EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

amber oxepin
amberketal (Givaudan)

Supplier Sponsors

Fragrance Demo Formulas
Name:5,5,9,13-tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane
CAS Number: 57345-19-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:260-686-4
FDA UNII: Search
Nikkaji Web:J349.139K
XlogP3-AA:4.70 (est)
Molecular Weight:278.43550000
Formula:C18 H30 O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 90.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:0.86400 to 0.87400 @ 25.00 °C.
Pounds per Gallon - (est).: 7.189 to 7.273
Refractive Index:1.43600 to 1.44600 @ 20.00 °C.
Boiling Point: 300.00 to 301.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.001100 mmHg @ 20.00 °C.
Flash Point: 252.00 °F. TCC ( 122.22 °C. )
logP (o/w): 5.700
Shelf Life: 12.00 month(s) or longer if stored properly.
Storage:store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
 alcohol
 water, 0.3507 mg/L @ 25 °C (est)
Stability:
 APC: traces - 0.5%
 candle: traces - 0.5%
 detergent: traces - 0.5%
 fine fragrances: traces - 2%
 shampoo: traces - 0.5%
 shower gel: traces - 1%
 soap: traces - 1%
 softener: traces - 0.5%
Similar Items:note
(3ar- (3aalpha,5abeta, 9aalpha,9bbeta))-dodecahydro-3a,6,6,9a-tetramethyl naphtho(2,1-b)furan
 
Organoleptic Properties:
Odor Type: amber
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
Substantivity: > 384 hour(s) at 100.00 %
dry amber powdery woody musk
Odor Description:at 10.00 % in dipropylene glycol. dry amber powdery woody musk
Luebke, William tgsc, (2009)
Odor sample from: Vigon International
Odor and/or flavor descriptions from others (if found).
Givaudan
Amberketal IPM (8.5% solution in isopropyl myristate)
Odor Description:Ambery, Dry, Woody
Amberketal is a powerful ambery note for use in most applications, with good stability in non aggressive media. It is effective as a modifier in association with existing woody/ambery ingredients.
Firmenich
Z11 10 MIP for fragrance
Odor Description:Dry, woody and ambery notes, with a strong trigeminal effect
Its dryness, tenacity and sleek elegance call to mind a precious wood rimmed in shining metal…unforgiving in its strength and designed for pure performance.
IFF
Ambermor Ketal Crystal
Odor Description:Extremely powerful amber and woody with elegant animalic, musky tonalities
IFF
Ambermor Ketal IPM
Odor Description:Extremely powerful amber and woody with elegant animalic, musky tonalities
Firmenich
Z11
Odor Description:Dry, woody and ambery notes, with a strong trigeminal effect
Its dryness, tenacity and sleek elegance call to mind a precious wood rimmed in shining metal…unforgiving in its strength and designed for pure performance.
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Associate Allied Chemicals
Amberketal
About
Azelis UK
Z11 10 MIP
BOC Sciences
For experimental / research use only.
Dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin
Ernesto Ventós
AMBERMOR KETAL IPM
Ernesto Ventós
AMBERMORE KETAL CRYSTALS
Ernesto Ventós
Z11 MIP FIRMENICH 992964
Odor: WOODY, AMBER, DRY
Firmenich
Z11 10 MIP
for fragrance
Odor: Dry, woody and ambery notes, with a strong trigeminal effect
Use: Its dryness, tenacity and sleek elegance call to mind a precious wood rimmed in shining metal…unforgiving in its strength and designed for pure performance.
Firmenich
Z11 MIP Via White Biotech
Odor: very dry ambery note with exceptional booster effects in fragrance
Use: Now via white biotech, we have sustainable supply and a price 1/3 the price of the original.
Firmenich
Z11
Odor: Dry, woody and ambery notes, with a strong trigeminal effect
Use: Its dryness, tenacity and sleek elegance call to mind a precious wood rimmed in shining metal…unforgiving in its strength and designed for pure performance.
