|
Category:fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 98.00 to 100.00 sum of isomers
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.94000 to 0.94500 @ 25.00 °C.
|
| Pounds per Gallon - (est).: | 7.822 to 7.863
|
| Refractive Index: | 1.46000 to 1.46400 @ 20.00 °C.
|
| Boiling Point: | 102.00 to 103.00 °C. @ 11.00 mm Hg
|
| Vapor Pressure: | 0.017000 mm/Hg @ 25.00 °C. (est) |
| Flash Point: | 196.00 °F. TCC ( 91.11 °C. )
|
| logP (o/w): | 4.391 (est) |
| Soluble in: |
| | alcohol | | | water, 34 mg/L @ 20 °C (exp) |
| Stability: |
| | alcoholic - good | | | antiperspirant spray - moderate | | | APC (pH = 10) - moderate | | | candles - good | | | damp fabric - good | | | dry fabric - poor | | | liquid bleach - poor | | | pH = 2 - poor | | | powder detergent - good | | | powder detergent + activator - moderate | | | soap - good | | | toiletries - good |
Organoleptic Properties:
| Odor Type: floral |
| Odor Strength:medium |
| Substantivity:20 hour(s) at 100.00 % |
| rose warm spicy fruity berry woody |
Odor Description:at 100.00 %. rose oxide warm spicy fruity berry damascone
Luebke, William tgsc, (1995) |
| Odor sample from: Givaudan Corporation |
| Odor and/or flavor descriptions from others (if found). |
| Givaudan |
| Givescone® |
Odor Description:Rosy, Spicy, Fruity, Woody
Givescone is used where real innovation is required. It has a complex odour picture, with floral, spicy, fruity, woody and even herbaceous nuances. It blends particularly well with rose, carnation, aldehydes, chypre and fougère, and with aromatic and spicy notes. |
| Pell Wall Perfumes |
| Givescone |
Odor Description:Floral-rose, rose oxide, warm, spicy, fruity-berry, damascone-like
Arcadi Boix Camps says that Givescone is “a well known chemical that is difficult to describe. It has many nuances of the damascenes and damascenone, but is less sharp-metalic and has more of a sweet-apple note. It combines very well with undecavertol … and it forms part of important international bases, important functional fragrances (Ariel Future) and alcoholic fragrances (Jean Marc Sinan for ladies).” |
| Moellhausen |
| GIVESCONE |
| Odor Description:Rosy, Spicy, Fruity, Woody |
Cosmetic Information:
Suppliers:
| BOC Sciences |
| For experimental / research use only. |
| Givescone
|
| Diffusions Aromatiques |
| GIVESCONE
|
| Ernesto Ventós |
| GIVESCONE
Odor: SPICY, ROSY, FRUITY, WOODY |
| Givaudan |
| Givescone®
Odor: Rosy, Spicy, Fruity, Woody Use: Givescone is used where real innovation is required. It has a complex odour picture, with floral, spicy, fruity, woody and even herbaceous nuances. It blends particularly well with rose, carnation, aldehydes, chypre and fougère, and with aromatic and spicy notes. |
| Indukern F&F |
| GIVESCONE
Odor: FRUITY, EARTHY, CAMPHORATED, FRESH |
| Moellhausen |
| GIVESCONE
|
| Pell Wall Perfumes |
| Givescone
Odor: Floral-rose, rose oxide, warm, spicy, fruity-berry, damascone-like Use: Arcadi Boix Camps says that Givescone is “a well known chemical that is difficult to describe. It has many nuances of the damascenes and damascenone, but is less sharp-metalic and has more of a sweet-apple note. It combines very well with undecavertol … and it forms part of important international bases, important functional fragrances (Ariel Future) and alcoholic fragrances (Jean Marc Sinan for ladies).” |
| Penta International |
| GIVESCONE
|
| PerfumersWorld |
| Givescone
|
| The Perfumers Apprentice |
| Givescone (G)
Odor: floral, spicy,fruity,woody and herbaceous nuances Use: blends well with rose, carnation, aldehydes, chypre and fougere, and with aromatic and spicy notes. |
| Vigon International |
| Givescone
Odor: Rosy, Spicy, Fruity, Woody |
Safety Information:
| European information : |
| Most important hazard(s): | | Xi - Irritant |
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 5000 mg/kg
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | fragrance agents |
| Recommendation for rose carboxylate usage levels up to: | | | 10.0000 % in the fragrance concentrate.
