EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

(E)-2-hexen-1-yl phenyl acetate
trans-2-hexenyl phenylacetate

Supplier Sponsors

Name:[(E)-hex-2-enyl] 2-phenylacetate
CAS Number: 68133-78-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:268-705-8
FDA UNII: Search
Nikkaji Web:J208.916E
MDL:MFCD00036543
XlogP3-AA:3.60 (est)
Molecular Weight:218.29586000
Formula:C14 H18 O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
DG SANTE Food Flavourings:09.400 (E)-hex-2-enyl phenylacetate
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.98300 to 0.99300 @ 25.00 °C.
Pounds per Gallon - (est).: 8.180 to 8.263
Refractive Index:1.49700 to 1.50400 @ 20.00 °C.
Melting Point: 37.00 °C. @ 760.00 mm Hg
Boiling Point: 97.00 °C. @ 1.00 mm Hg
Boiling Point: 336.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.001000 mmHg @ 25.00 °C. (est)
Vapor Density:>1 ( Air = 1 )
Flash Point: 230.00 °F. TCC ( 110.00 °C. )
logP (o/w): 4.391 (est)
Soluble in:
 alcohol
 water, 7.167 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items:note
allyl phenyl acetate
amyl phenyl acetate
isoamyl phenyl acetate
para-anisyl phenyl acetate
benzyl phenyl acetate
isobornyl phenyl acetate
butyl phenyl acetate
isobutyl phenyl acetate
cinnamyl phenyl acetate
citronellyl phenyl acetate
meta-cresyl phenyl acetate
para-cresyl phenyl acetate
cyclohexyl phenyl acetate
dimethyl octanyl phenyl acetate
ethyl phenyl acetate
eugenyl phenyl acetate
isoeugenyl phenyl acetate
furfuryl phenyl acetate
geranyl phenyl acetate
guaiacyl phenyl acetate
heptyl phenyl acetate
(Z)-3-hexen-1-yl phenyl acetate
hexyl phenyl acetate
linalyl phenyl acetate
menthyl phenyl acetate
laevo-menthyl phenyl acetate
methyl butyl phenyl acetate
methyl phenyl acetate
neryl phenyl acetate
nonyl phenyl acetate
octyl phenyl acetate
phenethyl phenyl acetate
phenyl propyl phenyl acetate
propyl 4-tert-butyl phenyl acetate
propyl phenyl acetate
isopropyl phenyl acetate
rhodinyl phenyl acetate
santalyl phenyl acetate
tetrahydrofurfuryl phenyl acetate
 
Organoleptic Properties:
Odor Type: green
green mossy rummy honey
Odor Description:at 100.00 %. green mossy rum honey
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
trans-2-HEXENYL PHENYL ACETATE
Odor Description:Green, rummy character with sweet honey-like dry down
Primarily used for persistent sweet notes in fragrances.
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
BOC Sciences
For experimental / research use only.
Phenylacetic acid trans-2-hexen-1-yl ester
Santa Cruz Biotechnology
For experimental / research use only.
trans-2-Hexen-1-yl Phenylacetate
TCI AMERICA
For experimental / research use only.
trans-2-Hexen-1-yl Phenylacetate
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Primarily used for persistent sweet notes in fragrances.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Primarily used for persistent sweet notes in fragrances.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for (E)-2-hexen-1-yl phenyl acetate usage levels up to:
  4.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.01 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 1800 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 4.100007.77000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 3.300005.95000
Edible ices, including sherbet and sorbet (03.0): 3.300005.95000
Processed fruit (04.1): --
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): 3.300005.95000
Confectionery (05.0): 6.170009.81000
Chewing gum (05.3): --
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 3.300005.95000
Bakery wares (07.0): 6.800009.71000
Meat and meat products, including poultry and game (08.0): 3.300005.95000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 3.300005.95000
Eggs and egg products (10.0): 3.300005.95000
Sweeteners, including honey (11.0): 3.300005.95000
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 1.000003.00000
Foodstuffs intended for particular nutritional uses (13.0): --
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 1.750002.69000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 1.320002.17000
Ready-to-eat savouries (15.0): 3.300005.95000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 3.300005.95000
 
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 200, Revision 1 (FGE.200 Rev.1): 74 a,ß-unsaturated aliphatic aldehydes and precursors from chemical subgroup 1.1.1 of FGE.19
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 5, Revision 3 (FGE.05Rev3): Branched- and straight-chain unsaturated aldehydes, dienals, unsaturated and saturated carboxylic acids and related esters with saturated and unsaturated aliphatic alcohols and a phenylacetic acid related ester from chemical groups 1, 2, 3, 5 and 15
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):68133-78-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5368236
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
[(E)-hex-2-enyl] 2-phenylacetate
Chemidplus:0068133788
 