Givaudan
Amberketal IPM
(8.5% solution in isopropyl myristate)
Odor: Ambery, Dry, Woody
Use: Amberketal is a powerful ambery note for use in most applications, with good stability in non aggressive media. It is effective as a modifier in association with existing woody/ambery ingredients.
IFF
Ambermor Ketal Crystal
Odor: Extremely powerful amber and woody with elegant animalic, musky tonalities
IFF
Ambermor Ketal IPM
Odor: Extremely powerful amber and woody with elegant animalic, musky tonalities
Indukern F&F
AMBERKETAL IPM
Odor: BITTER
Liaison Carbone
Z11 MIP
Lluch Essence
AMBERKETAL 8,5% IPM
Odor: WOODY, AMBER LIKE, DRY
Moellhausen
AMBERKETAL (10% IPM)
Odor: powerful ambery note
Penta International
AMBER KETAL IPM
Perfumery Laboratory
Z11 MIP 10% FIRMENICH (Z11 MIP 10% FIRMENICH)
Odor: Elegant, bewitching, amber, amber, woody
Vigon International
Amberketal IPM
Odor: dry amber powdery woody musk
Use: Luebke, William tgsc, (2009)
Vigon International
Z11 10 MIP
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for amber oxepin usage levels up to:
  1.0000 % in the fragrance concentrate.
 
Recommendation for amber oxepin flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):57345-19-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :93639
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
5,5,9,13-tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane
Chemidplus:0057345194
 
References:
 5,5,9,13-tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:57345-19-4
Pubchem (cid):93639
Pubchem (sid):135049841
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
satinaldehyde
FL/FR
aldehydic
aldehydic
decanal (aldehyde C-10)
FL/FR
dodecanal (aldehyde C-12 lauric)
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
amber
acetoxymethyl isolongifolene
FR
amber acetate
FR
amber butanol
FR
amber carane
FR
amber cyclohexanol
FR
amber furan
FR
amber naphthofuran
FL/FR
amber powdery floral fragrance
FR
amber spirolene
FR
ambergris specialty
FR
ambergris tincture
FL/FR
ambrette seed absolute
FL/FR
ambrette seed oil CO2 extract
FL/FR
ambroxan
FL/FR
ambroxide
FL/FR
cistus ladaniferus resinoid
FL/FR
formoxymethyl isolongifolene
FR
(cis+trans)-6,6a,7,8,9,9a-
hexahydro-7,7,8,9,9-pentamethyl-5H-cyclopenta[H]quinazoline
FR
hydroxymethyl isolongifolene 50% in dpg
FR
labdanum oil
FL/FR
animal
animal carbolactone
FR
costus valerolactone
FR
musk indenofuran
FR
anisic
para-
anisyl phenyl acetate
FL/FR
balsamic
amyris wood oil
FL/FR
siam
benzoin resin
FL/FR
siam
benzoin resinoid
FL/FR
benzyl cinnamate
FL/FR
benzyl salicylate
FL/FR
iso
bornyl acetate
FL/FR
iso
butyl cinnamate
FL/FR
cinnamyl alcohol
FL/FR
ethyl cinnamate
FL/FR
guaiacyl phenyl acetate
FL/FR
mastic gum resin
FR
methyl cinnamate
FL/FR
myrrh oil
FL/FR
opoponax absolute (commiphora erythraea var. glabrescens engle)
FL/FR
opoponax resinoid (commiphora erythraea var. glabrescens engle)
FR
oriental specialty
FR
peru balsam oil
FL/FR
3-
phenyl propyl alcohol
FL/FR
sclareol
FL/FR
styrax oil (liquidambar styraciflua)
FL/FR
styrax resinoid (liquidambar styraciflua)
FL/FR
berry
raspberry ketone methyl ether
FL/FR
citrus
bitter
orange peel oil
FL/FR
bitter
orange peel oil brazil
FL/FR
bitter
orange peel oil italy
FL/FR
creamy
veratraldehyde
FL/FR
fatty
decanol
FL/FR
floral
alpha-
amyl cinnamaldehyde
FL/FR
iso
amyl salicylate
FL/FR
benzyl alcohol
FL/FR
bois de rose oil brazil
FL/FR
boronia butenal
FR
coriander seed oil
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
dimethyl alpha-ionone
FR
dimethyl benzyl carbinol
FL/FR
floral pyranol
FR
gardenia oxide
FR
geranium oil bourbon
FL/FR
heliotropin
FL/FR
heliotropyl diethyl acetal
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
ho leaf oil
FR
alpha-
ionol
FL/FR
beta-
irone
FL/FR
alpha-
irone
FL/FR
laevo-
linalool
FL/FR
linalool
FL/FR
linalool oxide
FL/FR
methyl dihydrojasmonate
FL/FR
N-
methyl ionone
FR
mimosa absolute france
FL/FR
ocean propanal
FL/FR
orris pyridine 25% IPM
FR
peony alcohol
FR
phenethyl alcohol
FL/FR
phenethyl salicylate
FL/FR
rhodinol
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
tetrahydrolinalool
FL/FR
violet methyl carbonate
FR
ylang ylang flower oil
FL/FR
fresh
10-
undecen-1-yl acetate
FL/FR
fruity
allyl amyl glycolate
FR
allyl cyclohexyl propionate
FL/FR
benzaldehyde
FL/FR
beta-
damascone
FL/FR
green acetate
FR
green
galbanum oil
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl tiglate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
methyl cyclocitrone (IFF)
FR
3-
phenyl propionaldehyde
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
clary sage oil france
FL/FR
daucus carota fruit oil
FL/FR
herbal carene
FR
lavender absolute bulgaria
FL/FR
nopyl acetate
FR
beta-
pinene
FL/FR
laevo-beta-
pinene
FL/FR
marine
marine pyridine
FR
mossy
oakmoss absolute
FL/FR
veramoss (IFF)
FR
musk
dehydro beta-linalool
FL/FR
3-
methyl-6-cyclohexadecen-1-one
FR
musk decanolide
FR
musk ether
FR
musk indane
FR
musk indanone
FR
musk methyl ketone
FR
6,7,8,9-
tetrahydro-7,7,8,9,9-pentamethyl-5H-cyclopenta[H]quinazoline
FR
powdery
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
baby powder fragrance
FR
(E)-alpha-
methyl ionone (50-60%)
FL/FR
midnight passion fragrance
FR
smoky
2,6-
dimethoxyphenol
FL/FR
spicy
benzyl isoeugenol
FL/FR
cassia bark oil china
FL/FR
clove bud oil
FL/FR
eugenol
FL/FR
iso
eugenyl acetate
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
methyl isoeugenol
FL/FR
nutmeg oil
FL/FR
black
pepper oil
FL/FR
terpenic
angelica seed oil
FL/FR
frankincense oil
FL/FR
alpha-
terpineol
FL/FR
tonka
coumarin
FR
deertongue absolute
FR
tonka bean absolute
FR
vanilla
ethyl vanillin
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
waxy
1-
dodecanol
FL/FR
ethyl laurate
FL/FR
1-
undecanol
FL/FR
woody
acetyl cedrene
FR
amber carbinol
FR
amber dioxane
FR
amber formate
FR
amber pentadecane
FR
ambrene acetal
FR
cabreuva wood oil
FR
beta-
caryophyllene oxide
FL/FR
atlas
cedarwood absolute
FR
atlas
cedarwood oil
FR
cedrela wood oil
FR
alpha-
cedrene epoxide
