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BT
 

rose carboxylate
givescone (Givaudan)

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Flavor Demo Formulas
Fragrance Demo Formulas
Name: ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate
CAS Number: 57934-97-1Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 261-020-5
Nikkaji Web: J296.827D
XlogP3-AA: 3.40 (est)
Molecular Weight: 210.31674000
Formula: C13 H22 O2
NMR Predictor: Predict (works with chrome or firefox)
Name: ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate
CAS Number: 77851-07-1Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 278-776-7
Nikkaji Web: J319.692E
XlogP3-AA: 3.40 (est)
Molecular Weight: 210.31674000
Formula: C13 H22 O2
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
 
Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 98.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 0.94200 25.00 °C.
Refractive Index: 1.46200 @ 20.00 °C.
Boiling Point: 102.00 to 103.00 °C. @ 11.00 mm Hg
Vapor Pressure: 0.017000 mm/Hg @ 25.00 °C. (est)
Flash Point: 196.00 °F. TCC ( 91.11 °C. )
logP (o/w): 4.391 (est)
Soluble in:
 alcohol
 water, 34 mg/L @ 20 °C (exp)
Stability:
 alcoholic - good
 antiperspirant spray - moderate
 APC (pH = 10) - moderate
 candles - good
 damp fabric - good
 dry fabric - poor
 liquid bleach - poor
 pH = 2 - poor
 powder detergent - good
 powder detergent + activator - moderate
 soap - good
 toiletries - good
 
Organoleptic Properties:
Odor Type: floral
Odor Strength: medium
Substantivity: 20 hour(s) at 100.00 %
 rose warm spicy fruity berry woody
Odor Description:
at 100.00 %.
rose oxide warm spicy fruity berry damascone
Luebke, William tgsc, (1995)
Odor and/or flavor descriptions from others (if found).
Givaudan
Givescone®
Odor Description: Rosy, Spicy, Fruity, Woody
Givescone is used where real innovation is required. It has a complex odour picture, with floral, spicy, fruity, woody and even herbaceous nuances. It blends particularly well with rose, carnation, aldehydes, chypre and fougère, and with aromatic and spicy notes.
Pell Wall Perfumes
Givescone
Odor Description: Floral-rose, rose oxide, warm, spicy, fruity-berry, damascone-like
Arcadi Boix Camps says that Givescone is “a well known chemical that is difficult to describe. It has many nuances of the damascenes and damascenone, but is less sharp-metalic and has more of a sweet-apple note. It combines very well with undecavertol … and it forms part of important international bases, important functional fragrances (Ariel Future) and alcoholic fragrances (Jean Marc Sinan for ladies).”
 
Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
BOC Sciences
For experimental / research use only.
Givescone
CG Herbals
Givescone
Odor: Rosy, Spicy, Fruity, Woody
Use: Givescone is used where real innovation is required. It has a complex odour picture, with floral, spicy, fruity, woody and even herbaceous nuances. It blends particularly well with rose, carnation, aldehydes, chypre and fougere, and with aromatic and spicy notes.
Diffusions Aromatiques
GIVESCONE
Ernesto Ventós
GIVESCONE
Odor: SPICY, ROSY, FRUITY, WOODY
Givaudan
Givescone®
Odor: Rosy, Spicy, Fruity, Woody
Use: Givescone is used where real innovation is required. It has a complex odour picture, with floral, spicy, fruity, woody and even herbaceous nuances. It blends particularly well with rose, carnation, aldehydes, chypre and fougère, and with aromatic and spicy notes.
Indukern F&F
GIVESCONE
Odor: FRUITY, EARTHY, CAMPHORATED, FRESH
Pell Wall Perfumes
Givescone
Odor: Floral-rose, rose oxide, warm, spicy, fruity-berry, damascone-like
Use: Arcadi Boix Camps says that Givescone is “a well known chemical that is difficult to describe. It has many nuances of the damascenes and damascenone, but is less sharp-metalic and has more of a sweet-apple note. It combines very well with undecavertol and it forms part of important international bases, important functional fragrances (Ariel Future) and alcoholic fragrances (Jean Marc Sinan for ladies).”
Penta International
GIVESCONE
PerfumersWorld
Givescone
The Perfumers Apprentice
Givescone (G)
Odor: floral, spicy,fruity,woody and herbaceous nuances
Use: blends well with rose, carnation, aldehydes, chypre and fougere, and with aromatic and spicy notes.
Vigon International
Givescone
Odor: Rosy, Spicy, Fruity, Woody
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 5000 mg/kg
Arcadi Boix Camps says that Givescone is “a well known chemical that is difficult to describe. It has many nuances of the damascenes and damascenone, but is less sharp-metalic and has more of a sweet-apple note. It combines very well with undecavertol … and it forms part of important international bases, important functional fragrances (Ariel Future) and alcoholic fragrances (Jean Marc Sinan for ladies).”

