185.00 °F. TCC ( 85.00 °C. )
logP (o/w): 3.078 (est)
Soluble in:
 alcohol
 water, 247.3 mg/L @ 25 °C (est)
Insoluble in:
 water
Stability:
 alkalis
Similar Items: note
acrolein diethyl acetal
alpha-amyl cinnamaldehyde diethyl acetal
para-anisaldehyde diethyl acetal
benzaldehyde diethyl acetal
butyraldehyde diethyl acetal
isobutyraldehyde diethyl acetal
cinnamaldehyde diethyl acetal
citral diethyl acetal
citronellal diethyl acetal
citronellyl oxyacetaldehyde diethyl acetal
crotonaldehyde diethyl acetal
cyclamen aldehyde diethyl acetal
cyclohexanone diethyl acetal
decanal diethyl acetal
(Z)-4-decen-1-al diethyl acetal
dodecanal diethyl acetal
3-ethoxypropionaldehyde diethyl acetal
ethyl vanillin diethyl acetal
formaldehyde diethyl acetal
furfural diethyl acetal
heptanal diethyl acetal
(Z)-4-hepten-1-al diethyl acetal
hexanal diethyl acetal
(Z)-3-hexen-1-al diethyl acetal
(E)-2-hexen-1-al diethyl acetal
alpha-hexyl cinnamaldehyde diethyl acetal
hydroxycitronellal diethyl acetal
methional diethyl acetal
2-methyl butyraldehyde diethyl acetal
(E,Z)-2,6-nonadien-1-al diethyl acetal
nonanal diethyl acetal
isononanal diethyl acetal
octanal diethyl acetal
isooctanal diethyl acetal
phenyl acetaldehyde diethyl acetal
propionaldehyde diethyl acetal
tridecanal diethyl acetal
undecanal diethyl acetal
valeraldehyde diethyl acetal
isovaleraldehyde diethyl acetal
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
Odor Type: floral
Odor Strength: medium
 floral  sweet  spicy  heliotrope  spicy  
Odor Description:
at 100.00 %. 
mild floral sweet spicy meadow sweet
Luebke, William tgsc, (1997)
Substantivity: 88 Hour(s)
  
Synonyms   Articles   Notes   Search   Top
Cosmetic Information:
None found
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Suppliers:
Diffusions Aromatiques
HELIOTROPINE DIETHYL ACETAL
Ernesto Ventós
HELIOTROPINE DIETHYL ACETAL SYNAROME
Hermitage Oils
Heliotropine Diethyl Acetal
Odor: characteristic
Use: Arctander tells us that it has a “very mild floral, sweet odour of mildly green spicy type, remotely reminiscent of Heliotrope and Hawthorne but much weaker.” Interestingly he goes on to say : “The author finds that this material is of very little value and could not possibly arouse much interest among other perfumers even if the material were made commercially available.” Little did he know that 50 years on it would be a widely used material.
The Vault
Inoue Perfumery
PIPERONAL DIETHYL ACETAL
Pell Wall Perfumes
Heliotropine Diethyl Acetal
Penta International
HELOITROPIN DIETHYL ACETAL
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Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intraperitoneal-mouse LDLo  500 mg/kg
"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 7, Pg. 396, 1955.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
Synonyms   Articles   Notes   Search   Top
Safety in Use Information:
Category: fragrance agents
Recommendation for heliotropyl diethyl acetal usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for heliotropyl diethyl acetal flavor usage levels up to:
 not for flavor use.
