geranic oxide
Suppliers  organoleptics  properties  safety  references  cosmetics    FEMA Index    Home Page
Notes :
Blends well with wild notes.
 
Right Click Jmol Molecule For More Options. (Safari 1.2 (v125) Compatible). Jmol is a free download found Here.
 
IUPAC name :2-ethenyl-2,6,6-trimethyloxane
InChI :InChI=1/C10H18O/c1-5-10(4)8-6-7-9(2,3)11-10/h5H,1,6-8H2,2-4H3
InChIKey :NETOHYFTCONTDT-UHFFFAOYAS
SMILES :CC1(CCCC(O1)(C)C=C)C
cas number :7392-19-0
(EINECS) number :230-983-3
fema number :3735
coe number :10976
jecfa number :1236
fl. number :13.094
molar refractivity :49.37 ± 0.3 cm3
parachor :406.3 ± 4.0 cm3
index of refraction :1.475 ± 0.02
surface tension :28.9 ± 3.0 dyne/cm
density :0.880 ± 0.06 g/cm3
polarizability :19.57 ± 0.5 10-24cm3
XlogP : 2.60
XlogP3-AA : 2.40
molecular weight : 154.2493200 (IUPAC)
formula :C10 H18 O
NMR Predictor :Predict
 
 
IUPAC name :(2S)-2-ethenyl-2,6,6-trimethyltetrahydro-2H-pyran
InChI :InChI=1/C10H18O/c1-5-10(4)8-6-7-9(2,3)11-10/h5H,1,6-8H2,2-4H3
InChIKey :NETOHYFTCONTDT-UHFFFAOYAS
SMILES :O(C(C=C)(CCC1)C)C1(C)C
cas number :13837-56-4
(EINECS) number :237-550-8
molar refractivity :49.37 ± 0.3 cm3
parachor :406.3 ± 4.0 cm3
index of refraction :1.475 ± 0.02
surface tension :28.9 ± 3.0 dyne/cm
density :0.880 ± 0.06 g/cm3
polarizability :19.57 ± 0.5 10-24cm3
XlogP : 2.60
XlogP3-AA : 2.40
molecular weight : 154.2493200 (IUPAC)
formula :C10 H18 O
NMR Predictor :Predict
 
 
export tariff code :2932.99.6560
fda reg :unspecified
Suppliers :
Givaudan :Limetol
Odor:  Fresh, Camphoraceous, Woody, Cineole-Lime
Limetol is used where a lemon-woody note is desired. It also offers pine needle and lime nuances.
Penta :2,6,6-trimethyl-6-vinyltetrahydropyran
Penta :bois de rose oxide
Vigon :Limetol
organoleptics :
odor type :herbal
odor strength :medium ,
recommend smelling in a 10.00 % solution or less
odor description:
at 10.00 % in dipropylene glycol.  		fresh camphor herbal rosemary
Luebke, William tgsc, (1985)
odor sample from :Roure Bertrand Dupont Inc.
odor description:
Sweet, floral, citrus with woody, cooling, minty and camphoreous nuances
Mosciano, Gerard P&F 18, No. 3, 53, (1993)
taste description:
at 20.00 ppm.  		Sweet, camphoreous, woody, cooling, with floral nuances
Mosciano, Gerard P&F 18, No. 3, 53, (1993)
substantivity :4  Hour(s)
properties :
appearence :colorless clear liquid
assay : 95.00 to 100.00 %   sum of isomers
Food Chemicals Codex Listed :No
specific gravity :0.86400 to 0.87300 @ 25.00 °C.
pounds per gallon - calc. : 7.189 to 7.264
refractive index :1.44200 to 1.45000 @ 20.00 °C.
boiling point : 170.00 to 171.00 °C. @ 760.00 mm Hg
vapor pressure :2.01000 mm/Hg @ 25.00 °C.
flash point : 136.00  °F.  TCC  ( 57.78 °C. )
logP (o/w) : 3.13
safety :
most important hazard(s) :Xi - Irritant
  R 10 - Flammable.
R 38 - Irritating to skin.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Oral Toxicity(LD50) : 
  Oral-Rat   [sex: M,F]  2700.00-2800.00  mg/kg
(Sauer-Freeman, 1980)

Oral-Mouse   [sex: M,F]  4000.00-8000.00  mg/kg
(Roure Bertrand Dupont, 1979)

Dermal Toxicity(LD50) : 
  Not determined
Inhalation Toxicity(LC50) : 
  Not determined
 
safety in use :
Category :flavor and fragrance agents
Maximised Survey-derived Daily Intakes (MSDI-EU) :0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA) :8.00 (μg/capita/day)
 
recommendation for geranic oxide fragrance usage levels up to :
  3.0000 % in the fragrance concentrate.
recommendation for geranic oxide flavor usage levels up to :
  20.0000 ppm in the flavor.
safety references :
European Food Safety Athority(efsa) :Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
EPI System :view
Canada Domestic Sub. List :Yes
EPA Chem. Sub. Inventory : Yes
WISER :UN 1993
 
WGK Germany :2
 
 
 
 
2-ethenyl-2,6,6-trimethyloxane
(EINECS) number :230-983-3
chemidplus :007392190
EPA Substance Registry Services :7392-19-0
 
 
 
(2S)-2-ethenyl-2,6,6-trimethyltetrahydro-2H-pyran
(EINECS) number :237-550-8
chemidplus :007392190
EPA Substance Registry Services :13837-56-4
references :
 
