EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

para-anisyl formate
4-methoxybenzyl formate

Sponsors

Flavor Demo Formulas
Name:(4-methoxyphenyl)methyl formate
CAS Number: 122-91-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:204-582-9
FDA UNII:7N0ADO5BXI
Nikkaji Web:J31.559A
MDL:MFCD00021045
CoE Number:354
XlogP3:1.70 (est)
Molecular Weight:166.17630000
Formula:C9 H10 O3
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome or firefox)
EFSA/JECFA Comments:
At least 90%; secondary component 8% anisyl alcohol. (EFSA)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:872 anisyl formate
FLAVIS Number:09.087 (Old)
DG SANTE Food Flavourings:09.087 p-anisyl formate
FEMA Number:2101 anisyl formate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: ANISYL FORMATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 96.00 to 100.00
Food Chemicals Codex Listed: Yes
Specific Gravity:1.13800 to 1.14200 @ 25.00 °C.
Pounds per Gallon - (est).: 9.469 to 9.503
Refractive Index:1.52100 to 1.52500 @ 20.00 °C.
Boiling Point: 220.00 °C. @ 760.00 mm Hg
Boiling Point: 254.00 to 255.00 °C. @ 760.00 mm Hg (est)
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.017000 mm/Hg @ 25.00 °C. (est)
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 1.252 (est)
Soluble in:
 alcohol
 water, 2679 mg/L @ 25 °C (est)
Similar Items:note
allyl formate
amyl formate
isoamyl formate
benzyl formate
bornyl formate
isobornyl formate
butyl formate
isobutyl formate
sec-butyl formate
carvyl formate
cedryl formate
cinnamyl formate
citronellyl formate
para-cresyl formate
cyclododecyl formate
cyclohexyl formate
2-decalinyl formate
decyl formate
dimethyl benzyl carbinyl formate
ethyl formate
eugenyl formate
isoeugenyl formate
furfuryl formate
S-furfuryl thioformate
geranyl formate
heptyl formate
(E)-2-hexen-1-yl formate
(E)-3-hexen-1-yl formate
3-hexen-1-yl formate
(Z)-3-hexen-1-yl formate
hexyl formate
linalyl formate
menthadienyl formate
menthyl formate
laevo-menthyl formate
2-methyl butyl formate
methyl formate
myrtenyl formate
neryl formate
nonisyl formate
nonyl formate
nopyl formate
octyl formate
3-octyl formate
phenethyl formate
2-phenoxyethyl formate
3-phenyl propyl formate
prenyl formate
propyl formate
isopropyl formate
isopulegyl formate
rhodinyl formate
styralyl formate
sulfuryl formate
terpinyl formate
 
Organoleptic Properties:
Odor Type: spicy
Odor Strength:medium
Substantivity:104 hour(s) at 100.00 %
fruity floral anisic vanilla seaweed
Odor Description:at 100.00 %. fruity floral anisic vanilla seaweed
Luebke, William tgsc, (1985)
Odor sample from: Nickstadt Moeller, Inc.
sweet spicy vanilla powdery fruity
Odor Description:Sweet, spicy, vanilla-like with powdery fruity nuances
Mosciano, Gerard P&F 17, No. 3, 57, (1992)
Flavor Type: spicy
sweet vanilla spicy fruity heliotrope
Taste Description: at 50.00 ppm. Sweet, vanilla, spice, with fruity heliotropine-like nuances
Mosciano, Gerard P&F 17, No. 3, 57, (1992)
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Advanced Biotech
ANISYL FORMATE NATURAL
97% min.
Alfrebro
ANISYL FORMATE NATURAL
Odor: Sweet, Balsamic, Floral
BOC Sciences
For experimental / research use only.
para-Anisyl Formate
Citrus and Allied Essences
Anisyl Formate Extra FCC
Market Report
Diffusions Aromatiques
FORMIATE ANISYL
Ernesto Ventós
ANISYL FORMATE
Odor: SWEET, FLORAL, TONKA
Fleurchem
anisyl formate
Global Essence
Anisyl formate
Indukern F&F
ANISYL FORMATE
Odor: FRUITY, FLORAL, VANILLA
Inoue Perfumery
ANISYL FORMATE
M&U International
Nar. Anisyl Formate
Moellhausen
ANISYL FORMATE
Nactis Flavours
ANISYL FORMATE
Odor: powdery aniseed floral note with spicy, balsamic and fruity undertones
Natural Advantage
Anisyl Formate Nat
PCAS
Anisyl Formate, Kosher
Pearlchem Corporation
Anisyl Formate
Penta International
ANISYL FORMATE FCC, Kosher
Reincke & Fichtner
Anisyl Formate
Sigma-Aldrich
Anisyl formate, ≥90%, FCC, FG
Odor: floral; sweet
Certified Food Grade Products
The Lermond Company
Anisyl Formate
Vigon International
Anisyl Formate FCC
Odor: SWEET, FLORAL, TONKA-LIKE
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 1770 mg/kg
(Levenstein, 1975j)