References:
 [(E)-hex-2-enyl] 2-phenylacetate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:68133-78-8
Pubchem (cid):5368236
Pubchem (sid):135065868
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.39.7700
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
acidic
cyclohexyl acetic acid
FL/FR
aldehydic
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
muguet undecadienal
FR
animal
para-
cresyl phenyl acetate
FL/FR
1,2,3,4-
tetrahydroquinoline
FR
anisic
para-
anisyl phenyl acetate
FL/FR
balsamic
iso
amyl pyruvate
FL/FR
cinnamyl formate
FL/FR
guaiacyl phenyl acetate
FL/FR
caramellic
ethyl cyclopentenolone
FL/FR
immortelle absolute
FL/FR
cereal
bran absolute
FR
chocolate
iso
amyl phenyl acetate
FL/FR
cocoa pentenal
FL/FR
citrus
citral dimethyl acetal
FL/FR
(E)-4-
decenal
FL/FR
grapefruit pentanol
FR
tetrahydromyrcenyl acetate
FR
dairy
methyl butyl phenyl acetate
FL/FR
ethereal
decyl propionate
FL/FR
ethyl acetate
FL/FR
ethyl formate
FL/FR
ethyl pyruvate
FL/FR
1-
hexen-3-ol
FL/FR
(E)-
methyl tiglate
FL/FR
propyl formate
FL/FR
iso
valeraldehyde propylene glycol acetal
FL/FR
fatty
2-
decenal
FL/FR
methyl (E)-2-hexenoate
FL/FR
fermented
ethyl (E)-2-crotonate
FL/FR
floral
amyl benzoate
FL/FR
anisyl propanal / methyl anthranilate schiff's base
FR
alpha-
butyl cinnamaldehyde
FL/FR
cardamom absolute
FL/FR
citronellyl acetate
FL/FR
citronellyl isovalerate
FL/FR
citronellyl phenyl acetate
FL/FR
citronellyl propionate
FL/FR
citronellyl valerate
FL/FR
cumin carbinol
FR
cuminyl acetaldehyde
FL/FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
6,8-
dimethyl-2-nonanol
FR
ethyl 2-benzyl butyrate
FL/FR
ethyl hydrocinnamate
FL/FR
ethyl phenyl acetate
FL/FR
farnesyl acetate
FL/FR
floral butanal
FR
geranium oil bourbon
FL/FR
geranyl acetone
FL/FR
geranyl isobutyrate
FL/FR
geranyl phenyl acetate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hyacinth acetals
FL/FR
hydroxycitronellal diethyl acetal
FL/FR
jasmin cyclopentanol
FR
jonquil absolute
FR
kewda oil
CS
linalyl phenyl acetate
FL/FR
linalyl propionate
FL/FR
ortho-
methyl acetophenone
FL/FR
mimosa absolute france
FL/FR
muguet carbinol
FL/FR
neroli oil bigarde
FL/FR
nerolidol
FL/FR
ocean propanal / methyl anthranilate schiff's base
FR
octyl isovalerate
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute morocco
FL/FR
papaya isobutyrate
FL/FR
phenethyl acetate
FL/FR
phenethyl anthranilate
FL/FR
phenethyl benzoate
FL/FR
phenethyl hexanoate
FL/FR
phenethyl phenyl acetate
FL/FR
phenethyl propionate
FL/FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
phenyl glycol diacetate
FR
2-
phenyl propionaldehyde ethylene glycol acetal
FR
3-
phenyl propyl formate
FL/FR
(E)-2-
phenyl-1(2)-propene-1-yl acetate
FR
iso
propyl anthranilate
FL/FR
rhodinyl phenyl acetate
FL/FR
rose absolute (rosa centifolia) morocco
FL/FR
rose butanoate
FL/FR
rose carboxylate
FR
(Z)-
rose oxide
FL/FR
styralyl formate
FL/FR
terpinyl isobutyrate
FL/FR
verdyl acetate
FR
fruity
allyl hexanoate
FL/FR
allyl phenoxyacetate
FL/FR
benzyl methyl ether
FL/FR
berry pentadienoate
FL/FR
iso
butyl butyrate
FL/FR
butyl formate
FL/FR
cyclohexanone diethyl acetal
FL/FR
(E)-beta-
damascone
FL/FR
beta-
damascone
FL/FR
(Z)-beta-
damascone
FL/FR
dimethyl succinate
FL/FR
ethyl heptanoate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
ethyl propionate
FL/FR
fruity carboxylate
FR
3-
hexanone
FL/FR
methyl propionate
FL/FR