2-ethenyl-2,6,6-trimethyloxane
fl. number :13.094
jecfa number :1236
NIST Chemistry WebBook :1996629542
pubchem :10534342
 
(2S)-2-ethenyl-2,6,6-trimethyltetrahydro-2H-pyran
pubchem :13837-56-4
Cosmetics :
Cosmetic uses : perfuming agents
other :
CosIng :cosmetic data
VCF-Online: VCF Volatile Compounds in Food
RIFM :listed
FMA :listed
FDA Everything Added to Food in the United States (EAFUS)View
synonyms :
 bois de rose oxide
2-ethenyl tetrahydro-2,6,6-trimethyl-2H-pyran
2-ethenyl-2,6,6-trimethyloxane
 geranic oxide
 limetol
 tetrahydro-2,2,6-trimethyl-6-vinyl-2H-pyran
(±)-tetrahydro-2,6,6-trimethyl-2-vinyl-2H-pyran
 trimethoxy-2-vinyl tetrahydropyran
2,6,6-trimethyl-2-vinyl tetrahydropyran
2,2,6-trimethyl-6-ethenyl tetrahydropyran
2,2,6-trimethyl-6-vinyl tetrahydro-2H-pyran
2,2,6-trimethyl-6-vinyl tetrahydropyran
soluble in :
 alcohol
insoluble in :
 water
stability :
 detergent
 soap
potential blenders :    note
6-acetoxydihydrotheaspiraneFL/FR
isoamyl salicylateFL/FR
 anise indeneFR
3-benzyl-4-heptanoneFL/FR
3-benzylidene-2-butanoneFL/FR
 bigarade oxideFR
isoborneolFL/FR
isobornyl acetateFL/FR
 bornyl butyrateFL/FR
 bornyl isobutyrateFL/FR
beta-bourboneneFL/FR
 butyrophenoneFL/FR
delta-cadinene 
gamma-cadinene 
alpha-cadinol 
 calamus rhizome oilFR
 campheneFL/FR
(+)-campheneFL/FR
 camphenilone 
(±)-camphorFL/FR
dextro-camphorFL/FR
 camphor oilFL/FR
 cinnamon acroleinFL/FR
 cistus oilFL/FR
(S)-(-)-citronellalFL/FR
 coriander leaf oilFL/FR
 coriander oleoresinFL
 currant bud absolute blackFL/FR
beta-homocyclocitralFL/FR
isocyclocitralFL/FR
 decanal dimethyl acetalFL/FR
isodihydrolavandulolCS
isodihydrolavandulyl acetateCS
 epoxyoxophoroneFL
 farneseneFL/FR
 fenchoneFL/FR
dextro-fenchoneFL/FR
laevo-fenchoneFL/FR
 fenchyl alcoholFL/FR
 galangal root oilFL/FR
 geranic oxideFL/FR
 herbal cyclohexaneFR
 herbal ethanoneFR
 herbal undecanolFR
 herbal undecanoneFR
 hinoki leaf oilFR
6-hydroxydihydrotheaspirane (mixture of isomers)FL/FR
 hyssop oilFL/FR
 immortelle flower oilFR
 ivy carbaldehydeFL/FR
2,4-ivy carbaldehydeFL/FR
3,5-ivy carbaldehydeFL/FR
3,6-ivy carbaldehydeFL/FR
 jambu oleoresinFL
(Z)-jasmoneFL/FR
 karo karounde absoluteFR
 laurel bark oil 
 laurel leaf absoluteFL/FR
 laurel leaf oilFL/FR
 laurel stem oil 
 lavender flower oil lithuaniaFL/FR
 lavender oil franceFL/FR
 lavender oil spike franceFL/FR
 marine formateFR
 menthadienyl formateFR
laevo-menthyl acetateFL/FR
3-methyl cyclohexanoneFL
 methyl hexyl ketoneFL/FR
para-methyl hydratropaldehydeFL/FR
1-methyl pyrroleFL
2-methyl-3-butanoneFL
gamma-muurolene 
 nonisyl propionateFR
 parsley leaf oilFL/FR
 patchouli indeneFR
 pennyroyal oilFL/FR
 petitgrain bigarade oilFL/FR
 petitgrain heptaneFR
alpha-pineneFL/FR
 piperitenone oxideFL
 piperitoneFL/FR
 polylimoneneFL/FR
 prenyl salicylateFL/FR
4-isopropyl-2-cyclohexenoneFL/FR
 rosemary absoluteFL/FR
 rosemary oil egyptFL/FR
 saffron pyranoneFR
 spruce oilFL/FR
 sugandha kokila berry oil 
 tansy leaf oil dutch 
 tea leaf absoluteFL/FR
 tetrahydromyrcenyl acetateFR
 thyme oil wild or creepingFL/FR
 tricyclodecenyl propionateFR
 verbenoneFL/FR
 woody ketoneFL/FR
 yarrow oilFL/FR
potential uses :
 berry
 blueberry
 bois de rose rosewood
 camphor
 champagne
 cola
 fir needle
 floral
 geranium
 herbal
 lavender
 marjoram
 mint
 oregano
 rosemary
 tea
 woody
natural occurrence in :    note
 geranium bourbon  
data pagelime oil distilled mexico @ 0.22% S

information only - not sold by The Good Scents Company.


Please share your Information / Comments.

Your email Address:


Top of Page          The Good Scents Company Home
Copyright © 1980-2010 The Good Scents Company Disclaimer Privacy Policy
Html Last modified 02/21/2010