EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

anisyl propanal / methyl anthranilate schiff's base
canthoxal / methyl anthranilate schiff's base

Sponsors

Name:methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate
CAS Number: 111753-62-9Picture of molecule3D/inchi
Nikkaji Web:J1.558.078J
XlogP3-AA:3.80 (est)
Molecular Weight:311.38097000
Formula:C19 H21 N O3
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
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Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:yellow solid paste (est)
Assay: 90.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:1.09950 to 1.10750 @ 25.00 °C.
Pounds per Gallon - (est).: 9.149 to 9.216
Refractive Index:1.54800 to 1.55700 @ 20.00 °C.
Boiling Point: 465.00 to 466.00 °C. @ 760.00 mm Hg
Flash Point: 230.00 °F. TCC ( 110.00 °C. )
logP (o/w): 5.163 (est)
Shelf Life: 48.00 month(s) or longer if stored properly.
Soluble in:
 alcohol
 water, 1.461 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:medium ,
recommend smelling in a 50.00 % solution or less
Substantivity:400 hour(s) at 100.00 %
sweet anise hawthorn green floral cortex mimosa spicy powdery
Odor Description:at 50.00 % in dipropylene glycol. sweet anise hawthorn green floral cortex mimosa absolute spicy powdery
Luebke, William tgsc, (1988)
Odor sample from: Bedoukian Research, Inc.
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
SCHIFF'S BASE CANTHOXAL-METHYL ANTHRANILATE ≥92.0% (sum of isomers), Kosher
Odor Description:A floral, powdery, spicy note
Used in fine perfumes for its mimosa absolute character.
Prodasynth
CANTHOXALIA ISOMERS SUM >92%
Odor Description:SWEET, ANISE, GREEN, FLORAL
Robertet
Schiff canthoxal
Odor Description:Floral, orange flower, marine
 
Cosmetic Information:
None found
 
Suppliers:
Bedoukian Research
SCHIFF'S BASE CANTHOXAL-METHYL ANTHRANILATE
≥92.0% (sum of isomers), Kosher
Odor: A floral, powdery, spicy note
Use: Used in fine perfumes for its mimosa absolute character.
BOC Sciences
For experimental / research use only.
Benzoic acid 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]-, methyl ester
Charabot
Schiff canthoxal
Odor: Floral, orange flower, marine
Prodasynth
CANTHOXALIA
ISOMERS SUM >92%
Odor: SWEET, ANISE, GREEN, FLORAL
Robertet
Schiff canthoxal
Odor: Floral, orange flower, marine
Vigon International
Methyl Anthranilate / Anisyl Propanal Schiff Base
Odor: SWEET, FLORAL
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
IFRA Critical Effect: Sensitization
IFRA fragrance material specification:
 The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes.
Recommendation for anisyl propanal / methyl anthranilate schiff's base usage levels up to:
  8.0000 % in the fragrance concentrate.
 
Recommendation for anisyl propanal / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):111753-62-9
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :3034267
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate
Chemidplus:0111753629
 
