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2,4-ivy carbaldehyde / methyl anthranilate schiff's base
triplal/methyl anthranilate schiff base

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Fragrance Demo Formulas
Name:methyl 2-[(2,4-dimethyl-1-cyclohex-3-enyl)methylideneamino]benzoate
CAS Number: 68845-02-3Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:272-449-2
FDA UNII: Search
Nikkaji Web:J332.643H
XlogP3-AA:3.10 (est)
Molecular Weight:271.35977000
Formula:C17 H21 N O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
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Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:yellow to orange yellow viscous liquid to solid (est)
Assay: 90.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:1.04650 to 1.05450 @ 25.00 °C.
Pounds per Gallon - (est).: 8.708 to 8.774
Refractive Index:1.52400 to 1.53350 @ 20.00 °C.
Boiling Point: 68.00 °C. @ 4.00 mm Hg
Vapor Density:>1 ( Air = 1 )
Flash Point: 230.00 °F. TCC ( 110.00 °C. )
logP (o/w): 6.321 (est)
Soluble in:
 alcohol
 water, 1.322 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: green
Odor Strength:medium
Substantivity:268 hour(s) at 100.00 %
fresh aldehydic green natural cortex leafy narcissus
Odor Description:at 100.00 %. fresh aldehydic green natural cortex leafy narcissus
Luebke, William tgsc, (1996)
Odor sample from: The Good Scents Company
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
SCHIFF'S BASE TRIPLAL-METHYL ANTHRANILATE ≥90.0% (sum of isomers), Kosher
Odor Description:A very green, floral odor with a citrus note
Used in fine perfumes for its delicate floral citrus odor.
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Benzoic acid,2-[[(2,4-dimethyl-3-cyclohexen-1-yl)methylene]amino]-, methyl ester
Ernesto Ventós
SCHIFF BASE, TRIPLAL/METHYL ANTHRANILATE
Odor: GREEN, FLORAL, ALDEHYDIC, CITRUS
Indukern F&F
SCHIFF BASE TRIPLAL
Lluch Essence
SCHIFF BASE LIGUSTRAL/METHYL ANTHRANILATE
O'Laughlin Industries
VERTOLINE
Penta International
TRIPLAL/METHYL ANTHRANILATE SCHIFF BASE
Perfumer Supply House
Triplal/Methyl Anthranilate Schiff’s Base
Odor: very sweet, green, grassy , leafy, narcissus
Perfumery Laboratory
TRIPLAL / methyl anthranilate Schiff's (Triplal / Methyl Anthranilate Schiff's Base)
Odor: Very sweet, green, herbal, leaf, flower narcissus and orange blossom
Vigon International
Methyl Anthranilate / Triplal Schiff Base
Odor: Fresh-green, narcotic with nuances reminiscent of orange-blossom
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
2,4-ivy carbaldehyde Max. Found: 50.9 % and Reason: Sensitization
 View the IFRA Standard
Recommendation for 2,4-ivy carbaldehyde / methyl anthranilate schiff's base usage levels up to:
  4.0000 % in the fragrance concentrate.
 
Recommendation for 2,4-ivy carbaldehyde / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):68845-02-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :111378
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
methyl 2-[(2,4-dimethyl-1-cyclohex-3-enyl)methylideneamino]benzoate
Chemidplus:0068845023
 
