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(E)-benzyl tiglate
benzyl trans-2-methyl-2-butenoate

Supplier Sponsors

Fragrance Demo Formulas
Name:benzyl (E)-2-methylbut-2-enoate
CAS Number: 37526-88-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:253-544-8
FDA UNII:67UEP899RR
Nikkaji Web:J184.208K
MDL:MFCD00017279
CoE Number:2184
XlogP3-AA:2.80 (est)
Molecular Weight:190.24198000
Formula:C12 H14 O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:846 benzyl trans-2-methyl-2-butenoate
FLAVIS Number:09.494 (Old)
DG SANTE Food Flavourings:09.494 benzyl trans-2-methylcrotonate
FEMA Number:3330 benzyl trans-2-methyl-2-butenoate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):37526-88-8 ; BENZYL TRANS-2-METHYL-2-BUTENOATE
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 95.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:1.02900 to 1.03400 @ 25.00 °C.
Pounds per Gallon - (est).: 8.562 to 8.604
Refractive Index:1.51500 to 1.52100 @ 20.00 °C.
Boiling Point: 139.00 °C. @ 9.00 mm Hg
Boiling Point: 250.00 °C. @ 760.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.001000 mmHg @ 20.00 °C.
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 3.036 (est)
Soluble in:
 alcohol
 ether
 water, 61.75 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: balsamic
Odor Strength:medium
Substantivity: > 24 hour(s) at 100.00 %
balsamic earthy mushroom rose
Odor Description:at 100.00 %. balsamic earthy mushroom rose undertone
sweet balsamic cherry almond
Odor Description:Sweet, balsamic with a cherry / almond nuance
Mosciano, Gerard P&F 17, No. 3, 57, (1992)
Flavor Type: balsamic
balsamic spicy nutty almond
Taste Description: at 10.00 ppm. Balsamic, spice-like with a nutty almond note
Mosciano, Gerard P&F 17, No. 3, 57, (1992)
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
BENZYL TIGLATE ≥97.0%, Kosher
Odor Description:A vegetative, earthy, mushroom
Can lend an earthy note to gardenia, almond, grape, rose.
Taste Description:Musty, mushroom, vegetable notes
Can be used in mushroom flavors and for various root vegetables.
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Bedoukian Research
BENZYL TIGLATE
≥97.0%, Kosher
Odor: A vegetative, earthy, mushroom
Use: Can lend an earthy note to gardenia, almond, grape, rose.
Flavor: Musty, mushroom, vegetable notes
Can be used in mushroom flavors and for various root vegetables.
BOC Sciences
For experimental / research use only.
BENZYL TIGLATE 97.0%
Ernesto Ventós
BENZYL TIGLATE
Odor: VEGETABLE,EARTH,MUSHROOM,ROSE,APPLE
Indukern F&F
BENZYL TIGLATE
Odor: ROSE
Inoue Perfumery
BENZYL TIGLATE
Lluch Essence
BENZYL TIGLATE
Penta International
BENZYL TIGLATE
Santa Cruz Biotechnology
For experimental / research use only.
Tiglic Acid Benzyl Ester
Tadimety Aromatics
Benzyl Tiglate
Odor: balsamic earthy mushroom rose undertone
TCI AMERICA
For experimental / research use only.
Benzyl Tiglate >97.0%(GC)
WholeChem
Benzyl Tiglate
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
10% in petrolatum produced no irritation in humans.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
(Moreno, 1979d)

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for (E)-benzyl tiglate usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.03 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 6
 average usual ppmaverage maximum ppm
baked goods: -8.00000
beverages(nonalcoholic): --
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: -8.00000
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: --
fruit ices: --
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) on a request from the Commission related to Flavouring Group Evaluation 20 (FGE.20): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical group 23
View page or View pdf

Flavouring Group Evaluation 54 (FGE.54)[1] - Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20 (2005) - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf

Flavouring Group Evaluation 20, Revision 1 (FGE.20Rev1): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters from chemical group 23
View page or View pdf

Flavouring Group Evaluation 54, Revision 1 (FGE.54Rev1): Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20Rev1 (2009)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):37526-88-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :250096
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
benzyl (E)-2-methylbut-2-enoate
Chemidplus:0037526888
 