Synonyms   Articles   Notes   Search   Top
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 40527-42-2
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 95136
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 3
 5-(diethoxymethyl)-1,3-benzodioxole
Chemidplus: 0040527422
Synonyms   Articles   Notes   Search   Top
References:
 5-(diethoxymethyl)-1,3-benzodioxole
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 40527-42-2
Pubchem (cid): 95136
Pubchem (sid): 135054531
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2932.29.6550
ChemSpider: View
Synonyms   Articles   Notes   Search   Top
Potential Blenders and core components note
 
For Odor
No odor group found for these
 robinia pseudoacacia absoluteFR
aldehydic
 nonanal (aldehyde C-9)FL/FR
amber
 ambroxanFL/FR
 cistus ladaniferus resinoidFR
animal
 animal carbolactoneFR
isobutyl quinolineFR
anisic
para-anisaldehydeFL/FR
 estragoleFL/FR
 ocimum basilicum herb oilFL/FR
 ocimum basilicum herb oil egyptFL/FR
 ocimum basilicum leaf oil americaFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
 ocimum basilicum leaf oil indiaFL/FR
balsamic
2-acetyl furanFL/FR
 amyris wood oilFL/FR
siam benzoin resinoidFL/FR
 benzyl cinnamateFL/FR
 benzyl salicylateFL/FR
 brachyleana hutchinsii wood oilFR
isobutyl cinnamateFL/FR
 cinnamyl alcoholFL/FR
(E)-cinnamyl alcoholFL/FR
 ethyl cinnamateFL/FR
 fir balsam absoluteFR
 guaiyl acetateFL/FR
 khella oilFR
 methyl (E)-cinnamateFL/FR
 myrrh oilFL/FR
2-phenyl propyl alcoholFL/FR
3-phenyl propyl alcoholFL/FR
annus wormwood oil franceFL/FR
caramellic
 cycloteneFL/FR
 ethyl maltolFL/FR
 maltolFL/FR
 propyl pyruvateFL/FR
 strawberry furanoneFL/FR
chocolate
isoamyl phenyl acetateFL/FR
 chocolate pyrazine AFL/FR
citrus
 bergamot oilFL/FR
 bergamot oil bergaptene reduced italyFL/FR
 bergamot oil turkeyFL/FR
2-heptanolFL/FR
coconut
gamma-heptalactoneFL/FR
gamma-nonalactone (aldehyde C-18 (so-called))FL/FR
 wine lactoneFL/FR
fatty
 coconut absoluteFL/FR
(R)-gamma-octalactoneFL/FR
 undecanal propylene glycol acetalFL/FR
floral
 acetophenoneFL/FR
alpha-amyl cinnamaldehydeFL/FR
isoamyl salicylateFL/FR
 benzyl acetateFL/FR
 bois de rose oil brazilFL/FR
 cassis specialtyFR
 citronellolFL/FR
 coriander seed oilFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
 dimethyl anthranilateFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
 ethyl phenyl acetateFL/FR
 floral pyranolFR
 geraniolFL/FR
 geranium oilFL/FR
 geranium oil bourbonFL/FR
 heliotropinFL/FR
 heliotropyl acetoneFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 ho leaf oilFR
 hyacinth etherFR
 hydroxycitronellalFL/FR
 jonquil absoluteFR
 jonquil absolute replacerFR
 leerallFR
 lilac perfume baseFR
laevo-linaloolFL/FR
 linaloolFL/FR
 linalool oxideFL/FR
ortho-methoxybenzyl ethyl etherFR
para-methyl acetophenoneFL/FR
1-(2-methyl allyl oxy)-2-methyl butaneFR
 methyl dihydrojasmonateFL/FR
 nerolFL/FR
 nerolidolFL/FR
 ocean propanalFL/FR
bitter orangeflower concrete moroccoFR
 orris pyridine 25% IPMFR
 phenethyl acetateFL/FR
 phenethyl alcoholFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl lactateFL/FR
 phenethyl propionateFL/FR
 phenyl acetaldehyde 2,3-butylene glycol acetalFL/FR
 phenyl propyl phenyl acetateFR
(E)-2-phenyl-1(2)-propene-1-yl acetateFR
 rhodinolFL/FR
 rose absolute (rosa damascena) bulgariaFL/FR
 rose butanoateFL/FR
 rose concrete (rosa damascena)FR
 tetrahydrolinaloolFL/FR
 tuberose absolute (from concrete)FL/FR
 tuberose absolute (from pommade)FL/FR
 violet methyl carbonateFR
 ylang ylang flower absoluteFL/FR
fruity
 allyl amyl glycolateFR
isobutyl anthranilateFL/FR
 cinnamyl hexanoateFL/FR
 cyclohexyl crotonateFR
(E)-alpha-damasconeFL/FR
(E)-beta-damasconeFL/FR
gamma-decalactoneFL/FR
 green acetateFR
 methyl anthranilateFL/FR
 osmanthus flower absoluteFL/FR
