EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

2,4-dimethyl-3-cyclohexene-1-methanyl acetate
citrolate (IFF)

Sponsors

Name:(3,5-dimethyl-1-cyclohex-3-enyl)methyl acetate
CAS Number: 67634-25-7Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:266-830-2
Nikkaji Web:J333.259D
XlogP3-AA:2.10 (est)
Molecular Weight:182.26286000
Formula:C11 H18 O2
NMR Predictor:Predict (works with chrome or firefox)
Also(can) Contains:2,4-dimethyl cyclohex-3-ene-1-methyl acetate
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:pale yellow clear liquid (est)
Assay: 90.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:0.96000 to 0.96900 @ 25.00 °C.
Pounds per Gallon - (est).: 7.988 to 8.063
Specific Gravity:0.96100 to 0.97000 @ 20.00 °C.
Pounds per Gallon - est.: 8.006 to 8.081
Refractive Index:1.46200 to 1.46700 @ 20.00 °C.
Boiling Point: 225.75 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.085000 mm/Hg @ 25.00 °C. (est)
Flash Point: 185.00 °F. TCC ( 85.00 °C. )
logP (o/w): 3.480
Shelf Life: 36.00 month(s) or longer if stored properly.
Storage:store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
 alcohol
 water, 25.89 mg/L @ 25 °C (est)
Insoluble in:
 water
Stability:
 alcoholic lotion
 antiperspirant
 deo stick
 detergent
 fabric softener
 hard surface cleaner
 shampoo
 soap
 
Organoleptic Properties:
Odor Type: citrus
Odor Strength:medium
Substantivity:24 hour(s) at 100.00 %
citrus floral green grapefruit gardenia petal
Odor Description:at 100.00 %. citrus floral green grapefruit gardenia petal
Luebke, William tgsc, (1988)
Odor sample from: International Flavors & Fragrances Inc.
Odor and/or flavor descriptions from others (if found).
IFF
Citrolate™
Odor Description:Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil
Lluch Essence
JAFFARAL
Odor Description:GRAPEFRUIT, RHUBARB , GREEN
Perfumery Laboratory
CITROLATE ™ IFF (CITROLATE ™ IFF)
Odor Description:Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange
Tadimety Aromatics
Agrumenyl Acetate
Odor Description:Citrus, Neroli, Grape Fruit
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Azelis UK
Citrolate™
Services
Ernesto Ventós
FLORALATE IFF
Odor: CITRUS, FRUITY, GRAPEFRUIT, DRY
Global Essence
Jaffaral
IFF
Citrolate™
Odor: Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil
Kun Shan P&A
Floralate
Lluch Essence
JAFFARAL
Odor: GRAPEFRUIT, RHUBARB , GREEN
Penta International
2,4-DIMETHYL-3-CYCLOHEXENE-1-METHANYL ACETATE
Perfumery Laboratory
CITROLATE ™ IFF (CITROLATE ™ IFF)
Odor: Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange
Tadimety Aromatics
Agrumenyl Acetate
Odor: Citrus, Neroli, Grape Fruit
Taytonn
Floralate
The John D. Walsh Company
Floralate
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):67634-25-7
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :106748
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
(3,5-dimethyl-1-cyclohex-3-enyl)methyl acetate
Chemidplus:0067634257
 
References:
 (3,5-dimethyl-1-cyclohex-3-enyl)methyl acetate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:67634-25-7
Pubchem (cid):106748
Pubchem (sid):135062617
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2915.39.9050
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
2-
ethyl-N-methyl-N-(3-methyl phenyl) butyramide
FR
aldehydic
aldehydic
iso
butyraldehyde
FL/FR
decanal (aldehyde C-10)
FL/FR
6,7,8-
decen-1-ol
FR
dodecanal (aldehyde C-12 lauric)
FL/FR
(Z)-4-
dodecenal
FL/FR
mandarine undecenal
FL/FR
3-
methyl-4-hexyl oxybutyraldehyde
FR
nonanal (aldehyde C-9)
FL/FR
TMH aldehyde
FR
tridecanal
FL/FR
balsamic
abies alba cone oil
FR
cinnamyl formate
FL/FR
citronella
4,8-
dimethyl-7-nonen-2-ol
FR
citrus
acetaldehyde citronellyl methyl acetal
FR
benzyl anthranilate
FR
bergamot oil
FL/FR
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
beta-
bisabolol
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
citrus floral green fragrance
FR
citrus ocimenol
FR
citrus specialty
FR
dihydromyrcenol
FL/FR
dimethyl octenone
FR
dodecane nitrile
FR
2-
dodecanone
FL/FR
citrus
floral fragrance
FR
grapefruit indene
FR
grapefruit mercaptan
FL/FR
grapefruit nitrile
FR
grapefruit oil c.p. california
FL/FR
grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo)
FL/FR
grapefruit oil terpeneless
FL/FR
grapefruit pentanol
FR
lime octadienal
FR
lime oil distilled mexico
FL/FR
mandarin oil
FL/FR
mandarin oil italy
FL/FR
3-
methyl-4-(2-methyl butyl oxy) butyraldehyde
FR
myrmac aldehyde
FR
nonanal dimethyl acetal
FL/FR
(+)-
nootkatone
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
sweet
orange peel oil terpeneless
FL/FR
rhubafuran
FR
alpha-
terpinyl methyl ether
FL/FR
(E)-2-
tetradecenal
FL/FR
2-
tetradecenal
FL/FR
(±)-2,4,8-
trimethyl-7-nonen-2-ol
FL/FR
valencene
FL/FR
verbena fragrance
FR
ethereal
ethyl acetate
FL/FR
fatty
2-
decenal
FL/FR
floral
acetaldehyde dibutyl acetal
FL/FR
amyl benzoate
FL/FR
amyl salicylate
FL/FR
anisyl propanal / methyl anthranilate schiff's base
FR
bois de rose oil brazil
FL/FR
boronia concrete
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
cassis oxime 10%
FR
citronellyl acetate
FL/FR
citronellyl propionate
FL/FR
coriander seed oil CO2 extract
FL/FR
cumin carbinol
FR
dictamnus hispanicus oil
FR
dihydrocarvyl acetate
FL/FR
(±)-2,3-
dihydrofarnesol
FL/FR
dihydroisojasmonate methyl ester
FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
6,8-
dimethyl-2-nonanol
FR
2,4-
dimethyl-3-cyclohexene-1-methanol
FR
ethyl phenoxyacetate
FR
farnesol
FL/FR
farnesyl acetate
FL/FR
floral butanal
FR
floral undecenone
FR
gardenia absolute
FR
gardenia acetal
FR
gardenia amide
FR
gardenia concrete
FR
gardenia decalone
FR
gardenia pentyl acetate
FR
geranium oil
FL/FR
geranium oil africa
FL/FR
geranyl acetone
FL/FR
geranyl formate
FL/FR
(Z)-4-
hepten-2-yl salicylate
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hexyl lactate
FL/FR
hyacinth oil
FR
hydrangea fragrance
FR
hydroxycitronellal diethyl acetal
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
jasmin cyclopentanol
FR
jonquil absolute
FR
lilac absolute
FR
lily fragrance
FR
lily propanol
FR
linalool
FL/FR
linalyl phenyl acetate
FL/FR
lotus fragrance
FR
magnolia indene
FR
(2-
methoxy-1-methyl propyl) benzene
FR
(3-
methoxy-2-methyl propyl) benzene
FR
methoxycitronellal
FR
1-(2-
methyl allyl oxy)-2-methyl butane
FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
muguet nitrile
FR
nerol
FL/FR
neroli oil CO2 extract
FL/FR
neroli oil tunisia
FL/FR
nerolidol
FL/FR
(E)-
nerolidol
FL/FR
nerolidyl acetate
FL/FR
neryl acetate
FL/FR
neryl isovalerate
FL/FR
ocean propanal
FL/FR
ocean propanal / methyl anthranilate schiff's base
FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
orchid specialty
FR
palmarosa oil
FL/FR
papaya isobutyrate
FL/FR
peony acetonitrile
FR
petitgrain concrete
FR
petitgrain lemon oil
FL/FR
petitgrain oil morocco
FL/FR
phenyl acetaldehyde dicitronellyl acetal
FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
rhodinyl formate
FL/FR
rose butanoate
FL/FR
laevo-
rose oxide
FL/FR
(Z)-
rose oxide
FL/FR
rose pyran
FR
styralyl formate
FL/FR
sweet pea absolute
FR
terpinyl formate
FL/FR
terpinyl isobutyrate
FL/FR
tetrahydrolinalyl acetate
FR
5-
tricyclodecenyl acetate
FR
(E)-2,5,9-
trimethyl-4,9-decadien-1-al
FR
(S,E)-3,7,11-
trimethyldodeca-6,10-dienal
FR
undecanal dimethyl acetal
FR
verdyl acetate
FR
violet methyl carbonate
FR
ylang ylang flower oil III
FL/FR
fresh
3-(3-
propen-2-yl phenyl) butanal
FR
fruity
benzyl methyl ether
FL/FR
iso
butyl methyl anthranilate
FL/FR
citronellyl isobutyrate
FL/FR
cyclohexyl crotonate
FR
diethyl sebacate
FL/FR
dimethyl succinate
FL/FR
ethyl 3-hydroxyhexanoate
FL/FR
ethyl isobutyrate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
grape butyrate
FL/FR
grapefruit acetal
FR
heptanal cyclic ethylene acetal
FR
(Z)-3-
octen-1-ol
FL/FR
peach pivalate
FR
solanone
FL/FR
tropical ionone
FL/FR
(E)-2-
undecenal
FL/FR
2-
undecenal
FL/FR
fungal
jasmin nonane
FR
green
iso
amyl 3-(2-furan) propionate
FL/FR
iso
butyl benzyl carbinol
FL/FR
chrysanthemum oxide
FL/FR
citrus carbaldehyde / methyl anthranilate schiff's base
FR
3,7-
dimethyl-6-octenoic acid
FL/FR
earthy acetal
FL/FR
flower hexene
FR
green carboxylate
FR
green cyclopropionate
FR
(Z)-3-
hexen-1-yl acetoacetate
FL/FR
(Z)-3-
hexen-1-yl angelate
FR
hexen-1-yl oxypropane nitrile
FR
(Z)-3-
hexen-1-yl pyruvate
FL/FR
hexyl (Z)-tiglate
FL/FR
hyacinth absolute
FL/FR
ivy dioxolane
FR
melon acetal
FL/FR
melon nonenoate
FL/FR
(2-
methoxy-1-methyl butyl) benzene
FR
[(4E,4Z)-5-
methoxy-3-methyl-4-penten-1-yl] benzene
FR
methyl cyclocitrone (IFF)
FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
4-
methyl-4-phenyl pentanone
FR
(Z)-5-
octen-1-ol
FL/FR
octyl oxyacetaldehyde
FR
pelargonium graveolens stem leaf extract
FR
phenyl acetaldehyde solution
FL/FR
herbal
6-
acetoxydihydrotheaspirane
FL/FR
chrysanthemum ketone
FR
clary sage absolute
FL/FR
coriander oleoresin
FL/FR
dihexyl (E)-fumarate
FR
linalyl acetate
FL/FR
2-
methyl butyl salicylate
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
3-
octyl acetate
FL/FR
phenyl acetaldehyde diisoamyl acetal
FR
alpha-
terpinyl acetate
FL/FR
medicinal
kunzea ericoides leaf oil
FR
melon
(Z)-6-
nonen-1-yl acetate
FL/FR
(Z)-6-
nonenal
FL/FR
spicy
cinnamyl propionate
FL/FR
iso
cyclogeraniol (IFF)
FR
spicy carbonate
FR
sulfurous
grapefruit menthane
FL/FR
tea
camellia oleifera leaf extract
FL/FR
terpenic
(E,E)-2,6-allo
ocimene
FL/FR
waxy
decanal dimethyl acetal
FL/FR
3-
decanone
FL/FR
1-
undecanol
FL/FR
For Flavor
No flavor group found for these
acetaldehyde dibutyl acetal
FL/FR
6-
acetoxydihydrotheaspirane
FL/FR
amyl benzoate
FL/FR
boronia concrete
FL/FR
iso
butyl methyl anthranilate
FL/FR
beta-
cubebene
FL
decanal dimethyl acetal
FL/FR
3-
decanone
FL/FR
(±)-2,3-
dihydrofarnesol
FL/FR
dihydronootkatone
FL
(Z)-4-
dodecenal
FL/FR
earthy acetal
FL/FR
(Z)-3-
hexen-1-yl acetoacetate
FL/FR
hexyl (Z)-tiglate
FL/FR
hyacinth absolute
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
linalyl phenyl acetate
FL/FR
mandarine undecenal
FL/FR
4-
mercapto-4-methyl-2-pentanol
FL
2-
methyl butyl salicylate
FL/FR
nerolidyl acetate
FL/FR
(E,E)-2,6-allo
ocimene
FL/FR
phenyl acetaldehyde solution
FL/FR
solanone
FL/FR
styralyl formate
FL/FR
terpinyl isobutyrate
FL/FR
2-
tetradecenal
FL/FR
iso
amyl 3-(2-furan) propionate
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