References:
 methyl 2-[(2,4-dimethyl-1-cyclohex-3-enyl)methylideneamino]benzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:68845-02-3
Pubchem (cid):111378
Pubchem (sid):135067580
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2922.49.8050
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
6,7,8-
decen-1-ol
FR
fresh carbaldehyde
FR
muguet undecadienal
FR
octane nitrile
FR
amber
amber carane
FR
animal
para-
cresyl isobutyrate
FL/FR
para-
cresyl phenyl acetate
FL/FR
balsamic
cinnamyl formate
FL/FR
propyl cinnamate
FL/FR
tetrahydrofurfuryl cinnamate
FL/FR
citrus
citral
FL/FR
citral dimethyl acetal
FL/FR
citrus specialty
FR
(E)-4-
decenal
FL/FR
grapefruit pentanol
FR
lime pyran
FR
limonene aldehyde
FR
neroli ketone
FR
petitgrain combava oil
FR
tetrahydrocitral
FL/FR
fatty
2-
decenal
FL/FR
(E,Z)-2,6-
dodecadienal
FL/FR
(E)-2-
octenal
FL/FR
floral
allyl anthranilate
FL/FR
amyl benzoate
FL/FR
alpha-
amyl cinnamaldehyde diethyl acetal
FR
anisyl propanal / methyl anthranilate schiff's base
FR
benzaldehyde propylene glycol acetal
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
citronellyl acetate
FL/FR
citronellyl propionate
FL/FR
para-
cresyl acetate
FL/FR
cumin carbinol
FR
cuminyl acetaldehyde
FL/FR
cyclamen propanal
FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
2,4-
dimethyl cyclohexyl methyl acetate
FR
6,8-
dimethyl-2-nonanol
FR
ethyl 2-benzyl butyrate
FL/FR
farnesyl acetate
FL/FR
floral butanal
FR
geranium oil bourbon
FL/FR
geranyl acetone
FL/FR
geranyl isobutyrate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hydroxycitronellal diethyl acetal
FL/FR
jasmin cyclopentanol
FR
lilac pentanol
FL/FR
magnolia indene
FR
mimosa absolute france
FL/FR
narcissus acetate
FL/FR
neroli oil bigarde
FL/FR
nerolidol
FL/FR
ocean propanal
FL/FR
ocean propanal / methyl anthranilate schiff's base
FR
octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd
FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute morocco
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
papaya isobutyrate
FL/FR
clementine
petitgrain oil
FL/FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
iso
propyl phenyl acetate
FL/FR
reseda acetal
FR
rose absolute (rosa damascena) bulgaria
FL/FR
rose butanoate
FL/FR
laevo-
rose oxide
FL/FR
styralyl formate
FL/FR
tea acetate
FR
terpinyl isobutyrate
FL/FR
verdyl acetate
FR
fresh
3-(3-
propen-2-yl phenyl) butanal
FR
fruity
benzyl methyl ether
FL/FR
dimethyl succinate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
heptanal cyclic ethylene acetal
FR
2-
hexen-1-ol
FL/FR
(E)-2-
hexen-1-ol
FL/FR
peach pivalate
FR
green
acetaldehyde butyl phenethyl acetal
FL/FR
acetaldehyde di-(Z)-3-hexen-1-yl acetal
FL/FR
acetaldehyde ethyl phenethyl acetal
FL/FR
acetaldehyde methyl hexyl acetal
FR
iso
amyl 3-(2-furan) propionate
FL/FR
iso
butyl benzyl carbinol
FL/FR
2-iso
butyl thiazole
FL/FR
chrysanthemum oxide
FL/FR
cilantro leaf oil
FL/FR
cumin acetaldehyde
FL/FR
homo
cuminic aldehyde
FR
3,5,6-neo
cyclocitral
FR
iso
cyclocitral (IFF)
FL/FR
decanal propylene glycol acetal
FL/FR
diphenyl oxide
FL/FR
earthy acetal
FL/FR
fern specialty
FR
flower hexene
FR
galbanum oil
FL/FR
galbanum oil terpeneless
FL/FR
geranium absolute
FL/FR
green carbaldehyde
FR
green specialty
FR
heptyl cinnamate
FL/FR
(Z)-2-
hexen-1-ol
FL/FR
3-
hexen-1-ol
FL/FR
(E)-2-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(Z)-3-
hexen-1-yl lactate
FL/FR
(Z)-3-
hexen-1-yl methyl carbonate
FL/FR
3-
hexenal
FL/FR
hexoxyacetaldehyde dimethyl acetal
FR
hexyl heptanoate
FL/FR
3,5-
ivy carbaldehyde
FL/FR
2,4-
ivy carbaldehyde
FL/FR
ivy carbaldehyde
FL/FR
ivy dioxolane
FR
(Z)-
leaf acetal
FL/FR
leafy acetal
FL/FR
leafy oxime
FR
lilac acetaldehyde
FL/FR
marine specialty
FR
methyl cyclocitrone (IFF)
FR
methyl heptine carbonate
FL/FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
4-
methyl-4-phenyl pentanone
FR
narcissus flower absolute
FR
(E,Z)-2,6-
nonadien-1-yl acetate
FL/FR
octanal dimethyl acetal
FL/FR
(E)-2-
octen-1-yl acetate
FL/FR
(Z)-5-
octen-1-yl propionate
FL/FR
octyl oxyacetaldehyde
FR
olive oil absolute
FL/FR
phenethyl acetal
FR
phenoxyacetaldehyde 50% in benzyl alcohol
FR
phenyl acetaldehyde
FL/FR
3-
phenyl propionaldehyde
FL/FR
iso
propyl phenyl propionaldehyde
FR
iso
propyl quinoline
FR
rose leaf absolute (rosa centifolia)
FL/FR
styralyl acetate
FL/FR