 raspberry ketoneFL/FR
 raspberry ketone acetateFL/FR
 raspberry ketone methyl etherFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
fungal
 jasmin nonaneFR
green
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
 hexoxyacetaldehyde dimethyl acetalFR
 hop oil CO2 extractFL/FR
 murraya koenigii leaf oil indiaFL/FR
 octyl oxyacetaldehydeFR
 phenyl acetaldehydeFL/FR
 violet leaf absoluteFL/FR
hay
 beeswax absoluteFL/FR
 hay absoluteFR
herbal
 anethum graveolens herb oilFL/FR
 anethum graveolens herb tinctureFL/FR
 carrot seed oil (daucus carota ssp. gummifer hook. fil.) spainFR
 carrot seed oil (daucus carota ssp. maximus (desf.) ball)FR
wild carrot seed oil terpenelessFL/FR
 celery ketoneFL/FR
 clary sage absoluteFL/FR
 clary sage oil franceFL/FR
 daucus carota fruit oilFL/FR
 dill weed oil cubaFL/FR
 dill weed oil reunionFL/FR
 elder flower absolute (sambucus canadensis and s. nigra)FR
 hop absoluteFL/FR
 hop oilFL/FR
 linalyl acetateFL/FR
curled parsley seed oilFL/FR
 perilla leaf oilFL/FR
 petroselinum crispum seed oil CO2 extractFL/FR
 thyme absoluteFL/FR
honey
 methyl phenyl acetateFL/FR
licorice
 ocimum basilicum herb oil vietnamFL/FR
 ocimum basilicum leaf oil terpenelessFL/FR
mossy
 veramoss (IFF)FR
musk
 musk gx 100%FR
 musk gx 50% in BBFR
 musk gx 50% in DEPFR
naphthyl
beta-naphthyl ethyl etherFL/FR
powdery
para-anisyl acetateFL/FR
spicy
 allspice oilFL/FR
 benzyl isoeugenolFL/FR
isobutyl angelateFL/FR
 caraway seed oleoresinFL/FR
 carrot weed oilFL/FR
 cassia bark oil chinaFL/FR
 cinnamaldehyde dimethyl acetalFL/FR
 clove bud oilFL/FR
 cumin seed absoluteFL/FR
 cuminaldehydeFL/FR
black currant bud absoluteFL/FR
isocyclogeraniol (IFF)FR
 eugenolFL/FR
isoeugenyl acetateFL/FR
(E)-para-methoxycinnamaldehydeFL/FR
alpha-methyl cinnamaldehydeFL/FR
 methyl isoeugenolFL/FR
2-octanolFL/FR
 turmeric root oil chinaFL/FR
annus wormwood oil vietnamFL/FR
sulfurous
 lychee mercaptan acetateFL/FR
sweet
 vanilla bean absolute (vanilla planifolia)FL/FR
terpenic
(E,E)-2,6-alloocimeneFL/FR
alpha-terpineolFL/FR
tonka
 coumarinFR
gamma-hexalactoneFL/FR
 tonka bean absoluteFR
vanilla
 ethyl vanillinFL/FR
 vanillyl acetateFL/FR
woody
 amber carbinolFR
 dalbergia sissoo leaf oilFR
 guaiacwood oilFL/FR
 gurjun balsam oilFR
 hinoki root oilFR
 patchouli ethanoneFR
 santallFR
 spruce needle oil canadaFL/FR
 tobacarol (IFF)FR
4,6,11-trimethyl-5-oxatricyclo(6.2.2.0*4,9*)dodec-6-eneFR
 woody acetateFR
 
For Flavor
 
No flavor group found for these
 celery ketoneFL/FR
 chocolate pyrazine AFL/FR
(E)-cinnamyl alcoholFL/FR
 cinnamyl hexanoateFL/FR
 guaiyl acetateFL/FR
(E)-para-methoxycinnamaldehydeFL/FR
 methyl (E)-cinnamateFL/FR
(E,E)-2,6-alloocimeneFL/FR
(R)-gamma-octalactoneFL/FR
2-octanolFL/FR
 osmanthus flower absoluteFL/FR
 perilla leaf oilFL/FR
 phenethyl lactateFL/FR
 phenyl acetaldehyde 2,3-butylene glycol acetalFL/FR
2-phenyl propyl alcoholFL/FR
 propyl pyruvateFL/FR
 rose absolute (rosa damascena) bulgariaFL/FR
 undecanal propylene glycol acetalFL/FR
 wine lactoneFL/FR
annus wormwood oil franceFL/FR
aldehydic
 nonanal (aldehyde C-9)FL/FR
anisic
 ocimum basilicum herb oil egyptFL/FR
aromatic
 benzyl isoeugenolFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
balsamic
siam benzoin resinoidFL/FR
 benzyl salicylateFL/FR
isobutyl cinnamateFL/FR
 ethyl cinnamateFL/FR
 myrrh oilFL/FR
berry
 heliotropyl acetoneFL/FR
 raspberry ketone acetateFL/FR
 raspberry ketone methyl etherFL/FR
brown
 beeswax absoluteFL/FR
caramellic
 cycloteneFL/FR
 ethyl maltolFL/FR
 maltolFL/FR
 strawberry furanoneFL/FR
cherry
 heliotropinFL/FR
citrus
 bergamot oilFL/FR
 bergamot oil bergaptene reduced italyFL/FR
 bergamot oil turkeyFL/FR
laevo-linaloolFL/FR
 linaloolFL/FR
 nerolFL/FR
alpha-terpineolFL/FR
coconut
gamma-nonalactone (aldehyde C-18 (so-called))FL/FR
