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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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| JECFA Food Flavoring: | 1900 mixture of 2,4-, 3,5- and 3,6-dimethyl-3-cyclohexenylcarbaldehyde |
| FEMA Number: | 4505 mixture of 2,4-, 3,5- and 3,6-dimethyl-3-cyclohexenylcarbaldehyde |
| FDA: | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF): | 27939-60-2 ; (2,4)- AND (3,5)- AND (3,6)-DIMETHYL-3-CYCLOHEXENYLCARBALDEHYDE |
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 95.00 to 100.00 sum of isomers
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.92800 to 0.93500 @ 25.00 °C.
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| Pounds per Gallon - (est).: | 7.722 to 7.780
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| Refractive Index: | 1.46700 to 1.47000 @ 20.00 °C.
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| Boiling Point: | 176.00 to 179.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 99.00 to 101.00 °C. @ 30.00 mm Hg
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| Vapor Pressure: | 0.953000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 148.00 °F. TCC ( 64.44 °C. )
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| logP (o/w): | 2.621 (est) |
| Soluble in: |
| | alcohol | | | water, 311.5 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
| Odor Type: green |
Odor Strength:medium , recommend smelling in a 10.00 % solution or less |
| Substantivity: < 3 hour(s) at 100.00 % |
| green aldehydic weedy herbal cortex privet soapy |
Odor Description:at 10.00 % in dipropylene glycol. green aldehydic weedy herbal cortex privet soapy Luebke, William tgsc, (2009) |
| Odor sample from: International Flavors & Fragrances Inc. |
| Flavor Type: green |
| green weedy aldehydic herbal privet cortex grassy alfalfa |
Taste Description: green weedy aldehydic herbal privet cortex grassy alfalfa Luebke, William tgsc, (2009) |
| Odor and/or flavor descriptions from others (if found). |
| Pell Wall Perfumes |
| Triplal Extra |
Odor Description:green-herbal, citrus-aldehydic, soapy Widely used, versatile green note, particularly good in combination with citrus. Near-identical odour to conventional Triplal but some perfumers would argue it is finer. |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xn - Harmful. |
R 22 - Harmful if swallowed. R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection.
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| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 3100 mg/kg Widely used, versatile green note, particularly good in combination with citrus. Near-identical odour to conventional Triplal but some perfumers would argue it is finer.
oral-rat LD50 3600 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 29S, 1992.
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| Dermal Toxicity: |
skin-rabbit LD50 5000 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 29S, 1992.
skin-rabbit LD50 5000 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 29S, 1992.
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| IFRA Critical Effect: | | Dermal sensitization |
| | View the IFRA Standard |
| View IFRA Standards Library for complete information. |
| Please review Amendment 49 IFRA documentation for complete information. |
| IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): |
| Category 1: Products applied to the lips |
| 0.45 % |
| Category 2: Products applied to the axillae |
| 0.14 % |
| Category 3: Products applied to the face/body using fingertips |
| 2.70 % |
| Category 4: Products related to fine fragrance |
| 2.50 % |
| | Category 5: Products applied to the face and body using the hands (palms), primarily leave-on |
| Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on |
| 0.64 % |
| Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on |
| 0.64 % |
| Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on |
| 0.64 % |
| Category 5D: Baby Creams, baby Oils and baby talc |
| 0.64 % |
| Category 6: Products with oral and lip exposure |
| 1.50 % |
| | Category 7: Products applied to the hair with some hand contact |
| Category 7A: Rinse-off products applied to the hair with some hand contact |
| 5.20 % |
| Category 7B: Leave-on products applied to the hair with some hand contact |
| 5.20 % |
| Category 8: Products with significant anogenital exposure |
| 0.27 % |
| Category 9: Products with body and hand exposure, primarily rinse off |
| 4.90 % |
| | Category 10: Household care products with mostly hand contact |
| Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) |
| 18.00 % |
| Category 10B: Household aerosol/spray products |
| 18.00 % |
| | Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate |
| Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure |
| 9.80 % |
| Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure |
| 9.80 % |
| Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin |
| No Restriction |
| | Notes: |
| IFRA FLAVOR REQUIREMENTS: |
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. |
| |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 24 |
| Click here to view publication 24 |
| | average usual ppm | average maximum ppm |
| baked goods: | 0.20000 | 4.00000 |
| beverages(nonalcoholic): | 0.50000 | 5.00000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | 5.00000 | 50.00000 |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | 0.50000 | 4.00000 |
| fish products: | - | - |
| frozen dairy: | 0.50000 | 10.00000 |
| fruit ices: | 0.50000 | 10.00000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | 0.20000 | 5.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
References:
Other Information:
Potential Blenders and core components note
| For Odor |
| aldehydic |
adoxal (Givaudan) FL/FR |
citrus carbaldehyde FR |
decanal (aldehyde C-10) FL/FR |
6,7,8- decen-1-ol FR |
9- decenal FL/FR |
fresh carbaldehyde FR |
2- methyl undecanal (aldehyde C-12 mna) FL/FR |
nonanal (aldehyde C-9) FL/FR |
octanal (aldehyde C-8) FL/FR |
10- undecenal (aldehyde C-11 undecylenic) FL/FR |
| amber |
amber carane FR |
angelica root oil FL/FR |
| balsamic |
2- acetyl furan FL/FR |
iso amyl benzoate FL/FR |
benzyl benzoate FL/FR |
benzyl salicylate FL/FR |
laevo- bornyl acetate FL/FR |
iso bornyl acetate FL/FR |
cinnamyl alcohol FL/FR |
clover nitrile FR |
ethyl cinnamate FL/FR |
fir needle oil siberia FL/FR |
| citrus |
bergamot oil bergaptene reduced italy FL/FR |
citral FL/FR |
citrus specialty FR |
grapefruit oil c.p. california FL/FR |
grapefruit pentanol FR |
lemon oil c.p. california FL/FR |
lemongrass oil FL/FR |
lime oil distilled mexico FL/FR |
lime pyran FR |
limonene aldehyde FR |
litsea cubeba fruit oil FL/FR |
methyl heptenone FL/FR |
blood orange oil italy FL/FR |
sweet orange peel oil c.p. brazil FL/FR |
tetrahydrocitral FL/FR |
tetrahydromyrcenol FR |
| earthy |
methyl undecylenate FL/FR |
| fatty |
(E,Z)-2,6- dodecadienal FL/FR |
| floral |
alpha- amyl cinnamaldehyde diethyl acetal FR |
iso amyl salicylate FL/FR |
benzyl acetate FL/FR |
benzyl alcohol FL/FR |
benzyl isobutyrate FL/FR |
bois de rose oil brazil FL/FR |
iso butyl salicylate FL/FR |
citronellyl acetate FL/FR |
coriander seed oil FL/FR |
cyclamen aldehyde FL/FR |
cyclamen propanal FR |
cyclohexyl ethyl alcohol FL/FR |
dimethyl benzyl carbinol FL/FR |
floral pyranol FR |
gardenia oxide FR |
geraniol FL/FR |
geranium oil africa FL/FR |
geranyl acetate FL/FR |
heliotropyl diethyl acetal FR |
(Z)-3- hexen-1-yl salicylate FL/FR |
