Articles:
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Bedoukian Research, Inc. Constantly Improving Working closely with our customers to meet their requirements. Paul Bedoukian founded the company to fill a niche as a supplier of high quality specialty aroma and flavor ingredients. In 1975 the company began manufacturing insect pheromones which are chemically similar to flavor and fragrance ingredients. Today, Bedoukian Research offers more than 450 Aroma Chemicals and 50 Insect Pheromones, while also providing custom manufacturing services to the pharmaceutical, agrochemical, and specialty chemical industries. US Email: Customer Service US Voice: 1-203-830-4000 US Fax: 1-203-830-4010 Products List: View Product(s): 116 cis-3-HEXENYL TIGLATE ≥96.05% (cis), Kosher MSDS Can be used as a fresh topnote in mixed floral fragrances or herbal compositions.
Used in melon flavors and also for woody notes in herbal flavors.
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Indukern, S.A. F&F Ingredients Division Commitment to quality Idukern F&F Ingredients is your partner for the fragrance and flavor ingredients. Indukern F&F focuses in particular on the service it offers its clients in terms of quality, speed and direct consultancy with more than 1600 different products in stock ready for prompt shipment: Aromachemicals, Essential Oils and Natural Isolates. Email: Info Email: Laura Iglesias (Spain) Email: Luciana Soares (Brazil) Email: Jose Pablo Sanchez Bejos (Mexico) Email: Monica Taborda (Colombia) Voice: +34 93 506 91 00 Fax: +34 93 506 91 95 Product(s): CIS-3-HEXENYL TIGLATE
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Lluch Essence S.L. A family company dedicated to sales and distribution Flexibility, availability, price and quality. Flexibility, availability, price and quality make LLUCH ESSENCE S.L. one of Europe’s references when it comes to essential oils and aroma chemicals, and it is now well known all around the world. Email: Info Voice: 34 93 379 38 49 Fax: 34 93 370 65 04 Product(s): cis-3-HEXENYL TIGLATE
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Penta International Corporation Chemistry innovation At Penta, our products and services help businesses do business better. For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes. US Email: Technical Services US Email: Sales US Voice: (973) 740-2300 US Fax: (973) 740-1839 Product(s): 08-36000 cis-3-HEXENYL TIGLATE, Kosher
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SAFC Complete Supply Chain The perfect blend of products and services that bring your creativity to life. Sigma-Aldrich is a leading Life Science and High Technology company dedicated to providing high-quality, safe and certified flavor ingredients with transparent and easily accessible documentation to customers around the globe. Sigma-Aldrich also provides a suite of analytical tools that allow food analysts to simplify sample preparation, cleanup and analysis steps, while increasing sensitivity to trace ingredients and harmful substances to meet regulations and quality standards. Email: Information US Email: Sales US Voice: 800-244-1173 US Fax: 800-368-4661 Product(s): W393118 cis-3-Hexenyl tiglate ≥97%, Kosher MSDS
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SRS Aromatics Ltd For over 25 years Bringing flavour and fragrance into your world. As suppliers / distributors of ingredients to the fragrance and flavour industries, our goal is to provide high quality materials at competitive prices with an exceptional level of service. Established in 1984, SRS Aromatics Ltd is an independent family owned business which has become very well-respected within the fragrance and flavour industry as a reliable and trustworthy partner. Over the years this has allowed the company to develop strong relationships with many global manufacturers; several of whom we represent in the UK. A core aim of our business is to work extremely closely with both our suppliers and customers to maximise service levels with minimum disruption to supply. Email: Info Email: Sales Voice: +44 (0) 1284 704076 Fax: +44 (0) 1284 760819 Product(s): CIS 3 HEXENYL TIGLATE
