eugenyl formate
4-(2-propenyl)-2-methoxyphenyl formate
 
Notes:
Flavouring ingredient
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(2-methoxy-4-prop-2-enylphenyl) formate (Click)
CAS Number: 10031-96-6Picture of molecule
ECHA EINECS - REACH Pre-Reg: 233-099-6
FDA UNII: USW3U3L49G
Nikkaji Web: J69.596C
Beilstein Number: 3270015
CoE Number: 355
XlogP3: 2.30 (est)
Molecular Weight: 192.21424000
Formula: C11 H12 O3
NMR Predictor: Predict (works with chrome or firefox)
EFSA/JECFA Comments: According to JECFA: Min. assay value is "94 %" and secondary components "eugenol". Register name to be changed to Eugenyl formate.
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
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Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 1530  eugenyl formate
Flavis Number: 09.088 (Old)
DG SANTE Food Flavourings: 09.088  eugenyl formate
FEMA Number: 2473  eugenyl formate
FDA Mainterm: EUGENYL FORMATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
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Physical Properties:
Appearance: pale yellow clear liquid (est)
Assay: 94.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 1.11500 to 1.12500 @  25.00 °C.
Pounds per Gallon - (est).: 9.278 to  9.361
Refractive Index: 1.52400 to 1.52650 @  20.00 °C.
Boiling Point: 270.00 °C. @ 760.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure: 0.006000 mm/Hg @ 25.00 °C. (est)
Flash Point: 235.00 °F. TCC ( 112.78 °C. )
logP (o/w): 1.962 (est)
Soluble in:
 alcohol
 water, 339.9 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items: note
allyl formate
amyl formate
isoamyl formate
para-anisyl formate
benzyl formate
bornyl formate
isobornyl formate
butyl formate
isobutyl formate
sec-butyl formate
carvyl formate
cedryl formate
cinnamyl formate
citronellyl formate
para-cresyl formate
cyclododecyl formate
cyclohexyl formate
2-decalinyl formate
decyl formate
dimethyl benzyl carbinyl formate
ethyl formate
isoeugenyl formate
furfuryl formate
S-furfuryl thioformate
geranyl formate
heptyl formate
(E)-2-hexen-1-yl formate
(E)-3-hexen-1-yl formate
3-hexen-1-yl formate
(Z)-3-hexen-1-yl formate
hexyl formate
linalyl formate
menthadienyl formate
menthyl formate
laevo-menthyl formate
2-methyl butyl formate
methyl formate
myrtenyl formate
neryl formate
nonisyl formate
nonyl formate
nopyl formate
octyl formate
3-octyl formate
phenethyl formate
2-phenoxyethyl formate
3-phenyl propyl formate
prenyl formate
propyl formate
isopropyl formate
isopulegyl formate
rhodinyl formate
styralyl formate
sulfuryl formate
terpinyl formate
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Organoleptic Properties:
 
Odor Type: orris
 
Odor Strength: medium
 
 warm  woody  orris  dry  
Odor Description:
at 100.00 %. 
warm woody orris dry
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
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Suppliers:
BOC Sciences
For experimental / research use only.
4-Allyl-2-methoxyphenyl formate
Parchem
Eugenyl Formate
Chemical Sources Association
Need This Item for Flavor/Food?: You can contact the Chemical Sources Association
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Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
12 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50  3400 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 689, 1982.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 689, 1982.

Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for eugenyl formate usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.06 (μg/capita/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): --
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: -0.20000
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: --
fruit ices: --
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
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Safety References:
European Food Safety Athority(efsa): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Flavouring Group Evaluation 60 (FGE.60): Consideration of eugenol and related hydroxyallylbenzene derivatives evaluated by JECFA (65th meeting) structurally related to ring- substituted phenolic substances evaluated by EFSA in FGE.22 (2006)
View page or View pdf
EPI System: View
NLM Hazardous Substances Data Bank: Search
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 24835
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 (2-methoxy-4-prop-2-enylphenyl) formate
Chemidplus: 0010031966
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References:
 (2-methoxy-4-prop-2-enylphenyl) formate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 10031-96-6
Pubchem (cid): 24835
Pubchem (sid): 134990481
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS): View
HMDB (The Human Metabolome Database): HMDB37877
FooDB: FDB017030
Export Tariff Code: 2915.13.0000
Haz-Map: View
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 salvia atropatana bunge oil iran 
amber
 amber caraneFR
 musk indenofuranFR
anise
 estragon absoluteFR
sweet fennel seed oilFL/FR
anisic
 ocimum basilicum herb oilFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
balsamic
 cinnamyl alcoholFL/FR
 clover nitrileFR
 croton glabellus bark extractFL/FR
 frankincense absoluteFL/FR
 guaiyl acetateFL/FR
 khella oilFR
 myrrh resinoidFR
 opoponax absolute (balsamodendron kafal)FL/FR
2-phenyl propyl alcoholFL/FR
 valeriana wallichii root oilFR
citrus
 ocimene quintoxideFL/FR
earthy
3-octanolFL/FR
 octyl phenyl acetateFL/FR
floral
 amyl salicylateFL/FR
 bois de rose oil brazilFL/FR
isobutyl salicylateFL/FR
 butyl salicylateFL/FR
 cassie absoluteFL/FR
 cassis specialtyFR
 coranol (Firmenich)FR
 dihydrojasmoneFL/FR
 dihydrolinaloolFL/FR
3,6-dimethyl-3-octanolFL/FR
 ethyl linaloolFR
 ethyl linalyl acetalFR
 ethyl linalyl acetateFR
 ethyl linalyl etherFL/FR
 geranium oil bourbonFL/FR
 ho leaf oilFR
 ho wood oilFR
laevo-linaloolFL/FR
dextro-linaloolFL/FR
 linaloolFL/FR
 linalool oxideFL/FR
 linalyl anthranilateFL/FR
 mimosa absoluteFL/FR
 mimosa absolute franceFL/FR
 mimosa absolute indiaFL/FR
 phenyl propyl phenyl acetateFR
 propyl salicylateFR
 rose absolute (rosa damascena) bulgariaFL/FR
 rose concrete (rosa centifolia)FR
 tetrahydrolinaloolFL/FR
 methyl heptanoateFL/FR
green
 carrot leaf oil (daucus carota ssp.maximus)FR
 octanal diethyl acetalFL/FR
 phenyl acetaldehydeFL/FR
herbal
 acorus calamus rhizome oilFR
 anethum graveolens herb oilFL/FR
 anthemis nobilis flower oil romanFL/FR
sweet basil absoluteFL/FR
 calamintha clinopodium oilFR
 canarium luzonicum oilFL/FR
 carrot seed oil (daucus carota ssp. gummifer hook. fil.) spainFR
