EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

gardenia acetal
floropal (Symrise)

Sponsors

Fragrance Demo Formulas
Name:2,4,6-trimethyl-4-phenyl-1,3-dioxane
CAS Number: 5182-36-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:225-963-6
Nikkaji Web:J58.033C
XlogP3-AA:2.70 (est)
Molecular Weight:206.28486000
Formula:C13 H18 O2
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 90.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Boiling Point: 278.00 to 279.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.007000 mm/Hg @ 25.00 °C. (est)
Flash Point: 237.00 °F. TCC ( 113.89 °C. )
logP (o/w): 2.920 (est)
Soluble in:
 alcohol
 water, 90.26 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:medium
Substantivity:68 hour(s) at 100.00 %
fresh citrus gardenia green natural
Odor Description:at 100.00 %. fresh citrus gardenia green natural
Luebke, William tgsc, (1986)
Odor sample from: Harrmann & Reimer Corporation
Odor and/or flavor descriptions from others (if found).
Symrise
Floropal
Odor Description:fresh, green-floral, reminiscent of rhubarb, grapefruit, chrysanthemum, with nuances of cypress and gardenia
Stable in: body lotion (good), shampoo (very good), soap (very good), ap roll-on (very good), powder (very good), cleaner citric (good), cleaner apc (very good), bleach (very good).
Symrise
Vertacetal® coeur
Odor Description:fresh, radiant grapefruit note
Stable in: body lotion (very good), shampoo (excellent), soap (good), ap roll-on (good), powder (very good), cleaner citric (good), cleaner apc (very good), bleach (very good).
Takasago
Lorexan®
Odor Description:Fresh, citrus, gardenia, green, natural
Used in many perfume compositions especially in citrus and floral accords. Gives a citrus clean natural note.
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Associate Allied Chemicals
Floropal
About
Associate Allied Chemicals
Vertacetal
BOC Sciences
For experimental / research use only.
Floropal
Creatingperfume.com
Floropal (Symrise)
Odor: Fruity, grapefruit, rhubarb, gardenia
Ernesto Ventós
FLOROPAL SYMRISE
Odor: HERBAL-FRESH, FLORAL, GRAPEFRUIT
Indukern F&F
FLOROPAL
Odor: FLORAL, FRESH, GARDENIA
Moellhausen
FLOROPAL
Penta International
2,4,6-TRIMETHYL-4-PHENYL-1,3-DIOXANE, Kosher
Perfumery Laboratory
FLOROPAL ™ Symrise (Floropal ™ Symrise)
Odor: Bright floral fragrance of gardenia, green rhubarb with a touch of grapefruit
Symrise
Floropal
Odor: fresh, green-floral, reminiscent of rhubarb, grapefruit, chrysanthemum, with nuances of cypress and gardenia
Use: Stable in: body lotion (good), shampoo (very good), soap (very good), ap roll-on (very good), powder (very good), cleaner citric (good), cleaner apc (very good), bleach (very good).
Symrise
Vertacetal® coeur
Odor: fresh, radiant grapefruit note
Use: Stable in: body lotion (very good), shampoo (excellent), soap (good), ap roll-on (good), powder (very good), cleaner citric (good), cleaner apc (very good), bleach (very good).
Tadimety Aromatics
Floracetal
Odor: Fresh, Green-Floral reminiscent of rhubarb, Grapefruit, Chrysanthemum
Takasago
Lorexan®
Odor: Fresh, citrus, gardenia, green, natural
Use: Used in many perfume compositions especially in citrus and floral accords. Gives a citrus clean natural note.
The Fragrance Museum
The John D. Walsh Company
Floropal
The Lermond Company
Floropal
The Perfumers Apprentice
Floropal
Odor: herbalfresh, floral-green, similar to chrysanthemum, cyprus, and grapefruit
The Perfumers Apprentice
Vertacetal Coeur (Floropal)
Odor: fresh citrus gardenia green natural
Vigon International
Floropal
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 38 - Irritating to skin.
S 02 - Keep out of the reach of children.
S 24 - Avoid contact with skin.
S 37 - Wear suitable gloves.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
100%: mild skin irritation.
Oral/Parenteral Toxicity:
oral-rat LD50 > 2000 mg/kg
Used in many perfume compositions especially in citrus and floral accords. Gives a citrus clean natural note.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for gardenia acetal usage levels up to:
  6.0000 % in the fragrance concentrate.
 