References:
 methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:111753-62-9
Pubchem (cid):3034267
Pubchem (sid):135042434
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2922.49.8050
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
6,7,8-
decen-1-ol
FR
3-
methyl-4-hexyl oxybutyraldehyde
FR
amber
cistus ladaniferus resinoid
FR
balsamic
clover nitrile
FR
fir balsam absolute
FR
citrus
bergamot acetoacetate
FR
citrus floral green fragrance
FR
2,4-
dimethyl-3-cyclohexene-1-methanyl acetate
FR
grapefruit pentanol
FR
floral
cumin carbinol
FR
dictamnus hispanicus oil
FR
dihydroisojasmonate methyl ester
FR
6,8-
dimethyl-2-nonanol
FR
ethyl phenoxyacetate
FR
floral butanal
FR
floral pyranol
FR
floral undecenone
FR
gardenia absolute
FR
gardenia acetal
FR
gardenia concrete
FR
hawthorn acetate
FR
(Z)-4-
hepten-2-yl salicylate
FR
hyacinth ether
FR
hyacinth oil
FR
hydrangea fragrance
FR
jasmin cyclopentanol
FR
jonquil absolute
FR
leerall
FR
lilac absolute
FR
lily fragrance
FR
lily propanol
FR
lotus fragrance
FR
magnolia indene
FR
(2-
methoxy-1-methyl propyl) benzene
FR
(3-
methoxy-2-methyl propyl) benzene
FR
1-(2-
methyl allyl oxy)-2-methyl butane
FR
muguet carboxaldehyde
FR
ocean propanal / methyl anthranilate schiff's base
FR
orchid specialty
FR
orris pyridine 25% IPM
FR
peony alcohol
FR
phenyl acetaldehyde dicitronellyl acetal
FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
rose pyran
FR
sweet pea absolute
FR
5-
tricyclodecenyl acetate
FR
(S,E)-3,7,11-
trimethyldodeca-6,10-dienal
FR
verdyl acetate
FR
violet methyl carbonate
FR
fresh
3-(3-
propen-2-yl phenyl) butanal
FR
fruity
allyl amyl glycolate
FR
cyclohexyl crotonate
FR
dimethyl benzyl carbinyl isobutyrate
FR
green acetate
FR
peach pivalate
FR
fungal
jasmin nonane
FR
green
flower hexene
FR
green cyclopropionate
FR
(Z)-3-
hexen-1-yl angelate
FR
hexen-1-yl oxypropane nitrile
FR
ivy dioxolane
FR
(2-
methoxy-1-methyl butyl) benzene
FR
[(4E,4Z)-5-
methoxy-3-methyl-4-penten-1-yl] benzene
FR
methyl cyclocitrone (IFF)
FR
4-
methyl-4-phenyl pentanone
FR
octyl oxyacetaldehyde
FR
pelargonium graveolens stem leaf extract
FR
phenoxyacetaldehyde 50% in peomosa
FR
hay
hay absolute
FR
herbal
chrysanthemum ketone
FR
dihexyl (E)-fumarate
FR
phenyl acetaldehyde diisoamyl acetal
FR
medicinal
kunzea ericoides leaf oil
FR
melon
watermelon ketone
FR
mossy
veramoss (IFF)
FR
spicy
iso
cyclogeraniol (IFF)
FR
spicy carbonate
FR
tonka
tonka bean absolute
FR
woody
gurjun balsam oil
FR
santall
FR
tobacarol (IFF)
FR
woody acetate
FR
(Z)-
woody amylene
FR
woody propanol
FR
For Flavor
 
Potential Uses:
 angel
FRanise
 apple crabapple
FRapple red
FRapricot
FRbalsam
FRbanana
FL/FRbasil
FRbergamot
FRblackberry
 blossom tropical blossom
FRblueberry
 blueberry whortleberry red whortleberry
FRbouquet
FRboysenberry
FRbutterscotch
FRcabreuva
FRcassia
FRcherry
FRcherry black
FRcherry blossom
 chocolate cacao
FRchristmas blends
FRchypre
FRcolonia
 cookie
FRcotton candy
FRcrabapple blossom
FRcranberry
FRcucumber
FRcurrant
FRdaffodil narcissus
FReglantine sweet briar
 fantasy blends
FL/FRfennel
FRfern fougere
FRfetes
FRfig
FRfir balsam
FL/FRfir needle pine needle
FRfloral
FRforest
FRfrangipanni plumeria
FRfreesia
 fruit dried fruit
FRgardenia
FRgooseberry
FRgrape
FRhawthorn
FRheliotrope
FRherbal
FRhibiscus
FRhoneysuckle chevrefeuille
FRhyacinth jacinthe
 jackfruit
 jam
FRjasmin
 kiwi blossom
FRlicorice
FRlilac lilas syringa
FRlily
FRlinden blossom limeflower tilleul
FRloganberry dewberry
FRlychee
FRmagnolia
FRmango
FRmango flower
 marshmallow
FRmeadow country
 melon watermelon muskmelon cantaloupe
FRmimosa
FRmuguet lily of the valley
FRmulberry
FRmusk
 nectarine
FRoakmoss mousse de chene moss
FRorange blossom
FRoriental
FRpansy
FRpapaya
FRpassion blossom
FRpassion fruit
FRpeach
FRpeach blossom
FRpeony
FRpineapple
FRplum
 plum blossom
FRpomegranate
FRraspberry
FRraspberry black
 redwood
FRrose
FRrose white
 rose wild rose
 starfruit
FRstock evening scented
FRstrawberry
FRsweet pea
FRtobacco
FRtoffee
 tropical
FRtuberose
FL/FRvalerian
FRvanilla
FRviolet
FRwallflower
FRwisteria wistaria glycine
FRwoody
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 benzoic acid, 2-((3-(4-methoxyphenyl)-2-methylpropylidene)amino)-, methyl ester
2-((3-(4-methoxyphenyl)-2-methyl propylidene)amino) benzoic acid methyl ester
 methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate
 methyl anthranilate / anisyl propanal schiff's base
 methyl anthranilate / canthoxal schiff's base
 

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