 clary sage oil franceFL/FR
 coriander oleoresinFL/FR
 daucus carota fruit oilFL/FR
 dill seed oilFL/FR
 dill seed oil CO2 extractFL/FR
 dill weed oil cubaFL/FR
 dill weed oil reunionFL/FR
 hop absoluteFL/FR
 hop oilFL/FR
 linalyl acetateFL/FR
 nonisyl acetateFR
curled parsley seed oilFL/FR
 petroselinum crispum seed oil CO2 extractFL/FR
common tansy flower oilFR
common tansy flower oil dutchFR
 theaspiraneFL/FR
minty
 betula lenta bark oil americaFL/FR
5- and 6-isopropyl-1,3,3-trimethyl bicyclo(2.2.2)-5,7-octadien-2-one 
musk
 musk indanoneFR
para-isopropyl acetophenoneFL/FR
peppery
 asarum europaeum oilFR
phenolic
4-methyl-2,6-dimethoxyphenolFL/FR
saffron
 saffron stigmates absoluteFR
spicy
 allspice berry absoluteFL/FR
 allspice berry oilFL/FR
 allspice leaf oilFL/FR
 allspice oilFL/FR
 allspice oleoresinFL/FR
 anona squamosa leaf oilFR
 artemisia dracunculus herb oilFL/FR
 atractylis root oilFR
 atractylodes lancea root 
 ayou wood oilFR
isobutyl angelateFL/FR
 calamus leaf oilFR
 canella bark oilFR
 carrot weed oilFL/FR
 carvacrolFL/FR
 caryophylleneFL/FR
beta-caryophylleneFL/FR
alpha-caryophyllene alcoholFL/FR
 cascarilla oil replacerFL/FR
 cassia bark oil chinaFL/FR
 cassia leaf oilFL/FR
 cinnamaldehyde dimethyl acetalFL/FR
 cinnamon bark oilFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) indiaFL/FR
 cinnamon bark oil ceylonFL/FR
 cinnamon leaf oil ceylonFL/FR
 cinnamon oleoresin ceylonFL/FR
 clove bud absoluteFL/FR
 clove bud concreteFR
 clove bud oilFL/FR
 clove bud oil CO2 extractFL/FR
 clove bud oleoresinFL/FR
 clove leaf oilFL/FR
 clove leaf oil terpenelessFL/FR
 clove stem oilFL/FR
 croton eluteria bark oilFL/FR
 cubeb oilFL/FR
 cumin seed absoluteFL/FR
black currant bud absoluteFL/FR
 dihydroeugenolFL/FR
1,5-dimethyl-3-n-pentyl-2-oxabicyclo(2.2.2)octane 
4-ethyl guaiacolFL/FR
 ethyl isoeugenolFL/FR
isoeugenolFL/FR
 eugenolFL/FR
 eugenyl acetateFL/FR
 eugenyl benzoateFL/FR
 eugenyl isovalerateFL/FR
isoeugenyl phenyl acetateFL/FR
 galangal root oilFL/FR
 ginger oleoresin africaFL/FR
 ginger root oil brazilFL/FR
 ginger root oil chinaFL/FR
 grains of paradise oilFL/FR
 green oxaneFR
 mace absoluteFL/FR
 mace oilFL/FR
 machilus kusanoi leaf oilFR
 machilus kusanoi wood oilFR
 maja fragranceFR
 mastic fruit oil 
 methyl eugenolFL/FR
4-methyl guaiacolFL/FR
 methyl heptadienoneFL/FR
 methyl isoeugenolFL/FR
 myristica fragrans fruit extractFL/FR
 myristica fragrans seed tinctureFL/FR
 nutmeg oilFL/FR
2-octanolFL/FR
 orthodon dianthera maxim. oil vietnam 
black pepper absoluteFL/FR
 pepper hexanoneFR
black pepper oil CO2 extractFL/FR
 pepper tree berry absoluteFL/FR
 pepper tree berry oilFL/FR
 pepper tree berry oil CO2 extract 
 pimenta acris leaf oilFL/FR
 piper longum fruit oilFL/FR
 piper longum fruit oil CO2 extractFL/FR
 safroleCS
 spicy carbonateFR
 sugandha kokila berry oilFR
(E)-tiglic acidFL/FR
 turmeric root absoluteFL/FR
 zingiber officinale root extractFL/FR
 zingiber officinale root tinctureFL/FR
sulfurous
 lychee mercaptan acetateFL/FR
terpenic
para-cymeneFL/FR
 juniper branch oilFR
 pine needle oil dwarfFL/FR
thujonic
common tansy leaf oil dutch 
common tansy oil canadaFR
beta-thujone 
vanilla
 vanilla cresolFR
