amber carane
spirambrene (Givaudan)
 
Notes:
None found
  • Azelis
    • Azelis UK Life Sciences
      Chemical Distribution
      Azelis is a leading global distributor of speciality chemicals.
      Azelis is a leading global speciality chemicals distributor. We provide a diverse range of products and innovative services to more than 20,000 customers. Our in-depth local knowledge is supported by an international structure and value-added services including high levels of technical support and tailored solutions.
      Email: Graham Bott
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      Product(s):
      SPIRAMBRENE
       
  • Indukern F&F
  • Moellhausen
    • Moellhausen S.P.A.
      THE CHEMISTRY OF EMOTIONS
      Innovation and commitment in the name of excellence.
      After 50 years in business, Moellhausen stands out as one of the world’s leading family-run companies in the industry of flavors and fragrances, raw materials, and specialties. My personal history is inextricably bound to that of the company, and I continue to dedicate all my energy to it along with our partners and collaborators who have supported us thus far with dedication, passion, love, and experience. Continuous investments and a professionalism aimed at achieving the highest levels of performance in service and quality, along with that same dedication, passion, love, and experience, have together enabled us to reach the absolute avant-garde level that characterizes Moellhausen today, recognized worldwide for its modernity, innovation, creativity, and respect for the environment and the safety and rights of those who work with us. As President and CEO of the company for 32 years, I offer a well-deserved thank you to all of our numerous customers, suppliers, employees, and company friends for helping to sustain our unstoppable and honorable growth. And it is with the support of all of our stakeholders that we will confidently continue to pursue our commitment to further advancing the excellence that our industry demands.
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      Product(s):
      135500 SPIRAMBRENE
       
  • Ernesto Ventós
  • Vigon International
    • Vigon International, Inc.
      Passion for Simplicity
      Manufacturer and supplier of high quality flavor and fragrance ingredients.
      The growth and success of Vigon is due in large part to a unique corporate concept that Vigon has developed and established within the industry: Creative Partnerships. This partnership concept has been and continues to be the foundation and guiding principle for all of Vigon's activities.
      US Email: Sales
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      Products List: View
      Product(s):
      500932 Spirambrene
       
Synonyms   Articles   Notes   Search
Fragrance Demo Formulas
(1'S,4'S,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] (Click)
CAS Number: 121251-67-0Picture of molecule
XlogP3-AA: 3.70 (est)
Molecular Weight: 238.37062000
Formula: C15 H26 O2
NMR Predictor: Predict (works with chrome or firefox)
(1'S,4'R,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] (Click)
CAS Number: 121251-68-1Picture of molecule
XlogP3-AA: 3.70 (est)
Molecular Weight: 238.37062000
Formula: C15 H26 O2
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
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Perfumer and Flavorist: Search
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PubMed: Search
NCBI: Search
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Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 97.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 0.97920 to 0.90000 @  25.00 °C.
Pounds per Gallon - (est).: 8.148 to  7.489
Refractive Index: 1.49400 to 1.50000 @  20.00 °C.
Boiling Point: 251.00 to  252.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.003900 mm/Hg @ 20.00 °C.
Flash Point: 255.00 °F. TCC ( 123.89 °C. )
logP (o/w): 4.900
Soluble in:
 alcohol
 water, 50 mg/L @ 20 °C (exp)
Insoluble in:
 water
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
Odor Type: amber
Odor Strength: medium
 amber  woody  spicy  aldehydic  green  seaweed  
Odor Description:
at 100.00 %. 
amber woody spicy aldehydic green seaweed
Substantivity: 96 Hour(s)
  
Synonyms   Articles   Notes   Search   Top
Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
Synonyms   Articles   Notes   Search   Top
Suppliers:
Azelis
SPIRAMBRENE
Services
CG Herbals
Spirambrene
Odor: Woody-Ambery, Spicy, Aldehydic, Powerful
Use: Spirambrene blends well with sparkling, green, spicy and aldehydic top notes. It is an interesting complement in woody accords for providing a diffusive ambery effect. Due to its high impact, it produces unique and original effects when combined with other woody elements.
Ernesto Ventós
SPIRAMBRENE
Odor: WOODY-AMBERY,SPICY,ALDEHYDIC,POTENT
Givaudan
Spirambrene
Odor: Woody, Ambery, Spicy, Aldehydic, Powerful
Use: Spirambrene blends well with sparkling, green, spicy and aldehydic top notes. It is an interesting complement in woody accords for providing a diffusive ambery effect. Due to its high impact, it produces unique and original effects when combined with other woody elements
Indukern F&F
SPIRAMBRENE
Odor: WOODY, AMBER, ALDEHYDIC, SPICY
CROP CALENDAR
Moellhausen
SPIRAMBRENE
Odor: powerful amber-like, woody and aldehydic note
Vigon International
Spirambrene
Odor: Woody, Ambery, Spicy, Aldehydic, Powerful
Synonyms   Articles   Notes   Search   Top
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant, Dangerous for the environment.
R 38 - Irritating to skin.
R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50  5000 mg/kg

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
Synonyms   Articles   Notes   Search   Top
Safety in Use Information:
Category: fragrance agents
Recommendation for amber carane usage levels up to:
  3.0000 % in the fragrance concentrate.
 
