rose carboxylate
givescone (Givaudan)
 
Notes:
Blends well with aldehydes and damascones. Damascone substitute.
  • Azelis
    • Azelis UK Life Sciences
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      GIVESCONE
       
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      Product(s):
      Givescone (Rose Carboxylate)
      Also called rose carboxylate, this excellent alternative to the heavily restricted rose ketones, the odour is described as rose oxide, warm, spicy, fruity berry and damascone-like. Recommended usage is up to 10% of the formula but it is effective even in traces.
       
       
  • Indukern F&F
  • Pell Wall Perfumes
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      Givescone
      Arcadi Boix Camps says that Givescone is “a well known chemical that is difficult to describe. It has many nuances of the damascenes and damascenone, but is less sharp-metalic and has more of a sweet-apple note. It combines very well with undecavertol and it forms part of important international bases, important functional fragrances (Ariel Future) and alcoholic fragrances (Jean Marc Sinan for ladies).”
       
       
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      4RF06840 Givescone
       
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  • Vigon International
    • Vigon International, Inc.
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      The growth and success of Vigon is due in large part to a unique corporate concept that Vigon has developed and established within the industry: Creative Partnerships. This partnership concept has been and continues to be the foundation and guiding principle for all of Vigon's activities.
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      500893 Givescone
       
Synonyms   Articles   Notes   Search
Fragrance Demo Formulas    Flavor Demo Formulas
ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate (Click)
CAS Number: 57934-97-1Picture of molecule
ECHA EINECS - REACH Pre-Reg: 261-020-5
Nikkaji Web: J296.827D
XlogP3-AA: 3.40 (est)
Molecular Weight: 210.31674000
Formula: C13 H22 O2
NMR Predictor: Predict (works with chrome or firefox)
ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate (Click)
CAS Number: 77851-07-1Picture of molecule
ECHA EINECS - REACH Pre-Reg: 278-776-7
Nikkaji Web: J319.692E
XlogP3-AA: 3.40 (est)
Molecular Weight: 210.31674000
Formula: C13 H22 O2
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
IBM Patents: Obtain
Pubchem Patents: Search
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Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 98.00 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 0.94200 @  25.00 °C.
Refractive Index: 1.46200 @  20.00 °C.
Boiling Point: 102.00 to  103.00 °C. @ 11.00 mm Hg
Vapor Pressure: 0.017000 mm/Hg @ 25.00 °C. (est)
Flash Point: 196.00 °F. TCC ( 91.11 °C. )
logP (o/w): 4.391 (est)
Soluble in:
 alcohol
 water, 34 mg/L @ 20 °C (exp)
Insoluble in:
 water
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
Odor Type: floral
Odor Strength: medium
 rose  warm  spicy  fruity  berry  woody  
Odor Description:
at 100.00 %. 
rose oxide warm spicy fruity berry damascone
Luebke, William tgsc, (1995)
Substantivity: 20 Hour(s)
  
Synonyms   Articles   Notes   Search   Top
Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
Synonyms   Articles   Notes   Search   Top
Suppliers:
Azelis
GIVESCONE
Services
CG Herbals
Givescone
Odor: Rosy, Spicy, Fruity, Woody
Use: Givescone is used where real innovation is required. It has a complex odour picture, with floral, spicy, fruity, woody and even herbaceous nuances. It blends particularly well with rose, carnation, aldehydes, chypre and fougere, and with aromatic and spicy notes.
Diffusions Aromatiques
GIVESCONE
Ernesto Ventós
GIVESCONE
Odor: SPICY, ROSY, FRUITY, WOODY
Givaudan
Givescone®
Odor: Rosy, Spicy, Fruity, Woody
Use: Givescone is used where real innovation is required. It has a complex odour picture, with floral, spicy, fruity, woody and even herbaceous nuances. It blends particularly well with rose, carnation, aldehydes, chypre and fougère, and with aromatic and spicy notes.
Hermitage Oils
Givescone (Rose Carboxylate)
Odor: characteristic
Use: Also called rose carboxylate, this excellent alternative to the heavily restricted rose ketones, the odour is described as rose oxide, warm, spicy, fruity berry and damascone-like. Recommended usage is up to 10% of the formula but it is effective even in traces.
The Vault
Indukern F&F
GIVESCONE
Odor: FRUITY, EARTHY, CAMPHORATED, FRESH
CROP CALENDAR
Pell Wall Perfumes
Givescone
Odor: Floral-rose, rose oxide, warm, spicy, fruity-berry, damascone-like
Use: Arcadi Boix Camps says that Givescone is “a well known chemical that is difficult to describe. It has many nuances of the damascenes and damascenone, but is less sharp-metalic and has more of a sweet-apple note. It combines very well with undecavertol and it forms part of important international bases, important functional fragrances (Ariel Future) and alcoholic fragrances (Jean Marc Sinan for ladies).”
Penta International
GIVESCONE
PerfumersWorld
Givescone
The Perfumers Apprentice
Givescone (G)
Odor: floral, spicy,fruity,woody and herbaceous nuances
Use: blends well with rose, carnation, aldehydes, chypre and fougere, and with aromatic and spicy notes.
Vigon International
Givescone
Odor: Rosy, Spicy, Fruity, Woody
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Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50  5000 mg/kg
Luebke, William tgsc, (1995)

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
Synonyms   Articles   Notes   Search   Top
Safety in Use Information:
Category: fragrance agents
Recommendation for rose carboxylate usage levels up to:
  10.0000 % in the fragrance concentrate.
 