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The Lermond Company Your Sourcing Resource The Lermond family has been sourcing raw materials for the flavor and fragrance industry for nearly 7 decades. The Lermond Company is a women-owned distributor of raw materials primarily servicing the flavor and fragrance industry. For three generations, members of the Lermond family have been integral sourcing partners for the North American flavor and fragrance industry. We supply high quality essential oils, aroma chemicals, absolutes, concretes, resinoids and floral waters from around the world to the global industry. Email: Info Email: Tara Email: Erica Voice: 201-896-3300 Fax: 201-623-2910 Product(s): 16397 cis-3-Hexenyl Tiglate
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Ernesto Ventós S.A. Continued Customer Satisfaction We employ our five senses to do our job well. Ventós has specialized in the distribution of raw materials for the flavour and fragrance industry. With more than 1700 references permanently available from stock, we offer a just-in-time response to our customer needs, being able to deliver from 1kg to several tonnes all over the world. Email: Information Email: Gemma Parramon (Europe) US Email: Jordi Sort (Northern Europe and US) Email: Olivia Gautier (Asia, Africa and Oceania ) Email: Ramon Rubau (Latin America) Voice: +34 934706210 Fax: +34 934733010 Product(s): CIS-3-HEXENYL TIGLATE
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| [(Z)-hex-3-enyl] (Z)-2-methylbut-2-enoate (Click)
IUPAC Name: [(Z)-hex-3-enyl] (Z)-2-methylbut-2-enoate
Std.InChI: InChI=1S/C11H18O2/c1-4-6-7-8-9-13-11(12)10(3)5-2/h5-7H,4,8-9H2,1-3H3/b7-6+,10-5-
InChI: InChI=1/C11H18O2/c1-4-6-7-8-9-13-11(12)10(3)5-2/h5-7H,4,8-9H2,1-3H3/b7-6+,10-5-
Std.InChIKey: JNWQKXUWZWKUAY-BHHIIOOYSA-N
InChIKey: JNWQKXUWZWKUAY-BHHIIOOYBB
SMILES: CC/C=C\CCOC(=O)/C(=C\C)/C
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| CAS Number: | 67883-79-8 |
| ECHA EC Number: | 267-554-5 |
| FDA UNII: | 9S19N7N2QK |
| Beilstein Number: | 2961441 |
| MDL: | MFCD00036528 |
| FEMA Number: | 3931 |
| XlogP3-AA: | 3.10 (est) |
| Molecular Weight: | 182.26286000 |
| Formula: | C11 H18 O2 |
| NMR Predictor: | Predict |
| Category: | flavor and fragrance agents |
| US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: | |
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
| JECFA Food Flavoring: | 1277 cis-3-hexenyl tiglate |
| Flavis Number: | 09.559 (Old) |
| EU SANCO Food Flavourings: | 09.559 hex-3(cis)-enyl 2-methylcrotonate |
| FEMA Number: | 3931 cis-3-hexenyl tiglate |
| FDA Mainterm: | (Z)-3-HEXENYL(E)-2-METHYL-2-BUTENOATE |
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 98.00 to 100.00 % sum of isomers |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.91500 to 0.92100 @ 25.00 °C. |
| Pounds per Gallon - (est).: | 7.614 to 7.664 |
| Refractive Index: | 1.45800 to 1.46200 @ 20.00 °C. |
| Boiling Point: | 140.00 °C. @ 30.00 mm Hg |
| Boiling Point: | 105.00 °C. @ 5.00 mm Hg |
| Vapor Pressure: | 0.030600 mm/Hg @ 25.00 °C. (est) |
| Vapor Density: | >1 ( Air = 1 ) |
| Flash Point: | 146.00 °F. TCC ( 63.33 °C. ) |
| logP (o/w): | 4.200 (est) |
Organoleptic Properties:
| Odor Type: | green |
| Odor Strength: | high , recommend smelling in a 10.00 % solution or less |
| Odor Description: at 10.00 % in propylene glycol. | green vegetable green banana earthy cortex herbal Luebke, William tgsc, (1992) |
| Odor sample from: | Bedoukian Research, Inc. |