osmanthus flower absolute
FL/FR
peach pivalate
FR
2-
phenyl propyl butyrate
FL/FR
prenyl formate
FL/FR
rhubarb pyran
FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
strawberry glycidate 2
FL/FR
tetrahydrofurfuryl acetate
FL/FR
green
iso
amyl 3-(2-furan) propionate
FL/FR
iso
butyl benzyl carbinol
FL/FR
chrysanthemum oxide
FL/FR
decanal propylene glycol acetal
FL/FR
earthy acetal
FL/FR
flower hexene
FR
geranium absolute
FL/FR
heptyl acetate
FL/FR
(E)-2-
hexen-1-yl formate
FL/FR
ivy carbaldehyde / methyl anthranilate schiff's base
FR
ivy dioxolane
FR
methyl cyclocitrone (IFF)
FR
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
4-
methyl-4-phenyl pentanone
FR
octanal dimethyl acetal
FL/FR
octyl oxyacetaldehyde
FR
phenethyl isopropyl ether
FR
phenethyl oxyacetaldehyde
FR
phenethyl tiglate
FL/FR
phenyl acetaldehyde
FL/FR
hay
beeswax absolute
FL/FR
hay absolute
FR
tobacco leaf absolute
FL/FR
herbal
artemisyl ketone
FL/FR
clary sage absolute
FL/FR
matricaria chamomilla flower oil
FL/FR
honey
allyl phenyl acetate
FL/FR
butyl phenyl acetate
FL/FR
methyl hydrocinnamate
FL/FR
methyl phenyl acetate
FL/FR
phenethyl furoate
FL/FR
phenyl acetic acid
FL/FR
phenyl pyruvic acid
FL/FR
propyl phenyl acetate
FL/FR
jammy
ethyl 2-methyl-2-pentenoate
FR
leathery
4-tert-
butyl phenol
CS
marine
marine hexane
FR
mossy
oakmoss absolute
FL/FR
oakmoss phenol
FR
sea resorcylate
FR
veramoss (IFF)
FR
musty
cocoa butenal
FL/FR
spicy
alpha-
amyl cinnamyl alcohol
FL/FR
carnation absolute
FR
caryophyllene alcohol
FL/FR
beta-
caryophyllene alcohol
FL/FR
eugenyl phenyl acetate
FL/FR
iso
eugenyl phenyl acetate
FL/FR
thujonic
cistus cyclohexanone
FL/FR
waxy
decanal diethyl acetal
FL/FR
3-
decanone
FL/FR
dihydrocitronellyl acetate
FL/FR
1-
dodecanol
FL/FR
ethyl nonanoate
FL/FR
waxy acetate
FR
woody
santalyl phenyl acetate
FL/FR
For Flavor
No flavor group found for these
1-
acetyl cyclohexyl acetate
FL
amyl benzoate
FL/FR
iso
amyl pyruvate
FL/FR
artemisyl ketone
FL/FR
butyl formate
FL/FR
beta-
caryophyllene alcohol
FL/FR
caryophyllene alcohol
FL/FR
cistus cyclohexanone
FL/FR
citronellyl isovalerate
FL/FR
citronellyl valerate
FL/FR
cyclohexanone diethyl acetal
FL/FR
decanal propylene glycol acetal
FL/FR
3-
decanone
FL/FR
decyl propionate
FL/FR
dihydrocitronellyl acetate
FL/FR
earthy acetal
FL/FR
ethyl 2-benzyl butyrate
FL/FR
ethyl hydrocinnamate
FL/FR
eugenyl phenyl acetate
FL/FR
linalyl phenyl acetate
FL/FR
methyl (E)-2-hexenoate
FL/FR
methyl hydrocinnamate
FL/FR
(E)-
methyl tiglate
FL/FR
octyl isovalerate
FL/FR
phenethyl furoate
FL/FR
3-
phenyl propyl formate
FL/FR
prenyl formate
FL/FR
iso
propyl anthranilate
FL/FR
santalyl phenyl acetate
FL/FR
styralyl formate
FL/FR
terpinyl isobutyrate
FL/FR
iso
amyl 3-(2-furan) propionate
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
beta-
damascone
FL/FR
amber
amber
iso
butyl benzyl carbinol
FL/FR
anisic
para-
anisyl phenyl acetate
FL/FR
ortho-
methyl acetophenone
FL/FR
aromatic
hyacinth acetals
FL/FR
brown
beeswax absolute
FL/FR
tetrahydrofurfuryl acetate
FL/FR
caramellic
pyruvaldehyde
FL
citrus
citral dimethyl acetal
FL/FR
cucumber
2-
ethyl octine carbonate
FL
dairy
methyl butyl phenyl acetate
FL/FR
earthy
1-
hexen-3-yl acetate
FL
ethereal
ethyl acetate
FL/FR
ethyl formate
FL/FR
fatty
2-
decenal
FL/FR
floral
iso
amyl phenyl acetate
FL/FR
cardamom absolute
FL/FR
citronellyl acetate
FL/FR
citronellyl phenyl acetate
FL/FR
citronellyl propionate