|
| |
| Recommendation for rose carboxylate flavor usage levels up to: |
| | not for flavor use.
|
Safety References:
References:
Other Information:
Potential Blenders and core components note
| For Odor |
| No odor group found for these |
(E)-5- nonen-2-one
FL/FR |
| alliaceous |
| alliaceous |
methyl furfuryl disulfide
FL/FR |
| amber |
ambrette seed absolute
FL/FR |
| animal |
para- cresyl phenyl acetate
FL/FR |
| anisic |
ethyl para-anisate
FL/FR |
3- pentyl bicyclo[3.2.1]-6-octen-2-one
FR |
| balsamic |
butyl cinnamate
FL/FR |
ethyl cinnamate
FL/FR |
fir balsam concrete
FR |
fir carboxylate
FR |
pine needle absolute
FL/FR |
tolu balsam oil
FL/FR |
| berry |
blackberry infusions
FL/FR |
blackberry specialty
FR |
blueberry fragrance
FR |
blueberry infusions
FL/FR |
black currant fragrance
FR |
currant fragrance
FR |
black currant infusions
FL/FR |
gooseberry fragrance
FR |
huckleberry fragrance
FR |
methyl beta-ionyl acetate
FR |
raspberry essence
FL/FR |
black raspberry fragrance
FR |
raspberry infusions
FL/FR |
rubus fruticosus fruit extract
FL/FR |
| camphoreous |
3- benzylidene-2-butanone
FL/FR |
beta-homo cyclocitral
FL/FR |
| caramellic |
5- ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-one
FL/FR |
maltyl isobutyrate
FL/FR |
| cheesy |
2- heptanone
FL/FR |
| coconut |
tetrahydrojasmone
FR |
| earthy |
pinus sylvestris leaf absolute
FL/FR |
| ethereal |
propyl formate
FL/FR |
| fatty |
hexyl pivalate
FR |
| fermented |
valeraldehyde
FL/FR |
| floral |
anise indene
FR |
benzyl formate
FL/FR |
benzyl phenyl acetate
FL/FR |
cardamom absolute
FL/FR |
citronellyl isovalerate
FL/FR |
citronellyl phenyl acetate
FL/FR |
cyclohexyl phenyl acetate
FR |
alpha- damascone
FL/FR |
(Z)-4- decen-1-yl acetate
FL/FR |
dihydro-alpha-ionone
FL/FR |
ethyl hydrocinnamate
FL/FR |
ethyl phenyl acetate
FL/FR |
genet concrete
FR |
geranium oil bourbon
FL/FR |
geranium rose-scented oil cuba
FR |
geranyl phenyl acetate
FL/FR |
geranyl propionate
FL/FR |
2- hexylidene cyclopentanone
FL/FR |
beta- ionone
FL/FR |
beta- irone
FL/FR |
linalyl phenyl acetate
FL/FR |
nerolin fragarol
FL/FR |
neryl phenyl acetate
FR |
octyl isovalerate
FL/FR |
petitgrain lemon oil
FL/FR |
phenethyl acetate
FL/FR |
phenethyl phenyl acetate
FL/FR |
phenethyl pivalate
FL/FR |
rhodinyl acetate
FL/FR |
rhodinyl isobutyrate
FL/FR |
rosa alba flower oil CO2 extract
FR |
rose absolute (rosa centifolia) morocco
FL/FR |
rose concrete (rosa centifolia)
FR |
rose concrete (rosa damascena)
FR |
(Z)- rose oxide
FL/FR |
souroubea specialty
FR |
ylang ylang flower oil III
FL/FR |
| fruity |
para- anisyl methyl ketone
FL/FR |
3- benzyl-4-heptanone
FL/FR |
berry hexanoate
FR |
berry pentadienoate
FL/FR |
blueberry essence
FL/FR |
boysenberry essence