Recommendation for gardenia acetal flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):5182-36-5
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :107381
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
2,4,6-trimethyl-4-phenyl-1,3-dioxane
Chemidplus:0005182365
 
References:
Leffingwell:Chirality or Article
 2,4,6-trimethyl-4-phenyl-1,3-dioxane
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:5182-36-5
Pubchem (cid):107381
Pubchem (sid):135064347
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):HMDB36025
FooDB:FDB014843
Export Tariff Code:2932.99.80900
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
2-
ethyl-N-methyl-N-(3-methyl phenyl) butyramide
FR
aldehydic
aldehydic
iso
butyraldehyde
FL/FR
decanal (aldehyde C-10)
FL/FR
6,7,8-
decen-1-ol
FR
dodecanal (aldehyde C-12 lauric)
FL/FR
green hexanal
FL/FR
mandarine undecenal
FL/FR
3-
methyl-4-hexyl oxybutyraldehyde
FR
TMH aldehyde
FR
balsamic
cinnamyl formate
FL/FR
citronella
4,8-
dimethyl-7-nonen-2-ol
FR
citrus
acetaldehyde citronellyl methyl acetal
FR
benzyl anthranilate
FR
bergamot oil
FL/FR
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
beta-
bisabolol
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
citrus floral green fragrance
FR
citrus ocimenol
FR
citrus specialty
FR
(E)-4-
decenal
FL/FR
dihydromyrcenol
FL/FR
2,4-
dimethyl-3-cyclohexene-1-methanyl acetate
FR
2-
dodecanone
FL/FR
citrus
floral fragrance
FR
lime octadienal
FR
lime oil distilled mexico
FL/FR
mandarin oil
FL/FR
mandarin oil (citrus reticulata nova var. mandarin) uruguay
FL/FR
mandarin oil italy
FL/FR
3-
methyl-4-(2-methyl butyl oxy) butyraldehyde
FR
nonanal dimethyl acetal
FL/FR
(+)-
nootkatone
FL/FR
rhubafuran
FR
tangerine acetate
FR
(E)-2-
tetradecenal
FL/FR
2-
tetradecenal
FL/FR
(±)-2,4,8-
trimethyl-7-nonen-2-ol
FL/FR
verbena fragrance
FR
fatty
2-
decenal
FL/FR
floral
acetaldehyde dibutyl acetal
FL/FR
amyl benzoate
FL/FR
amyl salicylate
FL/FR
anisyl propanal / methyl anthranilate schiff's base
FR
bois de rose oil brazil
FL/FR
boronia concrete
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
cinnamyl phenyl acetate
FL/FR
citronellyl acetate
FL/FR
citronellyl butyrate
FL/FR
citronellyl propionate
FL/FR
coriander seed oil CO2 extract
FL/FR
cumin carbinol
FR
cuminyl acetaldehyde
FL/FR
cyclamen aldehyde
FL/FR
dictamnus hispanicus oil
FR
dihydrocarvyl acetate
FL/FR
(±)-2,3-
dihydrofarnesol
FL/FR
dihydroisojasmonate methyl ester
FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
6,8-
dimethyl-2-nonanol
FR
ethyl 2-benzyl butyrate
FL/FR
ethyl phenoxyacetate
FR
farnesol
FL/FR
farnesyl acetate
FL/FR
floral butanal
FR
floral undecenone
FR
gardenia absolute
FR
gardenia concrete
FR
gardenia decalone
FR
gardenia oxide
FR
gardenia pentyl acetate
FR
geranium oil
FL/FR
geranium oil africa
FL/FR
geranyl acetone
FL/FR
geranyl formate
FL/FR
(Z)-4-
hepten-2-yl salicylate
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hexyl lactate
FL/FR
hyacinth oil
FR
hydrangea fragrance
FR
hydroxycitronellal diethyl acetal
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
jasmin cyclopentanol
FR
para-
jasmone
FR
jonquil absolute
FR
leerall
FR
lilac absolute
FR
lily fragrance
FR
lily propanol
FR
linalool
FL/FR
linalyl phenyl acetate
FL/FR
lotus fragrance
FR
magnolia indene
FR
(2-
methoxy-1-methyl propyl) benzene
FR
(3-
methoxy-2-methyl propyl) benzene
FR
1-(2-
methyl allyl oxy)-2-methyl butane
FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
muguet nitrile
FR
nerol
FL/FR
neroli oil CO2 extract
FL/FR
neroli oil tunisia
FL/FR
(E)-
nerolidol
FL/FR
nerolidol
FL/FR
nerolidyl acetate
FL/FR
ocean propanal
FL/FR
ocean propanal / methyl anthranilate schiff's base
FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
orchid specialty
FR
palmarosa oil
FL/FR
papaya isobutyrate
FL/FR
peony acetonitrile
FR
petitgrain concrete
FR
petitgrain lemon oil
FL/FR
petitgrain oil morocco
FL/FR
phenethyl butyl ether
FR
phenyl acetaldehyde dicitronellyl acetal
FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
phenyl glycol diacetate
FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
rhodinyl formate
FL/FR
rose butanoate
FL/FR
(Z)-
rose oxide
FL/FR
laevo-
rose oxide
FL/FR
rose pyran
FR
styralyl formate
FL/FR
styralyl propionate
FL/FR
sweet pea absolute
FR
terpinyl isobutyrate
FL/FR
tetrahydrolinalyl acetate
FR
5-
tricyclodecenyl acetate
FR
(S,E)-3,7,11-
trimethyldodeca-6,10-dienal
FR
undecanal dimethyl acetal
FR
verdyl acetate
FR
violet methyl carbonate
FR
ylang ylang flower oil III
FL/FR
fresh
3-(3-
propen-2-yl phenyl) butanal
FR
fruity
benzyl methyl ether
FL/FR
citronellyl isobutyrate
FL/FR
cyclohexyl crotonate
FR
dimethyl succinate
FL/FR
ethyl levulinate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
peach pivalate
FR
rhubarb pyran
FR
rhubarb undecane
FR
4-(para-
tolyl)-2-butanone
FL/FR
tropical ionone
FL/FR
fungal
jasmin nonane
FR
green
acetaldehyde dipropyl acetal
FL/FR
iso
amyl 3-(2-furan) propionate
FL/FR
benzyl hexanoate
FL/FR
iso
butyl benzyl carbinol
FL/FR
chrysanthemum carbaldehyde
FR
chrysanthemum oxide
FL/FR
3,5,6-neo
cyclocitral
FR
decanal propylene glycol acetal
FL/FR
3,7-
dimethyl-6-octenoic acid
FL/FR
earthy acetal
FL/FR
flower hexene
FR
green cyclopropionate
FR
green dioxolane
FR
iso
green methanoindene
FR
(Z)-3-
hexen-1-yl acetoacetate
FL/FR
(Z)-3-
hexen-1-yl angelate
FR
(Z)-3-
hexen-1-yl oxyacetaldehyde
FR
hexen-1-yl oxypropane nitrile
FR
hexyl (Z)-tiglate
FL/FR
hyacinth absolute
FL/FR
3,6-
ivy carbaldehyde
FL/FR
2,4-
ivy carbaldehyde
FL/FR
ivy carbaldehyde
FL/FR
3,5-
ivy carbaldehyde
FL/FR
ivy carbaldehyde / methyl anthranilate schiff's base
FR
ivy dioxolane
FR
melon heptenal propylene glycol acetal
FL/FR
(2-
methoxy-1-methyl butyl) benzene
FR
[(4E,4Z)-5-
methoxy-3-methyl-4-penten-1-yl] benzene
FR
methyl cyclocitrone (IFF)
FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
4-
methyl-4-phenyl pentanone
FR
octanal diethyl acetal
FL/FR
(E)-2-
octen-1-ol
FL/FR
octyl oxyacetaldehyde
FR
pelargonium graveolens stem leaf extract
FR
phenyl acetaldehyde
FL/FR
phenyl acetaldehyde solution
FL/FR
styralyl acetate
FL/FR
herbal
chrysanthemum ketone
FR
clary sage absolute
FL/FR
coriander oleoresin
FL/FR
dihexyl (E)-fumarate
FR
ethyl chrysanthemate
FR
linalyl acetate
FL/FR
2-
methyl butyl salicylate
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
phenyl acetaldehyde diisoamyl acetal
FR
tagette carboxylate
FR
alpha-
terpinyl acetate
FL/FR
marine
marine hexane
FR
medicinal
kunzea ericoides leaf oil
FR
spicy
cinnamyl propionate
FL/FR
iso
cyclogeraniol (IFF)
FR
spicy carbonate
FR
tea
camellia oleifera leaf extract
FL/FR
terpenic
(E,E)-2,6-allo
ocimene
FL/FR
alpha-
terpineol
FL/FR
waxy
decanal dimethyl acetal
FL/FR
3-
decanone
FL/FR
1-
undecanol
FL/FR
woody
rhubarb oxirane
FR
For Flavor
No flavor group found for these
acetaldehyde dibutyl acetal
FL/FR
amyl benzoate
FL/FR
benzyl hexanoate
FL/FR
boronia concrete
FL/FR
cinnamyl phenyl acetate
FL/FR
decanal dimethyl acetal
FL/FR
decanal propylene glycol acetal
FL/FR
3-
decanone
FL/FR
(±)-2,3-
dihydrofarnesol
FL/FR
earthy acetal
FL/FR
ethyl 2-benzyl butyrate
FL/FR
(Z)-3-
hexen-1-yl acetoacetate
FL/FR
hexyl (Z)-tiglate
FL/FR
hyacinth absolute
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
3,5-
ivy carbaldehyde
FL/FR
ivy carbaldehyde
FL/FR
linalyl phenyl acetate
FL/FR
