EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

geranyl acetoacetate
trans-3,7-dimethyl-2,6-octadien-1-yl 3-oxobutanoate

Sponsors

Name:[(2E)-3,7-dimethylocta-2,6-dienyl] 3-oxobutanoate
CAS Number: 10032-00-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:233-101-5
FDA UNII:08QN2PN8MT
Nikkaji Web:J54.985A
CoE Number:243
XlogP3-AA:3.30 (est)
Molecular Weight:238.32694000
Formula:C14 H22 O3
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:599 geranyl acetoacetate
FLAVIS Number:09.405 (Old)
DG SANTE Food Flavourings:09.405 geranyl acetoacetate
FEMA Number:2510 geranyl acetoacetate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: GERANYL ACETOACETATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
 
Physical Properties:
Appearance:colorless to pale yellow clear oily liquid (est)
Assay: 97.00 to 100.00
Food Chemicals Codex Listed: No
Boiling Point: 127.00 to 129.00 °C. @ 22.00 mm Hg
Vapor Pressure:0.000115 mm/Hg @ 25.00 °C. (est)
Flash Point: 291.00 °F. TCC ( 143.89 °C. )
logP (o/w): 3.517 (est)
Soluble in:
 alcohol
 oils
 water, 33.71 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items:note
amyl acetoacetate
isoamyl acetoacetate
para-anisyl acetoacetate
benzyl acetoacetate
bergamot acetoacetate
butyl acetoacetate
isobutyl acetoacetate
cinnamyl acetoacetate
cyclohexyl acetoacetate
dodecyl acetoacetate
ethyl 2-ethyl acetoacetate
ethyl acetoacetate
heptyl acetoacetate
(Z)-3-hexen-1-yl acetoacetate
hexyl acetoacetate
jasmin acetoacetate
laevo-menthyl acetoacetate
methyl acetoacetate
spicy acetoacetate
 
Organoleptic Properties:
Odor Type: fruity
Odor Strength:medium
sweet fruity winey fermented apple skin
Odor Description:at 100.00 %. sweet fruity winey fermented apple skin
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Alfrebro
GERANYL ACETOACETATE
Odor: Sweet, Fruity, Wine, Fermented, Apple
BOC Sciences
For experimental / research use only.
Geranyl Acetoacetate
Nagar Haveli Perfumes & Aromatics
Geranyl Acetoacetate
Odor: Sweet fruity winey fermented apple skin
Penta International
GERANYL ACETOACETATE, Kosher
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
4 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
(Moreno, 1976k)

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for geranyl acetoacetate usage levels up to:
  6.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): ND (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.04 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
 average usual ppmaverage maximum ppm
baked goods: 1.0000010.00000
beverages(nonalcoholic): 0.500000.50000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: 1.000001.00000
fruit ices: 1.000001.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: 1.000003.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) on a request from the Commission related to - Flavouring Group Evaluation 10: Aliphatic primary and secondary saturated and unsaturated alcohols, aldehydes, acetals, carboxylic acids and esters containing an additional oxygenated functional group and lactones from chemical groups 9, 13 and 30 - (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf

Flavouring Group Evaluation 10, Revision 1 (FGE10 Rev1)[1] - Aliphatic primary and secondary saturated and unsaturated alcohols, aldehydes, acetals, carboxylic acids and esters containing an additional oxygenated functional group and lactones from chemical groups 9, 13 and 30 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food (AFC)
View page or View pdf

Flavouring Group Evaluation 202: 3-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.3 of FGE.19[1]
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 10, Revision 2 (FGE.10Rev2): Aliphatic primary and secondary saturated and unsaturated alcohols, aldehydes, acetals, carboxylic acids and esters containing an additional oxygenated functional group and lactones from chemical groups 9, 13 and 30
View page or View pdf

EPI System: View
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5956805
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
[(2E)-3,7-dimethylocta-2,6-dienyl] 3-oxobutanoate
Chemidplus:0010032005
 
References:
 [(2E)-3,7-dimethylocta-2,6-dienyl] 3-oxobutanoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:10032-00-5
Pubchem (cid):5956805
Pubchem (sid):134990482
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
CHEBI:View
HMDB (The Human Metabolome Database):HMDB38256
FooDB:FDB017550
Export Tariff Code:2915.39.9050
ChemSpider:View
FAO:Geranyl acetoacetate
 
Potential Blenders and core components note
For Odor
No odor group found for these
propyl 2-methyl butyrate
FL/FR
alcoholic
alcoholic
fusel oil
FL/FR
propyl alcohol
FL/FR
balsamic
cinnamyl butyrate
FL/FR
opoponax oil (balsamodendron kafal)
FL/FR
opoponax resinoid (balsamodendron kafal)
FR
terpinyl cinnamate
FL/FR
caramellic
diethyl malate
FL/FR
creamy
butyl lactate
FL/FR
earthy
amyl octanoate
FL/FR
octyl phenyl acetate
FL/FR
ethereal
iso
amyl acetoacetate
FL/FR
iso
butyl alcohol
FL/FR
methyl acetate
FL/FR
fatty
butyl undecylenate
FL/FR
3-
decen-2-one
FL/FR
fermented
butyl laevo-lactate
FL/FR
methyl decanoate
FL/FR
3-
methyl-1-pentanol
FL/FR
2-
pentanol
FL/FR
valeraldehyde
FL/FR
floral
bois de rose oil brazil
FL/FR
coranol (Firmenich)
FR
gamma-
damascone
FR
alpha-
damascone
FL/FR
dihydrolinalool
FL/FR
dimethyl anthranilate
FL/FR
3,6-
dimethyl-3-octanol
FL/FR
ethyl linalool
FR
ethyl linalyl acetal
FR
ethyl linalyl acetate
FR
ethyl linalyl ether
FL/FR
ho leaf oil
FR
ho wood oil
FR
dextro-
linalool
FL/FR
linalool
FL/FR
laevo-
linalool
FL/FR
linalool oxide
FL/FR
linalyl anthranilate
FL/FR
methyl citronellate
FL/FR
rose oil (rosa damascena) bulgaria
FL/FR
tetrahydrolinalool
FL/FR
fruity
acetaldehyde diisoamyl acetal
FL/FR
amyl 2-methyl butyrate
FL/FR
amyl isobutyrate
FL/FR
amyl isovalerate
FL/FR
iso
amyl valerate
FL/FR
apple ketal
FL/FR
benzyl isovalerate
FL/FR
benzyl propionate
FL/FR
butyl acetoacetate
FL/FR
iso
butyl acetoacetate
FL/FR
butyl anthranilate
FL/FR
butyl hexanoate
FL/FR
iso
butyl isovalerate
FL/FR
butyl isovalerate
FL/FR
cyclohexyl butyrate
FL/FR
cyclohexyl isovalerate
FL/FR
diethyl laevo-tartrate
FL/FR
diethyl sebacate
FL/FR
dodecyl propionate
FL/FR
ethyl 2-ethyl acetoacetate
FL/FR
ethyl 3,5,5-trimethyl hexanoate
FR
ethyl heptanoate
FL/FR
ethyl isovalerate
FL/FR
ethyl valerate
FL/FR
farnesyl acetone
FL/FR
fruity ketal
FL/FR
geranyl 2-methyl butyrate
FL/FR
geranyl isovalerate
FL/FR
grape butyrate
FL/FR
(Z)-3-
hexen-1-yl isobutyrate
FL/FR
hexyl formate
FL/FR
methyl butyrate
FL/FR
methyl isovalerate
FL/FR
methyl nonanoate
FL/FR
methyl valerate
FL/FR
nonyl isovalerate
FL/FR
2-
pentanone
FL/FR
propyl heptanoate
FL/FR
iso
propyl isovalerate
FL/FR
propyl isovalerate
FL/FR
sorbyl butyrate
FL/FR
green
benzaldehyde dimethyl acetal
FL/FR
butyl heptanoate
FL/FR
green
cognac oil
FL/FR
heptanal (aldehyde C-7)
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(E)-2-
hexen-1-yl butyrate
FL/FR
(Z)-3-
hexen-1-yl butyrate
FL/FR
(E)-2-
hexen-1-yl propionate
FL/FR
(E)-2-
hexen-1-yl valerate
FL/FR
(Z)-3-
hexen-1-yl valerate
FL/FR
(Z)-3-
hexenal diethyl acetal
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl butyrate
FL/FR
hexyl isobutyrate
FL/FR
hexyl phenyl acetate
FL/FR
manzanate (Givaudan)
FL/FR
(E)-2-
pentenal
FL/FR
herbal
iso
amyl tiglate
FL/FR
clary sage concrete
FL/FR
white
cognac oil
FL/FR
ethyl chrysanthemate
FR
phenethyl senecioate
FL/FR
honey
methyl hydrocinnamate
FL/FR
roasted
2-
methyl-1-butanol
FL/FR
spicy
cubeb oil
FL/FR
waxy
allyl nonanoate
FL/FR
iso
amyl laurate
FL/FR
ethyl decanoate
FL/FR
ethyl nonanoate
FL/FR
ethyl octanoate
FL/FR
winey
butyl angelate
FL/FR
2-
hexanol
FL/FR
methyl 3-acetoxyoctanoate
FL/FR
woody
kaempferia galanga rhizome oil
FL/FR
marine formate
FR
For Flavor
No flavor group found for these
acetaldehyde diisoamyl acetal
FL/FR
amyl 2-methyl butyrate
FL/FR
amyl isobutyrate
FL/FR
amyl isovalerate
FL/FR
amyl octanoate
FL/FR
iso
amyl tiglate
FL/FR
2-
amyl-5 or 6-keto-1,4-dioxane
FL
butyl acetoacetate
FL/FR
butyl angelate
FL/FR
2-
butyl furan
FL
iso
butyraldehyde propylene glycol acetal
FL
cyclohexyl butyrate
FL/FR
diethyl laevo-tartrate
FL/FR
diethyl malate
FL/FR
dodecyl propionate
FL/FR
ethyl 3-hydroxyoctanoate
FL
ethyl aconitate
FL
ethyl linalyl ether
FL/FR
farnesyl acetone
FL/FR
geranyl 2-methyl butyrate
FL/FR
heptyl 2-methyl butyrate
FL
2-
hexanol
FL/FR
(Z)-3-
hexenal diethyl acetal
FL/FR
(E)-2-
hexenal dimethyl acetal
FL
dextro-
linalool
FL/FR
methyl 3-acetoxyoctanoate
FL/FR
methyl hydrocinnamate
FL/FR
2-
methyl-1-butanol
FL/FR
nonyl isovalerate
FL/FR
octyl phenyl acetate
FL/FR
oenanthic ether
FL
phenethyl senecioate
FL/FR
propyl 2-methyl butyrate
FL/FR
iso
propyl isovalerate
FL/FR
propyl isovalerate
FL/FR
sorbyl propionate
FL
alcoholic
alcoholic
propyl alcohol
FL/FR
balsamic
opoponax oil (balsamodendron kafal)
FL/FR
buttery
butyl laevo-lactate
FL/FR
camphoreous
kaempferia galanga rhizome oil
FL/FR
citrus
linalool
FL/FR
laevo-
linalool
FL/FR
coffee
diisoamyl thiomalate
FL
cooling
manzanate (Givaudan)
FL/FR
dairy
butyl lactate
FL/FR
ethereal
iso
butyl alcohol
FL/FR
methyl acetate
FL/FR
fatty
iso
amyl laurate
FL/FR
methyl decanoate
FL/FR
fermented
methyl thio isovalerate
FL
floral
bois de rose oil brazil
FL/FR
dihydrolinalool
FL/FR
linalyl anthranilate
FL/FR
methyl citronellate
FL/FR
rose oil (rosa damascena) bulgaria
FL/FR
tetrahydrolinalool
FL/FR
fruity
iso
amyl acetoacetate
FL/FR
iso
amyl valerate
FL/FR
apple ketal
FL/FR
benzyl isovalerate
FL/FR
benzyl propionate
FL/FR
iso
butyl acetoacetate
FL/FR
butyl anthranilate
FL/FR
butyl heptanoate
FL/FR
butyl hexanoate
FL/FR
butyl isovalerate
FL/FR
cyclohexyl isovalerate
FL/FR
alpha-
damascone
FL/FR
diethyl sebacate
FL/FR
dimethyl anthranilate
FL/FR
ethyl 2-ethyl acetoacetate
FL/FR
ethyl heptanoate
FL/FR
ethyl isovalerate
FL/FR
ethyl valerate
FL/FR
fruity ketal
FL/FR
fusel oil
FL/FR
(Z)-3-
hexen-1-yl isobutyrate
FL/FR
hexyl phenyl acetate
FL/FR
methyl isovalerate
FL/FR
methyl valerate
FL/FR
2-
pentanone
FL/FR
sorbyl butyrate
FL/FR
terpinyl cinnamate
FL/FR
fusel
white
cognac oil
FL/FR
green
cognac oil
FL/FR
methyl butyrate
FL/FR
green
benzaldehyde dimethyl acetal
FL/FR
iso
butyl isovalerate
FL/FR
3-
decen-2-one
FL/FR
geranyl isovalerate
FL/FR
grape butyrate
FL/FR
heptanal (aldehyde C-7)
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(E)-2-
hexen-1-yl butyrate
FL/FR
(Z)-3-
hexen-1-yl butyrate
FL/FR
(E)-2-
hexen-1-yl propionate
FL/FR
(E)-2-
hexen-1-yl valerate
FL/FR
(Z)-3-
hexen-1-yl valerate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl butyrate
FL/FR
hexyl formate
FL/FR
hexyl isobutyrate
FL/FR
linalool oxide
FL/FR
(E)-2-
pentenal
FL/FR
herbal
clary sage concrete
FL/FR
3,6-
dimethyl-3-octanol
FL/FR
musty
2-
pentanol
FL/FR
propionaldehyde
FL
spicy
cubeb oil
FL/FR
waxy
allyl nonanoate
FL/FR
butyl undecylenate
FL/FR
ethyl decanoate
FL/FR
ethyl nonanoate
FL/FR
ethyl octanoate
FL/FR
propyl heptanoate
FL/FR
whiskey
3-
methyl-1-pentanol
FL/FR
winey
cinnamyl butyrate
FL/FR
methyl nonanoate
FL/FR
valeraldehyde
FL/FR
 