Recommendation for rose carboxylate flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 57934-97-1
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 93847
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate
Chemidplus: 0057934971
 ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate
Chemidplus: 077851071
Synonyms   Articles   Notes   Search   Top
References:
 ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 57934-97-1
Pubchem (cid): 93847
Pubchem (sid): 135050950
 ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 77851-07-1
Pubchem (cid): 166500
Pubchem (sid): 743888
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
(E)-5-nonen-2-oneFL/FR
alliaceous
 methyl furfuryl disulfideFL/FR
amber
 ambrette seed absoluteFL/FR
animal
para-cresyl phenyl acetateFL/FR
balsamic
 ethyl cinnamateFL/FR
 fir carboxylateFR
 tolu balsam oilFL/FR
caramellic
5-ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-oneFL/FR
 maltyl isobutyrateFL/FR
cheesy
2-heptanoneFL/FR
ethereal
 propyl formateFL/FR
fatty
 hexyl pivalateFR
fermented
 valeraldehydeFL/FR
floral
 anise indeneFR
 benzyl formateFL/FR
 citronellyl isovalerateFL/FR
 citronellyl phenyl acetateFL/FR
 cyclohexyl phenyl acetateFR
alpha-damasconeFL/FR
(Z)-4-decen-1-yl acetateFL/FR
 ethyl hydrocinnamateFL/FR
 ethyl phenyl acetateFL/FR
 genet concreteFR
 geranium oil bourbonFL/FR
 geranium rose-scented oil cubaFR
 geranyl phenyl acetateFL/FR
2-hexylidene cyclopentanoneFL/FR
beta-iononeFL/FR
 linalyl phenyl acetateFL/FR
 nerolin fragarolFL/FR
 octyl isovalerateFL/FR
 petitgrain lemon oilFL/FR
 phenethyl acetateFL/FR
 phenethyl phenyl acetateFL/FR
 phenethyl pivalateFL/FR
 rhodinyl acetateFL/FR
 rhodinyl isobutyrateFL/FR
 rose absolute (rosa centifolia) moroccoFL/FR
 rose concrete (rosa damascena)FR
(Z)-rose oxideFL/FR
fruity
para-anisyl methyl ketoneFL/FR
3-benzyl-4-heptanoneFL/FR
 berry hexanoateFR
 butyl hexanoateFL/FR
beta-damasconeFL/FR
(Z)-beta-damasconeFL/FR
(E)-beta-damasconeFL/FR
 dihydroactinidolideFL/FR
 ethyl 2-hydroxy-3-methyl valerateFL/FR
 ethyl methyl-para-tolyl glycidateFL/FR
 green acetateFR
 heliotropyl isobutyrateFL/FR
beta-ionone epoxideFL/FR
 linalool oxide acetatesFL/FR
 methyl 2-methyl valerateFL/FR
3-nonen-2-oneFL/FR
 osmanthus flower absoluteFL/FR
isopropenyl acetateFL/FR
 styralyl butyrateFL/FR
 vanilla carboxylateFL/FR
(Z)-3-hexen-1-yl 2-methyl butyrateFL/FR
 octanal diethyl acetalFL/FR
 thiogeraniolFL/FR
 violet decenolFR
 lavender absolute bulgariaFL/FR
 methyl cyclogeranateFR
 nonisyl acetateFR
beta-sesquiphellandrene 
 rose oil (rosa centifolia) moroccoFL/FR
honey
 butyl phenyl acetateFL/FR
 phenethyl furoateFL/FR
mentholic
 menthyl acetate racemicFL/FR
soapy
 ambrettolideFL/FR
spicy
alpha-amyl cinnamyl alcoholFL/FR
 cadinadiene 
 cinnamyl propionateFL/FR
 clove bud oilFL/FR
(E)-propyl 2-furan acrylateFL/FR
sulfurous
 blackberry thiophenoneFL/FR
 buchu mercaptanFL/FR
waxy
(E)-2-octen-1-yl butyrateFL/FR
 waxy acetateFR
winey
 butyl angelateFL/FR
woody
 cedryl acetateFL/FR
 myrtenyl isobutyrate 
 patchouli oilFL/FR
 sandalwood oilFL/FR
 woody acetateFR
 