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for rose carboxylate usage levels up to:
  10.0000 % in the fragrance concentrate.
 
Recommendation for rose carboxylate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 57934-97-1
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 93847
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate
Chemidplus: 0057934971
 ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate
Chemidplus: 077851071
 
References:
 ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 57934-97-1
Pubchem (cid): 93847
Pubchem (sid): 135050950
 ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 77851-07-1
Pubchem (cid): 166500
Pubchem (sid): 743888
 
Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
ChemSpider: View
 
Potential Blenders and core components note
For Odor
anisic
3-
pentyl bicyclo[3.2.1]-6-octen-2-one
FR
balsamic
fir balsam concrete
FR
fir carboxylate
FR
berry
blackberry specialty
FR
blueberry fragrance
FR
black
currant fragrance
FR
currant fragrance
FR
gooseberry fragrance
FR
huckleberry fragrance
FR
methyl beta-ionyl acetate
FR
black
raspberry fragrance
FR
coconut
tetrahydrojasmone
FR
fatty
hexyl pivalate
FR
floral
anise indene
FR
cyclohexyl phenyl acetate
FR
genet concrete
FR
geranium rose-scented oil cuba
FR
neryl phenyl acetate
FR
rosa alba flower oil CO2 extract
FR
rose concrete (rosa centifolia)
FR
rose concrete (rosa damascena)
FR
souroubea specialty
FR
fruity
berry hexanoate
FR
1,4-
diethyl-6,8-dioxabicyclo(3.2.1)octane
FR
etaspirene
FR
ethyl (R)-2-hydroxy-4-methyl pentanoate
FR
ethyl (S)-2-hydroxy-4-methyl pentanoate
FR
fruit specialty
FR
green acetate
FR
raspberry fragrance
FR
raspberry fruit oil
FR
iso
spirene
FR
xanthoxylum fruit oil
FR
green
thuja occidentalis leaf absolute
FR
violet decenol
FR
herbal
methyl cyclogeranate (Firmenich)
FR
nonisyl acetate
FR
spicy
carnation absolute
FR
2,5-
dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate + 1,4-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate
FR
waxy
waxy acetate
FR
woody
vetiver oil fractions
FR
woody acetate
FR
For Flavor
No flavor group found for these
allyl tiglate
FL
benzyl methyl tiglate
FL
(E)-2-
octen-4-ol
FL
hexyl 3-mercaptobutanoate
FL
caramellic
caramellic
5-
ethyl-3,4,5,6-tetramethyl cyclohexen-2-one
FL
fruity
ethyl 3-oxohexanoate
FL
furfuryl isovalerate
FL
 
Potential Uses:
 appleFR
 carnation dianthus oeilletFR
 fern fougereFR
 floralFR
 herbalFR
 honey mielFR
 roseFR
 rose tea roseFR
 spiceFR
 
Occurrence (nature, food, other): note
 not found in nature
 
Synonyms:
2-cyclohexene-1-carboxylic acid, 2-ethyl-6,6-dimethyl-, ethyl ester
 ethyl 2-ethyl-6-dimethyl-2-cyclohexene carboxylate
 ethyl 2-ethyl-6,6-dimethyl-2-cyclohexene carboxylate
 ethyl 2-ethyl-6,6-dimethyl-2-cyclohexene-carboxylate
 ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate
 ethyl 2,3,6,6-tetramethyl-2-cyclohexene carboxylate
 ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate
 ethyl ethyl dimethyl cyclohexene-1-carboxylate
2-ethyl-6,6-dimethyl-2-cyclohexene-1-carboxylic acid ethyl ester
 givescone (Givaudan)
 rose carboxylate
 
 
Notes:
Blends well with aldehydes and damascones. Damascone substitute.
 
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