Potential Uses:
FRapple
FRblueberry
FRcherry
FRfloral
FRfruit
FRherbal
FRmango
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 acetoacetic acid, 3,7-dimethyl-2,6-octadienyl ester, (E)-
 butanoic acid, 3-oxo-, (2E)-3,7-dimethyl-2,6-octadien-1-yl ester
 butanoic acid, 3-oxo-, 3,7-dimethyl-2,6-octadienyl ester, (E)-
(E)-3,7-dimethyl-2,6-octadien-1-yl 3-oxobutanoate
trans-3,7-dimethyl-2,6-octadien-1-yl 3-oxobutanoate
3,7-dimethyl-2,6-octadien-1-yl 3-oxobutanoate, trans-
(E)-3,7-dimethyl-2,6-octadien-1-yl acetoacetate
trans-3,7-dimethyl-2,6-octadien-1-yl acetoacetate
3,7-dimethyl-2,6-octadien-1-yl acetoacetate, trans-
3,7-dimethyl-2,6-octadienyl 3-oxobutanoate, (E)-
(E)-3,7-dimethyl-2,6-octadienyl acetoacetate
3,7-dimethyl-2,6-octadienyl acetoacetate, (E)-
(2E)-3,7-dimethylocta-2,6-dien-1-yl 3-oxobutanoate
[(2E)-3,7-dimethylocta-2,6-dienyl] 3-oxobutanoate
(E)-geranyl 3-oxobutanoate
 geranyl acetoacetate
(E)-geranyl beta-ketobutyrate
(E)-neryl acetoacetate
 
 
Notes:
None found
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2018 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy