EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

ivy carbaldehyde / methyl anthranilate schiff's base
vertosine (Symrise)

Sponsors

Name:methyl 2-[[(E)-(2,4-dimethyl-1-cyclohex-3-enylidene)methyl]amino]benzoate
CAS Number: 68738-99-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:272-124-5
XlogP3-AA:3.90 (est)
Molecular Weight:271.35977000
Formula:C17 H21 N O2
NMR Predictor:Predict (works with chrome or firefox)
Also(can) Contains:2,4-ivy carbaldehyde / methyl anthranilate schiff's base
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
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EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:yellow solid (est)
Assay: 94.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:1.08300 to 1.09100 @ 25.00 °C.
Pounds per Gallon - (est).: 9.012 to 9.078
Refractive Index:1.59900 to 1.60500 @ 20.00 °C.
Boiling Point: 401.00 to 405.00 °C. @ 760.00 mm Hg
Boiling Point: 405.00 to 406.00 °C. @ 760.00 mm Hg (est)
Flash Point: 291.00 °F. TCC ( 143.89 °C. )
logP (o/w): 5.856 (est)
Soluble in:
 alcohol
 diethyl phthalate
 dipropylene glycol
 isopropyl myristate
 paraffin oil
 water, 1.322 mg/L @ 25 °C (est)
Insoluble in:
 water
Stability:
 ph from 12.2
 
Organoleptic Properties:
Odor Type: green
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
Substantivity:400 hour(s) at 100.00 %
fresh green sweet floral orangeflower leafy
Odor Description:at 10.00 % in dipropylene glycol. fresh green sweet floral orangeflower leafy
Luebke, William tgsc, (1988)
Odor sample from: Harrmann & Reimer Corporation
Odor and/or flavor descriptions from others (if found).
Symrise
Vertosine
Odor Description:intense green, floral-aldehydic, reminiscent of the green note of broom (genet)
Stable in: body lotion (good), shampoo (good), soap (poor), ap roll-on (good), powder (good), cleaner citric (good), cleaner apc (good), bleach (poor).
IFF
Agrumea
Odor Description:A fresh green, sweet floral note with orange flower characteristics
Moellhausen
VERTOSINE
Odor Description:floreal, herbaceous, citrusy, lemon and mandarin note
Ernesto Ventós
SCHIFF BASE, TRIPLAL/METHYL ANTHRANILATE
Odor Description:GREEN, FLORAL, ALDEHYDIC, CITRUS
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
BOC Sciences
For experimental / research use only.
Vertosine
CG Herbals
Ligantraal
Odor: powerful green, orange blossom note
Use: Often used in combination with Ligustral in toiletries and detergents at 1 or 2%. A 10% dilution can be used at levels up to 5% in other areas to give long-lasting green-floral freshness.
Ernesto Ventós
SCHIFF BASE, TRIPLAL/METHYL ANTHRANILATE
Odor: GREEN, FLORAL, ALDEHYDIC, CITRUS
IFF
Agrumea
Odor: A fresh green, sweet floral note with orange flower characteristics
Lluch Essence
LIGANTRAAL
Moellhausen
VERTOSINE
Odor: floreal, herbaceous, citrusy, lemon and mandarin note
Penta International
METHYL ANTHRANILATE/2,4(OR 3,5)-DIMETHYL-3-CYCLOHEXENE-1-CARBOXALDEHYDE
Symrise
Vertosine
Odor: intense green, floral-aldehydic, reminiscent of the green note of broom (genet)
Use: Stable in: body lotion (good), shampoo (good), soap (poor), ap roll-on (good), powder (good), cleaner citric (good), cleaner apc (good), bleach (poor).
 
Safety Information:
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
No effects detrimental to health are known.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
IFRA Critical Effect: Sensitization
IFRA fragrance material specification:
 The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes.
Recommendation for ivy carbaldehyde / methyl anthranilate schiff's base usage levels up to:
  4.0000 % in the fragrance concentrate.
 