FR
cedrenyl acetate
FR
cedrol methyl ether
FR
cedryl acetate
FL/FR
cedryl formate
FR
cedryl methyl ether
FR
dihydro-beta-ionone
FL/FR
4-(3,3-
dimethyl bicyclo(2.2.1)hept-2-yl)-5-methyl-2-oxabicyclo(2.2.2)octane
FR
frankincense resinoid
FL/FR
guaiacwood oil
FL/FR
gurjun balsam oil
FR
hinoki root oil
FR
labdanum ethanone
FR
iso
longifolene epoxide
FR
iso
longifolene ketone
FR
para-
menth-3-en-1-ol
FL/FR
2-
methoxy-4-vinyl phenol
FL/FR
methyl cedryl ketone
FL/FR
delta-
methyl ionone
FL/FR
methyl vetivate
FR
patchouli ethanone
FR
patchouli oil
FL/FR
sandal pentenol
FL/FR
sandal pentenone
FR
sandalwood oil west australia (santalum spicatum)
FR
santall
FR
sclareolide
FL/FR
timber propanol
FR
tobacarol (IFF)
FR
tobacco nonene
FR
4,6,11-
trimethyl-5-oxatricyclo(6.2.2.0*4,9*)dodec-6-ene
FR
vetiver oil haiti
FL/FR
vetiver specialty
FR
vetiveryl acetate
FL/FR
woody acetate
FR
(Z)-
woody amylene
FR
woody cyclohexanone
FR
woody dioxolane
FR
woody epoxide
FR
woody nonane (ethoxy)
FR
woody propanol
FR
For Flavor
No flavor group found for these
ambergris tincture
FL/FR
ambroxide
FL/FR
cistus ladaniferus resinoid
FL/FR
dehydro beta-linalool
FL/FR
para-
menth-3-en-1-ol
FL/FR
delta-
methyl ionone
FL/FR
(E)-alpha-
methyl ionone (50-60%)
FL/FR
laevo-beta-
pinene
FL/FR
sandal pentenol
FL/FR
vetiveryl acetate
FL/FR
beta-
damascone
FL/FR
aldehydic
aldehydic
1-
undecanol
FL/FR
amber
amber naphthofuran
FL/FR
ambrette seed oil CO2 extract
FL/FR
angelica seed oil
FL/FR
labdanum oil
FL/FR
anisic
para-
anisyl phenyl acetate
FL/FR
balsamic
siam
benzoin resin
FL/FR
siam
benzoin resinoid
FL/FR
benzyl salicylate
FL/FR
iso
butyl cinnamate
FL/FR
ethyl cinnamate
FL/FR
myrrh oil
FL/FR
opoponax absolute (commiphora erythraea var. glabrescens engle)
FL/FR
peru balsam oil
FL/FR
styrax oil (liquidambar styraciflua)
FL/FR
styrax resinoid (liquidambar styraciflua)
FL/FR
berry
raspberry ketone methyl ether
FL/FR
cherry
heliotropin
FL/FR
citrus
laevo-
linalool
FL/FR
linalool
FL/FR
bitter
orange peel oil
FL/FR
bitter
orange peel oil italy
FL/FR
alpha-
terpineol
FL/FR
creamy
veratraldehyde
FL/FR
fatty
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
floral
bois de rose oil brazil
FL/FR
geranium oil bourbon
FL/FR
beta-
irone
FL/FR
methyl dihydrojasmonate
FL/FR
ocean propanal
FL/FR
phenethyl alcohol
FL/FR
rhodinol
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
satinaldehyde
FL/FR
tetrahydrolinalool
FL/FR
ylang ylang flower oil
FL/FR
fruity
allyl cyclohexyl propionate
FL/FR
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
benzaldehyde
FL/FR
benzyl alcohol
FL/FR
bitter
orange peel oil brazil
FL/FR
greasy
10-
undecen-1-yl acetate
FL/FR
green
iso
amyl salicylate
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
cinnamyl alcohol
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
galbanum oil
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl tiglate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
linalool oxide
FL/FR
oakmoss absolute
FL/FR
3-
phenyl propionaldehyde