aldehydic
aldehydic
iso
butyraldehyde
FL/FR
nonanal (aldehyde C-9)
FL/FR
1-
undecanol
FL/FR
amber
iso
butyl benzyl carbinol
FL/FR
aromatic
amyl salicylate
FL/FR
citrus
bergamot oil
FL/FR
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
beta-
bisabolol
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
dehydronootkatone
FL
grapefruit mercaptan
FL/FR
grapefruit oil c.p. california
FL/FR
grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo)
FL/FR
grapefruit oil terpeneless
FL/FR
lime oil distilled mexico
FL/FR
linalool
FL/FR
mandarin oil
FL/FR
mandarin oil italy
FL/FR
nerol
FL/FR
neroli oil tunisia
FL/FR
(+)-
nootkatone
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
sweet
orange peel oil terpeneless
FL/FR
petitgrain lemon oil
FL/FR
petitgrain oil morocco
FL/FR
(±)-2,4,8-
trimethyl-7-nonen-2-ol
FL/FR
valencene
FL/FR
ethereal
ethyl acetate
FL/FR
ethyl isobutyrate
FL/FR
fatty
2-
decenal
FL/FR
(E,E)-2,4-
dodecadienal
FL
2-
dodecanone
FL/FR
(Z)-3-
octen-1-ol
FL/FR
floral
bois de rose oil brazil
FL/FR
cinnamyl propionate
FL/FR
citronellyl acetate
FL/FR
citronellyl propionate
FL/FR
dihydrocarvyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
3,7-
dimethyl-6-octenoic acid
FL/FR
farnesol
FL/FR
farnesyl acetate
FL/FR
geranium oil
FL/FR
geranium oil africa
FL/FR
geranyl acetone
FL/FR
linalyl acetate
FL/FR
neroli oil CO2 extract
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
laevo-
rose oxide
FL/FR
tropical ionone
FL/FR
ylang ylang flower oil III
FL/FR
fruity
benzyl methyl ether
FL/FR
citronellyl isobutyrate
FL/FR
diethyl sebacate
FL/FR
dimethyl succinate
FL/FR
ethyl 3-hydroxyhexanoate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
hexyl lactate
FL/FR
neryl isovalerate
FL/FR
rhodinyl formate
FL/FR
rose butanoate
FL/FR
terpinyl formate
FL/FR
grassy
palmarosa oil
FL/FR
green
chrysanthemum oxide
FL/FR
clary sage absolute
FL/FR
dihydromyrcenol
FL/FR
geranyl formate
FL/FR
grape butyrate
FL/FR
(Z)-3-
hexen-1-yl pyruvate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
melon acetal
FL/FR
melon nonenoate
FL/FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
(E)-
nerolidol
FL/FR
nerolidol
FL/FR
nonanal dimethyl acetal
FL/FR
(Z)-6-
nonen-1-yl acetate
FL/FR
(Z)-6-
nonenal
FL/FR
(Z)-5-
octen-1-ol
FL/FR
3-
octyl acetate
FL/FR
papaya isobutyrate
FL/FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
(Z)-
rose oxide
FL/FR
herbal
coriander oleoresin
FL/FR
coriander seed oil CO2 extract
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
melon
hydroxycitronellal diethyl acetal
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
spicy
cinnamyl formate
FL/FR
sulfurous
grapefruit menthane
FL/FR
1-
methyl thio-2-propanone
FL
tea
camellia oleifera leaf extract
FL/FR
waxy
decanal (aldehyde C-10)
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
(E)-2-
tetradecenal
FL/FR
tridecanal
FL/FR
2-
undecenal
FL/FR
(E)-2-
undecenal
FL/FR
woody
(1S,5R)-
myrtenyl acetate
FL/FR
alpha-
terpinyl acetate
FL/FR
alpha-
terpinyl methyl ether
FL/FR
 
Potential Uses:
FRcitrus
FRgrapefruit
FRgreen
 melon watermelon muskmelon cantaloupe
FL/FRorange bitter orange peel
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 agrumenyl acetate (Tadimety)
 citrolate (IFF)
3-cyclohexene-1-methanol, 3,5-dimethyl-, acetate
3,5-dimethyl cyclohex-3-ene-1-methyl acetate
(3,5-dimethyl-1-cyclohex-3-enyl)methyl acetate
2,4-dimethyl-3-cyclohexene-1-methanyl acetate
3,5-dimethyl-3-cyclohexene-1-methyl acetate
3,5-dimethylcyclohex-3-ene-1-methyl acetate
 floralate
 jaffaral
 

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Notes:
To overcome the candy sweet notes from lemon and orange oils.
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