EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

(Z)-3-hexenoic acid
cis-3-hexenoic acid

Supplier Sponsors

Name:(Z)-hex-3-enoic acid
CAS Number: 1775-43-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:217-205-8
FDA UNII:86H58C39ZV
Nikkaji Web:J98.005F
Beilstein Number:1902955
XlogP3-AA:1.20 (est)
Molecular Weight:114.14410000
Formula:C6 H10 O2
NMR Predictor:Predict (works with chrome or firefox)
Category:flavoring agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:2181 cis-3-hexenoic acid
FEMA Number:4493 cis-3-hexenoic acid
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: CIS-3-HEXENOIC ACID
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.96200 to 0.96800 @ 25.00 °C.
Pounds per Gallon - (est).: 8.005 to 8.055
Refractive Index:1.43700 to 1.44300 @ 20.00 °C.
Boiling Point: 100.00 °C. @ 4.00 mm Hg
Boiling Point: 209.00 to 210.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.083000 mm/Hg @ 25.00 °C. (est)
Vapor Density:>1 ( Air = 1 )
Flash Point: 210.00 °F. TCC ( 98.89 °C. )
logP (o/w): 1.344 (est)
Shelf Life: 24.00 month(s) or longer if stored properly.
Storage:store in cool, dry place in tightly sealed containers, protected from heat and light. store under nitrogen.
Storage:store under nitrogen.
Soluble in:
 water, 7069 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor Type: green
Odor Strength:high ,
recommend smelling in a 0.10 % solution or less
green grassy sweaty fruity cheesy acidic
Odor Description:at 1.00 % in propylene glycol. green grass sweaty fruity cheesy acid
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
cis-3-HEXENOIC ACID BRI (NATURAL) ≥95.0%, Kosher
Odor Description:Green like grass, fruity, cheesy, musty, waxy, ripe, heavy, and slightly buttery
Taste Description:green
Use in fruity cheese like Blue Cheese/Swiss Cheese or a smaller amount in Cheddar cheese. Use in raspberry, passionfruit, grape, tea, wine, melon.
FCI SAS
CIS-3-HEXENOIC ACID
Odor Description:Powerful fruity honey odor slightly acrid
Taste Description:Fruity sweet honey
 
Cosmetic Information:
None found
 
Suppliers:
Axsyn
For experimental / research use only.
3-Hexenoic acid, (3Z)-
Bedoukian Research
cis-3-HEXENOIC ACID BRI (NATURAL)
≥95.0%, Kosher
Odor: Green like grass, fruity, cheesy, musty, waxy, ripe, heavy, and slightly buttery
Flavor: green
Use in fruity cheese like Blue Cheese/Swiss Cheese or a smaller amount in Cheddar cheese. Use in raspberry, passionfruit, grape, tea, wine, melon.
BOC Sciences
For experimental / research use only.
(Z)-Hex-2-enoic acid
FCI SAS
CIS-3-HEXENOIC ACID
Odor: Powerful fruity honey odor slightly acrid
Flavor: Fruity sweet honey
Kingchem Laboratories
C3 HEXENOIC ACID
Odor: Powerful fruity, honey
Parchem
(Z)-3-hexenoic acid
Penta International
cis-3-HEXENOIC ACID, Kosher
 
Safety Information:
European information :
Most important hazard(s):
Xn - Harmful.
R 34 - Causes burns.
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavoring agents
Recommendation for (Z)-3-hexenoic acid usage levels up to:
 not for fragrance use.
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 24
 average usual ppmaverage maximum ppm
baked goods: 7.0000016.00000
beverages(nonalcoholic): 2.000004.00000
beverages(alcoholic): 2.000004.00000
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: 4.000008.00000
fruit ices: --
gelatins / puddings: 2.000005.00000
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 7.0000015.00000
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):1775-43-5
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5355152
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 3265
WGK Germany:3
(Z)-hex-3-enoic acid
Chemidplus:0001775435
 