Recommendation for amber carane flavor usage levels up to:
 not for flavor use.
Synonyms   Articles   Notes   Search   Top
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 121251-67-0
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 44152459
National Institute of Allergy and Infectious Diseases: Data
WISER: UN 3082
WGK Germany: 2
 (1'S,4'S,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane]
Chemidplus: 0121251670
 (1'S,4'R,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane]
Chemidplus: 0121251681
Synonyms   Articles   Notes   Search   Top
References:
 (1'S,4'S,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane]
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 121251-67-0
Pubchem (cid): 44152459
Pubchem (sid): 135203301
 (1'S,4'R,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane]
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 121251-68-1
Pubchem (cid): 44154128
Pubchem (sid): 135203302
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
Wikipedia: View
RSC Learn Chemistry: View
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Potential Blenders and core components note
 
For Odor
aldehydic
 citrus carbaldehydeFR
 dodecanal (aldehyde C-12 lauric)FL/FR
amber
 ambroxanFL/FR
 angelica root oilFL/FR
 cistus ladaniferus resinoidFR
animal
 animal carbolactoneFR
isobutyl quinolineFR
 costus valerolactoneFR
para-cresyl caprylateFL/FR
 indoleFL/FR
anisic
para-anisaldehydeFL/FR
balsamic
isoamyl benzoateFL/FR
 amyris wood oilFL/FR
 benzyl cinnamateFL/FR
 benzyl salicylateFL/FR
laevo-bornyl acetateFL/FR
isobutyl cinnamateFL/FR
 cinnamyl alcoholFL/FR
 clover nitrileFR
 fir balsam absoluteFR
 methyl (E)-cinnamateFL/FR
3-phenyl propyl alcoholFL/FR
citrus
 bergamot oil bergaptene reduced italyFL/FR
floral
alpha-amyl cinnamaldehydeFL/FR
isoamyl salicylateFL/FR
 benzyl acetateFL/FR
 benzyl alcoholFL/FR
 benzyl isobutyrateFL/FR
 bois de rose oil brazilFL/FR
isobutyl salicylateFL/FR
 citronellolFL/FR
 citronellyl acetateFL/FR
 coriander seed oilFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
9-decen-1-olFL/FR
 dihydrojasmoneFL/FR
 dimethyl anthranilateFL/FR
 dimethyl benzyl carbinolFL/FR
 ethyl phenyl acetateFL/FR
 floral pyranolFR
 gardenia oxideFR
 geraniolFL/FR
 geranyl acetateFL/FR
 heliotropyl acetoneFL/FR
 heliotropyl diethyl acetalFR
(Z)-3-hexen-1-yl salicylateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 hyacinth etherFR
 leerallFR
 linaloolFL/FR
laevo-linaloolFL/FR
 linalool oxideFL/FR
 methyl dihydrojasmonateFL/FR
 mimosa absolute franceFL/FR
 muguet carboxaldehydeFR
 nerolFL/FR
 nerolidolFL/FR
 neryl acetateFL/FR
 ocean propanalFL/FR
 orris pyridine 25% IPMFR
 peony alcoholFR
 phenethyl acetateFL/FR
 phenethyl alcoholFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl propionateFL/FR
 rhodinolFL/FR
 rose butanoateFL/FR
 violet methyl carbonateFR
fruity
 artemisia pallens herb oilFL/FR
 benzyl propionateFL/FR
(E)-beta-damasconeFL/FR
(E)-alpha-damasconeFL/FR
 dimethyl benzyl carbinyl isobutyrateFR
 green acetateFR
 methyl anthranilateFL/FR
 raspberry ketone methyl etherFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
green
(Z)-3-hexen-1-olFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
2,4-ivy carbaldehydeFL/FR
 melon nonenoateFL/FR
3-phenyl propionaldehydeFL/FR
 styralyl acetateFL/FR
 violet leaf absoluteFL/FR
herbal
 carum carvi fruit oilFL/FR
 clary sage oil franceFL/FR
 daucus carota fruit oilFL/FR
 linalyl acetateFL/FR
alpha-terpinyl acetateFL/FR
melon
 watermelon ketoneFR
mossy
 oakmoss absoluteFL/FR
 veramoss (IFF)FR
powdery
para-anisyl alcoholFL/FR
spicy
 clove bud oilFL/FR
black currant bud absoluteFL/FR
isoeugenyl acetateFL/FR
terpenic
 frankincense oilFL/FR
alpha-terpineolFL/FR
tonka
 tonka bean absoluteFR
vanilla
 ethyl vanillinFL/FR
waxy
1-dodecanolFL/FR
 ethyl laurateFL/FR
woody
 amber carbinolFR
 guaiacwood oilFL/FR
 methyl cedryl ketoneFL/FR
 patchouli ethanoneFR
 santallFR
 vetiver oil haitiFL/FR
 woody acetateFR
(Z)-woody amyleneFR
 woody propanolFR
 
