EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

beta-sinensal
2,6-dimethyl-10-methylene-2,6,11-dodecatrienal

Sponsors

Name:(2E,6E)-2,6-dimethyl-10-methylidenedodeca-2,6,11-trienal
CAS Number: 60066-88-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:262-043-3
FDA UNII:TJW2V5DYI3
Nikkaji Web:J14.807E
CoE Number:10381
XlogP3-AA:4.80 (est)
Molecular Weight:218.33954000
Formula:C15 H22 O
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:1227 2,6-dimethyl-10-methylene-2,6,11-dodecatrienal
FEMA Number:3141 beta-sinensal
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: 2,6-DIMETHYL-10-METHYLENE-2,6,11-DODECATRIENAL
 
Physical Properties:
Appearance:colorless to orange clear liquid (est)
Assay: 99.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:0.91700 to 0.92300 @ 25.00 °C.
Pounds per Gallon - (est).: 7.630 to 7.680
Refractive Index:1.50400 to 1.51300 @ 20.00 °C.
Boiling Point: 180.00 °C. @ 1.00 mm Hg
Boiling Point: 331.00 to 333.00 °C. @ 760.00 mm Hg
Acid Value: 3.00 max. KOH/g
Vapor Pressure:0.000137 mm/Hg @ 25.00 °C. (est)
Flash Point: 312.00 °F. TCC ( 155.56 °C. )
logP (o/w): 4.624 (est)
Soluble in:
 alcohol
 oils
 water, 0.4912 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: citrus
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
orange sweet fresh waxy juicy
Odor Description:at 10.00 % in dipropylene glycol. orange sweet fresh waxy juicy
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
Artiste
Sinensal Natural
BOC Sciences
For experimental / research use only.
2,6-Dimethyl-10-methylenedodeca-2,6,11-trien-1-al
Citrus and Allied Essences
Sinensal 18/20% ex orange (natural)
Market Report
Ernesto Ventós
SINENSAL NATURAL (EX ORANGE)
Odor: CITRIC, SWEET, FRESH, WAXY
Florida Chemical
Sinensals
Frutarom
NATURAL SINENSAL EX ORANGE
Frutarom
SINENSAL FRACTION
Lluch Essence
SINENSAL NATURAL EX-ORANGE
Penta International
SINENSAL, NATURAL, MIXTURE OF ALPHA & BETA, Kosher
Prodasynth
SINENSAL, NATURAL (EX ORANGE)
SUM OF ALPHA + BETA-SINENSAL > 20
Odor: CITRIC, SWEET, FRESH, WAXY
Reincke & Fichtner
beta-Sinensal natural
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for beta-sinensal usage levels up to:
  4.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.91 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.50 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 4. Update in publication number(s): 18
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): -10.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -10.00000
fruit ices: -10.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -10.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

List of apha, beta-Unsaturated Aldehydes and Ketones representative of FGE.19 substances for Genotoxicity Testing [1] - Statement of the Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
View page or View pdf

Flavouring Group Evaluation 201: 2-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.2 of FGE.19[1]
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 201 Revision 1 (FGE.201Rev1): 2-Alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19.
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):60066-88-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5281535
National Institute of Allergy and Infectious Diseases:Data
(2E,6E)-2,6-dimethyl-10-methylidenedodeca-2,6,11-trienal
Chemidplus:0060066888
 
