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Category:flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 98.00 to 100.00 sum of isomers
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| Food Chemicals Codex Listed: | No |
| Boiling Point: | 78.00 °C. @ 23.00 mm Hg
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| Boiling Point: | 60.00 °C. @ 24.00 mm Hg
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| Vapor Pressure: | 0.375000 mmHg @ 25.00 °C. (est) |
| Vapor Density: | >1 ( Air = 1 ) |
| Flash Point: | 165.00 °F. TCC ( 73.89 °C. )
|
| logP (o/w): | 1.794 (est) |
| Soluble in: |
| | alcohol | | | water, 5489 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
| Odor Type: green |
Odor Strength:medium , recommend smelling in a 10.00 % solution or less |
| Substantivity:8 hour(s) at 100.00 % |
| fresh oily fatty creamy vegetable dairy green grassy |
Odor Description:at 10.00 % in dipropylene glycol. fresh oily fatty creamy vegetable dairy green grassy Luebke, William tgsc, (2009) |
| Odor sample from: Bedoukian Research, Inc. |
| Flavor Type: green |
| sweet green tomato leaf oily tuna creamy vegetable brothy fishy |
Taste Description: sweet green tomato leaf oily tuna creamy vegetable brothy fishy Luebke, William tgsc, (2009) |
| Odor and/or flavor descriptions from others (if found). |
| Bedoukian Research |
| cis-4-HEPTEN-1-OL ≥93.0% (cis), Kosher |
Odor Description:Green, grassy odor similar to cis-3-hexenol with savory nuances Used for green topnotes. |
Taste Description:Sweet, green, dry, strawberry, tomato vine Very good for strawberry, tomato, dry, hay notes of mimosa and tomato vine. |
Cosmetic Information:
Suppliers:
| Bedoukian Research |
| cis-4-HEPTEN-1-OL
≥93.0% (cis), Kosher Odor: Green, grassy odor similar to cis-3-hexenol with savory nuances Use: Used for green topnotes. Flavor: Sweet, green, dry, strawberry, tomato vine Very good for strawberry, tomato, dry, hay notes of mimosa and tomato vine. |
| BOC Sciences |
| For experimental / research use only. |
| cis-4-HEPTEN-1-OL 98.0% (sum of isomers)
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| Parchem |
| (Z)-4-hepten-1-ol
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| Penta International |
| CIS-4-HEPTEN-1-OL
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| Santa Cruz Biotechnology |
| For experimental / research use only. |
| cis-4-Hepten-1-ol
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| Sigma-Aldrich |
| For experimental / research use only. |
| cis-4-Hepten-1-ol purum, ≥95.0% (GC)
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| Synerzine |
| cis-4-Hepten-1-ol
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| TCI AMERICA |
| For experimental / research use only. |
| cis-4-Hepten-1-ol >95.0%(GC)
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Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | None - None found. |
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
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Not determined
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| Dermal Toxicity: |
|
Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for (Z)-4-hepten-1-ol usage levels up to: | | | 1.0000 % in the fragrance concentrate.
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| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 1.20 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 2.00 (μg/capita/day) |
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | ND (μg/person/day) |
| Threshold of Concern: | 1800 (μg/person/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 18 |
| Click here to view publication 18 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | - |
| beverages(nonalcoholic): | 2.00000 | 10.00000 |
| beverages(alcoholic): | 5.00000 | 20.00000 |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | 50.00000 | 100.00000 |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | - |
| fruit ices: | - | - |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | 5.00000 | 20.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | 5.00000 | 20.00000 |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | 5.00000 | 20.00000 |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | 5.00000 | 20.00000 |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
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European Food Safety Authority (EFSA) reference(s):
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Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf
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Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008) View page or View pdf
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| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):6191-71-5 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :5367536 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:3 |
| (Z)-hept-4-en-1-ol |
| Chemidplus:0006191715 |
References:
Other Information:
Potential Blenders and core components note
| For Odor |
| aldehydic |
acetyl nonyryl FL/FR |
iso valeraldehyde FL/FR |
| alliaceous |
dibutyl sulfide FL/FR |
| buttery |
acetoin FL/FR |
acetyl butyryl FL/FR |
acetyl isobutyryl FL/FR |
acetyl propionyl FL/FR |
butyl butyryl lactate FL/FR |
| caramellic |
2-oxo butyric acid FL/FR |
levulinic acid FL/FR |
strawberry furanone acetate FL/FR |
| cheesy |
butyric acid FL/FR |
2- methyl hexanoic acid FL/FR |
| citrus |
litsea cubeba fruit oil FL/FR |
| coconut |
coconut decanone methyl FR |
delta- decalactone FL/FR |
delta-2- dodecenolactone FL/FR |
delta- nonalactone FL/FR |
gamma- octalactone FL/FR |
delta- undecalactone FL/FR |
| coffee |
furfuryl mercaptan FL/FR |
| creamy |
gamma- butyrolactone FL/FR |
creamy lactone FL/FR |
3- heptyl dihydro-5-methyl-2(3H)-furanone FL/FR |
para- vanillic acid FL/FR |
para- vanillyl alcohol FL/FR |
| earthy |
1- nonen-3-ol FL/FR |
| fatty |
butter esters FL/FR |
(Z)- dairy lactone FL/FR |
(Z)- ethyl oleate FL/FR |
ethyl undecylenate FL/FR |
4- methyl octanoic acid FL/FR |
perilla seed oil FL/FR |
sorbitan oleate CS |
(E,Z,Z)-2,4,7- tridecatrienal FL/FR |
| fermented |
butyl laevo-lactate FL/FR |
| floral |
farnesol FL/FR |
mimosa absolute france FL/FR |
octanal / methyl anthranilate schiff's base FR |
2- pentadecanone FL/FR |
| fruity |
acetoin acetate FL/FR |
butyl 2-decenoate FL/FR |
gamma- decalactone FL/FR |
alpha,alpha- dimethyl benzyl isobutyrate FL/FR |
dodecyl isobutyrate FL/FR |
farnesyl acetone FL/FR |
(R)-(-)-2- heptanol FL/FR |
methyl (Z)-5-octenoate FL/FR |
2- methyl-2-pentenal FL/FR |
gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR |
2- undecanone FL/FR |
| green |
bark carbaldehyde FR |
iso butyl benzyl carbinol FL/FR |
butyl heptanoate FL/FR |
butyl lactate FL/FR |
sec- butyl-3-methyl but-2-ene thioate FL/FR |
3,7- dimethyl-6-octenoic acid FL/FR |
(Z)-3- hepten-1-ol FL/FR |
3- hepten-2-one FL/FR |
(Z)-4- heptenal FL/FR |
(Z)-4- heptenal diethyl acetal FL/FR |
heptyl heptanoate FL/FR |
hexanal dihexyl acetal FL/FR |
(Z)-4- hexen-1-ol FL/FR |
(Z)-3- hexenal FL/FR |
lilac acetaldehyde FL/FR |
neryl butyrate FL/FR |
phenyl acetaldehyde dimethyl acetal FL/FR |
propylene acetal FL/FR |
3,5,5- trimethyl hexanol FL/FR |
| herbal |
clary sage resin america FR |
| milky |
laevo- glutamine CS |
| mushroom |
(S)-(+)-2- heptanol FL/FR |
3- octen-2-ol FL/FR |
| oily |
amyl laurate FL/FR |
butter acids FL/FR |
| spicy |
3-(2- furyl) acrolein FL/FR |
| sweet |
vanilla oleoresin bali FL/FR |
| tonka |
6- amyl-alpha-pyrone FL/FR |
mint lactone FL/FR |
| vanilla |
ortho- dimethyl hydroquinone FL/FR |
ethyl vanillin FL/FR |
ethyl vanillin isobutyrate FL/FR |
ethyl vanillin propylene glycol acetal FL/FR |
vanillin FL/FR |
vanillyl acetate FL/FR |
vanillyl isobutyrate FL/FR |
vanillylidene acetone FL/FR |
| vegetable |
methional FL/FR |
| waxy |
allyl nonanoate FL/FR |
iso amyl laurate FL/FR |
ethyl palmitate FL/FR |
methyl laurate FL/FR |
2- nonanol FL/FR |
octyl isobutyrate FL/FR |
palmitic acid FR |
delta- tetradecalactone FL/FR |
undecanoic acid FL/FR |
| woody |
nopyl aldehyde FR |
