EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

dibenzyl ether
1,1-(oxybis(methylene))bisbenzene

Supplier Sponsors

Name:phenylmethoxymethylbenzene
CAS Number: 103-50-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:203-118-2
FDA UNII:2O6CNO27RJ
Nikkaji Web:J1.181I
Beilstein Number:1911156
MDL:MFCD00004780
CoE Number:11856
XlogP3:3.30 (est)
Molecular Weight:198.26478000
Formula:C14 H14 O
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:1256 dibenzyl ether
FLAVIS Number:03.004 (Old)
DG SANTE Food Flavourings:03.004 dibenzyl ether
FEMA Number:2371 dibenzyl ether
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):103-50-4 ; DIBENZYL ETHER
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 99.00 to 100.00
Food Chemicals Codex Listed: Yes
Specific Gravity:1.03900 to 1.04400 @ 25.00 °C.
Pounds per Gallon - (est).: 8.646 to 8.687
Refractive Index:1.56100 to 1.56200 @ 20.00 °C.
Melting Point: 1.50 to 3.50 °C. @ 760.00 mm Hg
Boiling Point: 295.00 to 298.00 °C. @ 760.00 mm Hg
Boiling Point: 170.00 °C. @ 16.00 mm Hg
Vapor Pressure:0.001030 mmHg @ 25.00 °C.
Vapor Density:6.8 ( Air = 1 )
Flash Point: 275.00 °F. TCC ( 135.00 °C. )
logP (o/w): 3.310
Soluble in:
 alcohol
 water, 40 mg/L @ 35 °C (exp)
Insoluble in:
 water
Stability:
 cream
 lipstick
 non-discoloring in most media
 shampoo
 soap
 
Organoleptic Properties:
Odor Type: earthy
Odor Strength:medium
Substantivity:400 hour(s) at 100.00 %
sweet fruity cherry earthy mushroom rose plastic
Odor Description:at 100.00 %. sweet fruity cherry earthy mushroom rose plastic
Luebke, William tgsc, (1987)
Odor sample from: Harrmann & Reimer Corporation
Flavor Type: fruity
fruity cherry fungal plastic mushroom
Taste Description: fruity cherry fungal plastic mushroom
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Augustus Oils
Dibenzyl Ether
Services
Berjé
Dibenzyl Ether
Happening at Berje
BOC Sciences
For experimental / research use only.
Dibenzyl Ether
EMD Millipore
For experimental / research use only.
Dibenzyl Ether
Lluch Essence
DIBENZYL ETHER 98%
Odor: FRUITY, FLORAL
Moellhausen
DIBENZYL OXIDE
Odor: aromatic, floral, somewhat fruity; rose-like connotations
Flavor: fruity, spicy, nut-like
OQEMA
Dibenzyl Ether
Penta International
DIBENZYL ETHER FCC
Penta International
DIBENZYL ETHER
R C Treatt & Co Ltd
Dibenzyl Oxide
Reincke & Fichtner
Dibenzyl Ether
Sigma-Aldrich
Benzyl ether, ≥98%, FCC, FG
Odor: almond; chocolate; spicy; fruity; sweet.
Certified Food Grade Products
TCI AMERICA
For experimental / research use only.
Dibenzyl Ether >95.0%(GC)
The John D. Walsh Company
Dibenzyl Ether
Vigon International
Dibenzyl Ether
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi N - Irritant, Dangerous for the environment.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
4 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-mouse LD50 4300 mg/kg
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: FOOD INTAKE (ANIMAL)
Toksikologicheskii Vestnik. Vol. (1), Pg. 34, 1997.

oral-rat LD50 2500 mg/kg
Food and Cosmetics Toxicology. Vol. 16, Pg. 703, 1978.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
IFRA Critical Effect: Sensitization
IFRA: View Standard
Fragrance usage is IFRA RESTRICTED. View Standard for complete information.
Please review all IFRA documents for complete information.
IFRA categories: limits in the finished product: (For a description of the categories, refer to the IFRA QRA Information Booklet.)
Category 1:
See Note (1)
0.07 % (1)
Category 2:  0.08 %
Category 3:  0.35 %
Category 4:  1.04 %
Category 5:  0.55 %
Category 6:
See Note (1)
1.67 % (1)
Category 7:  0.17 %
Category 8:  2.00 %
Category 9:  5.00 %
Category 10:  2.50 %
Category 11: See Note (2)
 Notes:
 