References:
 (2E,6E)-2,6-dimethyl-10-methylidenedodeca-2,6,11-trienal
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:60066-88-8
Pubchem (cid):5281535
Pubchem (sid):135020411
Flavornet:60066-88-8
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
CHEBI:View
KEGG (GenomeNet):C09730
HMDB (The Human Metabolome Database):HMDB35643
FooDB:FDB014570
Export Tariff Code:3301.10
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
Wikipedia:View
RSC Learn Chemistry:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
octyl valerate
FR
aldehydic
aldehydic
decanal (aldehyde C-10)
FL/FR
lily pentanal
FR
3-
methyl-4-heptyl oxybutyraldehyde
FR
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
undecanal
FL/FR
anisic
para-
anisaldehyde
FL/FR
ocimum basilicum herb oil
FL/FR
balsamic
iso
amyl benzoate
FL/FR
amyris wood oil
FL/FR
siam
benzoin resinoid
FL/FR
cinnamyl alcohol
FL/FR
clover nitrile
FR
ethyl cinnamate
FL/FR
methyl cinnamate
FL/FR
myrrh oil
FL/FR
berry
raspberry ketone methyl ether
FL/FR
citrus
bergamot oil
FL/FR
citral
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
citrus paradisi peel extract
FL/FR
citrus reticulata blanco var. tangerine oil
FL/FR
citrus unshiu peel oil
FL/FR
(Z)-4-
decenal
FL/FR
4-
decenal
FL/FR
(E)-4-
decenal
FL/FR
(Z)-4-
decenal diethyl acetal
FR
dodecane nitrile
FR
2-
ethyl-1-hexanol
FL/FR
grapefruit oil c.p. california
FL/FR
lemon oil c.p. california
FL/FR
lime oil distilled mexico
FL/FR
clementine
mandarin fragrance
FR
mandarin oil
FL/FR
mandarin oil italy
FL/FR
(+)-
nootkatone
FL/FR
octanal glycol acetal
FR
orange fruit oil
FL/FR
blood
orange oil italy
FL/FR
bitter
orange peel oil
FL/FR
bitter
orange peel oil brazil
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
sweet
orange peel oil c.p. california
FL/FR
sweet
orange peel oil c.p. florida
FL/FR
sweet
orange peel oil c.p. valencia
FL/FR
sweet
orange peel oil distilled
FL/FR
bitter
orange peel oil italy
FL/FR
sweet
orange peel oil terpeneless
FL/FR
bitter
orange peel oil terpeneless
FL/FR
panax quinquefolius root tincture
FL/FR
alpha-
sinensal
FL/FR
tangerine oil america
FL/FR
tangerine oil california
FL/FR
fatty
(E,Z)-2,6-
dodecadienal
FL/FR
floral
alpha-
amyl cinnamaldehyde
FL/FR
iso
amyl salicylate
FL/FR
benzyl acetate
FL/FR
bois de rose oil brazil
FL/FR
citronellol
FL/FR
citronellyl ethyl ether
FR
coriander seed oil
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
dimethyl anthranilate
FL/FR
ethyl anthranilate
FL/FR
floral pyranol
FR
gardenia oxide
FR
geraniol
FL/FR
geranium oil bourbon
FL/FR
heliotropin
FL/FR
heliotropyl diethyl acetal
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
ho leaf oil
FR
hyacinth ether
FR
hydroxycitronellal
FL/FR
hydroxycitronellal / methyl anthranilate schiff's base
FR
leerall
FR
linalool
FL/FR
laevo-
linalool
FL/FR
linalool oxide
FL/FR
methyl dihydrojasmonate
FL/FR
mimosa absolute france
FL/FR
muguet carboxaldehyde
FR
muguet octadienol
FR
nerol
FL/FR
neroli oil bigarde
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
bitter
orangeflower absolute morocco
FL/FR
orris pyridine 25% IPM
FR
peony alcohol
FR
petitgrain mandarin oil terpeneless
FL/FR
petitgrain oil paraguay
FL/FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
phenethyl isobutyrate
FL/FR
phenethyl phenyl acetate
FL/FR
phenethyl propionate
FL/FR
rhodinol
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
rose butanoate
FL/FR
tetrahydrolinalool
FL/FR
undecanal dimethyl acetal
FR
(E)-2-
undecen-1-ol
FL/FR
violet methyl carbonate
FR
fruity
allyl amyl glycolate
FR
allyl cyclohexyl propionate
FL/FR
benzyl propionate
FL/FR
dimethyl benzyl carbinyl isobutyrate
FR
ethyl methyl anthranilate
FL/FR
methyl anthranilate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
(E)-2-
undecenal
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(E)-2-
hexenal
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
3-
phenyl propionaldehyde
FL/FR
violet leaf absolute
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
cardamom liquid resin
FR
(R)-(+)-
citronellal
FL/FR
clary sage oil france
FL/FR
(E)-2-
dodecenal
FL/FR
beta-
elemene
FL/FR
lavender absolute bulgaria
FL/FR
linalyl acetate
FL/FR
mossy
veramoss (IFF)
FR
powdery
para-
anisyl alcohol
FL/FR
spicy
mace oil
FL/FR
terpenic
alpha-
terpineol
FL/FR
tonka
coumarin
FR
tonka bean absolute
FR
tropical
passiflora edulis fruit extract
FL/FR
waxy
3-
decanone
FL/FR
2-
nonanol
FL/FR
woody
guaiacwood oil
FL/FR
santall
FR
For Flavor
No flavor group found for these
(R)-(+)-
citronellal
FL/FR
citrus unshiu peel oil
FL/FR
3-
decanone
FL/FR
4-
decenal
FL/FR
beta-
elemene
FL/FR
ethyl methyl anthranilate
FL/FR
(E)-2-
hexenal
FL
rose absolute (rosa damascena) bulgaria
FL/FR
alpha-
sinensal
FL/FR
(E)-2-
undecen-1-ol
FL/FR
panax quinquefolius root tincture
FL/FR
aldehydic
aldehydic
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
balsamic
siam
benzoin resinoid
FL/FR
ethyl cinnamate
FL/FR
myrrh oil
FL/FR
berry
raspberry ketone methyl ether
FL/FR
cherry
heliotropin
FL/FR
citrus
bergamot oil
FL/FR
citral
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
citrus paradisi peel extract
FL/FR
citrus reticulata blanco var. tangerine oil
FL/FR
(Z)-4-
decenal
FL/FR
grapefruit oil c.p. california
FL/FR
lemon oil c.p. california
FL/FR
lime oil distilled mexico
FL/FR
linalool
FL/FR
laevo-
linalool
FL/FR
mandarin oil
FL/FR
mandarin oil italy
FL/FR
nerol
FL/FR
(+)-
nootkatone
FL/FR
orange fruit oil
FL/FR
blood
orange oil italy
FL/FR
bitter
orange peel oil
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
sweet
orange peel oil c.p. california
FL/FR
sweet
orange peel oil c.p. florida
FL/FR
sweet
orange peel oil c.p. valencia
FL/FR
sweet
orange peel oil distilled
FL/FR
bitter
orange peel oil italy
FL/FR
bitter
orange peel oil terpeneless
FL/FR
sweet
orange peel oil terpeneless
FL/FR
petitgrain oil paraguay
FL/FR
tangerine oil america
FL/FR
tangerine oil california
FL/FR
alpha-
terpineol
FL/FR
creamy
para-
anisaldehyde
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
earthy
panax quinquefolius root extract
FL
fatty
2,4-
decadienal
FL
2-
ethyl-1-hexanol
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
floral
bois de rose oil brazil
FL/FR
citronellol
FL/FR
geraniol
FL/FR
geranium oil bourbon
FL/FR
linalyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
neroli oil bigarde
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
bitter
orangeflower absolute morocco
FL/FR
phenethyl alcohol
FL/FR
phenethyl propionate
FL/FR
rhodinol
FL/FR
tetrahydrolinalool
FL/FR
fruity
allyl cyclohexyl propionate
FL/FR
iso
amyl benzoate
FL/FR
para-
anisyl alcohol
FL/FR
benzyl acetate
FL/FR
benzyl propionate
FL/FR
dimethyl anthranilate
FL/FR
ethyl anthranilate
FL/FR
methyl anthranilate
FL/FR
bitter
orange peel oil brazil
FL/FR
petitgrain mandarin oil terpeneless
FL/FR
rose butanoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
iso
amyl salicylate
FL/FR
cinnamyl alcohol
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
(E,Z)-2,6-
dodecadienal
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
(E)-2-
hexenal
FL/FR
linalool oxide
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
3-
phenyl propionaldehyde
FL/FR
violet leaf absolute
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
clary sage oil france
FL/FR
coriander seed oil
FL/FR
lavender absolute bulgaria
FL/FR
ocimum basilicum herb oil
FL/FR
honey
phenethyl acetate
FL/FR
phenethyl isobutyrate
FL/FR
phenethyl phenyl acetate
FL/FR
ripe
(E)-4-
decenal
FL/FR
spicy
mace oil
FL/FR
methyl cinnamate
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
passiflora edulis fruit extract
FL/FR
waxy
decanal (aldehyde C-10)
FL/FR
(E)-2-
dodecenal
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hydroxycitronellal
FL/FR
mimosa absolute france
FL/FR
2-
nonanol
FL/FR
undecanal
FL/FR
(E)-2-
undecenal
FL/FR
woody
amyris wood oil
FL/FR
guaiacwood oil
FL/FR
 