References:
 benzyl (E)-2-methylbut-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:37526-88-8
Pubchem (cid):250096
Pubchem (sid):135019369
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB32177
FooDB:FDB009018
Export Tariff Code:2916.19.6000
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
balsamic
amyris wood oil
FL/FR
siam
benzoin absolute
FL/FR
sumatra
benzoin absolute
FL/FR
benzoin absolute replacer
FL/FR
siam
benzoin CO2 extract
FL/FR
siam
benzoin resin
FL/FR
sumatra
benzoin resinoid
FL/FR
siam
benzoin resinoid
FL/FR
alpha-
bisabolene
FL/FR
iso
bornyl isobutyrate
FL/FR
T-
cadinol
FL/FR
cinnamyl benzoate
FL/FR
cinnamyl formate
FL/FR
copaiba balsam oil
FL/FR
juniper berry oil terpeneless
FL/FR
methyl cinnamate
FL/FR
myrrh resinoid
FR
opoponax oil (balsamodendron kafal)
FL/FR
opoponax resinoid (balsamodendron kafal)
FR
buttery
3,4-
hexane dione
FL/FR
creamy
butyl lactate
FL/FR
earthy
benzyl tiglate
FL/FR
dibenzyl ether
FL/FR
1-
nonen-3-ol
FL/FR
3-
octanol
FL/FR
1-
octen-3-ol
FL/FR
1-
octen-3-one
FL/FR
fatty
(E)-2-
decenal
FL/FR
fermented
butyl laevo-lactate
FL/FR
floral
cananga oil
FL/FR
6,8-
dimethyl-2-nonanol
FR
herbal pyran
FR
nonyl octanoate
FL/FR
allo
ocimene
FL/FR
octyl acetate
FL/FR
phenethyl butyl ether
FR
2-
phenyl propionaldehyde dimethyl acetal
FL/FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
tuberose absolute chassis
FL/FR
fruity
octyl propionate
FL/FR
fungal
1-
decen-3-ol
FL/FR
methyl 2-furoate
FL/FR
green
galbanum absolute
FL/FR
galbanum absolute replacer
FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
(Z)-
leaf acetal
FL/FR
lilac acetaldehyde
FL/FR
melon acetal
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
tiglaldehyde
FL/FR
herbal
cardamom oleoresin
FL/FR
3-
octanone
FL/FR
honey
phenethyl furoate
FL/FR
metallic
1,4-
dipentyl-6,8-dioxabicyclo(3.2.1)octane
FR
moldy
strawberry furanone methyl ether
FL/FR
mushroom
3-
octen-2-ol
FL/FR
(R)-1-
octen-3-ol
FL/FR
1-
octen-3-yl butyrate
FL/FR
nutty
2-
methyl-3-(methyl thio) pyrazine
FL/FR
phenolic
para-alpha-
dimethyl styrene
FL/FR
spicy
benzyl isoeugenol
FL/FR
nutmeg oil CO2 extract
FL/FR
spicy acetoacetate
FL/FR
terpenic
cypress leaf oil
FR
vegetable
methional
FL/FR
waxy
methyl laurate
FL/FR
(Z)-3-
nonen-1-ol
FL/FR
woody
agarwood oil (aetoxylon sympetalum)
FR
cistus twig/leaf oil
FL/FR
guaiacwood oil
FL/FR
guaiene
FL/FR
patchouli oil
FL/FR
patchouli oil decolorized
FL/FR
patchouli oil molecular distilled
FL/FR
vetiver oil haiti
FL/FR
vetiveria zizanioides root oil
FL/FR
yeasty
2-
octen-4-one
FL/FR
For Flavor
No flavor group found for these
benzyl tiglate
FL/FR
alpha-
bisabolene
FL/FR
T-
cadinol
FL/FR
cinnamyl benzoate
FL/FR
furfural diethyl acetal
FL
tris(
methyl thio) methane
FL
2-
methyl-3-(methyl thio) pyrazine
FL/FR
nonyl octanoate
FL/FR
1,5-
octadien-3-ol
FL
(E)-2-
penten-1-ol
FL
2-
pentyl-1-buten-3-one
FL
phenethyl furoate
FL/FR
balsamic
balsamic
benzoin absolute replacer
FL/FR
siam
benzoin resin
FL/FR
sumatra
benzoin resinoid
FL/FR
siam
benzoin resinoid
FL/FR
iso
bornyl isobutyrate
FL/FR
copaiba balsam oil
FL/FR
opoponax oil (balsamodendron kafal)
FL/FR
buttery
butyl laevo-lactate
FL/FR
3,4-
hexane dione
FL/FR
caramellic
methyl 2-furoate
FL/FR
citrus
allo
ocimene
FL/FR
cocoa
2-
methyl furan
FL
coffee
difurfuryl ether
FL
creamy
acetyl ethyl carbinol
FL
dairy
butyl lactate
FL/FR
earthy
1-
decen-3-ol
FL/FR
1-
nonen-3-ol
FL/FR
1,8-
octane dithiol
FL
1-
octen-3-one
FL/FR
tamarind distillates
FL
2-
thienyl disulfide
FL
estery
octyl propionate
FL/FR
fatty
dimethyl sulfoxide
FL
fermented
methyl thio isovalerate
FL
floral
2-
acetyl-5-methyl thiophene
FL
cananga oil
FL/FR
tuberose absolute chassis
FL/FR
fruity
dibenzyl ether
FL/FR
2,4-
hexadien-1-ol
FL
lilac acetaldehyde
FL/FR
2-
phenyl propionaldehyde dimethyl acetal
FL/FR
tiglaldehyde
FL/FR
green
galbanum absolute
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
(Z)-
leaf acetal
FL/FR
melon acetal
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
herbal
cardamom oleoresin
FL/FR
moldy
strawberry furanone methyl ether
FL/FR
mushroom
3-
octanone
FL/FR
3-
octen-2-ol
FL/FR
(R)-1-
octen-3-ol
FL/FR
1-
octen-3-ol
FL/FR
1-
octen-3-yl butyrate
FL/FR
musty
3-
octanol
FL/FR
spicy
sumatra
benzoin absolute
FL/FR
siam
benzoin absolute
FL/FR
siam
benzoin CO2 extract
FL/FR
benzyl isoeugenol
FL/FR
chocolate cinnamon hazelnut flavor
FL
cinnamon hazelnut flavor
FL
cinnamon macadamia nut flavor
FL
cinnamyl formate
FL/FR
para-alpha-
dimethyl styrene
FL/FR
methyl cinnamate
FL/FR
nutmeg oil CO2 extract
FL/FR
spicy acetoacetate
FL/FR
sulfurous
1-(
methyl thio)-2-butanone
FL
2-
naphthyl mercaptan
FL
tomato
methional
FL/FR
vegetable
2-
octen-4-one
FL/FR
waxy
(E)-2-
decenal
FL/FR
methyl laurate
FL/FR
(Z)-3-
nonen-1-ol
FL/FR
octyl 2-furoate
FL
octyl acetate
FL/FR
woody
amyris wood oil
FL/FR
cistus twig/leaf oil
FL/FR
guaiacwood oil
FL/FR
guaiene
FL/FR
juniper berry oil terpeneless
FL/FR
patchouli oil
FL/FR
patchouli oil decolorized
FL/FR
patchouli oil molecular distilled
FL/FR
vetiver oil haiti
FL/FR
vetiveria zizanioides root oil
FL/FR
 