 vanillin propylene glycol acetalFL/FR
woody
ar-abietatriene 
isocaryophylleneCS
 caryophyllene alcohol acetateFR
 caryophyllene formateFL/FR
beta-caryophyllene oxideFL/FR
atlas cedarwood oilFR
 cedrela wood oilFR
alpha-copaene 
 curcuma zedoaria bark extractFL/FR
 dacrydium franklinii wood oilFR
 frankincense resinoidFL/FR
(E)-germacrene DFL/FR
 guaiacwood oilFL/FR
 guaiacwood oil 20% in gurjun balsam oilFR
 guaiacyl acetateFL/FR
 hedychium spicatum root oilFR
 jatamansi root oilFR
 juniper berry oleoresinFL/FR
 methyl methylene tricyclodecanolFR
gamma-muurolene 
 patchouli absoluteFR
4-isopropyl phenolFL/FR
 rhubarb oxiraneFR
 sabineneFL/FR
 santal penten-2-olFR
 spicy pentanoneFL/FR
 spikenard oilFL/FR
 spikenard oil CO2 extractFL/FR
 zedoary bark oilFL/FR
 zedoary root oilFL/FR
 zedoary root oil CO2 extractFL/FR
 
For Flavor
 
No flavor group found for these
ar-abietatriene 
 atractylodes lancea root 
 butyl salicylateFL/FR
alpha-caryophyllene alcoholFL/FR
 caryophyllene formateFL/FR
alpha-copaene 
 costus root absoluteFL
 costus root resinoidFL
 croton glabellus bark extractFL/FR
 ethyl linalyl etherFL/FR
 eugenyl benzoateFL/FR
 eugenyl isovalerateFL/FR
(E)-germacrene DFL/FR
 grains of paradise oilFL/FR
 guaiyl acetateFL/FR
dextro-linaloolFL/FR
 mastic fruit oil 
 methyl furfuracrylateFL
gamma-muurolene 
 octyl phenyl acetateFL/FR
 orthodon dianthera maxim. oil vietnam 
 piper longum fruit oil CO2 extractFL/FR
5- and 6-isopropyl-1,3,3-trimethyl bicyclo(2.2.2)-5,7-octadien-2-one 
 rose absolute (rosa damascena) bulgariaFL/FR
 salvia atropatana bunge oil iran 
 spikenard oilFL/FR
 spikenard oil CO2 extractFL/FR
common tansy leaf oil dutch 
beta-thujone 
alliaceous
 truffle sulfideFL
anise
sweet fennel seed oilFL/FR
aromatic
 amyl salicylateFL/FR
balsamic
 opoponax absolute (balsamodendron kafal)FL/FR
brown
(E)-tiglic acidFL/FR
burnt
4-isopropyl phenolFL/FR
citrus
 linaloolFL/FR
laevo-linaloolFL/FR
cooling
isobutyl salicylateFL/FR
 theaspiraneFL/FR
floral
 bois de rose oil brazilFL/FR
 dihydrojasmoneFL/FR
 dihydrolinaloolFL/FR
 geranium oil bourbonFL/FR
 linalyl acetateFL/FR
 linalyl anthranilateFL/FR
 tetrahydrolinaloolFL/FR
fruity
 methyl heptanoateFL/FR
 spicy pentanoneFL/FR
green
isobutyl angelateFL/FR
 canarium luzonicum oilFL/FR
 carrot weed oilFL/FR
 cinnamyl alcoholFL/FR
 coriander oleoresinFL/FR
(E,E)-2,4-hexadienalFL
 linalool oxideFL/FR
 methyl heptadienoneFL/FR
 ocimene quintoxideFL/FR
 octanal diethyl acetalFL/FR
2-phenyl propyl alcoholFL/FR
herbal
 anethum graveolens herb oilFL/FR
 anthemis nobilis flower oil romanFL/FR
sweet basil absoluteFL/FR
 clary sage oil franceFL/FR
 daucus carota fruit oilFL/FR
 dill seed oilFL/FR
 dill seed oil CO2 extractFL/FR
 dill weed oil cubaFL/FR
 dill weed oil reunionFL/FR
3,6-dimethyl-3-octanolFL/FR
 hop absoluteFL/FR
 hop oilFL/FR
 ocimum basilicum herb oilFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
curled parsley seed oilFL/FR
 petroselinum crispum seed oil CO2 extractFL/FR
honey
 phenyl acetaldehydeFL/FR
juicy
 lychee mercaptan acetateFL/FR
medicinal
 frankincense absoluteFL/FR
minty
 betula lenta bark oil americaFL/FR
musty
3-octanolFL/FR
orris
 costus root oilFL
phenolic