alpha- hexyl cinnamaldehyde FL/FR |
ho leaf oil FR |
hyacinth ether FR |
leerall FR |
lily of the valley fragrance FR |
lily of the valley specialty FR |
linalool FL/FR |
laevo- linalool FL/FR |
linalool oxide FL/FR |
methyl dihydrojasmonate FL/FR |
mimosa absolute france FL/FR |
muguet carboxaldehyde FR |
muguet octadienol FR |
nerol FL/FR |
nerolidol FL/FR |
neryl acetate FL/FR |
ocean propanal FL/FR |
octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd FR |
orris pyridine 25% IPM FR |
peony alcohol FR |
clementine petitgrain oil FL/FR |
petitgrain oil paraguay FL/FR |
phenethyl acetate FL/FR |
phenethyl alcohol FL/FR |
propyl anthranilate FL/FR |
rhodinol FL/FR |
rose butanoate FL/FR |
tetrahydrolinalool FL/FR |
violet methyl carbonate FR |
| fruity |
allyl amyl glycolate FR |
allyl cyclohexyl propionate FL/FR |
allyl hexanoate FL/FR |
bitter almond oil FL/FR |
iso amyl acetate FL/FR |
benzaldehyde FL/FR |
benzyl propionate FL/FR |
diethyl malonate FL/FR |
green acetate FR |
hexyl acetate FL/FR |
methyl 2-methyl valerate FL/FR |
strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR |
gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR |
| green |
acetaldehyde dipropyl acetal FL/FR |
acetaldehyde ethyl phenethyl acetal FL/FR |
acetaldehyde methyl hexyl acetal FR |
iso cyclocitral (IFF) FL/FR |
fern fragrance FR |
galbanum oil FL/FR |
green carbaldehyde FR |
(Z)-3- hexen-1-ol FL/FR |
(Z)-3- hexen-1-yl acetate FL/FR |
(Z)-3- hexen-1-yl benzoate FL/FR |
(Z)-3- hexen-1-yl formate FL/FR |
(Z)-3- hexen-1-yl tiglate FL/FR |
hexyl 2-methyl butyrate FL/FR |
hexyl tiglate FL/FR |
2,4- ivy carbaldehyde FL/FR |
3,6- ivy carbaldehyde FL/FR |
3,5- ivy carbaldehyde FL/FR |
ivy carbaldehyde / methyl anthranilate schiff's base FR |
2,4- ivy carbaldehyde / methyl anthranilate schiff's base FR |
english ivy leaf absolute FR |
(Z)- leaf acetal FL/FR |
melon nonenoate FL/FR |
nerol oxide FL/FR |
(E,Z)-2,6- nonadien-1-ol FL/FR |
(E,Z)-2,6- nonadienal FL/FR |
(E)-2- octen-1-yl acetate FL/FR |
olive oil absolute FL/FR |
phenyl acetaldehyde FL/FR |
3- phenyl propionaldehyde FL/FR |
styralyl acetate FL/FR |
violet leaf absolute FL/FR |
| herbal |
anthemis nobilis flower oil roman FL/FR |
clary acetate FR |
clary sage oil france FL/FR |
daucus carota fruit oil FL/FR |
dihexyl (E)-fumarate FR |
eucalyptus globulus oil FL/FR |
herbal undecanone FR |
lavender absolute bulgaria FL/FR |
linalyl acetate FL/FR |
nopyl acetate FR |
2- pentyl acetate FL/FR |
alpha- terpinyl acetate FL/FR |
| marine |
marine pyridine FR |
| melon |
melon heptenal FL/FR |
watermelon ketone FR |
| phenolic |
methyl benzoate FL/FR |
| powdery |
para- anisyl acetate FL/FR |
| spicy |
iso butyl angelate FL/FR |
| terpenic |
frankincense oil FL/FR |
juniperus communis fruit oil FL/FR |
alpha- terpineol FL/FR |
| waxy |
decanal diethyl acetal FL/FR |
ethyl laurate FL/FR |
| woody |
amber carbinol FR |
patchouli ethanone FR |
spruce needle oil canada FL/FR |
thuja occidentalis leaf oil FL/FR |
vetiver oil haiti FL/FR |
woody acetate FR |
(Z)- woody amylene FR |
woody propanol FR |
| For Flavor |
| No flavor group found for these |
9- decenal FL/FR |
epoxy-2-decenal FL |
3,5- ivy carbaldehyde FL/FR |
propyl anthranilate FL/FR |
tetrahydrocitral FL/FR |
| aldehydic |
| aldehydic |
nonanal (aldehyde C-9) FL/FR |
octanal (aldehyde C-8) FL/FR |
| apple |
(E,Z)-2,6- nonadien-1-ol FL/FR |
| balsamic |
benzyl benzoate FL/FR |
benzyl salicylate FL/FR |
laevo- bornyl acetate FL/FR |
ethyl cinnamate FL/FR |
fir needle oil siberia FL/FR |
| citrus |
bergamot oil bergaptene reduced italy FL/FR |
citral FL/FR |
grapefruit oil c.p. california FL/FR |
lemon oil c.p. california FL/FR |
lemongrass oil FL/FR |
lime oil distilled mexico FL/FR |
linalool FL/FR |
