EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

green cyclopropionate
montaverdi (IFF)

Supplier Sponsors

Fragrance Demo Formulas
Name:[(Z)-hex-3-enyl] cyclopropanecarboxylate
CAS Number: 188570-78-7Picture of molecule3D/inchi
ECHA ELINCS - REACH Pre-Reg:425-200-9
FDA UNII: Search
Nikkaji Web:J2.402.062B
XlogP3-AA:2.30 (est)
Molecular Weight:168.23592000
Formula:C10 H16 O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 98.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:0.93500 to 0.94000 @ 25.00 °C.
Pounds per Gallon - (est).: 7.780 to 7.822
Refractive Index:1.44900 to 1.46600 @ 20.00 °C.
Boiling Point: 225.00 to 226.00 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.086000 mmHg @ 25.00 °C. (est)
Flash Point: 201.00 °F. TCC ( 93.89 °C. )
logP (o/w): 3.240
Shelf Life: 12.00 month(s) or longer if stored properly.
Storage:store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
 alcohol
 water, 76.75 mg/L @ 25 °C (est)
Stability:
 alcoholic lotion
 antiperspirant
 deo stick
 fabric softener
 shampoo
 soap
 
Organoleptic Properties:
Odor Type: green
Odor Strength:medium
Substantivity: > 3 hour(s) at 100.00 %
fresh floral green natural fruit tropical fruit
Odor Description:at 100.00 %. fresh flower shop green natural green tropical fruit
Luebke, William tgsc, (2007)
Odor sample from: International Flavors & Fragrances Inc.
Odor and/or flavor descriptions from others (if found).
IFF
Montaverdi®
Odor Description:Imparts fresh, natural green notes to fragrances. Fruity, apple, pear, green
 
Cosmetic Information:
None found
 
Suppliers:
Apple Flavor & Fragrance
cis-3-Hexenyl cyclopropyl formate
Azelis UK
MONTAVERDI
BOC Sciences
For experimental / research use only.
cis-3-Hexenyl cyclopropyl formate
Ernesto Ventós
MONTAVERDI IFF
Odor: GREEN, FRESH
Fine Fragrances Pvt Ltd
Montaverdi
IFF
Montaverdi®
Odor: Imparts fresh, natural green notes to fragrances. Fruity, apple, pear, green
Indukern F&F
MONTAVERDI
Lluch Essence
MONTAVERDI
M&U International
Montaverdi(IFF# : 131621)
Taytonn ASCC
Montaverdi®
Odor: Fresh, Fruity, Green
The John D. Walsh Company
Montaverdi
Tianjin Danjun International
[(Z)-3-hexenyl] cyclopropanecarboxylate
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
no sensitization at 1.0%
Oral/Parenteral Toxicity:
oral-rat LD50 > 2000 mg/kg

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for green cyclopropionate usage levels up to:
  1.0000 % in the fragrance concentrate.
 
Recommendation for green cyclopropionate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):188570-78-7
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :44152604
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 1993
WGK Germany:1
[(Z)-hex-3-enyl] cyclopropanecarboxylate
Chemidplus:0188570787
 