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for para-anisyl formate usage levels up to:
  4.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 39.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 24.00 (μg/capita/day)
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
 average usual ppmaverage maximum ppm
baked goods: -14.00000
beverages(nonalcoholic): -3.20000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -3.90000
fruit ices: -3.90000
gelatins / puddings: -0.20000
granulated sugar: --
gravies: --
hard candy: -7.90000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) on a request from the Commission related to Flavouring Group Evaluation 20 (FGE.20): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical group 23
View page or View pdf

Flavouring Group Evaluation 52 (FGE.52): Consideration of hydroxy- and alkoxy-substituted benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters evaluated by EFSA in FGE.20 (2005) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf

Flavouring Group Evaluation 20, Revision 1 (FGE.20Rev1): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters from chemical group 23
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):122-91-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :61054
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
(4-methoxyphenyl)methyl formate
Chemidplus:0000122918
 
References:
 (4-methoxyphenyl)methyl formate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:122-91-8
Pubchem (cid):61054
Pubchem (sid):135018865
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB34993
FooDB:FDB013596
Export Tariff Code:2915.13.0000
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
citrus carbaldehyde
FR
nonanal (aldehyde C-9)
FL/FR
amber
ambroxan
FL/FR
cistus ladaniferus resinoid
FR
anise
anise seed oil
FL/FR
anisic
para-
anisaldehyde
FL/FR
dihydroanethol
FL/FR
balsamic
iso
amyl benzoate
FL/FR
amyris wood oil
FL/FR
sumatra
benzoin resin
FL/FR
benzoin resin replacer
FR
sumatra
benzoin resinoid
FL/FR
siam
benzoin resinoid
FL/FR
benzyl cinnamate
FL/FR
iso
butyl cinnamate
FL/FR
cinnamyl alcohol
FL/FR
clover nitrile
FR
ethyl cinnamate
FL/FR
fir balsam absolute
FR
methyl (E)-cinnamate
FL/FR
peru balsam absolute
FL/FR
peru balsam oil
FL/FR
3-
phenyl propyl alcohol
FL/FR
terpinyl cinnamate
FL/FR
berry
raspberry ketone
FL/FR
raspberry ketone acetate
FL/FR
raspberry ketone methyl ether
FL/FR
bready
coffee furanone
FL/FR
buttery
acetoin
FL/FR
caramellic
cyclotene
FL/FR
ethyl maltol
FL/FR
immortelle absolute
FL/FR
maltol
FL/FR
strawberry furanone
FL/FR
chocolate
iso
amyl phenyl acetate
FL/FR
chocolate specialty
FR
vanillyl ethyl ether
FL/FR
citrus
dihydromyrcenol
FL/FR
blood
orange oil italy
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
coconut
gamma-
heptalactone
FL/FR
gamma-
nonalactone (aldehyde C-18 (so-called))
FL/FR
gamma-
octalactone
FL/FR
creamy
para-
vanillic acid
FL/FR
earthy
dibenzyl ether
FL/FR
floral
acetophenone
FL/FR
alpha-
amyl cinnamyl acetate
FL/FR
bois de rose oil brazil
FL/FR
iso
butyl salicylate
FL/FR
cassie absolute
FL/FR
citronellol
FL/FR
para-
cresyl acetate
FL/FR
beta-
damascenone
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
ethyl phenyl acetate
FL/FR
floral pyranol
FR
geraniol
FL/FR
heliotropin
FL/FR
heliotropyl acetate
FL/FR
linalool oxide
FL/FR
para-
methyl acetophenone
FL/FR
methyl dihydrojasmonate
FL/FR
alpha-iso
methyl ionone (50% min.)
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
nonanol
FL/FR
ocean propanal
FL/FR
papaya isobutyrate
FL/FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
phenethyl isobutyrate
FL/FR
phenethyl phenyl acetate
FL/FR
phenethyl propionate
FL/FR
rose butanoate
FL/FR
tetrahydrolinalool
FL/FR
fruity
acetyl methyl anthranilate
FL/FR
allyl amyl glycolate
FR
iso
amyl butyrate
FL/FR
bread thiophene
FL/FR
(E)-alpha-
damascone
FL/FR
(E)-beta-
damascone
FL/FR
gamma-
decalactone
FL/FR
dimethyl benzyl carbinyl isobutyrate
FR
ethyl isovalerate
FL/FR
green acetate
FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
green
galbanum oil
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(Z)-3-
hexen-1-yl propionate
FL/FR
hexyl 2-methyl butyrate
FL/FR
(E)-2-
pentenal
FL/FR
hay
beeswax absolute
FL/FR
hay absolute
FR
herbal
carum carvi fruit oil
FL/FR
clary sage oil france
FL/FR
honey
methyl phenyl acetate
FL/FR
phenyl acetic acid
FL/FR
licorice
(E)-
anethol
FL/FR
mossy
veramoss (IFF)
FR
musk
musk indane
FR
musk tetralin
FR
naphthyl
2,4-