Recommendation for ivy carbaldehyde / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):68738-99-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :3034893
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
methyl 2-[[(E)-(2,4-dimethyl-1-cyclohex-3-enylidene)methyl]amino]benzoate
Chemidplus:0068738998
 
References:
 methyl 2-[[(E)-(2,4-dimethyl-1-cyclohex-3-enylidene)methyl]amino]benzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:68738-99-8
Pubchem (cid):3034893
Pubchem (sid):135067327
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2922.50.35
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
adoxal (Givaudan)
FL/FR
citrus carbaldehyde
FR
decanal (aldehyde C-10)
FL/FR
9-
decenal
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
amber
angelica root oil
FL/FR
balsamic
2-
acetyl furan
FL/FR
iso
amyl benzoate
FL/FR
benzyl benzoate
FL/FR
benzyl salicylate
FL/FR
iso
bornyl acetate
FL/FR
laevo-
bornyl acetate
FL/FR
cinnamyl alcohol
FL/FR
clover nitrile
FR
ethyl cinnamate
FL/FR
fir needle oil siberia
FL/FR
valerian rhizome absolute
FL/FR
citrus
bergamot oil bergaptene reduced italy
FL/FR
citral
FL/FR
grapefruit oil c.p. california
FL/FR
grapefruit pentanol
FR
lemon oil c.p. california
FL/FR
lemongrass oil
FL/FR
lime oil distilled mexico
FL/FR
litsea cubeba fruit oil
FL/FR
methyl heptenone
FL/FR
blood
orange oil italy
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
petitgrain combava oil
FR
tetrahydromyrcenol
FR
earthy
methyl undecylenate
FL/FR
floral
iso
amyl salicylate
FL/FR
amyl salicylate
FL/FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
benzyl isobutyrate
FL/FR
bois de rose oil brazil
FL/FR
iso
butyl salicylate
FL/FR
citronellyl acetate
FL/FR
coriander seed oil
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
dimethyl benzyl carbinol
FL/FR
floral pyranol
FR
gardenia absolute
FR
gardenia oxide
FR
geraniol
FL/FR
geranyl acetate
FL/FR
heliotropyl diethyl acetal
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
hexyl 2-furoate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
ho leaf oil
FR
hyacinth ether
FR
leerall
FR
laevo-
linalool
FL/FR
linalool
FL/FR
linalool oxide
FL/FR
methyl dihydrojasmonate
FL/FR
mimosa absolute france
FL/FR
muguet carboxaldehyde
FR
muguet octadienol
FR
nerol
FL/FR
nerolidol
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
orris pyridine 25% IPM
FR
peony alcohol
FR
petitgrain oil paraguay
FL/FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
propyl anthranilate
FL/FR
rhodinol
FL/FR
rose butanoate
FL/FR
tetrahydrolinalool
FL/FR
violet methyl carbonate
FR
fruity
allyl amyl glycolate
FR
allyl cyclohexyl propionate
FL/FR
allyl hexanoate
FL/FR
bitter
almond oil
FL/FR
iso
amyl acetate
FL/FR
iso
amyl butyrate
FL/FR
amyl hexanoate
FL/FR
benzaldehyde
FL/FR
benzyl propionate
FL/FR
iso
butyl propionate
FL/FR
diethyl malonate
FL/FR
endo-
ethyl bicyclo(2.2.1)-5-heptene-2-carboxylate
FR
green acetate
FR
hexyl acetate
FL/FR
methyl 2-methyl valerate
FL/FR
methyl dimethyl anthranilate
FL/FR
4-
phenyl-2-butyl acetate
FL/FR
pineapple pentenoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
tropical indene
FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
acetaldehyde methyl hexyl acetal
FR
fern fragrance
FR
galbanum oil
FL/FR
green carboxylate
FR
green heptenal
FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(Z)-3-
hexen-1-yl formate
FL/FR
(Z)-3-
hexen-1-yl lactate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl tiglate
FL/FR
ivy carbaldehyde
FL/FR
3,6-
ivy carbaldehyde
FL/FR
english
ivy leaf absolute
FR
(Z)-
leaf acetal
FL/FR
melon nonenoate
FL/FR
nerol oxide
FL/FR
neryl butyrate
FL/FR
(E,Z)-2,6-
nonadien-1-ol
FL/FR
(E,Z)-2,6-
nonadienal
FL/FR
phenyl acetaldehyde
FL/FR
3-
phenyl propionaldehyde
FL/FR
1-
phenyl-2-pentanol
FL/FR
2-
propenyl-para-cymene
FR
rose leaf absolute (rosa centifolia)
FL/FR
styralyl acetate
FL/FR
violet leaf absolute
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
clary acetate
FR
clary sage oil france
FL/FR
daucus carota fruit oil
FL/FR
dihexyl (E)-fumarate
FR
eucalyptus globulus oil
FL/FR
herbal undecanone
FR
hexanol
FL/FR
lavender absolute bulgaria