References:
 [(Z)-hex-3-enyl] cyclopropanecarboxylate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):44152604
Pubchem (sid):135261014
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:291620
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
iso
butyraldehyde
FL/FR
citrus carbaldehyde
FR
decanal (aldehyde C-10)
FL/FR
6,7,8-
decen-1-ol
FR
dodecanal (aldehyde C-12 lauric)
FL/FR
3-
methyl-4-hexyl oxybutyraldehyde
FR
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
animal
iso
butyl quinoline
FR
costus valerolactone
FR
balsamic
iso
amyl benzoate
FL/FR
amyris wood oil
FL/FR
benzyl cinnamate
FL/FR
benzyl salicylate
FL/FR
laevo-
bornyl acetate
FL/FR
iso
bornyl acetate
FL/FR
iso
butyl cinnamate
FL/FR
cinnamyl formate
FL/FR
clover nitrile
FR
ethyl cinnamate
FL/FR
fir balsam absolute
FR
fir needle oil siberia
FL/FR
methyl (E)-cinnamate
FL/FR
3-
phenyl propyl alcohol
FL/FR
berry
raspberry ketone
FL/FR
citrus
bergamot oil
FL/FR
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
citral dimethyl acetal
FL/FR
citrus floral green fragrance
FR
2,4-
dimethyl-3-cyclohexene-1-methanyl acetate
FR
grapefruit pentanol
FR
methyl heptenone
FL/FR
nonanal dimethyl acetal
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
(E)-2-
tetradecenal
FL/FR
2-
tetradecenal
FL/FR
fatty
2-
decenal
FL/FR
floral
acetaldehyde dibutyl acetal
FL/FR
amyl benzoate
FL/FR
alpha-
amyl cinnamaldehyde
FL/FR
iso
amyl salicylate
FL/FR
amyl salicylate
FL/FR
anisyl propanal / methyl anthranilate schiff's base
FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
bois de rose oil brazil
FL/FR
boronia concrete
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
iso
butyl salicylate
FL/FR
citronellyl acetate
FL/FR
citronellyl propionate
FL/FR
coriander seed oil
FL/FR
coriander seed oil CO2 extract
FL/FR
cumin carbinol
FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
dictamnus hispanicus oil
FR
dihydrocarvyl acetate
FL/FR
(±)-2,3-
dihydrofarnesol
FL/FR
dihydroisojasmonate methyl ester
FR
dihydrojasmone
FL/FR
dimethyl anthranilate
FL/FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
6,8-
dimethyl-2-nonanol
FR
ethyl phenoxyacetate
FR
ethyl safranate
FR
farnesol
FL/FR
farnesyl acetate
FL/FR
floral butanal
FR
floral pyranol
FR
floral undecenone
FR
white
frangipani absolute
FR
white
frangipani concrete
FR
freesia specialty
FR
gardenia absolute
FR
gardenia acetal
FR
gardenia concrete
FR
gardenia oxide
FR
geraniol
FL/FR
geranium oil
FL/FR
geranium oil africa
FL/FR
geranyl acetate
FL/FR
geranyl acetone
FL/FR
geranyl formate
FL/FR
heliotropyl acetone
FL/FR
(Z)-4-
hepten-2-yl salicylate
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hexyl lactate
FL/FR
hyacinth ether
FR
hyacinth oil
FR
hydrangea fragrance
FR
hydroxycitronellal
FL/FR
hydroxycitronellal diethyl acetal
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
jasmin cyclopentanol
FR
jonquil absolute
FR
leerall
FR
lilac absolute
FR
lily fragrance
FR
lily propanol
FR
linalool
FL/FR
laevo-
linalool
FL/FR
linalool oxide
FL/FR
linalyl phenyl acetate
FL/FR
lotus fragrance
FR
magnolia indene
FR
(2-
methoxy-1-methyl propyl) benzene
FR
(3-
methoxy-2-methyl propyl) benzene
FR
1-(2-
methyl allyl oxy)-2-methyl butane
FR
methyl dihydrojasmonate
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
muguet carboxaldehyde
FR
muguet dienal
FR
nerol
FL/FR
neroli oil CO2 extract
FL/FR
(E)-
nerolidol
FL/FR
nerolidol
FL/FR
neryl acetate
FL/FR
nonanol
FL/FR
ocean propanal
FL/FR
ocean propanal / methyl anthranilate schiff's base
FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
orchid specialty
FR
papaya isobutyrate
FL/FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
phenyl acetaldehyde dicitronellyl acetal
FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
rhodinol
FL/FR
rhodinyl formate
FL/FR
rose butanoate
FL/FR
(Z)-
rose oxide
FL/FR
laevo-
rose oxide
FL/FR
rose pyran
FR
styralyl formate
FL/FR
sweet pea absolute
FR
terpinyl isobutyrate
FL/FR
tetrahydrolinalool
FL/FR
5-
tricyclodecenyl acetate
FR
verdyl acetate
FR
violet methyl carbonate
FR
ylang ylang flower oil III
FL/FR
fresh
3-(3-
propen-2-yl phenyl) butanal
FR
fruity
allyl amyl glycolate
FR
benzyl methyl ether
FL/FR
benzyl propionate
FL/FR
citronellyl isobutyrate
FL/FR
cyclohexyl crotonate
FR
dimethyl succinate
FL/FR
ethyl 3-methyl valerate
FL/FR
ethyl heptanoate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
green acetate
FR
hexyl acetate
FL/FR
osmanthus flower absolute
FL/FR
peach pivalate
FR
tropical ionone
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
fungal
jasmin nonane
FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
iso
amyl 3-(2-furan) propionate
FL/FR
iso
butyl benzyl carbinol
FL/FR
chrysanthemum oxide
FL/FR
3,7-
dimethyl-6-octenoic acid
FL/FR
earthy acetal
FL/FR
flower hexene
FR
galbanum oil
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl acetoacetate
FL/FR
(Z)-3-
hexen-1-yl angelate
FR
(Z)-3-
hexen-1-yl methyl carbonate
FL/FR
hexen-1-yl oxypropane nitrile
FR
(Z)-3-
hexen-1-yl propionate
FL/FR
hexyl (Z)-tiglate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl tiglate
FL/FR
hyacinth absolute
FL/FR
ivy dioxolane
FR
(Z)-
leaf acetal
FL/FR
melon nonenoate
FL/FR
(2-
methoxy-1-methyl butyl) benzene
FR
[(4E,4Z)-5-
methoxy-3-methyl-4-penten-1-yl] benzene
FR
methyl cyclocitrone (IFF)
FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
4-
methyl-4-phenyl pentanone
FR
octyl oxyacetaldehyde
FR
pelargonium graveolens stem leaf extract
FR
phenyl acetaldehyde dimethyl acetal
FL/FR
phenyl acetaldehyde solution
FL/FR
3-
propyl bicyclo(3.2.1)-6-octen-2-one
FR
styralyl acetate
FL/FR
violet leaf absolute
FL/FR
herbal
chrysanthemum ketone
FR
clary sage absolute
FL/FR
clary sage oil france
FL/FR
coriander oleoresin
FL/FR
daucus carota fruit oil
FL/FR
dihexyl (E)-fumarate
FR
lavender absolute bulgaria
FL/FR
linalyl acetate
FL/FR
2-
methyl butyl salicylate
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
phenyl acetaldehyde diisoamyl acetal
FR
medicinal
kunzea ericoides leaf oil
FR
melon
melon heptenal
FL/FR
watermelon ketone
FR
mossy
veramoss (IFF)
FR
powdery
para-
anisyl alcohol
FL/FR
spicy
benzyl isoeugenol
FL/FR
cinnamyl propionate
FL/FR
iso
cyclogeraniol (IFF)
FR
iso
eugenyl acetate
FL/FR
spicy carbonate
FR
sulfurous
(S)-1-
methoxy-3-heptane thiol
FL/FR
tea
camellia oleifera leaf extract
FL/FR
terpenic
alpha-
terpineol
FL/FR
tonka
tonka bean absolute
FR
vanilla
ethyl vanillin
FL/FR
waxy
3-
decanone
FL/FR
woody
amber carbinol
FR
patchouli ethanone
FR
santall
FR
tobacarol (IFF)
FR
vetiver oil haiti
FL/FR
(Z)-
woody amylene
FR
For Flavor
No flavor group found for these
acetaldehyde dibutyl acetal
FL/FR
amyl benzoate
FL/FR
boronia concrete
FL/FR
3-
decanone
FL/FR
earthy acetal
FL/FR
ethyl 3-methyl valerate
FL/FR
(Z)-3-
hexen-1-yl acetoacetate
FL/FR
hexyl (Z)-tiglate
FL/FR
hyacinth absolute
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
linalyl phenyl acetate
FL/FR
methyl (E)-cinnamate
FL/FR
2-
methyl butyl salicylate
FL/FR
phenyl acetaldehyde solution
FL/FR
styralyl formate
FL/FR
terpinyl isobutyrate
FL/FR
2-
tetradecenal
FL/FR
iso
amyl 3-(2-furan) propionate
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
aldehydic
aldehydic
iso
butyraldehyde
FL/FR
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
amber
iso
butyl benzyl carbinol
FL/FR
aromatic
amyl salicylate
FL/FR
balsamic
benzyl salicylate
FL/FR
laevo-
bornyl acetate
FL/FR
iso
butyl cinnamate
FL/FR
ethyl cinnamate
FL/FR