(1) IFRA would recommend that any material used to impart perfume or flavour in products intended for human ingestion should consist of ingredients that are in compliance with appropriate regulations for foods and food flavourings in the countries of planned distribution and, where these are lacking, with the recommendations laid down in the Code of Practice of IOFI (International Organisation of the Flavor Industry). Further information about IOFI can be found on its website (www.iofi.org).

 

(2) Category 11 includes all non-skin contact or incidental skin contact products. Due to the negligible skin contact from these types of products there is no justification for a restriction of the concentration of this fragrance ingredient in the finished product.

 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.49 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 241.00 (μg/capita/day)
Structure Class: III
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
 average usual ppmaverage maximum ppm
baked goods: -25.00000
beverages(nonalcoholic): -8.30000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: 85.00000160.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -5.60000
fruit ices: -5.60000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -23.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 59 (FGE.59): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 (2006) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010)
View page or View pdf

EPI System: View
NLM Hazardous Substances Data Bank:Search
Chemical Carcinogenesis Research Information System:Search
Toxicology Citations:Search
Env. Mutagen Info. Center:Search
EPA Substance Registry Services (TSCA):103-50-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :7657
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 3082
WGK Germany:2
phenylmethoxymethylbenzene
Chemidplus:0000103504
EPA/NOAA CAMEO:hazardous materials
RTECS:DQ6125000 for cas# 103-50-4
 
References:
 phenylmethoxymethylbenzene
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:103-50-4
Pubchem (cid):7657
Pubchem (sid):134972229
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
CHEBI:View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB32078
FooDB:FDB008793
Export Tariff Code:2909.30.6000
Haz-Map:View
VCF-Online:VCF Volatile Compounds in Food
Formulations/Preparations:
grade: technical
 