FL/FR
linalyl acetate
FL/FR
marigold oil mexico
FL/FR
nopyl acetate
FR
3-
octanone
FL/FR
alpha-
terpinyl acetate
FL/FR
marine
marine pyridine
FR
melon
melon heptenal
FL/FR
watermelon ketone
FR
orris
iso
eugenyl formate
FL/FR
phenolic
methyl benzoate
FL/FR
powdery
para-
anisyl acetate
FL/FR
spicy
carrot weed oil
FL/FR
terpenic
frankincense oil
FL/FR
juniperus communis fruit oil
FL/FR
alpha-
terpineol
FL/FR
thujonic
thuja occidentalis leaf oil
FL/FR
waxy
ethyl laurate
FL/FR
methyl octanoate
FL/FR
woody
amber carbinol
FR
patchouli ethanone
FR
spruce needle oil canada
FL/FR
vetiver oil haiti
FL/FR
woody acetate
FR
(Z)-
woody amylene
FR
woody propanol
FR
For Flavor
No flavor group found for these
9-
decenal
FL/FR
iso
eugenyl formate
FL/FR
ivy carbaldehyde
FL/FR
methyl dimethyl anthranilate
FL/FR
4-
phenyl-2-butyl acetate
FL/FR
propyl anthranilate
FL/FR
thuja occidentalis leaf oil
FL/FR
aldehydic
aldehydic
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
apple
(E,Z)-2,6-
nonadien-1-ol
FL/FR
aromatic
amyl salicylate
FL/FR
balsamic
benzyl benzoate
FL/FR
benzyl salicylate
FL/FR
laevo-
bornyl acetate
FL/FR
ethyl cinnamate
FL/FR
fir needle oil siberia
FL/FR
citrus
bergamot oil bergaptene reduced italy
FL/FR
citral
FL/FR
grapefruit oil c.p. california
FL/FR
lemon oil c.p. california
FL/FR
lemongrass oil
FL/FR
lime oil distilled mexico
FL/FR
linalool
FL/FR
laevo-
linalool
FL/FR
litsea cubeba fruit oil
FL/FR
nerol
FL/FR
blood
orange oil italy
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
petitgrain oil paraguay
FL/FR
alpha-
terpineol
FL/FR
cooling
iso
butyl salicylate
FL/FR
creamy
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
fatty
(Z)-3-
hexen-1-yl benzoate
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
floral
bois de rose oil brazil
FL/FR
citronellyl acetate
FL/FR
geraniol
FL/FR
linalyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
phenethyl alcohol
FL/FR
rhodinol
FL/FR
tetrahydrolinalool
FL/FR
fruity
allyl cyclohexyl propionate
FL/FR
allyl hexanoate
FL/FR
bitter
almond oil
FL/FR
iso
amyl acetate
FL/FR
iso
amyl benzoate
FL/FR
amyl hexanoate
FL/FR
para-
anisyl acetate
FL/FR
benzaldehyde
FL/FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
benzyl isobutyrate
FL/FR
benzyl propionate
FL/FR
iso
butyl propionate
FL/FR
diethyl malonate
FL/FR
hexyl acetate
FL/FR
methyl 2-methyl valerate
FL/FR
1-
phenyl-2-pentanol
FL/FR
pineapple pentenoate
FL/FR
rose butanoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
styralyl acetate
FL/FR
valerian rhizome absolute
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
iso
amyl salicylate
FL/FR
angelica root oil
FL/FR
carrot weed oil
FL/FR
cinnamyl alcohol
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
galbanum oil
FL/FR
geranyl acetate
FL/FR
hexanol
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl formate
FL/FR
(Z)-3-
hexen-1-yl lactate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl 2-furoate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl tiglate
FL/FR
3,6-
ivy carbaldehyde
FL/FR
(Z)-
leaf acetal
FL/FR
linalool oxide
FL/FR
melon heptenal
FL/FR
melon nonenoate
FL/FR
methyl heptenone
FL/FR
methyl octanoate
FL/FR
nerol oxide
FL/FR
nerolidol
FL/FR
neryl butyrate
FL/FR
(E,Z)-2,6-
nonadienal
FL/FR
3-
phenyl propionaldehyde
FL/FR
rose leaf absolute (rosa centifolia)
FL/FR
violet leaf absolute
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
clary sage oil france
FL/FR
coriander seed oil
FL/FR
daucus carota fruit oil
FL/FR
eucalyptus globulus oil
FL/FR
lavender absolute bulgaria
FL/FR
marigold oil mexico
FL/FR
honey
phenethyl acetate
FL/FR
phenyl acetaldehyde
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
mushroom
3-
octanone
FL/FR
nutty
2-
acetyl furan
FL/FR
phenolic
methyl benzoate
FL/FR
terpenic
juniperus communis fruit oil
FL/FR
waxy
adoxal (Givaudan)
FL/FR
iso
amyl butyrate
FL/FR
decanal (aldehyde C-10)
FL/FR
ethyl laurate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
methyl undecylenate
FL/FR
mimosa absolute france
FL/FR
woody
iso
bornyl acetate
FL/FR
frankincense oil
FL/FR
spruce needle oil canada
FL/FR
alpha-
terpinyl acetate
FL/FR
vetiver oil haiti
FL/FR
 