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
clary sage oil france
FL/FR
coriander seed oil
FL/FR
daucus carota fruit oil
FL/FR
lavender absolute bulgaria
FL/FR
medicinal
2,6-
dimethoxyphenol
FL/FR
dimethyl benzyl carbinol
FL/FR
phenethyl salicylate
FL/FR
phenolic
guaiacyl phenyl acetate
FL/FR
pine
beta-
pinene
FL/FR
smoky
2-
methoxy-4-vinyl phenol
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
1-
dodecanol
FL/FR
spicy
benzyl cinnamate
FL/FR
benzyl isoeugenol
FL/FR
cassia bark oil china
FL/FR
clove bud oil
FL/FR
eugenol
FL/FR
iso
eugenyl acetate
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
methyl cinnamate
FL/FR
methyl isoeugenol
FL/FR
nutmeg oil
FL/FR
black
pepper oil
FL/FR
3-
phenyl propyl alcohol
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
vanilla
ethyl vanillin
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
waxy
decanal (aldehyde C-10)
FL/FR
decanol
FL/FR
ethyl laurate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
mimosa absolute france
FL/FR
woody
ambrette seed absolute
FL/FR
ambroxan
FL/FR
amyris wood oil
FL/FR
iso
bornyl acetate
FL/FR
beta-
caryophyllene oxide
FL/FR
cedryl acetate
FL/FR
dihydro-beta-ionone
FL/FR
frankincense oil
FL/FR
frankincense resinoid
FL/FR
guaiacwood oil
FL/FR
alpha-
ionol
FL/FR
alpha-
irone
FL/FR
methyl cedryl ketone
FL/FR
patchouli oil
FL/FR
sclareol
FL/FR
sclareolide
FL/FR
vetiver oil haiti
FL/FR
 
Potential Uses:
FRabronia
FRaldehydic
FRamber
FRambergris
FRambreine
FRanimal
FRautumn
FRbalsam
FRbark
FRchamomile
FRchypre
FRcigar
FL/FRcistus
FRcountry meadow
FL/FRcroton eluteria bark
FRdahlia
FRdaisy
FRdaphne
FRdeertongue absolute replacer
FRdogwood
FRfern
 fir
FRfir balsam
FRfir needle oil replacer
FRflouve
FRflouve blossom
FRforest
FRfrankincense
FL/FRgalangal root
FRgardenia
FRgenet
FRginger white ginger
FL/FRguaiacwood
FRhabuba
FRhay new mown hay
FRheather
FRincense
FRlabdanum
FRlavender
FRleather
FL/FRlovage root
FRmusk
FRocean sea
FRopoponax
FRoriental
FRpatchouli
FRpine
FRpine forest
FRpinion
FRpowder
FRsaffron
FRspikenard oil replacer
FRsweet grass
FRtobacco
FRtonka bean
FL/FRvalerian
FRverbena
FRviolet
FRwoodruff
FL/FRyerba mate
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 amber oxepin
 amberketal (Givaudan)
 ambermor ketal crystal (IFF)
 ambermor ketal IPM (IFF)
 ambraketal
 dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth(2,1-c)oxepin
 dodecahydro-3,8,8,11a-tetramethyl-5H-3,5a-epoxynaphth[2,1-c]oxepin
 dodecahydrotetramethyl epoxynaphthoxepin
5H-3,5a-epoxynaphth(2,1-c)oxepin, dodecahydro-3,8,8,11a-tetramethyl-
5H-3,5a-epoxynaphth[2,1-c]oxepin, dodecahydro-3,8,8,11a-tetramethyl-, [3R-(3a,5aa,7aβ,11aβ,11ba)]-
5H-3,5a-epoxynaphth[2,1-c]oxepin, dodecahydro-3,8,8,11a-tetramethyl-, [3S-(3a,5aa,7aa,11aβ,11ba)]-
5,5,9,13-tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane
 Z11 DIPG (Firmenich)
 Z11 MIP (Firmenich)
 Z11 MIP via white biotech (Firmenich)
 
 
Notes:
Blends well with absolutes.
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