FL/FR
cocoa pentenal
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
farnesyl acetate
FL/FR
geranium oil bourbon
FL/FR
geranyl acetone
FL/FR
geranyl isobutyrate
FL/FR
geranyl phenyl acetate
FL/FR
methyl phenyl acetate
FL/FR
muguet carbinol
FL/FR
neroli oil bigarde
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower absolute morocco
FL/FR
phenethyl anthranilate
FL/FR
phenethyl benzoate
FL/FR
phenethyl propionate
FL/FR
phenyl acetic acid
FL/FR
rose absolute (rosa centifolia) morocco
FL/FR
fruity
allyl hexanoate
FL/FR
allyl phenoxyacetate
FL/FR
benzyl methyl ether
FL/FR
berry pentadienoate
FL/FR
iso
butyl butyrate
FL/FR
(Z)-beta-
damascone
FL/FR
(E)-beta-
damascone
FL/FR
dimethyl succinate
FL/FR
ethyl heptanoate
FL/FR
ethyl methyl-para-tolyl glycidate
FL/FR
ethyl propionate
FL/FR
3-
hexanone
FL/FR
methyl propionate
FL/FR
osmanthus flower absolute
FL/FR
propyl formate
FL/FR
rose butanoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
strawberry glycidate 2
FL/FR
iso
valeraldehyde propylene glycol acetal
FL/FR
grassy
tobacco leaf absolute
FL/FR
green
chrysanthemum oxide
FL/FR
cocoa butenal
FL/FR
cuminyl acetaldehyde
FL/FR
(E)-4-
decenal
FL/FR
geranium absolute
FL/FR
heptyl acetate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
1-
hexen-3-ol
FL/FR
(E)-3-
hexenoic acid
FL
immortelle absolute
FL/FR
methyl 2-undecynoate
FL
para-
methyl hydratropaldehyde
FL/FR
methyl octine carbonate
FL/FR
nerolidol
FL/FR
oakmoss absolute
FL/FR
octanal dimethyl acetal
FL/FR
papaya isobutyrate
FL/FR
phenethyl tiglate
FL/FR
phenyl acetaldehyde diisobutyl acetal
FL/FR
(Z)-
rose oxide
FL/FR
herbal
clary sage absolute
FL/FR
linalyl propionate
FL/FR
matricaria chamomilla flower oil
FL/FR
honey
allyl phenyl acetate
FL/FR
butyl phenyl acetate
FL/FR
ethyl phenyl acetate
FL/FR
phenethyl acetate
FL/FR
phenethyl phenyl acetate
FL/FR
phenyl acetaldehyde
FL/FR
propyl phenyl acetate
FL/FR
jammy
ethyl cyclopentenolone
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
melon
hydroxycitronellal diethyl acetal
FL/FR
musty
ethyl (E)-2-crotonate
FL/FR
phenolic
para-
cresyl phenyl acetate
FL/FR
guaiacyl phenyl acetate
FL/FR
phenyl pyruvic acid
FL/FR
rummy
ethyl pyruvate
FL/FR
(E)-2-
hexen-1-yl formate
FL/FR
soapy
1-
dodecanol
FL/FR
sour
2,4-
dimethyl-2-pentenoic acid
FL
spicy
alpha-
amyl cinnamyl alcohol
FL/FR
cinnamyl formate
FL/FR
iso
eugenyl phenyl acetate
FL/FR
2-
phenyl propyl butyrate
FL/FR
sweet
cyclohexyl acetic acid
FL/FR
waxy
decanal diethyl acetal
FL/FR
ethyl nonanoate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
mimosa absolute france
FL/FR
phenethyl hexanoate
FL/FR
rhodinyl phenyl acetate
FL/FR
 
Potential Uses:
FRfreesia
FRgreen
FRhoney
FRmoss
FRneroli
FRorange blossom
FRorchid
FRsaffron
 
Occurrence (nature, food, other):note
 mentha oils
 
Synonyms:
 benzeneacetic acid, (2E)-2-hexen-1-yl ester
 benzeneacetic acid, (2E)-2-hexenyl ester
 benzeneacetic acid, 2-hexenyl ester, (E)-
(2E)-hex-2-en-1-yl phenylacetate
(E)-hex-2-enyl phenyl acetate
(E)-hex-2-enyl phenylacetate
[(E)-hex-2-enyl] 2-phenylacetate
(E)-2-hexen-1-yl phenyl acetate
trans-2-hexen-1-yl phenyl acetate
trans-2-hexen-1-yl phenylacetate
(E)-2-hexenyl phenyl acetate
trans-2-hexenyl phenyl acetate
(E)-2-hexenyl phenylacetate
trans-2-hexenyl phenylacetate
 phenylacetic acid trans-2-hexen-1-yl ester
 
 
Notes:
None found
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