Potential Blenders and core components note
For Odor
anisic
para-
acetanisole
FL/FR
balsamic
benzyl cinnamate
FL/FR
(E)-
benzyl tiglate
FL/FR
methyl (E)-cinnamate
FL/FR
methyl cinnamate
FL/FR
terpinyl cinnamate
FL/FR
berry
raspberry ketone methyl ether
FL/FR
camphoreous
butyrophenone
FL/FR
creamy
butyl lactate
FL/FR
earthy
benzyl tiglate
FL/FR
heptanal cyclic acetal with glycerol
FL/FR
heptanal glyceryl acetal
FL/FR
methyl undecylenate
FL/FR
1-
nonen-3-ol
FL/FR
3-
octanol
FL/FR
1-
octen-3-ol
FL/FR
1-
octen-3-one
FL/FR
ethereal
cyclohexyl formate
FL/FR
fatty
(E)-2-
decenal
FL/FR
methyl 10-undecenoate
FL/FR
fermented
butyl laevo-lactate
FL/FR
floral
alpha-
amyl cinnamyl acetate
FL/FR
iso
butyl salicylate
FL/FR
cassie absolute
FL/FR
para-
cresyl acetate
FL/FR
beta-
damascenone
FL/FR
6,8-
dimethyl-2-nonanol
FR
herbal pyran
FR
para-
methyl acetophenone
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
nonyl octanoate
FL/FR
octyl acetate
FL/FR
phenethyl butyl ether
FR
2-
phenyl propionaldehyde dimethyl acetal
FL/FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
para-
tolualdehyde propylene glycol acetal
FL/FR
fruity
allyl 2-ethyl butyrate
FL/FR
allyl benzoate
FR
allyl isovalerate
FL/FR
bitter
almond oil
FL/FR
iso
amyl 2-methyl butyrate
FL/FR
amyl butyrate
FL/FR
para-
anisyl propionate
FL/FR
benzaldehyde
FL/FR
benzaldehyde / methyl anthranilate schiff's base
FR
benzaldehyde glycrol acetal
FL/FR
bread thiophene
FL/FR
butyl propionate
FL/FR
cherry oxyacetate
FL/FR
cherry pentenoate
FL/FR
cherry propanol
FL/FR
cyclohexyl cinnamate
FL/FR
4-
ethyl benzaldehyde
FL/FR
ethyl benzoyl acetate
FL/FR
ethyl isovalerate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
heptyl isobutyrate
FL/FR
3-
methyl-2-butenal
FL/FR
octyl propionate
FL/FR
prunus amygdalus amara seed extract
FL/FR
meta-
tolualdehyde
FL/FR
para-
tolualdehyde
FL/FR
tolualdehydes (mixed o,m,p)
FL/FR
fungal
1-
decen-3-ol
FL/FR
methyl 2-furoate
FL/FR
green
earthy acetal
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
(Z)-
leaf acetal
FL/FR
lilac acetaldehyde
FL/FR
melon acetal
FL/FR
(E)-2-
pentenal
FL/FR
phenethyl isopropyl ether
FR
phenyl acetaldehyde dimethyl acetal
FL/FR
herbal
3-
octanone
FL/FR
laevo-
perillaldehyde
FL/FR
honey
phenethyl furoate
FL/FR
metallic
1,4-
dipentyl-6,8-dioxabicyclo(3.2.1)octane
FR
mushroom
3-
octen-2-ol
FL/FR
(R)-1-
octen-3-ol
FL/FR
1-
octen-3-yl butyrate
FL/FR
naphthyl
2,4-
dimethyl benzaldehyde
FL/FR
nutty
nutty cyclohexenone
FL/FR
phenolic
2'-
hydroxyacetophenone
FL/FR
powdery
para-
anisyl acetate
FL/FR
spicy
para-
anisyl formate
FL/FR
(E)-
cinnamyl isovalerate
FL/FR
cinnamyl isovalerate
FL/FR
(E)-para-
methoxycinnamaldehyde
FL/FR
para-
methoxycinnamaldehyde
FL/FR
waxy
methyl laurate
FL/FR
(Z)-3-
nonen-1-ol
FL/FR
woody
spicy pentanone
FL/FR
yeasty
2-
octen-4-one
FL/FR
For Flavor
No flavor group found for these
para-
anisyl propionate
FL/FR
benzyl tiglate
FL/FR
butyrophenone
FL/FR
cyclohexyl cinnamate
FL/FR
earthy acetal
FL/FR
ethyl 2-phenyl-3-furoate
FL
4-
ethyl benzaldehyde
FL/FR
furfural diethyl acetal
FL
heptanal cyclic acetal with glycerol
FL/FR
heptanal glyceryl acetal
FL/FR
(E)-para-
methoxycinnamaldehyde
FL/FR
methyl (E)-cinnamate
FL/FR
methyl furfuracrylate
FL
tris(
methyl thio) methane
FL
nonyl octanoate
FL/FR
1,5-
octadien-3-ol
FL
(E)-2-
penten-1-ol
FL
2-
pentyl-1-buten-3-one
FL
phenethyl furoate
FL/FR
para-
tolualdehyde propylene glycol acetal