laevo- linalool FL/FR |
litsea cubeba fruit oil FL/FR |
nerol FL/FR |
blood orange oil italy FL/FR |
sweet orange peel oil c.p. brazil FL/FR |
clementine petitgrain oil FL/FR |
alpha- terpineol FL/FR |
| cooling |
iso butyl salicylate FL/FR |
| creamy |
gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR |
| dairy |
2- pentyl acetate FL/FR |
| fatty |
(Z)-3- hexen-1-yl benzoate FL/FR |
10- undecenal (aldehyde C-11 undecylenic) FL/FR |
| floral |
bois de rose oil brazil FL/FR |
citronellyl acetate FL/FR |
geraniol FL/FR |
geranium oil africa FL/FR |
linalyl acetate FL/FR |
methyl dihydrojasmonate FL/FR |
neryl acetate FL/FR |
ocean propanal FL/FR |
phenethyl alcohol FL/FR |
rhodinol FL/FR |
tetrahydrolinalool FL/FR |
| fruity |
allyl cyclohexyl propionate FL/FR |
allyl hexanoate FL/FR |
bitter almond oil FL/FR |
iso amyl acetate FL/FR |
iso amyl benzoate FL/FR |
para- anisyl acetate FL/FR |
benzaldehyde FL/FR |
benzyl acetate FL/FR |
benzyl alcohol FL/FR |
benzyl isobutyrate FL/FR |
benzyl propionate FL/FR |
diethyl malonate FL/FR |
hexyl acetate FL/FR |
methyl 2-methyl valerate FL/FR |
rose butanoate FL/FR |
strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR |
styralyl acetate FL/FR |
| green |
acetaldehyde dipropyl acetal FL/FR |
acetaldehyde ethyl phenethyl acetal FL/FR |
iso amyl salicylate FL/FR |
angelica root oil FL/FR |
iso butyl angelate FL/FR |
cinnamyl alcohol FL/FR |
cyclamen aldehyde FL/FR |
iso cyclocitral (IFF) FL/FR |
cyclohexyl ethyl alcohol FL/FR |
(E,Z)-2,6- dodecadienal FL/FR |
galbanum oil FL/FR |
geranyl acetate FL/FR |
2,4- hexadienal FL |
(Z)-3- hexen-1-ol FL/FR |
(Z)-3- hexen-1-yl acetate FL/FR |
(Z)-3- hexen-1-yl formate FL/FR |
(Z)-3- hexen-1-yl salicylate FL/FR |
(Z)-3- hexen-1-yl tiglate FL/FR |
hexyl 2-methyl butyrate FL/FR |
hexyl tiglate FL/FR |
2,4- ivy carbaldehyde FL/FR |
3,6- ivy carbaldehyde FL/FR |
(Z)- leaf acetal FL/FR |
linalool oxide FL/FR |
melon heptenal FL/FR |
melon nonenoate FL/FR |
methyl heptenone FL/FR |
nerol oxide FL/FR |
nerolidol FL/FR |
(E,Z)-2,6- nonadienal FL/FR |
(E)-2- octen-1-yl acetate FL/FR |
3- phenyl propionaldehyde FL/FR |
violet leaf absolute FL/FR |
| herbal |
anthemis nobilis flower oil roman FL/FR |
celery seed oleoresin FL |
clary sage oil france FL/FR |
coriander seed oil FL/FR |
daucus carota fruit oil FL/FR |
eucalyptus globulus oil FL/FR |
lavender absolute bulgaria FL/FR |
petitgrain oil paraguay FL/FR |
| honey |
phenethyl acetate FL/FR |
phenyl acetaldehyde FL/FR |
| medicinal |
dimethyl benzyl carbinol FL/FR |
| nutty |
2- acetyl furan FL/FR |
| oily |
olive oil absolute FL/FR |
| phenolic |
methyl benzoate FL/FR |
| pungent |
acetaldehyde FL |
| terpenic |
juniperus communis fruit oil FL/FR |
| waxy |
adoxal (Givaudan) FL/FR |
decanal (aldehyde C-10) FL/FR |
decanal diethyl acetal FL/FR |
ethyl laurate FL/FR |
alpha- hexyl cinnamaldehyde FL/FR |
2- methyl undecanal (aldehyde C-12 mna) FL/FR |
methyl undecylenate FL/FR |
mimosa absolute france FL/FR |
| woody |
iso bornyl acetate FL/FR |
frankincense oil FL/FR |
spruce needle oil canada FL/FR |
alpha- terpinyl acetate FL/FR |
thuja occidentalis leaf oil FL/FR |
vetiver oil haiti FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| 3- | cyclohexene-1-carboxaldehyde, 1,2-dimethyl- | | 3- | cyclohexene-1-carboxaldehyde, dimethyl- | | 3- | cyclohexene-1-carboxaldehyde,dimethyl- | | 1,2- | dimethyl cyclohex-3-ene-1-carbaldehyde | | | dimethyl-3-cyclohexene-1-carboxaldehyde | | mixture of 2,4-, 3,5- and 3,6- | dimethyl-3-cyclohexenylcarbaldehyde | | | dimethylcyclohex-3-ene-1-carbaldehyde | | 1,2- | dimethylcyclohex-3-ene-1-carbaldehyde | | | ivy carbaldehyde | | | triplal extra | | | trivertal |
Articles:
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