FL/FR |
butyl hexanoate
FL/FR |
red currant essence
FL/FR |
black currant essence
FL/FR |
cyclohexyl isovalerate
FL/FR |
(E)-beta- damascenone
FL/FR |
(Z)-beta- damascone
FL/FR |
(E)-beta- damascone
FL/FR |
beta- damascone
FL/FR |
1,4- diethyl-6,8-dioxabicyclo(3.2.1)octane
FR |
dihydroactinidolide
FL/FR |
etaspirene
FR |
ethyl (R)-2-hydroxy-4-methyl pentanoate
FR |
ethyl (S)-2-hydroxy-4-methyl pentanoate
FR |
ethyl 2-hydroxy-3-methyl valerate
FL/FR |
ethyl methyl-para-tolyl glycidate
FL/FR |
filbert hexenone
FL/FR |
fruit specialty
FR |
green acetate
FR |
heliotropyl isobutyrate
FL/FR |
beta- ionone epoxide
FL/FR |
linalool oxide acetates
FL/FR |
maltyl butyrate
FL/FR |
methyl 2-methyl valerate
FL/FR |
2- methyl butyl 2-methyl butyrate
FL/FR |
3- nonen-2-one
FL/FR |
osmanthus flower absolute
FL/FR |
iso propenyl acetate
FL/FR |
black raspberry essence
FL/FR |
red raspberry essence
FL/FR |
raspberry fragrance
FR |
raspberry fruit oil
FR |
ribes nigrum fruit extract
FL/FR |
ribes rubrum fruit extract
FL/FR |
iso spirene
FR |
strawberry furanone butyrate
FL/FR |
strawberry glycidate 2
FL/FR |
strawberry infusions
FL/FR |
styralyl butyrate
FL/FR |
vanilla carboxylate
FL/FR |
xanthoxylum fruit oil
FR |
| green |
(Z)-3- hexen-1-yl 2-methyl butyrate
FL/FR |
(Z)-3- hexen-1-yl phenyl acetate
FL/FR |
octanal diethyl acetal
FL/FR |
phenoxyethyl isobutyrate
FL/FR |
thiogeraniol
FL/FR |
thuja occidentalis leaf absolute
FR |
violet decenol
FR |
| herbal |
barosma betulina leaf oil
FL/FR |
(S)- campholene acetate
FL/FR |
dimethyl benzyl carbinyl crotonate
FL/FR |
lavender absolute bulgaria
FL/FR |
methyl cyclogeranate (Firmenich)
FR |
T- muurolol
FL/FR |
myrtle oil
FL/FR |
myrtle oil morocco
FL/FR |
nonisyl acetate
FR |
rose oil (rosa centifolia) morocco
FL/FR |
| honey |
butyl phenyl acetate
FL/FR |
methyl phenyl acetate
FL/FR |
phenethyl furoate
FL/FR |
| mentholic |
menthyl acetate racemic
FL/FR |
| powdery |
dibenzyl ketone
FL/FR |
| soapy |
ambrettolide
FL/FR |
| spicy |
alpha- amyl cinnamyl alcohol
FL/FR |
carnation absolute
FR |
cinnamyl propionate
FL/FR |
clove bud oil
FL/FR |
black currant bud absolute
FL/FR |
2,5- dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate + 1,4-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate
FR |
eugenyl isovalerate
FL/FR |
eugenyl phenyl acetate
FL/FR |
iso eugenyl phenyl acetate
FL/FR |
(E)- propyl 2-furan acrylate
FL/FR |
| sulfurous |
blackberry thiophenone
FL/FR |
buchu mercaptan
FL/FR |
mango thiol
FL/FR |
| waxy |
dihydrocitronellyl acetate
FL/FR |
(E)-2- octen-1-yl butyrate
FL/FR |
orris rhizome oil CO2 extract
FL/FR |
waxy acetate
FR |
| winey |
butyl angelate
FL/FR |
| woody |
beta- caryophyllene alcohol acetate
FL/FR |
cedryl acetate
FL/FR |