References:
 (Z)-hex-3-enoic acid
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:1775-43-5
Pubchem (cid):5355152
Pubchem (sid):135031518
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
CHEBI:View
HMDB (The Human Metabolome Database):HMDB31501
FooDB:FDB021772
Export Tariff Code:2916.19.6000
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
acidic
iso
butyric acid
FL/FR
2-
ethyl butyric acid
FL/FR
2-
methyl butyric acid
FL/FR
2-
methyl-2-pentenoic acid
FL/FR
aldehydic
tridecanal
FL/FR
iso
valeraldehyde
FL/FR
alliaceous
dibutyl sulfide
FL/FR
balsamic
cinnamic acid
FL/FR
terpinyl butyrate
FL/FR
valerian rhizome absolute
FL/FR
burnt
rum ether
FL/FR
buttery
acetoin
FL/FR
acetyl butyryl
FL/FR
butyl butyryl lactate
FL/FR
2,3-
heptane dione
FL/FR
caramellic
alpha,alpha-
dimethyl anisyl acetone
FL/FR
levulinic acid
FL/FR
cheesy
butyric acid
FL/FR
heptanoic acid
FL/FR
2-
heptanone
FL/FR
2-
methyl hexanoic acid
FL/FR
S-(
methyl thio) butyrate
FL/FR
2-
methyl valeric acid
FL/FR
valeric acid
FL/FR
iso
valeric acid
FL/FR
chemical
propyl propionate
FL/FR
citrus
(E+Z)-4,8-
dimethyl-3,7-nonadien-2-yl acetate
FL/FR
lemon oil c.p. california
FL/FR
lemongrass oil
FL/FR
lime oil distilled mexico
FL/FR
litsea cubeba fruit oil
FL/FR
nonanal dimethyl acetal
FL/FR
bitter
orange peel oil brazil
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
tetrahydrocitral
FL/FR
coconut
delta-
heptalactone
FL/FR
creamy
butyl lactate
FL/FR
para-
vanillic acid
FL/FR
ethereal
acetaldehyde dimethyl acetal
FL/FR
ethyl pyruvate
FL/FR
(E)-
methyl tiglate
FL/FR
fatty
decanoic acid
FL/FR
(E)-2-
hepten-1-ol
FL/FR
hexanoic acid
FL/FR
(E)-2-
nonenal
FL/FR
octanoic acid
FL/FR
fermented
butyl laevo-lactate
FL/FR
ethyl (E)-2-crotonate
FL/FR
ethyl crotonate
FL/FR
hexanal diethyl acetal
FL/FR
floral
benzyl lactate
FL/FR
dimethyl benzyl carbinol
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
mimosa absolute morocco
FL/FR
neryl isovalerate
FL/FR
beta-
ocimene
FL/FR
fruity
amyl formate
FL/FR
cyclohexyl carboxylic acid
FL/FR
ethyl 2-methyl butyrate
FL/FR
ethyl hexanoate
FL/FR
ethyl lactate
FL/FR
ethyl levulinate
FL/FR
filbert hexenone
FL/FR
4-
heptanone
FL/FR
(E)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl isobutyrate
FL/FR
hexyl isovalerate
FL/FR
methyl 4-methyl valerate
FL/FR
2-
methyl-2-pentenal
FL/FR
(Z)-3-
octen-1-ol
FL/FR
pineapple pentenoate
FL/FR
prenyl ethyl ether
FL/FR
iso
propenyl acetate
FL/FR
iso
propyl butyrate
FL/FR
propyl isovalerate
FL/FR
sorbyl butyrate
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
alfalfa oil
FL/FR
alfalfa resinoid
FL/FR
benzaldehyde dimethyl acetal
FL/FR
butyl 2-methyl butyrate
FL/FR
butyl heptanoate
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
cilantro leaf oil
FL/FR
iso
cyclocitral (IFF)
FL/FR
3,7-
dimethyl-6-octenoic acid
FL/FR
geranic acid
FL/FR
3-
heptanone
FL/FR
(Z)-4-
hepten-1-ol
FL/FR
(Z)-3-
hepten-1-ol
FL/FR
3-
hepten-2-one
FL/FR
(Z)-4-
heptenal
FL/FR
heptyl hexanoate
FL/FR
hexanal (aldehyde C-6)
FL/FR
(E)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(E)-2-
hexenal
FL/FR