dimethyl benzaldehyde
FL/FR
beta-
naphthyl ethyl ether
FL/FR
popcorn
2-
acetyl pyrazine
FL/FR
2-
acetyl pyridine
FL/FR
powdery
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
alpha-
methyl ionone
FL/FR
(E)-alpha-
methyl ionone (74-80%)
FL/FR
smoky
2,6-
dimethoxyphenol
FL/FR
spicy
cassia bark oil china
FL/FR
clove bud oil
FL/FR
black
currant bud absolute
FL/FR
dianthus ethone
FR
eugenol
FL/FR
iso
eugenyl acetate
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
4-
methyl guaiacol
FL/FR
methyl isoeugenol
FL/FR
terpenic
frankincense oil
FL/FR
tonka
coumarin
FR
gamma-
hexalactone
FL/FR
tonka bean absolute
FR
vanilla
ethyl vanillin
FL/FR
heliotropyl alcohol
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
vanillylidene acetone
FL/FR
waxy
decyl acetate
FL/FR
woody
guaiacwood oil
FL/FR
gurjun balsam oil
FR
santall
FR
spicy pentanone
FL/FR
tobacarol (IFF)
FR
woody acetate
FR
For Flavor
No flavor group found for these
heliotropyl alcohol
FL/FR
methyl (E)-cinnamate
FL/FR
aldehydic
aldehydic
nonanal (aldehyde C-9)
FL/FR
anise
(E)-
anethol
FL/FR
anise seed oil
FL/FR
aromatic
para-
cresyl acetate
FL/FR
balsamic
sumatra
benzoin resin
FL/FR
siam
benzoin resinoid
FL/FR
sumatra
benzoin resinoid
FL/FR
iso
butyl cinnamate
FL/FR
ethyl cinnamate
FL/FR
peru balsam absolute
FL/FR
peru balsam oil
FL/FR
vanillylidene acetone
FL/FR
berry
raspberry ketone
FL/FR
raspberry ketone acetate
FL/FR
raspberry ketone methyl ether
FL/FR
brown
beeswax absolute
FL/FR
caramellic
caramel furanone
FL
cyclotene
FL/FR
ethyl maltol
FL/FR
maltol
FL/FR
strawberry furanone
FL/FR
cherry
heliotropin
FL/FR
citrus
blood
orange oil italy
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
coconut
gamma-
nonalactone (aldehyde C-18 (so-called))
FL/FR
cooling
iso
butyl salicylate
FL/FR
corn chip
2-
acetyl pyridine
FL/FR
2-
acetyl-2-thiazoline
FL
creamy
acetoin
FL/FR
para-
anisaldehyde
FL/FR
gamma-
hexalactone
FL/FR
para-
methyl acetophenone
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
para-
vanillic acid
FL/FR
earthy
alpha-
amyl cinnamyl acetate
FL/FR
fatty
(Z)-3-
hexen-1-yl benzoate
FL/FR
floral
iso
amyl phenyl acetate
FL/FR
bois de rose oil brazil
FL/FR
citronellol
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
geraniol
FL/FR
heliotropyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
alpha-iso
methyl ionone (50% min.)
FL/FR
(E)-alpha-
methyl ionone (74-80%)
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
methyl phenyl acetate
FL/FR
ocean propanal
FL/FR
phenethyl alcohol
FL/FR
phenethyl propionate
FL/FR
phenyl acetic acid
FL/FR
tetrahydrolinalool
FL/FR
fruity
acetyl methyl anthranilate
FL/FR
iso
amyl benzoate
FL/FR
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
bread thiophene
FL/FR
(E)-alpha-
damascone
FL/FR
(E)-beta-
damascone
FL/FR
gamma-
decalactone
FL/FR
dibenzyl ether
FL/FR
ethyl isovalerate
FL/FR
alpha-
methyl ionone
FL/FR
rose butanoate
FL/FR
spicy pentanone
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
terpinyl cinnamate
FL/FR
green
cinnamyl alcohol
FL/FR
dihydromyrcenol
FL/FR
galbanum oil
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl propionate
FL/FR
hexyl 2-methyl butyrate
FL/FR
immortelle absolute
FL/FR
linalool oxide
FL/FR
papaya isobutyrate
FL/FR
(E)-2-
pentenal
FL/FR
herbal
carum carvi fruit oil
FL/FR
clary sage oil france
FL/FR
dihydroanethol
FL/FR
honey
ethyl phenyl acetate
FL/FR
phenethyl acetate
FL/FR
phenethyl isobutyrate
FL/FR
phenethyl phenyl acetate
FL/FR
lactonic
gamma-
heptalactone
FL/FR
gamma-
octalactone
FL/FR
medicinal
2,6-
dimethoxyphenol
FL/FR
naphthyl
2,4-
dimethyl benzaldehyde
FL/FR
nutty
coffee furanone
FL/FR
furfural acetone
FL
powdery
acetophenone
FL/FR
beta-
naphthyl ethyl ether
FL/FR
powdery ketone
FL
roasted
2-
acetyl pyrazine
FL/FR
rummy
vanillyl ethyl ether
FL/FR
spicy
benzyl cinnamate
FL/FR
cassia bark oil china
FL/FR
cassie absolute
FL/FR
clove bud oil
FL/FR
black
currant bud absolute
FL/FR
eugenol
FL/FR
iso
eugenyl acetate
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
methyl isoeugenol
FL/FR
3-
phenyl propyl alcohol
FL/FR
chai
vanilla flavor
FL
tea
red rooibos
tea leaf distillates
FL
vanilla
vanilla
chai flavor
FL
ethyl vanillin
FL/FR
4-
methyl guaiacol
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
waxy
iso
amyl butyrate
FL/FR
decyl acetate
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
nonanol
FL/FR
woody
ambroxan
FL/FR
amyris wood oil
FL/FR
beta-
damascenone
FL/FR
frankincense oil
FL/FR
guaiacwood oil
FL/FR
 