triplal / ethyl anthranilate schiff's base
FR
herbal
sweet
basil absolute
FL/FR
clary sage absolute
FL/FR
herbal heptane
FR
1-(2-
methyl allyl oxy) heptane
FR
marine
marine hexane
FR
minty
iso
pulegyl formate
FL/FR
waxy
allyl nonanoate
FL/FR
decanal diethyl acetal
FL/FR
3-
decanone
FL/FR
For Flavor
No flavor group found for these
acetaldehyde di-(Z)-3-hexen-1-yl acetal
FL/FR
allyl anthranilate
FL/FR
amyl benzoate
FL/FR
decanal propylene glycol acetal
FL/FR
3-
decanone
FL/FR
earthy acetal
FL/FR
ethyl 2-benzyl butyrate
FL/FR
heptyl cinnamate
FL/FR
3-
hexen-1-ol
FL/FR
hexyl heptanoate
FL/FR
3,5-
ivy carbaldehyde
FL/FR
ivy carbaldehyde
FL/FR
iso
pulegyl formate
FL/FR
styralyl formate
FL/FR
terpinyl isobutyrate
FL/FR
tetrahydrocitral
FL/FR
tetrahydrofurfuryl cinnamate
FL/FR
iso
amyl 3-(2-furan) propionate
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
amber
amber
iso
butyl benzyl carbinol
FL/FR
aromatic
para-
cresyl acetate
FL/FR
para-
cresyl isobutyrate
FL/FR
leafy acetal
FL/FR
citrus
cilantro leaf oil
FL/FR
citral
FL/FR
citral dimethyl acetal
FL/FR
clementine
petitgrain oil
FL/FR
fatty
2-
decenal
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(E)-2-
octenal
FL/FR
floral
citronellyl acetate
FL/FR
citronellyl propionate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
farnesyl acetate
FL/FR
geranium oil bourbon
FL/FR
geranyl acetone
FL/FR
geranyl isobutyrate
FL/FR
neroli oil bigarde
FL/FR
ocean propanal
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute morocco
FL/FR
bitter
orangeflower absolute tunisia
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
laevo-
rose oxide
FL/FR
fruity
benzaldehyde propylene glycol acetal
FL/FR
benzyl methyl ether
FL/FR
dimethyl succinate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
2-
hexen-1-ol
FL/FR
lilac acetaldehyde
FL/FR
lilac pentanol
FL/FR
propyl cinnamate
FL/FR
rose butanoate
FL/FR
styralyl acetate
FL/FR
green
acetaldehyde butyl phenethyl acetal
FL/FR
acetaldehyde ethyl phenethyl acetal
FL/FR
2-iso
butyl thiazole
FL/FR
chrysanthemum oxide
FL/FR
cumin acetaldehyde
FL/FR
cuminyl acetaldehyde
FL/FR
iso
cyclocitral (IFF)
FL/FR
(E)-4-
decenal
FL/FR
diphenyl oxide
FL/FR
(E,Z)-2,6-
dodecadienal
FL/FR
galbanum oil
FL/FR
galbanum oil terpeneless
FL/FR
geranium absolute
FL/FR
(Z)-2-
hexen-1-ol
FL/FR
(E)-2-
hexen-1-ol
FL/FR
(E)-2-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl lactate
FL/FR
(Z)-3-
hexen-1-yl methyl carbonate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
3-
hexenal
FL/FR
2,4-
ivy carbaldehyde
FL/FR
(Z)-
leaf acetal
FL/FR
methyl heptine carbonate
FL/FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
narcissus acetate
FL/FR
nerolidol
FL/FR
(E,Z)-2,6-
nonadien-1-yl acetate
FL/FR
octanal dimethyl acetal
FL/FR
(E)-2-
octen-1-yl acetate
FL/FR
(Z)-5-
octen-1-yl propionate
FL/FR
papaya isobutyrate
FL/FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
3-
phenyl propionaldehyde
FL/FR
rose leaf absolute (rosa centifolia)
FL/FR
herbal
sweet
basil absolute
FL/FR
clary sage absolute
FL/FR
honey
phenyl acetaldehyde
FL/FR
iso
propyl phenyl acetate
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
melon
hydroxycitronellal diethyl acetal
FL/FR
oily
olive oil absolute
FL/FR
phenolic
para-
cresyl phenyl acetate
FL/FR
spicy
cinnamyl formate
FL/FR
waxy
allyl nonanoate
FL/FR
decanal diethyl acetal
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
mimosa absolute france
FL/FR
 
Potential Uses:
FRfloral
FRgreen
FRhyacinth
FRhydrangea
FRlilac
FRlily of the valley
FRmagnolia
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 benzoic acid, 2-(((2,4-dimethyl-3-cyclohexen-1-yl)methylene)amino)-, methyl ester
N-(2,4-dimethyl-3-cyclohexenyl) methylidene anthranilic acid methyl ester
N-(2,4-dimethyl-3-cyclohexenyl)methylideneanthranilic acid, methyl ester
 methyl 2-(((2,4-dimethyl-3-cyclohexen-1-yl)methylene)amino) benzoate
 methyl 2-(((2,4-dimethyl-3-cyclohexen-1-yl)methylene)amino)benzoate
 methyl 2-[(2,4-dimethyl-1-cyclohex-3-enyl)methylideneamino]benzoate
 methyl 2-[(2,4-dimethylcyclohex-3-en-1-yl)methylideneamino]benzoate
 methyl anthranilate / 2,4-ivy carbaldehyde schiff's base
 methyl anthranilate / triplal schiff base
 schiff's base triplal-methyl anthranilate
 schiff's base tripleame
 triplal/methyl anthranilate schiff base
 vertoline
 

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