Potential Uses:
FRalmond
FRbalsam
FRcherry
FRfungus
FRgardenia
FRgrape
FRmelon
FRpeach
FRrose
 
Occurrence (nature, food, other):note
 champaca concrete @ 0.02%
Data GC Search Trop Picture
 clary sage oil greece @ trace%
Data GC Search Trop Picture
 hyacinthus orientalis absolute @ 0.80-0.13%
Data GC Search Trop Picture
 narcissus absolute @ 0.12%
Data GC Search Trop Picture
 
Synonyms:
 benzyl (2E)-2-methylbut-2-enoate
 benzyl (E)-2-methyl crotonate
 benzyl (E)-2-methyl-2-butenoate
 benzyl (E)-2-methylbut-2-enoate
 benzyl (E)-2,3-dimethyl acrylate
 benzyl trans-2-methyl crotonate
 benzyl trans-2-methyl-2-butenoate
 benzyl trans-2-methylcrotonate
 benzyl trans-2,3-dimethyl acrylate
 benzyl trans-2,3-dimethylacrylate
trans-2-butenoic acid, 2-methyl-, phenylmethyl ester
2-butenoic acid, 2-methyl-, phenylmethyl ester, (2E)-
2-butenoic acid, 2-methyl-, phenylmethyl ester, (E)-
2-methyl-(E)-2-butenoic acid phenyl methyl ester
(E)-2-methyl-2-butenoic acid phenyl methyl ester
 phenyl methyl (E)-2.methyl-2-butenoate
(E)-phenyl methyl 2-methyl-2-butenoate
 phenylmethyl (2E)-2-methylbut-2-enoate
 phenylmethyl (E)-2-methylbut-2-enoate
 phenylmethyl 2-methyl-2-butenoate, (E)-
 
 
Notes:
Used as a food additive [EAFUS]
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