4-methyl-2,6-dimethoxyphenolFL/FR
pine
 pine needle oil dwarfFL/FR
smoky
 prosopis juliflora wood extractFL
solvent
 methyl phenyl sulfideFL
spicy
 allspice berry absoluteFL/FR
 allspice berry oilFL/FR
 allspice leaf oilFL/FR
 allspice oilFL/FR
 allspice oleoresinFL/FR
 artemisia dracunculus herb oilFL/FR
 carvacrolFL/FR
beta-caryophylleneFL/FR
 caryophylleneFL/FR
 cascarilla oil replacerFL/FR
 cassia bark oil chinaFL/FR
 cassia leaf oilFL/FR
 cassie absoluteFL/FR
 cinnamaldehyde dimethyl acetalFL/FR
 cinnamon bark oilFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) indiaFL/FR
 cinnamon bark oil ceylonFL/FR
 cinnamon leaf oil ceylonFL/FR
 cinnamon oleoresin ceylonFL/FR
 clove bud absoluteFL/FR
 clove bud oilFL/FR
 clove bud oil CO2 extractFL/FR
 clove bud oleoresinFL/FR
 clove leaf oilFL/FR
 clove leaf oil terpenelessFL/FR
 clove stem oilFL/FR
 croton eluteria bark oilFL/FR
 cubeb oilFL/FR
 cumin seed absoluteFL/FR
black currant bud absoluteFL/FR
 dihydroeugenolFL/FR
1,5-dimethyl-3-n-pentyl-2-oxabicyclo(2.2.2)octane 
 ethyl isoeugenolFL/FR
 eugenolFL/FR
isoeugenolFL/FR
 eugenyl acetateFL/FR
isoeugenyl phenyl acetateFL/FR
 galangal root oilFL/FR
 ginger oleoresin africaFL/FR
 ginger root oil brazilFL/FR
 ginger root oil chinaFL/FR
 mace absoluteFL/FR
 mace oilFL/FR
 methyl eugenolFL/FR
 methyl isoeugenolFL/FR
 myristica fragrans fruit extractFL/FR
 myristica fragrans seed tinctureFL/FR
 nutmeg oilFL/FR
2-octanolFL/FR
black pepper absoluteFL/FR
black pepper oil CO2 extractFL/FR
white pepper oleoresinFL
 pepper tree berry absoluteFL/FR
 pepper tree berry oilFL/FR
 pepper tree berry oil CO2 extract 
 pimenta acris leaf oilFL/FR
 piper longum fruit oilFL/FR
para-isopropyl acetophenoneFL/FR
 turmeric oleoresinFL
 turmeric root absoluteFL/FR
 zingiber officinale root extractFL/FR
 zingiber officinale root tinctureFL/FR
terpenic
para-cymeneFL/FR
vanilla
4-methyl guaiacolFL/FR
 vanillin propylene glycol acetalFL/FR
waxy
 mimosa absoluteFL/FR
 mimosa absolute franceFL/FR
 mimosa absolute indiaFL/FR
woody
beta-caryophyllene oxideFL/FR
 curcuma zedoaria bark extractFL/FR
4-ethyl guaiacolFL/FR
 frankincense resinoidFL/FR
 guaiacwood oilFL/FR
 guaiacyl acetateFL/FR
 juniper berry oleoresinFL/FR
 sabineneFL/FR
 zedoary bark oilFL/FR
 zedoary root oilFL/FR
 zedoary root oil CO2 extractFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 cedarFR
 oakmoss mousse de chene mossFR
 orris irisFR
 patchouliFR
 woodyFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 not found in nature
Synonyms   Articles   Notes   Search   Top
Synonyms:
4-allyl-2-methoxyphenol formate
4-allyl-2-methoxyphenyl formate
 eugenol formate
2-methoxy-4-(2-propenyl) phenyl formate
2-methoxy-4-(2-propenyl)phenyl formate
(2-methoxy-4-prop-2-enylphenyl) formate
 phenol, 2-methoxy-4-(2-propen-1-yl)-, formate
 phenol, 2-methoxy-4-(2-propenyl)-, formate
 phenol, 4-allyl-2-methoxy-, formate
4,2-propen-1-yl-2-methoxyphenyl formate
4-(2-propen-1-yl)-2-methoxyphenyl formate
4-(2-propenyl)-2-methoxyphenyl formate
4-(2-propenyl)-2-methoxyphenyl methanoate
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Synonyms   Articles   Notes   Search   Top
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