| Odor Description: at 1.00 %. | Green, earthy vegetative with mushroom and radish nuances Mosciano, Gerard P&F 25, No. 5, 72, (2000) |
| Taste Description: at 1.00 - 5.00 ppm. | Green vegetative mushroom with herbaceous and fatty nuances Mosciano, Gerard P&F 25, No. 5, 72, (2000) |
| Substantivity: | 4 Hour(s) |
Cosmetic Information:
| CosIng: | cosmetic data |
| Cosmetic Uses: |
perfuming agents |
Suppliers:
Safety Information:
| European information : | |||
| Most important hazard(s): | |||
| None - None found. | |||
|
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. | |||
| Hazards identification | |||
| Classification of the substance or mixture | |||
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |||
| None found. | |||
| GHS Label elements, including precautionary statements | |||
| Pictogram | |||
| Hazard statement(s) | |||
| None found. | |||
| Precautionary statement(s) | |||
| None found. | |||
| Oral/Parenteral Toxicity: | |||
|
oral-rat LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 17, Pg. 809, 1979. | |||
| Dermal Toxicity: | |||
|
skin-rabbit LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 17, Pg. 809, 1979. | |||
| Inhalation Toxicity: | |||
| Not determined | |||
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.024 (μg/capita/day) | ||
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 70.00 (μg/capita/day) | ||
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 3900 (μg/person/day) | ||
| Threshold of Concern: | 1800 (μg/person/day) | ||
| Structure Class: | I | ||
| Recommendation for (Z)-3-hexen-1-yl tiglate usage levels up to: | |||
| 6.0000 % in the fragrance concentrate. | |||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA on the "Resources" link. | |||
| publication number: 19. Update in publication number(s): 20 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | 16.00000 | 30.00000 | |
| beverages(nonalcoholic): | 2.00000 | 5.00000 | |
| beverages(alcoholic): | 4.10000 | 8.10000 | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | 0.10000 | 0.10000 | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | 7.00000 | 15.00000 | |
| fruit ices: | - | - | |
| gelatins / puddings: | 4.00000 | 8.00000 | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | 0.20000 | 0.20000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | 2.00000 | 4.00000 | |
| meat products: | - | - | |
| milk products: | 0.50000 | 5.00000 | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | 2.00000 | 3.00000 | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
| Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). | |||
| Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. | |||
| average usage mg/kg | maximum usage mg/kg | ||
| Dairy products, excluding products of category 02.0 (01.0): | 7.00000 | 35.00000 | |
| Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 5.00000 | 25.00000 | |
| Edible ices, including sherbet and sorbet (03.0): | 10.00000 | 50.00000 | |
| Processed fruit (04.1): | 7.00000 | 35.00000 | |
| Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - | |
| Confectionery (05.0): | 10.00000 | 50.00000 | |
| Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 | |
| Bakery wares (07.0): | 10.00000 | 50.00000 | |
| Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 | |
| Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 | |
| Eggs and egg products (10.0): | - | - | |
| Sweeteners, including honey (11.0): | - | - | |
| Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 | |
| Foodstuffs intended for particular nutritional uses (13.0): | 10.00000 | 50.00000 | |
| Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 5.00000 | 25.00000 | |
| Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 | |
| Ready-to-eat savouries (15.0): | 20.00000 | 100.00000 | |
| Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 | |
Safety References:
| European Food Safety Athority(efsa): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): | |
| Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) on a request from the Commission related to Flavouring Group Evaluation 5: Esters of 23 branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and 24 branched- and straight-chain unsaturated carboxylic acids from chemical groups 1, 2, and 5 page or pdf | |
| Flavouring Group Evaluation 5, Revision 1 (FGE.05Rev1):Esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids from chemical groups 1, 2, and 5 (Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) page or pdf | |
| Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) page or pdf | |
| Flavouring Group Evaluation 5, Revision 2 (FGE.05Rev2): Branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols from chemical groups 1, 2, 3 and 5 page or pdf | |
| Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008) page or pdf | |
| EPI System: | View |
| Chemicalize.org: | Calculate predicted properties |
| EPA Substance Registry Services (TSCA): | 67883-79-8 |
| EPA ACToR: | Toxicology Data |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 2 |
| [(Z)-hex-3-enyl] (Z)-2-methylbut-2-enoate | |
| Chemidplus: | 0067883798 |
| RTECS: | EM9253500 for cas# 67883-79-8 |
References:
| [(Z)-hex-3-enyl] (Z)-2-methylbut-2-enoate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 67883-79-8 |
| Pubchem (cid): | 16220109 |
| Pubchem (sid): | 135209398 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2009 |
| (IUPAC): | Atomic Weights of the Elements 2009 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Everything Added to Food in the United States (EAFUS): | View |
| Export Tariff Code: | 2916.19.6000 |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
Potential Blenders and core components note
Potential Uses:
| banana | FR | |
| bark | ||
| fern fougere | FR | |
| floral | FR | |
| foliage | ||
| fungus mushroom | FR | |
| gardenia | FR | |
| green | FR | |
| green leaf | FR | |
| herbal | FR | |
| jasmin | FR | |
| mango | FR | |
| melon watermelon muskmelon cantaloupe | ||
| oakmoss mousse de chene moss | FR | |
| pepper green | FL | |
| tomato | FL | |
| woody | FR |
Natural Occurrence in: note
| champaca concrete @ 0.02% Data GC GRIN Trop Picture | |
| gardenia GRIN Trop Picture | |
| vassoura oil @ <0.01% Data GC GRIN Trop Picture |
Synonyms:
| cis- | hex-3-ene-1-yl trans-2-methyl-2-butenoate | ||
| [(Z)- | hex-3-enyl] (Z)-2-methylbut-2-enoate | ||
| hex-3(cis)-enyl 2-methylcrotonate | |||
| (Z)-3- | hexen-1-yl 2-methyl crotonate | ||
| cis-3- | hexen-1-yl 2-methyl crotonate | ||
| (Z)-3- | hexen-1-yl alpha-methyl crotonate | ||
| cis-3- | hexen-1-yl alpha-methyl crotonate | ||
| (Z)-3- | hexen-1-yl tiglate | ||
| cis-3- | hexen-1-yl tiglate | ||
| cis-3- | hexen-1-yl trans-2-methyl 2-butenoate | ||
| cis-3- | hexen-1-yl-2-methyl-trans-2-butenoate | ||
| (Z)-3- | hexenyl (E)-2-methyl 2-butenoate | ||
| (Z,Z)-3- | hexenyl 2-methyl-2-butenoate | ||
| (Z)-3- | hexenyl tiglate | ||
| C3 | hexenyl tiglate | ||
| cis-3- | hexenyl tiglate | ||
| cis-3- | hexenyl trans-2-methyl 2-butenoate | ||
| cis-3- | hexenyle tiglate | ||
| (2E)-2- | methyl-2-butenoic acid (3Z)-3-hexen-1-yl ester | ||
| (E,Z)-2- | methyl-2-butenoic acid 3-hexen-1-yl ester |
click on the picture(s) below to interact with the 3D model | |
| |
| Similar Items: note | |
| allyl tiglate | |
| amyl tiglate | |
| isoamyl tiglate | |
| benzyl methyl tiglate | |
| benzyl tiglate | |
| butyl tiglate | |
| isobutyl tiglate | |
| cinnamyl tiglate | |
| (E)-citronellyl tiglate | |
| (E)-ethyl tiglate | |
| geranyl methyl tiglate | |
| geranyl tiglate | |
| hexyl tiglate | |
| methyl tiglate | |
| 3-octyl tiglate | |
| phenethyl tiglate | |
| propyl tiglate | |
| isopropyl tiglate | |
| Soluble in: | |
| alcohol | |
| water, 23.73 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |