EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

benzyl methyl tiglate
benzyl 2,3-dimethylcrotonate

Sponsors

Name:benzyl 2,3-dimethylbut-2-enoate
CAS Number: 7492-69-5Picture of molecule3D/inchi
FDA UNII:Q2Z1O33EAA
Nikkaji Web:J1.536.419J
CoE Number:11868
XlogP3-AA:3.40 (est)
Molecular Weight:204.26892000
Formula:C13 H16 O2
NMR Predictor:Predict (works with chrome or firefox)
Category:flavoring agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:847 benzyl 2,3-dimethylcrotonate
FLAVIS Number:09.508 (Old)
DG SANTE Food Flavourings:09.508 benzyl 2,3-dimethylcrotonate
FEMA Number:2143 benzyl 2,3-dimethylcrotonate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: BENZYL 2,3-DIMETHYLCROTONATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
 
Physical Properties:
Appearance:colorless to pale yellow clear oily liquid (est)
Assay: 97.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.01700 to 1.02300 @ 25.00 °C.
Pounds per Gallon - (est).: 8.462 to 8.512
Refractive Index:1.51000 to 1.51700 @ 20.00 °C.
Boiling Point: 259.00 °C. @ 760.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.002000 mm/Hg @ 25.00 °C. (est)
Flash Point: 296.00 °F. TCC ( 146.67 °C. )
logP (o/w): 3.454 (est)
Soluble in:
 alcohol
 water, 17.87 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items:note
allyl tiglate
amyl tiglate
isoamyl tiglate
benzyl tiglate
butyl tiglate
isobutyl tiglate
cinnamyl tiglate
(E)-citronellyl tiglate
(E)-ethyl tiglate
geranyl methyl tiglate
geranyl tiglate
(Z)-3-hexen-1-yl tiglate
hexyl tiglate
methyl tiglate
3-octyl tiglate
phenethyl tiglate
propyl tiglate
isopropyl tiglate
 
Organoleptic Properties:
Odor Type: herbal
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
warm herbal fruity spicy
Odor Description:at 10.00 % in dipropylene glycol. warm herbal fruity spicy
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
Parchem
Benzyl Methyl Tiglate
Chemical Sources Association
Need This Item for Flavor/Food?: You can contact the Chemical Sources Association
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavoring agents
Recommendation for benzyl methyl tiglate usage levels up to:
 not for fragrance use.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 1.00 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
 average usual ppmaverage maximum ppm
baked goods: -1.50000
beverages(nonalcoholic): -0.75000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -2.80000
fruit ices: -2.80000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -1.80000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) on a request from the Commission related to Flavouring Group Evaluation 20 (FGE.20): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical group 23
View page or View pdf

Flavouring Group Evaluation 54 (FGE.54)[1] - Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20 (2005) - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf

Flavouring Group Evaluation 20, Revision 1 (FGE.20Rev1): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters from chemical group 23
View page or View pdf

Flavouring Group Evaluation 54, Revision 1 (FGE.54Rev1): Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20Rev1 (2009)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

EPI System: View
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :61402
National Institute of Allergy and Infectious Diseases:Data
benzyl 2,3-dimethylbut-2-enoate
Chemidplus:0007492695
 
References:
 benzyl 2,3-dimethylbut-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:7492-69-5
Pubchem (cid):61402
Pubchem (sid):135018884
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
HMDB (The Human Metabolome Database):HMDB36224
FooDB:FDB015082
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
para-
menth-1-en-9-al
FL/FR
aldehydic
aldehydic
agrumen nitrile
FR
anisic
amyl furoate
FL/FR
ethyl para-anisate
FL/FR
balsamic
iso
amyl benzoate
FL/FR
butyl cinnamate
FL/FR
(E)-
cinnamyl alcohol
FL/FR
cinnamyl alcohol
FL/FR
ethyl cinnamate
FL/FR
guaiyl acetate
FL/FR
tolu balsam oil
FL/FR
tolu balsam oil
FL/FR
caramellic
diethyl malate
FL/FR
5-
ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-one
FL/FR
cheesy
2-
heptanone
FL/FR
citrus
2-
heptanol
FL/FR
earthy
3-
octen-2-one
FL/FR
pinus sylvestris leaf absolute
FL/FR
ethereal
ethyl 4-pentenoate
FL/FR
2-
methyl valeraldehyde
FL/FR
fatty
methyl (E)-2-hexenoate
FL/FR
floral
iso
amyl angelate
FL/FR
alpha-
amyl cinnamaldehyde
FL/FR
benzyl acetone
FL/FR
benzyl formate
FL/FR
boronia absolute
FL/FR
butyl tiglate
FR
cassis cyclohexene
FR
coriander seed oil
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
geranyl tiglate
FL/FR
2-
hexylidene cyclopentanone
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
menthadienyl formate
FR
methyl benzyl acetate (mixed ortho-,meta-,para-)
FL/FR
nonan-3-yl acetate
FL/FR
3-
nonanone
FL/FR
rhodinyl isobutyrate
FL/FR
rose carboxylate
FR
rose undecene
FR
terpinyl isobutyrate
FL/FR
ylang ylang flower oil III
FL/FR
fruity
allyl amyl glycolate
FR
allyl butyrate
FL/FR
iso
amyl butyrate
FL/FR
iso
amyl isovalerate
FL/FR
iso
amyl octanoate
FL/FR
para-
anisyl methyl ketone
FL/FR
para-
anisyl propionate
FL/FR
butyl isobutyrate
FL/FR
iso
butyl propionate
FL/FR
cherry pentenoate
FL/FR
2-
cyclopentyl cyclopentanone
FL/FR
diethyl malonate
FL/FR
dimethyl succinate
FL/FR
ethyl 2-cyclohexyl propionate
FR
ethyl 2-octenoate
FL/FR
ethyl 3-acetoxyhexanoate
FL/FR
ethyl 3,5,5-trimethyl hexanoate
FR
ethyl acetoacetate
FL/FR
heptanal cyclic ethylene acetal
FR
2-
hexen-1-ol
FL/FR
(E)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl isobutyrate
FL/FR
hexyl (E)-tiglate
FL/FR
hexyl acetate
FL/FR
para-
menth-1-ene-9-ol
FL/FR
methyl 3-nonenoate
FL/FR
2-
methyl butyl 2-methyl butyrate
FL/FR
2-
methyl butyl isovalerate
FL/FR
methyl heptanoate
FL/FR
nerolidyl isobutyrate
FR
octen-1-yl cyclopentanone
FL/FR
octyl butyrate
FL/FR
2-
pentyl furan
FL/FR
perillyl acetate
FL/FR
pineapple pentenoate
FL/FR
prenol
FL/FR
prenyl ethyl ether
FL/FR
prenyl hexanoate
FL/FR
iso
propyl 2-methyl butyrate
FL/FR
rhubarb undecane
FR
strawberry furanone butyrate
FL/FR
tetrahydrofurfuryl butyrate
FL/FR
tropical indene
FR
tropical thiazole
FL/FR
tropical thiazole
FL/FR
green
iso
amyl formate
FL/FR
iso
butyl heptanoate
FL/FR
butyl heptanoate
FL/FR
iso
butyl methyl ketone
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
carrot leaf oil (daucus carota ssp.maximus)
FR
alpha-
decalactone
FL/FR
(E)-2-
hexen-1-yl formate
FL/FR
(E)-2-
hexen-1-yl hexanoate
FL/FR
(Z)-3-
hexen-1-yl hexanoate
FL/FR
hexyl octanoate
FL/FR
hexyl tiglate
FL/FR
magnolia flower oil CO2 extract
FL/FR
manzanate (Givaudan)
FL/FR
octanal diethyl acetal
FL/FR
phenoxyethyl isobutyrate
FL/FR
privet dioxane
FR
propylene acetal
FL/FR
violet dienyne
FR
herbal
iso
amyl heptanoate
FL/FR
buchu mercaptan acetate
FL/FR
butyl levulinate
FL/FR
carvacryl methyl ether
FL/FR
chamomile propionate
FR
chamomile valerate
FR
coriander oleoresin
FL/FR
coriander seed absolute
FL/FR
cuminyl acetate
FL/FR
dehydroxylinalool oxide
FL/FR
dimethyl benzyl carbinyl crotonate
FL/FR
herbal acetal
FR
lavender absolute bulgaria
FL/FR
lavender absolute france
FL/FR
linalyl formate
FL/FR
linalyl octanoate
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
methyl hexyl ether
FL/FR
T-
muurolol
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
myrtle oil
FL/FR
myrtle oil morocco
FL/FR
3-
nonanol
FL/FR
nonisyl acetate
FR
3-
octanon-1-ol
FL/FR
curled
parsley seed oil
FL/FR
rue oil
FL/FR
rue oil cuba
FL/FR
saffron indenone
FL/FR
safranal
FL/FR
tagete oil CO2 extract
FL/FR
tagete oil egypt
FL/FR
tagete oil india
FL/FR
tagete oil rwanda
FL/FR
tagete oil south africa
FL/FR
tagete oil turkey
FL/FR
tagete oil zambia
FL/FR
thymyl methyl ether
FL/FR
tricyclodecenyl propionate
FR
viridiflorol
FL/FR
viridiflorol
FL/FR
honey
methyl phenyl acetate
FL/FR
minty
betula lenta bark oil america
FL/FR
orris
orris capronate
FL/FR
spicy
alpha-
amyl cinnamyl alcohol
FL/FR
iso
butyl (E,E)-2,4-decadienamide
FL/FR
carrot weed oil
FL/FR
carvacryl ethyl ether
FL/FR
cinnamaldehyde dimethyl acetal
FL/FR
cinnamyl propionate
FL/FR
(-)-
cubenol
FL/FR
cuminyl alcohol
FL/FR
black
currant bud absolute
FL/FR
eugenyl isovalerate
FL/FR
ginger oleoresin africa
FL/FR
2-
octanol
FL/FR
origanum majorana oil
FL/FR
origanum majorana oil cuba
FL/FR
origanum majorana oil morocco
FL/FR
(E)-
propyl 2-furan acrylate
FL/FR
tropical
beta-
cyclocitral
FL/FR
waxy
octyl 2-methyl butyrate
FL/FR
woody
beta-
caryophyllene alcohol acetate
FL/FR
kaempferia galanga rhizome oil
FL/FR
patchouli absolute
FR
spicy pentanone
FL/FR
verdoxan
FR
For Flavor
No flavor group found for these
iso
amyl angelate
FL/FR
amyl furoate
FL/FR
para-
anisyl propionate
FL/FR
iso
butyl (E,E)-2,4-decadienamide
FL/FR
butyl cinnamate
FL/FR
iso
butyl heptanoate
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
carvacryl ethyl ether
FL/FR
carvacryl methyl ether
FL/FR
beta-
caryophyllene alcohol acetate
FL/FR
(E)-
cinnamyl alcohol
FL/FR
cuminyl acetate
FL/FR
2-
cyclopentyl cyclopentanone
FL/FR
alpha-
decalactone
FL/FR
diethyl malate
FL/FR
(±)-(cis+trans)-1,2-
dihydroperillaldehyde
FL
2,4-
dimethyl anisole
FL
dimethyl benzyl carbinyl crotonate
FL/FR
ethyl 3-acetoxyhexanoate
FL/FR
ethyl 4-pentenoate
FL/FR
5-
ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-one
FL/FR
eugenyl isovalerate
FL/FR
guaiyl acetate
FL/FR
2-
hexenal
FL
2-
hexenal diethyl acetal
FL
hexyl (E)-2-hexenoate
FL
2-
hexylidene cyclopentanone
FL/FR
linalyl formate
FL/FR
magnolia flower oil CO2 extract
FL/FR
para-
menth-1-en-9-al
FL/FR
methyl (E)-2-hexenoate
FL/FR
methyl benzyl acetate (mixed ortho-,meta-,para-)
FL/FR
2-
methyl-2-octenal
FL
(E)-2-
methyl-2-octenal
FL
3-
methyl-3-pentanol
FL
T-
muurolol
FL/FR
myrtle oil morocco
FL/FR
nonan-3-yl acetate
FL/FR
3-
nonanol
FL/FR
(E,E)-3,5-
octadien-2-one
FL
3-
octanon-1-ol
FL/FR
pinus sylvestris leaf absolute
FL/FR
prenyl ethyl ether
FL/FR
prenyl hexanoate
FL/FR
propylene acetal
FL/FR
terpinyl isobutyrate
FL/FR
viridiflorol
FL/FR
viridiflorol
FL/FR
althaea officinalis root tincture
FL
hexyl 3-mercaptobutanoate
FL
acidic
acidic
(E)-2-
hexenoic acid
FL
alliaceous
tropical thiazole
FL/FR
tropical thiazole
FL/FR
anise
ethyl para-anisate
FL/FR
balsamic
ethyl cinnamate
FL/FR
tolu balsam oil
FL/FR
tolu balsam oil
FL/FR
berry
perillyl acetate
FL/FR
camphoreous
kaempferia galanga rhizome oil
FL/FR
caramellic
5-
ethyl-3,4,5,6-tetramethyl cyclohexen-2-one
FL
cheesy
2-
heptanone
FL/FR
cooling
manzanate (Givaudan)
FL/FR
creamy
althaea officinalis root extract
FL
2,4-
heptadienal
FL
3-
octen-2-one
FL/FR
estery
ethyl acetoacetate
FL/FR
ethereal
methyl hexyl ether
FL/FR
fatty
2,4-
undecadienal
FL
floral
cinnamyl propionate
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
geranyl tiglate
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
methyl phenyl acetate
FL/FR
rhodinyl isobutyrate
FL/FR
ylang ylang flower oil III
FL/FR
fruity
iso
amyl benzoate
FL/FR
iso
amyl octanoate
FL/FR
benzyl acetone
FL/FR
benzyl formate
FL/FR
boronia absolute
FL/FR
buchu mercaptan acetate
FL/FR
butyl heptanoate
FL/FR
butyl isobutyrate
FL/FR
iso
butyl propionate
FL/FR
cherry pentenoate
FL/FR
diethyl malonate
FL/FR
dimethyl succinate
FL/FR
ethyl (E)-2-octenoate
FL
ethyl 2-octenoate
FL/FR
furfuryl propionate
FL
2-
heptanol
FL/FR
2-
hexen-1-ol
FL/FR
(E)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl isobutyrate
FL/FR
hexyl acetate
FL/FR
linalyl octanoate
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
methyl (E)-3-nonenoate
FL
methyl 3-nonenoate
FL/FR
2-
methyl butyl 2-methyl butyrate
FL/FR
2-
methyl butyl isovalerate
FL/FR
methyl heptanoate
FL/FR
octen-1-yl cyclopentanone
FL/FR
pineapple pentenoate
FL/FR
prenol
FL/FR
(E)-
propyl 2-furan acrylate
FL/FR
iso
propyl 2-methyl butyrate
FL/FR
spicy pentanone
FL/FR
strawberry furanone butyrate
FL/FR
tagete oil CO2 extract
FL/FR
tagete oil rwanda
FL/FR
tagete oil south africa
FL/FR
tagete oil turkey
FL/FR
tagete oil zambia
FL/FR
tetrahydrofurfuryl butyrate
FL/FR
green
allyl butyrate
FL/FR
iso
amyl formate
FL/FR
iso
amyl isovalerate
FL/FR
iso
butyl methyl ketone
FL/FR
carrot weed oil
FL/FR
cinnamyl alcohol
FL/FR
coriander oleoresin
FL/FR
(E)-2-
hexen-1-yl hexanoate
FL/FR
(Z)-3-
hexen-1-yl hexanoate
FL/FR
(E)-2-
hexenal diethyl acetal
FL
hexyl (E)-tiglate
FL/FR
hexyl octanoate
FL/FR
hexyl tiglate
FL/FR
methyl 2-undecynoate
FL
3-
nonanone
FL/FR
octanal diethyl acetal
FL/FR
2-
pentyl furan
FL/FR
phenoxyethyl isobutyrate
FL/FR
herbal
iso
amyl heptanoate
FL/FR
butyl levulinate
FL/FR
coriander seed absolute
FL/FR
coriander seed oil
FL/FR
lavender absolute bulgaria
FL/FR
lavender absolute france
FL/FR
para-
menth-1-ene-9-ol
FL/FR
origanum majorana oil
FL/FR
curled
parsley seed oil
FL/FR
rue oil
FL/FR
rue oil cuba
FL/FR
saffron indenone
FL/FR
tagete oil egypt
FL/FR
tagete oil india
FL/FR
minty
betula lenta bark oil america
FL/FR
musty
thymyl methyl ether
FL/FR
orris
orris capronate
FL/FR
rummy
(E)-2-
hexen-1-yl formate
FL/FR
spicy
alpha-
amyl cinnamyl alcohol
FL/FR
para-
anisyl methyl ketone
FL/FR
cinnamaldehyde dimethyl acetal
FL/FR
(-)-
cubenol
FL/FR
cuminyl alcohol
FL/FR
black
currant bud absolute
FL/FR
ginger oleoresin africa
FL/FR
myrtle oil
FL/FR
2-
octanol
FL/FR
origanum majorana oil cuba
FL/FR
origanum majorana oil morocco
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
beta-
cyclocitral
FL/FR
vegetable
2-
methyl valeraldehyde
FL/FR
waxy
iso
amyl butyrate
FL/FR
octyl 2-methyl butyrate
FL/FR
octyl butyrate
FL/FR
woody
dehydroxylinalool oxide
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
safranal
FL/FR
 
Potential Uses:
 fruit
FLgreen
FLherbal
FLspice
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 benzyl 2,3-dimethyl crotonate
 benzyl 2,3-dimethyl-2-butenoate
 benzyl 2,3-dimethylbut-2-enoate
 benzyl 2,3-dimethylcrotonate
 benzyl methyltiglate
2-butenoic acid, 2,3-dimethyl-, phenylmethyl ester
 crotonic acid, 2,3-dimethyl-, benzyl ester
2,3-dimethyl crotonic acid benzyl ester
2,3-dimethyl-2-butenoic acid benzyl ester
2,3-dimethyl-2-butenoic acid phenyl methyl ester
 phenyl methyl 2,3-dimethyl-2-butenoate
 phenylmethyl 2,3-dimethyl-2-butenoate
 phenylmethyl 2,3-dimethylbut-2-enoate
 
 
Notes:
Flavouring agent
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