Potential Uses:
FRbalsam
FRcitrus
 fir
FRfresh and clean
FRgardenia
FRgenet
FRgreen
FRherbal
FRhoneysuckle
FRjasmin
 leaf
FRlily
FRlinden flower
FRmimosa
FRnarcissus
 natural
FRorange blossom
 peel
FRpine
FRtuberose
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 agrumea (iff)
 benzoic acid, 2-(((2,4(or 3,5)-dimethyl-3-cyclohexen-1-yl)methylene)amino)-, methyl ester
2-(((2,4(3,5)-dimethyl-3-cyclohexen-1-yl)methylene)amino) methyl benzoate
 ivy carbaldehyde / methyl anthranilate schiff's base
 ligantraal (Quest)
 methyl 2-((-1-(2,4-dimethyl-3-cyclohexenyl)methylidene)amino)-1-benzene carboxylate
 methyl 2-(((2,4(or 3,5)-dimethyl-3-cyclohexen-1-yl)methylene)amino) benzoate
 methyl 2-(((2,4(or 3,5)-dimethyl-3-cyclohexen-1-yl)methylene)amino)benzoate
 methyl 2-(((2,4(or 3,5)-dimethyl-3-cyclohexenyl)methylene)amino) benzoate
 methyl 2-[[(E)-(2,4-dimethyl-1-cyclohex-3-enylidene)methyl]amino]benzoate
 methyl anthranilate / ivy carbaldehyde schiff's base
 methyl anthranilate / 2,4(or 3,5)-dimethyl-3-cyclohexene-1-carboxaldehyde
 methyl dimethyl cyclohexenyl methylene aminobenzoate
 methyl-(3,5-dimethyl-3-cyclohexene-1-yl) methylene anthranilate
 vertosine (Symrise)
 

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