fir needle oil siberia
FL/FR
berry
heliotropyl acetone
FL/FR
raspberry ketone
FL/FR
citrus
bergamot oil
FL/FR
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
citral dimethyl acetal
FL/FR
linalool
FL/FR
laevo-
linalool
FL/FR
nerol
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
alpha-
terpineol
FL/FR
cooling
iso
butyl salicylate
FL/FR
creamy
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
fatty
2-
decenal
FL/FR
floral
bois de rose oil brazil
FL/FR
cinnamyl propionate
FL/FR
citronellyl acetate
FL/FR
citronellyl propionate
FL/FR
dihydrocarvyl acetate
FL/FR
(±)-2,3-
dihydrofarnesol
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
3,7-
dimethyl-6-octenoic acid
FL/FR
farnesol
FL/FR
farnesyl acetate
FL/FR
geraniol
FL/FR
geranium oil
FL/FR
geranium oil africa
FL/FR
geranyl acetone
FL/FR
linalyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
neroli oil CO2 extract
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
phenethyl alcohol
FL/FR
rhodinol
FL/FR
laevo-
rose oxide
FL/FR
tetrahydrolinalool
FL/FR
tropical ionone
FL/FR
ylang ylang flower oil III
FL/FR
fruity
iso
amyl benzoate
FL/FR
para-
anisyl alcohol
FL/FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
benzyl methyl ether
FL/FR
benzyl propionate
FL/FR
citronellyl isobutyrate
FL/FR
dimethyl anthranilate
FL/FR
dimethyl succinate
FL/FR
ethyl heptanoate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
hexyl acetate
FL/FR
hexyl lactate
FL/FR
(S)-1-
methoxy-3-heptane thiol
FL/FR
osmanthus flower absolute
FL/FR
rhodinyl formate
FL/FR
rose butanoate
FL/FR
styralyl acetate
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
iso
amyl salicylate
FL/FR
chrysanthemum oxide
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
galbanum oil
FL/FR
geranyl acetate
FL/FR
geranyl formate
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl methyl carbonate
FL/FR
(Z)-3-
hexen-1-yl propionate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl tiglate
FL/FR
(Z)-
leaf acetal
FL/FR
linalool oxide
FL/FR
melon heptenal
FL/FR
melon nonenoate
FL/FR
methyl heptenone
FL/FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
(E)-
nerolidol
FL/FR
nerolidol
FL/FR
nonanal dimethyl acetal
FL/FR
papaya isobutyrate
FL/FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
(Z)-
rose oxide
FL/FR
violet leaf absolute
FL/FR
herbal
clary sage absolute
FL/FR
clary sage oil france
FL/FR
coriander oleoresin
FL/FR
coriander seed oil
FL/FR
coriander seed oil CO2 extract
FL/FR
daucus carota fruit oil
FL/FR
lavender absolute bulgaria
FL/FR
honey
phenethyl acetate
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
melon
hydroxycitronellal diethyl acetal
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
spicy
benzyl cinnamate
FL/FR
benzyl isoeugenol
FL/FR
cinnamyl formate
FL/FR
iso
eugenyl acetate
FL/FR
3-
phenyl propyl alcohol
FL/FR
tea
camellia oleifera leaf extract
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
vanilla
ethyl vanillin
FL/FR
waxy
decanal (aldehyde C-10)
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hydroxycitronellal
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
nonanol
FL/FR
(E)-2-
tetradecenal
FL/FR
woody
amyris wood oil
FL/FR
iso
bornyl acetate
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
vetiver oil haiti
FL/FR
 
Potential Uses:
FRfloral
FRfreesia
FRfresh and clean
FRgreen
FRherbal
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 cyclopropane carboxylic acid (3Z)-3-hexen-1-yl ester
(3Z)-hex-3-en-1-yl cyclopropanecarboxylate
[(Z)-hex-3-enyl] cyclopropanecarboxylate
(Z)-3-hexen-1-yl cyclopropionate
cis-3-hexen-1-yl cyclopropionate
(Z)-3-hexenyl cyclopropionate
 montaverdi (IFF)
 
 
Notes:
None found
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