hexyl butyrate
FL/FR
hexyl hexanoate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
(E)-2-
octen-1-yl acetate
FL/FR
1-
penten-3-ol
FL/FR
2-
pentenal
FL/FR
3,5,5-
trimethyl hexanol
FL/FR
herbal
rue oil
FL/FR
honey
phenoxyacetic acid
FL/FR
phenyl pyruvic acid
FL/FR
medicinal
meta-
dimethyl hydroquinone
FL/FR
minty
(-)-iso
pulegol
FL/FR
iso
pulegol
FL/FR
mushroom
1-
octen-3-yl butyrate
FL/FR
pungent
4-
methyl-2-pentanol
FL/FR
spicy
cumin seed oil
FL/FR
waxy
decanal diethyl acetal
FL/FR
2-
methyl heptanoic acid
FL/FR
nonanoic acid
FL/FR
2-
nonanol
FL/FR
octyl isobutyrate
FL/FR
undecanoic acid
FL/FR
For Flavor
No flavor group found for these
2-
acetyl-4-isopropenyl pyridine
FL
2-
acetyl-4-isopropyl pyridine
FL
benzyl lactate
FL/FR
butyl 2-methyl butyrate
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
cinnamic acid
FL/FR
alpha,alpha-
dimethyl anisyl acetone
FL/FR
(E+Z)-4,8-
dimethyl-3,7-nonadien-2-yl acetate
FL/FR
2,3-
epoxydecanal
FL
2,3-
epoxyheptanal
FL
ethyl cyclohexyl carboxylate
FL
2-
ethyl-2-heptenal
FL
3-(2-
furyl) acrolein
FL
(E,E)-2,4-
heptadien-1-ol
FL
(E)-2-
hepten-1-ol
FL/FR
(Z)-3-
hepten-1-ol
FL/FR
(E)-2-
heptenoic acid
FL
2-
heptenoic acid
FL
heptyl hexanoate
FL/FR
hexanal diethyl acetal
FL/FR
5-
methyl hexanoic acid
FL
3-(
methyl thio) hexanal
FL
(E)-
methyl tiglate
FL/FR
4-
methyl valeric acid
FL
4-
methyl-2-pentanol
FL/FR
3-
methyl-3-pentanol
FL
(E,E)-3,5-
octadien-2-one
FL
2-
pentenal
FL/FR
4-
pentenyl isothiocyanate
FL
phenoxyacetic acid
FL/FR
prenyl ethyl ether
FL/FR
propyl isovalerate
FL/FR
2-iso
propyl-3-(methyl thio) pyrazine
FL
sodium 4-methyl-2-oxovalerate
FL
terpinyl butyrate
FL/FR
tetrahydrocitral
FL/FR
3-(
methyl thio) methyl thiophene
FL
acetic
acetic
formic acid
FL
acidic
iso
butyric acid
FL/FR
2-
ethyl butyric acid
FL/FR
levulinic acid
FL/FR
propionic acid
FL
valeric acid
FL/FR
burnt
rum ether
FL/FR
buttery
butyl laevo-lactate
FL/FR
butyroin
FL
2,3-
heptane dione
FL/FR
2-
methyl valeric acid
FL/FR
(E)-2-
pentenoic acid
FL
caramellic
pyruvaldehyde
FL
pyruvic acid
FL
cheesy
ammonium isovalerate 30% in pg
FL
2-
heptanone
FL/FR
hexanoic acid
FL/FR
iso
valeric acid
FL/FR
chemical
meta-
dimethyl hydroquinone
FL/FR
citrus
cilantro leaf oil
FL/FR
lemon oil c.p. california
FL/FR
lemongrass oil
FL/FR
lime oil distilled mexico
FL/FR
litsea cubeba fruit oil
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
cocoa
butyraldehyde
FL
corn chip
2-
acetyl-2-thiazoline
FL
creamy
acetoin
FL/FR
acetoin butyrate
FL
acetyl butyryl
FL/FR
butyl butyryl lactate
FL/FR
3-
hepten-2-one
FL/FR
2-
methyl-4-pentenoic acid
FL
octyl isobutyrate
FL/FR
para-
vanillic acid
FL/FR
dairy
butyl lactate
FL/FR
4-
pentenoic acid
FL
eggy
iso
propyl mercaptan
FL
ethereal
acetaldehyde dimethyl acetal
FL/FR
4-
hexen-3-one
FL
iso
propenyl acetate
FL/FR
fatty
dimethyl sulfoxide
FL
(E,E)-2,4-
heptadienal
FL
nonanoic acid
FL/FR
(Z)-3-
octen-1-ol
FL/FR
(E)-2-
octenoic acid
FL
(E,E)-2,4-
undecadienal
FL
fishy
trimethyl amine
FL
floral
3,7-
dimethyl-6-octenoic acid
FL/FR
mimosa absolute morocco
FL/FR
fruity
acetyl isovaleryl
FL