creamy
para-anisaldehydeFL/FR
gamma-hexalactoneFL/FR
para-methyl acetophenoneFL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
fatty
 coconut absoluteFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
floral
isoamyl phenyl acetateFL/FR
 bois de rose oil brazilFL/FR
 citronellolFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
 geraniolFL/FR
 geranium oilFL/FR
 geranium oil bourbonFL/FR
 linalyl acetateFL/FR
 methyl dihydrojasmonateFL/FR
 methyl phenyl acetateFL/FR
 ocean propanalFL/FR
 phenethyl alcoholFL/FR
 rhodinolFL/FR
 tetrahydrolinaloolFL/FR
 tuberose absolute (from concrete)FL/FR
 tuberose absolute (from pommade)FL/FR
 ylang ylang flower absoluteFL/FR
fruity
para-anisyl acetateFL/FR
 benzyl acetateFL/FR
isobutyl anthranilateFL/FR
(E)-alpha-damasconeFL/FR
gamma-decalactoneFL/FR
 dimethyl anthranilateFL/FR
2-heptanolFL/FR
 methyl anthranilateFL/FR
 raspberry ketoneFL/FR
 rose butanoateFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
green
isoamyl salicylateFL/FR
 anethum graveolens herb tinctureFL/FR
isobutyl angelateFL/FR
 carrot weed oilFL/FR
 cinnamyl alcoholFL/FR
 clary sage absoluteFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
(E)-beta-damasconeFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
 linalool oxideFL/FR
 nerolidolFL/FR
 violet leaf absoluteFL/FR
herbal
 anethum graveolens herb oilFL/FR
wild carrot seed oil terpenelessFL/FR
 clary sage oil franceFL/FR
 coriander seed oilFL/FR
 daucus carota fruit oilFL/FR
 dill weed oil cubaFL/FR
 dill weed oil reunionFL/FR
 hop absoluteFL/FR
 hop oilFL/FR
 ocimum basilicum herb oilFL/FR
 ocimum basilicum leaf oil americaFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
 ocimum basilicum leaf oil indiaFL/FR
curled parsley seed oilFL/FR
 petroselinum crispum seed oil CO2 extractFL/FR
 thyme absoluteFL/FR
honey
 ethyl phenyl acetateFL/FR
 phenethyl acetateFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl propionateFL/FR
 phenyl acetaldehydeFL/FR
juicy
 lychee mercaptan acetateFL/FR
lactonic
gamma-heptalactoneFL/FR
licorice
 estragoleFL/FR
 ocimum basilicum herb oil vietnamFL/FR
 ocimum basilicum leaf oil terpenelessFL/FR
nutty
2-acetyl furanFL/FR
powdery
 acetophenoneFL/FR
beta-naphthyl ethyl etherFL/FR
spicy
 allspice oilFL/FR
 benzyl cinnamateFL/FR
 caraway seed oleoresinFL/FR
 cassia bark oil chinaFL/FR
 cinnamaldehyde dimethyl acetalFL/FR
 clove bud oilFL/FR
 cumin seed absoluteFL/FR
 cuminaldehydeFL/FR
black currant bud absoluteFL/FR
 eugenolFL/FR
isoeugenyl acetateFL/FR
 hop oil CO2 extractFL/FR
alpha-methyl cinnamaldehydeFL/FR
 methyl isoeugenolFL/FR
 murraya koenigii leaf oil indiaFL/FR
3-phenyl propyl alcoholFL/FR
 turmeric root oil chinaFL/FR
annus wormwood oil vietnamFL/FR
sweet
 vanilla bean absolute (vanilla planifolia)FL/FR
tropical
alpha-amyl cinnamaldehydeFL/FR
vanilla
 ethyl vanillinFL/FR
 vanillyl acetateFL/FR
waxy
alpha-hexyl cinnamaldehydeFL/FR
 hydroxycitronellalFL/FR
woody
 ambroxanFL/FR
 amyris wood oilFL/FR
 guaiacwood oilFL/FR
 spruce needle oil canadaFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 amberFR
 gardeniaFR
 hawthornFR
 hay new mown hay foin coupeFR
 heliotropeFR
 jasminFR
 lilac lilas syringaFR
 meadowsweet spiraeaFR
 muguet lily of the valleyFR
 spiceFR
 tonka beanFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 not found in nature
Synonyms   Articles   Notes   Search   Top
Synonyms:
1,3-benzodioxole, 5-(diethoxymethyl)
5-diethoxymethyl-1,3-benzodioxole
5-(diethoxymethyl)-1,3-benzodioxole
 heliotropin DEA
 heliotropin diethyl acetal
 heloitropin diethyl acetal
 piperonal diethyl acetal
 piperonal, diethyl acetal
 piperonyl diethyl acetal
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Articles:
 None found yet.
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