For Flavor
 
No flavor group found for these
 allyl tiglateFL
 benzyl methyl tiglateFL
 blackberry thiophenoneFL/FR
 butyl angelateFL/FR
 cadinadiene 
 cedryl acetateFL/FR
 citronellyl isovalerateFL/FR
 citronellyl phenyl acetateFL/FR
(Z)-beta-damasconeFL/FR
(Z)-4-decen-1-yl acetateFL/FR
 dihydroactinidolideFL/FR
 ethyl 2-hydroxy-3-methyl valerateFL/FR
 ethyl hydrocinnamateFL/FR
5-ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-oneFL/FR
 heliotropyl isobutyrateFL/FR
2-hexylidene cyclopentanoneFL/FR
beta-ionone epoxideFL/FR
 linalool oxide acetatesFL/FR
 linalyl phenyl acetateFL/FR
 menthyl acetate racemicFL/FR
 myrtenyl isobutyrate 
(E)-5-nonen-2-oneFL/FR
(E)-2-octen-1-yl butyrateFL/FR
(E)-2-octen-4-olFL
 octyl isovalerateFL/FR
 osmanthus flower absoluteFL/FR
beta-sesquiphellandrene 
 phenethyl furoateFL/FR
 phenethyl pivalateFL/FR
 rhodinyl acetateFL/FR
 rhodinyl isobutyrateFL/FR
 hexyl 3-mercaptobutanoateFL
aromatic
para-cresyl phenyl acetateFL/FR
balsamic
 ethyl cinnamateFL/FR
 tolu balsam oilFL/FR
caramellic
5-ethyl-3,4,5,6-tetramethyl cyclohexen-2-oneFL
 maltyl isobutyrateFL/FR
cheesy
2-heptanoneFL/FR
citrus
 petitgrain lemon oilFL/FR
coffee
 methyl furfuryl disulfideFL/FR
ethereal
isopropenyl acetateFL/FR
floral
 cinnamyl propionateFL/FR
 geranium oil bourbonFL/FR
 geranyl phenyl acetateFL/FR
 rose absolute (rosa centifolia) moroccoFL/FR
fruity
 benzyl formateFL/FR
3-benzyl-4-heptanoneFL/FR
 butyl hexanoateFL/FR
alpha-damasconeFL/FR
 ethyl 3-oxohexanoateFL
 ethyl methyl-para-tolyl glycidateFL/FR
 furfuryl isovalerateFL
 methyl 2-methyl valerateFL/FR
 nerolin fragarolFL/FR
(E)-propyl 2-furan acrylateFL/FR
 propyl formateFL/FR
 styralyl butyrateFL/FR
 vanilla carboxylateFL/FR
green
(E)-beta-damasconeFL/FR
beta-damasconeFL/FR
(Z)-3-hexen-1-yl 2-methyl butyrateFL/FR
 octanal diethyl acetalFL/FR
(Z)-rose oxideFL/FR
herbal
 lavender absolute bulgariaFL/FR
 rose oil (rosa centifolia) moroccoFL/FR
honey
 butyl phenyl acetateFL/FR
 ethyl phenyl acetateFL/FR
 phenethyl acetateFL/FR
 phenethyl phenyl acetateFL/FR
minty
 thiogeraniolFL/FR
oily
3-nonen-2-oneFL/FR
soapy
 ambrettolideFL/FR
spicy
alpha-amyl cinnamyl alcoholFL/FR
para-anisyl methyl ketoneFL/FR
 clove bud oilFL/FR
sulfurous
 buchu mercaptanFL/FR
winey
 valeraldehydeFL/FR
woody
 ambrette seed absoluteFL/FR
beta-iononeFL/FR
 patchouli oilFL/FR
 sandalwood oilFL/FR
 
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Potential Uses:
 appleFR
 carnation dianthus oeilletFR
 fern fougereFR
 floralFR
 herbalFR
 honey mielFR
 roseFR
 rose tea roseFR
 spiceFR
Synonyms   Articles   Notes   Search   Top
Natural Occurrence in: note
 not found in nature
Synonyms   Articles   Notes   Search   Top
Synonyms:
2-cyclohexene-1-carboxylic acid, 2-ethyl-6,6-dimethyl-, ethyl ester
 ethyl 2-ethyl-6-dimethyl-2-cyclohexene carboxylate
 ethyl 2-ethyl-6,6-dimethyl-2-cyclohexene carboxylate
 ethyl 2-ethyl-6,6-dimethyl-2-cyclohexene-carboxylate
 ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate
 ethyl 2,3,6,6-tetramethyl-2-cyclohexene carboxylate
 ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate
 ethyl ethyl dimethyl cyclohexene-1-carboxylate
2-ethyl-6,6-dimethyl-2-cyclohexene-1-carboxylic acid ethyl ester
 givescone (Givaudan)
 rose carboxylate
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