amyl formate
FL/FR
butyl heptanoate
FL/FR
cyclohexyl carboxylic acid
FL/FR
ethyl 2-methyl butyrate
FL/FR
ethyl 3-oxohexanoate
FL
ethyl hexanoate
FL/FR
ethyl lactate
FL/FR
ethyl levulinate
FL/FR
filbert hexenone
FL/FR
4-
heptanone
FL/FR
(E)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl isobutyrate
FL/FR
hexyl hexanoate
FL/FR
methyl 4-methyl valerate
FL/FR
2-
methyl allyl butyrate
FL
2-
methyl butyric acid
FL/FR
2-
methyl-2-pentenal
FL/FR
neryl isovalerate
FL/FR
bitter
orange peel oil brazil
FL/FR
pineapple pentenoate
FL/FR
iso
propyl butyrate
FL/FR
sorbyl butyrate
FL/FR
iso
valeraldehyde
FL/FR
valerian rhizome absolute
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
alfalfa oil
FL/FR
alfalfa resinoid
FL/FR
benzaldehyde dimethyl acetal
FL/FR
iso
cyclocitral (IFF)
FL/FR
dibutyl sulfide
FL/FR
geranic acid
FL/FR
(Z)-4-
hepten-1-ol
FL/FR
(E)-2-
heptenal
FL
(Z)-4-
heptenal
FL/FR
hexanal (aldehyde C-6)
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(E)-3-
hexen-1-ol
FL/FR
(E)-2-
hexenal
FL/FR
(E)-3-
hexenoic acid
FL
hexyl butyrate
FL/FR
hexyl isovalerate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
4-
methyl-2-pentenal
FL
nonanal dimethyl acetal
FL/FR
(E)-2-
nonenal
FL/FR
beta-
ocimene
FL/FR
(E)-2-
octen-1-yl acetate
FL/FR
1-
penten-3-ol
FL/FR
3,5,5-
trimethyl hexanol
FL/FR
herbal
rue oil
FL/FR
ketonic
3-
heptanone
FL/FR
lactonic
delta-
heptalactone
FL/FR
meaty
12-
methyl tridecanal
FL
medicinal
dimethyl benzyl carbinol
FL/FR
minty
iso
pulegol
FL/FR
(-)-iso
pulegol
FL/FR
mushroom
1-
octen-3-yl butyrate
FL/FR
musty
ethyl (E)-2-crotonate
FL/FR
S-(
methyl thio) butyrate
FL/FR
oily
2-
methyl hexanoic acid
FL/FR
phenolic
phenyl pyruvic acid
FL/FR
pungent
acetaldehyde
FL
rummy
ethyl crotonate
FL/FR
ethyl pyruvate
FL/FR
soapy
decanoic acid
FL/FR
octanoic acid
FL/FR
sour
acetic acid
FL
butyric acid
FL/FR
2,4-
dimethyl-2-pentenoic acid
FL
3-
methyl valeric acid
FL
2-
methyl-2-pentenoic acid
FL/FR
spicy
cumin seed oil
FL/FR
tropical
propyl propionate
FL/FR
waxy
decanal diethyl acetal
FL/FR
heptanoic acid
FL/FR
2-
methyl heptanoic acid
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
2-
nonanol
FL/FR
tridecanal
FL/FR
undecanoic acid
FL/FR
 
Potential Uses:
FLcheese blue cheese
FLcheese cheddar cheese
FLcheese swiss cheese
FLgrape
FLmelon
FRpassion fruit
FLraspberry
FLtea
FLwine
 
Occurrence (nature, food, other):note
 banana fruit
Search Trop Picture
 beer
Search PMC Picture
 choke cherry black choke cherry
Search PMC Picture
 cocoa
Search Trop Picture
 grape
Search Trop Picture
 kiwi fruit
Search Trop Picture
 passion fruit yellow
Search Trop Picture
 raspberry red raspberry fruit
Search Trop Picture
 tea
Search Trop Picture
 wine white wine
Search Picture
 
Synonyms:
(3Z)-hex-3-enoic acid
(Z)-hex-3-enoic acid
cis-hex-3-enoic acid
(3Z)-3-hexenoic acid
C3 hexenoic acid
cis-3-hexenoic acid
cis-3-hexenoic acid BRI (natural)
3-hexenoic acid, (3Z)-
3-hexenoic acid, (Z)-
cis-3-hexenoicacid
 
 
Notes:
Flavouring ingredient; Isol from black tea var. assamica [CCD]
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