For Flavor
 
No flavor group found for these
laevo-bornyl acetateFL/FR
para-cresyl caprylateFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
9-decen-1-olFL/FR
 dimethyl benzyl carbinolFL/FR
2,4-ivy carbaldehydeFL/FR
laevo-linaloolFL/FR
 methyl (E)-cinnamateFL/FR
 methyl cedryl ketoneFL/FR
 phenethyl propionateFL/FR
animal
 indoleFL/FR
balsamic
 benzyl salicylateFL/FR
isobutyl cinnamateFL/FR
berry
 heliotropyl acetoneFL/FR
 raspberry ketone methyl etherFL/FR
citrus
 bergamot oil bergaptene reduced italyFL/FR
 linaloolFL/FR
 nerolFL/FR
alpha-terpineolFL/FR
cooling
isobutyl salicylateFL/FR
creamy
para-anisaldehydeFL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
floral
 bois de rose oil brazilFL/FR
 citronellolFL/FR
 citronellyl acetateFL/FR
 dihydrojasmoneFL/FR
 geraniolFL/FR
 linalyl acetateFL/FR
 methyl dihydrojasmonateFL/FR
 neryl acetateFL/FR
 ocean propanalFL/FR
 phenethyl alcoholFL/FR
 rhodinolFL/FR
fruity
isoamyl benzoateFL/FR
para-anisyl alcoholFL/FR
 artemisia pallens herb oilFL/FR
 benzyl acetateFL/FR
 benzyl alcoholFL/FR
 benzyl isobutyrateFL/FR
 benzyl propionateFL/FR
(E)-alpha-damasconeFL/FR
 dimethyl anthranilateFL/FR
 methyl anthranilateFL/FR
 rose butanoateFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
 styralyl acetateFL/FR
green
isoamyl salicylateFL/FR
 angelica root oilFL/FR
 cinnamyl alcoholFL/FR
(E)-beta-damasconeFL/FR
 geranyl acetateFL/FR
(Z)-3-hexen-1-olFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
 linalool oxideFL/FR
 melon nonenoateFL/FR
 nerolidolFL/FR
 oakmoss absoluteFL/FR
3-phenyl propionaldehydeFL/FR
 violet leaf absoluteFL/FR
herbal
 carum carvi fruit oilFL/FR
 clary sage oil franceFL/FR
 coriander seed oilFL/FR
 daucus carota fruit oilFL/FR
honey
 ethyl phenyl acetateFL/FR
 phenethyl acetateFL/FR
 phenethyl isobutyrateFL/FR
soapy
 dodecanal (aldehyde C-12 lauric)FL/FR
1-dodecanolFL/FR
spicy
 benzyl cinnamateFL/FR
 clove bud oilFL/FR
black currant bud absoluteFL/FR
isoeugenyl acetateFL/FR
3-phenyl propyl alcoholFL/FR
tropical
alpha-amyl cinnamaldehydeFL/FR
vanilla
 ethyl vanillinFL/FR
waxy
 ethyl laurateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 mimosa absolute franceFL/FR
woody
 ambroxanFL/FR
 amyris wood oilFL/FR
 frankincense oilFL/FR
 guaiacwood oilFL/FR
alpha-terpinyl acetateFL/FR
 vetiver oil haitiFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 aldehydicFR
 amberFR
 greenFR
 spiceFR
 woodyFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 not found in nature
Synonyms   Articles   Notes   Search   Top
Synonyms:
 amber carane
2,3,3,7,7-pentamethyl spiro(1,3-dioxane)-5,2-norcarane
(1,3,6)-2',2',3,7,7-pentamethyl spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane)
(1alpha,3alpha, 6alpha)-2',2',3,7,7-pentamethyl spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane)
 pentamethyl spirobicycloheptane dioxane
(1alpha,3alpha,6alpha)-2',2',3,7,7-pentamethylspiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane)
(1'S,4'R,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane]
(1'S,4'S,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane]
 spirambrene (Givaudan)
 spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane), 2',2',3,7,7-pentamethyl-, (1alpha,3alpha,6alpha)-
 spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane), 2',2',3,7,7-pentamethyl-, (1R,3S,6S)-rel-
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