kaempferia galanga rhizome oil
FL/FR |
patchouli oil
FL/FR |
sandalwood oil
FL/FR |
spicy pentanone
FL/FR |
vetiver oil fractions
FR |
woody acetate
FR |
| For Flavor |
| No flavor group found for these |
allyl tiglate
FL |
benzyl methyl tiglate
FL |
3- benzylidene-2-butanone
FL/FR |
blackberry thiophenone
FL/FR |
butyl angelate
FL/FR |
butyl cinnamate
FL/FR |
beta- caryophyllene alcohol acetate
FL/FR |
citronellyl isovalerate
FL/FR |
(E)-beta- damascenone
FL/FR |
(Z)-4- decen-1-yl acetate
FL/FR |
dihydroactinidolide
FL/FR |
dihydrocitronellyl acetate
FL/FR |
dimethyl benzyl carbinyl crotonate
FL/FR |
ethyl 2-hydroxy-3-methyl valerate
FL/FR |
ethyl hydrocinnamate
FL/FR |
5- ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-one
FL/FR |
eugenyl isovalerate
FL/FR |
eugenyl phenyl acetate
FL/FR |
2- hexylidene cyclopentanone
FL/FR |
beta- ionone epoxide
FL/FR |
linalool oxide acetates
FL/FR |
linalyl phenyl acetate
FL/FR |
menthyl acetate racemic
FL/FR |
T- muurolol
FL/FR |
myrtle oil morocco
FL/FR |
(E)-5- nonen-2-one
FL/FR |
(E)-2- octen-1-yl butyrate
FL/FR |
(E)-2- octen-4-ol
FL |
octyl isovalerate
FL/FR |
phenethyl furoate
FL/FR |
phenethyl pivalate
FL/FR |
pine needle absolute
FL/FR |
pinus sylvestris leaf absolute
FL/FR |
|
beta- damascone
FL/FR |
hexyl 3-mercaptobutanoate
FL |
| anise |
| anise |
ethyl para-anisate
FL/FR |
| balsamic |
ethyl cinnamate
FL/FR |
tolu balsam oil
FL/FR |
| berry |
blackberry infusions
FL/FR |
blueberry essence
FL/FR |
blueberry infusions
FL/FR |
black currant infusions
FL/FR |
dihydro-alpha-ionone
FL/FR |
maltyl butyrate
FL/FR |
raspberry essence
FL/FR |
raspberry infusions
FL/FR |
rubus fruticosus fruit extract
FL/FR |
| bitter |
dibenzyl ketone
FL/FR |
| camphoreous |
kaempferia galanga rhizome oil
FL/FR |
| caramellic |
5- ethyl-3,4,5,6-tetramethyl cyclohexen-2-one
FL |
| cheesy |
2- heptanone
FL/FR |
| citrus |
petitgrain lemon oil
FL/FR |
| coffee |
methyl furfuryl disulfide
FL/FR |
| cooling |
beta-homo cyclocitral
FL/FR |
| ethereal |
iso propenyl acetate
FL/FR |
| floral |
cardamom absolute
FL/FR |
cinnamyl propionate
FL/FR |
citronellyl phenyl acetate
FL/FR |
geranium oil bourbon
FL/FR |
geranyl phenyl acetate
FL/FR |
beta- irone
FL/FR |
methyl phenyl acetate
FL/FR |
rhodinyl acetate
FL/FR |
rhodinyl isobutyrate
FL/FR |
rose absolute (rosa centifolia) morocco
FL/FR |
ylang ylang flower oil III
FL/FR |
| fruity |
benzyl formate
FL/FR |
3- benzyl-4-heptanone
FL/FR |
berry pentadienoate
FL/FR |
boysenberry essence
FL/FR |
butyl hexanoate
FL/FR |
black currant essence
FL/FR |
red currant essence
FL/FR |
cyclohexyl isovalerate
FL/FR |
alpha- damascone
FL/FR |
(E)-beta- damascone
FL/FR |
(Z)-beta- damascone
FL/FR |
ethyl 3-oxohexanoate
FL |
ethyl methyl-para-tolyl glycidate