FL/FR
anisic
anisic
para-
acetanisole
FL/FR
aromatic
para-
cresyl acetate
FL/FR
laevo-
perillaldehyde
FL/FR
balsamic
(E)-
benzyl tiglate
FL/FR
berry
heptyl isobutyrate
FL/FR
raspberry ketone methyl ether
FL/FR
bitter
methyl ethoxypyrazine
FL
buttery
butyl laevo-lactate
FL/FR
caramellic
methyl 2-furoate
FL/FR
cherry
para-
methoxycinnamaldehyde
FL/FR
coffee
difurfuryl ether
FL
cooling
iso
butyl salicylate
FL/FR
creamy
acetyl ethyl carbinol
FL
para-
methyl acetophenone
FL/FR
dairy
butyl lactate
FL/FR
earthy
alpha-
amyl cinnamyl acetate
FL/FR
1-
decen-3-ol
FL/FR
1-
nonen-3-ol
FL/FR
1,8-
octane dithiol
FL
1-
octen-3-one
FL/FR
tamarind distillates
FL
2-
thienyl disulfide
FL
estery
octyl propionate
FL/FR
ethereal
allyl 2-ethyl butyrate
FL/FR
fatty
dimethyl sulfoxide
FL
(Z)-3-
hexen-1-yl benzoate
FL/FR
fermented
methyl thio isovalerate
FL
fruity
allyl isovalerate
FL/FR
bitter
almond oil
FL/FR
iso
amyl 2-methyl butyrate
FL/FR
amyl butyrate
FL/FR
para-
anisyl acetate
FL/FR
benzaldehyde
FL/FR
benzaldehyde glycrol acetal
FL/FR
bread thiophene
FL/FR
butyl propionate
FL/FR
cherry oxyacetate
FL/FR
cherry pentenoate
FL/FR
cherry propanol
FL/FR
cinnamyl isovalerate
FL/FR
(E)-
cinnamyl isovalerate
FL/FR
ethyl benzoyl acetate
FL/FR
ethyl isovalerate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
lilac acetaldehyde
FL/FR
3-
methyl-2-butenal
FL/FR
2-
phenyl propionaldehyde dimethyl acetal
FL/FR
spicy pentanone
FL/FR
terpinyl cinnamate
FL/FR
meta-
tolualdehyde
FL/FR
tolualdehydes (mixed o,m,p)
FL/FR
green
cyclohexyl formate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
(Z)-
leaf acetal
FL/FR
melon acetal
FL/FR
(E)-2-
pentenal
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
mushroom
3-
octanone
FL/FR
3-
octen-2-ol
FL/FR
(R)-1-
octen-3-ol
FL/FR
1-
octen-3-ol
FL/FR
1-
octen-3-yl butyrate
FL/FR
musty
3-
octanol
FL/FR
naphthyl
2,4-
dimethyl benzaldehyde
FL/FR
2'-
hydroxyacetophenone
FL/FR
nutty
nutty cyclohexenone
FL/FR
prunus amygdalus amara seed extract
FL/FR
powdery
powdery ketone
FL
spicy
para-
anisyl formate
FL/FR
benzyl cinnamate
FL/FR
cassie absolute
FL/FR
methyl cinnamate
FL/FR
para-
tolualdehyde
FL/FR
sulfurous
1-(
methyl thio)-2-butanone
FL
2-
naphthyl mercaptan
FL
tea
red rooibos
tea leaf distillates
FL
vegetable
2-
octen-4-one
FL/FR
waxy
(E)-2-
decenal
FL/FR
methyl 10-undecenoate
FL/FR
methyl laurate
FL/FR
methyl undecylenate
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
(Z)-3-
nonen-1-ol
FL/FR
octyl 2-furoate
FL
octyl acetate
FL/FR
woody
beta-
damascenone
FL/FR
 
Potential Uses:
FRalmond
FRbalsam
FRearth
FRfungus
FRgeranium
FRherbal
FRlavender
FRnarcissus
 plastic
FRrose
FRwoody
 
Occurrence (nature, food, other):note
 dill oil
Search Trop Picture
 dill plant
Search Trop Picture
 not found in nature
 
Synonyms:
 benzene, 1,1'-(oxybis(methylene))bis-
 benzene, 1,1'-[oxybis(methylene)]bis-
 benzene, 1,1'-oxybis(methylene-
 benzene,1'-[oxybis(methylene)]bis-
 benzyl ether
 benzyl oxide
 di benzyl ether
 dibenzyl ether FCC
 dibenzyl oxide
 dibenzylether
 ether, dibenzyl
1,1-oxybismethylene, bis benzene
1,1'-oxybis(methylene) benzene
1,1'-(oxybis(methylene)) bisbenzene
1,1-(oxybis(methylene))bisbenzene
1,1'-(oxybis(methylene))bisbenzene
1,1'-[oxybis(methylene)]dibenzene
 phenylmethoxymethylbenzene
 plasticator BA
 plastikator BA
 
 
Notes:
Flavouring ingredient
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