| For Flavor |
| No flavor group found for these |
allyl methyl trisulfide FL |
amyl laurate FL/FR |
sec- butyl-3-methyl but-2-ene thioate FL/FR |
6- decenoic acid FL |
ortho- dimethyl hydroquinone FL/FR |
delta-2- dodecenolactone FL/FR |
dodecyl isobutyrate FL/FR |
2- ethyl pyridine FL |
2- ethyl-4,5-dimethyl oxazole FL |
farnesyl acetone FL/FR |
3-(2- furyl) acrolein FL/FR |
(R)-(-)-2- heptanol FL/FR |
(S)-(+)-2- heptanol FL/FR |
(Z)-3- hepten-1-ol FL/FR |
2- heptenoic acid FL |
hexanal dihexyl acetal FL/FR |
(Z)-3- hexenoic acid FL |
3- methyl crotonic acid FL |
3-( methyl thio) hexanal FL |
(E,E)-3,5- octadien-2-one FL |
perilla seed oil FL/FR |
propylene acetal FL/FR |
| acidic |
| acidic |
levulinic acid FL/FR |
| aldehydic |
acetyl nonyryl FL/FR |
| alliaceous |
benzyl mercaptan FL |
| amber |
iso butyl benzyl carbinol FL/FR |
| balsamic |
vanillylidene acetone FL/FR |
| bitter |
(E,Z,Z)-2,4,7- tridecatrienal FL/FR |
| brown |
2-oxo butyric acid FL/FR |
| buttery |
butyl laevo-lactate FL/FR |
diacetyl FL |
| cabbage |
methyl 2-thiofuroate FL |
| caramellic |
strawberry furanone acetate FL/FR |
| citrus |
litsea cubeba fruit oil FL/FR |
| coconut |
delta- decalactone FL/FR |
massoia bark oil CO2 extract FL |
(R)- massoia lactone FL |
6- methyl coumarin FL |
| coffee |
furfuryl mercaptan FL/FR |
| creamy |
acetoin FL/FR |
acetyl butyryl FL/FR |
acetyl isobutyryl FL/FR |
6- amyl-alpha-pyrone FL/FR |
butter esters FL/FR |
butyl butyryl lactate FL/FR |
creamy lactone FL/FR |
3- hepten-2-one FL/FR |
mint lactone FL/FR |
delta- nonalactone FL/FR |
octyl isobutyrate FL/FR |
delta- undecalactone FL/FR |
gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR |
para- vanillic acid FL/FR |
para- vanillyl alcohol FL/FR |
| dairy |
methyl (Z)-5-octenoate FL/FR |
| earthy |
1- nonen-3-ol FL/FR |
| fatty |
iso amyl laurate FL/FR |
butter acids FL/FR |
(Z)- dairy lactone FL/FR |
dimethyl sulfoxide FL |
(Z)- ethyl oleate FL/FR |
ethyl undecylenate FL/FR |
4- methyl octanoic acid FL/FR |
2,4- octadien-1-ol FL |
2- pentadecanone FL/FR |
| floral |
3,7- dimethyl-6-octenoic acid FL/FR |
farnesol FL/FR |
| fruity |
acetoin acetate FL/FR |
acetyl isovaleryl FL |
butyl 2-decenoate FL/FR |
butyl heptanoate FL/FR |
gamma- decalactone FL/FR |
alpha,alpha- dimethyl benzyl isobutyrate FL/FR |
3- heptyl dihydro-5-methyl-2(3H)-furanone FL/FR |
lilac acetaldehyde FL/FR |
2- methyl-2-pentenal FL/FR |
iso valeraldehyde FL/FR |
| green |
butyl lactate FL/FR |
dibutyl sulfide FL/FR |
heptanal 2,3-butane diol acetal FL |
(Z)-4- heptenal FL/FR |
(E)-2- heptenal FL |
(Z)-4- heptenal diethyl acetal FL/FR |
heptyl heptanoate FL/FR |
(Z)-4- hexen-1-ol FL/FR |
(Z)-3- hexenal FL/FR |
(E)-3- hexenoic acid FL |
neryl butyrate FL/FR |
2,4- octadienal FL |
phenyl acetaldehyde dimethyl acetal FL/FR |
3,5,5- trimethyl hexanol FL/FR |
| lactonic |
gamma- octalactone FL/FR |
| milky |
gamma- butyrolactone FL/FR |
| mushroom |
methional diethyl acetal FL |
3- octen-2-ol FL/FR |
| nutty |
arachis hypogaea fruit extract FL |
| oily |
2- methyl hexanoic acid FL/FR |
| sour |
butyric acid FL/FR |
| spicy |
benzylidene acetone FL |
| sulfurous |
methyl thioacetate FL |
| sweet |
vanilla oleoresin bali FL/FR |
| toasted |
acetyl propionyl FL/FR |
| tomato |
methional FL/FR |
| vanilla |
ethyl vanillin FL/FR |
ethyl vanillin isobutyrate FL/FR |
ethyl vanillin propylene glycol acetal FL/FR |
vanillin FL/FR |
vanillyl acetate FL/FR |
vanillyl isobutyrate FL/FR |
| waxy |
allyl nonanoate FL/FR |
ethyl palmitate FL/FR |
methyl laurate FL/FR |
mimosa absolute france FL/FR |
2- nonanol FL/FR |
octyl 2-furoate FL |
delta- tetradecalactone FL/FR |
undecanoic acid FL/FR |
2- undecanone FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| (4Z)- | hept-4-en-1-ol | | (Z)- | hept-4-en-1-ol | | cis- | hept-4-en-1-ol | | cis- | hept-4-enol | | (4Z)-4- | hepten-1-ol | | cis-4- | hepten-1-ol | | 4- | hepten-1-ol, (4Z)- | | 4- | hepten-1-ol, cis- | | (Z)-4- | heptenol | | cis-4- | heptenol |
Articles:
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