mandarine undecenal
FL/FR
melon heptenal propylene glycol acetal
FL/FR
2-
methyl butyl salicylate
FL/FR
nerolidyl acetate
FL/FR
(E,E)-2,6-allo
ocimene
FL/FR
phenyl acetaldehyde solution
FL/FR
styralyl formate
FL/FR
terpinyl isobutyrate
FL/FR
2-
tetradecenal
FL/FR
iso
amyl 3-(2-furan) propionate
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
aldehydic
aldehydic
iso
butyraldehyde
FL/FR
1-
undecanol
FL/FR
amber
iso
butyl benzyl carbinol
FL/FR
aromatic
amyl salicylate
FL/FR
citrus
bergamot oil
FL/FR
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
beta-
bisabolol
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
lime oil distilled mexico
FL/FR
linalool
FL/FR
mandarin oil
FL/FR
mandarin oil (citrus reticulata nova var. mandarin) uruguay
FL/FR
mandarin oil italy
FL/FR
nerol
FL/FR
neroli oil tunisia
FL/FR
(+)-
nootkatone
FL/FR
petitgrain lemon oil
FL/FR
petitgrain oil morocco
FL/FR
styralyl propionate
FL/FR
alpha-
terpineol
FL/FR
(±)-2,4,8-
trimethyl-7-nonen-2-ol
FL/FR
fatty
2-
decenal
FL/FR
2-
dodecanone
FL/FR
(E)-2-
octen-1-ol
FL/FR
floral
bois de rose oil brazil
FL/FR
cinnamyl propionate
FL/FR
citronellyl acetate
FL/FR
citronellyl propionate
FL/FR
dihydrocarvyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
3,7-
dimethyl-6-octenoic acid
FL/FR
farnesol
FL/FR
farnesyl acetate
FL/FR
geranium oil
FL/FR
geranium oil africa
FL/FR
geranyl acetone
FL/FR
linalyl acetate
FL/FR
neroli oil CO2 extract
FL/FR
ocean propanal
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
laevo-
rose oxide
FL/FR
tropical ionone
FL/FR
ylang ylang flower oil III
FL/FR
fruity
benzyl methyl ether
FL/FR
citronellyl butyrate
FL/FR
citronellyl isobutyrate
FL/FR
dimethyl succinate
FL/FR
ethyl levulinate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
hexyl lactate
FL/FR
rhodinyl formate
FL/FR
rose butanoate
FL/FR
styralyl acetate
FL/FR
4-(para-
tolyl)-2-butanone
FL/FR
grassy
palmarosa oil
FL/FR
green
acetaldehyde dipropyl acetal
FL/FR
chrysanthemum oxide
FL/FR
clary sage absolute
FL/FR
cuminyl acetaldehyde
FL/FR
cyclamen aldehyde
FL/FR
dihydromyrcenol
FL/FR
geranyl formate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
3,6-
ivy carbaldehyde
FL/FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
nerolidol
FL/FR
(E)-
nerolidol
FL/FR
nonanal dimethyl acetal
FL/FR
octanal diethyl acetal
FL/FR
papaya isobutyrate
FL/FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
(Z)-
rose oxide
FL/FR
herbal
coriander oleoresin
FL/FR
coriander seed oil CO2 extract
FL/FR
green hexanal
FL/FR
honey
phenyl acetaldehyde
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
melon
hydroxycitronellal diethyl acetal
FL/FR
ripe
(E)-4-
decenal
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
spicy
cinnamyl formate
FL/FR
tea
camellia oleifera leaf extract
FL/FR
waxy
decanal (aldehyde C-10)
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
mimosa absolute
FL/FR
mimosa absolute france
FL/FR
mimosa absolute india
FL/FR
(E)-2-
tetradecenal
FL/FR
woody
(1S,5R)-
myrtenyl acetate
FL/FR
alpha-
terpinyl acetate
FL/FR
 
Potential Uses:
FRcitrus
FRfresh and clean
FRgardenia
FRgreen
FRlily
FRlinden flower
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
1,3-dioxane, 2,4,6-trimethyl-4-phenyl-
 floracetal (Tadimety)
 floropal (Symrise)
 gardenia acetal
 lorexan (Takasago)
2,4,6-trimethyl-4-phenyl-[1,3]dioxane
2,4,6-trimethyl-4-phenyl-1,3-dioxane
2,4,6-trimethyl-4-phenyl-m-dioxane
2,4,6-trimethyl-4-phenyl-meta-dioxane
 vertacetaal
 vertacetal (Symrise)
 vertacetal coeur (Symrise)
 

Articles:

 None found yet.
 
Notes:
Fragrance ingredient with a grapefruit-like aroma
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