FL/FR |
filbert hexenone
FL/FR |
furfuryl isovalerate
FL |
heliotropyl isobutyrate
FL/FR |
methyl 2-methyl valerate
FL/FR |
2- methyl butyl 2-methyl butyrate
FL/FR |
nerolin fragarol
FL/FR |
osmanthus flower absolute
FL/FR |
(E)- propyl 2-furan acrylate
FL/FR |
propyl formate
FL/FR |
red raspberry essence
FL/FR |
black raspberry essence
FL/FR |
ribes nigrum fruit extract
FL/FR |
ribes rubrum fruit extract
FL/FR |
spicy pentanone
FL/FR |
strawberry furanone butyrate
FL/FR |
strawberry glycidate 2
FL/FR |
strawberry infusions
FL/FR |
styralyl butyrate
FL/FR |
vanilla carboxylate
FL/FR |
| green |
(Z)-3- hexen-1-yl 2-methyl butyrate
FL/FR |
(Z)-3- hexen-1-yl phenyl acetate
FL/FR |
octanal diethyl acetal
FL/FR |
phenoxyethyl isobutyrate
FL/FR |
(Z)- rose oxide
FL/FR |
| herbal |
barosma betulina leaf oil
FL/FR |
lavender absolute bulgaria
FL/FR |
rose oil (rosa centifolia) morocco
FL/FR |
| honey |
benzyl phenyl acetate
FL/FR |
butyl phenyl acetate
FL/FR |
ethyl phenyl acetate
FL/FR |
phenethyl acetate
FL/FR |
phenethyl phenyl acetate
FL/FR |
| jammy |
(S)- campholene acetate
FL/FR |
maltyl isobutyrate
FL/FR |
| minty |
thiogeraniol
FL/FR |
| oily |
3- nonen-2-one
FL/FR |
| phenolic |
para- cresyl phenyl acetate
FL/FR |
| soapy |
ambrettolide
FL/FR |
| spicy |
alpha- amyl cinnamyl alcohol
FL/FR |
para- anisyl methyl ketone
FL/FR |
clove bud oil
FL/FR |
black currant bud absolute
FL/FR |
iso eugenyl phenyl acetate
FL/FR |
myrtle oil
FL/FR |
| sulfurous |
buchu mercaptan
FL/FR |
mango thiol
FL/FR |
| waxy |
geranyl propionate
FL/FR |
| winey |
valeraldehyde
FL/FR |
| woody |
ambrette seed absolute
FL/FR |
cedryl acetate
FL/FR |
beta- ionone
FL/FR |
orris rhizome oil CO2 extract
FL/FR |
patchouli oil
FL/FR |
sandalwood oil
FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| 2- | cyclohexene-1-carboxylic acid, 2-ethyl-6,6-dimethyl-, ethyl ester | | | ethyl 2-ethyl-6-dimethyl-2-cyclohexene carboxylate | | | ethyl 2-ethyl-6,6-dimethyl-2-cyclohexene carboxylate | | | ethyl 2-ethyl-6,6-dimethyl-2-cyclohexene-carboxylate | | | ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate | | | ethyl 2,3,6,6-tetramethyl-2-cyclohexene carboxylate | | | ethyl 2,3,6,6-tetramethylcyclohex-2-ene-1-carboxylate | | | ethyl ethyl dimethyl cyclohexene-1-carboxylate | | 2- | ethyl-6,6-dimethyl-2-cyclohexene-1-carboxylic acid ethyl ester | | | givescone (Givaudan) | | | rose carboxylate |
Articles:
| US Patents:4,609,491 - Tri- and tetra-substituted cyclohexen-1-methyl acetates as odorants |
| US Patents:4,570,648 - Flavorants containing esters of 2,3,6,6-tetramethylcyclohexenyl carboxylic acids |
| US Patents:4,570,648 - Flavorants containing esters of 2,3,6,6-tetramethylcyclohexenyl carboxylic acids |
|
3D/inchi
3D/inchi