Potential Uses:
FRacacia
FRbalsam
FRblackberry
FRcurrant
FRcypress oil replacer
 fir
FRgardenia
FRhawthorn
FRheliotrope
FRjasmin
FRlicorice
FRlilac
FRraspberry
FRroot beer
FRseaweed absolute replacer
FRstrawberry
FRtonka bean
FRtuberose
FRvanilla
FRylang ylang
 
Occurrence (nature, food, other):note
 ribes species
Search PMC Picture
 vanilla fragrans
Search Trop Picture
 
Synonyms:
 anisyl alcohol formate
 anisyl alcohol, formate
 anisyl formate
p-anisyl formate
 anisyl formate extra FCC
 anisyl formate FCC
 anisyl formate natural
 anisyl methanoate
 benzenemethanol, 4-methoxy-, formate
 benzyl alcohol, p-methoxy-, formate
4-methoxybenzene methanol methanoate
4-methoxybenzene methyl formate
4-methoxybenzenemethanolmethanoate
4-methoxybenzenemethyl formate
p-methoxybenzyl alcohol formate
para-methoxybenzyl alcohol formate
p-methoxybenzyl alcohol, formate
4-methoxybenzyl formate
p-methoxybenzyl formate
para-methoxybenzyl formate
p-methoxybenzyl methanoate
para-methoxybenzyl methanoate
 methoxybenzyl methanoate, p-
p-methoxybenzylmethanoate
para-methoxybenzylmethanoate
(4-methoxyphenyl)methyl formate
 
 
Notes:
Used extensively in food flavouring
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