Potential Uses:
FRagrumen aldehyde
FRaldehydic
FRamber
FRbergamot
FRberry jam
FRblackberry
FRbouquet
FRboysenberry
FRcherry black cherry
FRcitrus
FRcologne
FRcolonia
FRcurrant
FL/FRcurrant bud absolute replacer
FRdate
 emeraude
FRfrangipani plumeria
FRfreesia
 fruit tropical fruit
FRgrape
FRgrape concord grape
FLgrape white grape
FRhibiscus
FRhoneysuckle
FL/FRimmortelle
FRiris blossom
 kiwi blossom
FRkumquat
FRlemon
FRlime
FRlychee
FRmandarin
FL/FRmarjoram
 millefleurs
FRmock orange
FRmoss
FLnecterine
FRneroli
FRorange
FL/FRorange bitter orange peel
FRorange blossom
FRpassion blossom
FRpetitgrain
FL/FRpetitgrain bergamot petitgrain
FL/FRpetitgrain mandarin oil replacer
 petitgrain orange petitgrain
 petitgrain tangerine petitgrain
FRplum
 plum blossom
FLplum greengage plum
FRplum mirabelle plum
 plum mirabille blossom
 presence
FRprune
FRraisin
FRraspberry
 rose wild rose
FL/FRrue
FRscented stock
FRsweet pea
 tabu
FRtangerine
FRtangerine
FRwallflower
FRwine
 
Occurrence (nature, food, other):note
 bergamot oil @ trace%
Data GC Search Trop Picture
 blood orange oil (citrus sinensis l. var. sanguinello) italy @ 0.021%
Data GC Search Trop Picture
 blood orange oil (citrus sinensis l. var. tarocco) italy @ 0.023%
Data GC Search Trop Picture
 blood orange oil italy @ 0.036%
Data GC Search Trop Picture
 feverfew flower oil @ 2.6%
Data GC Search Trop Picture
 grapefruit oil c.p. @ 0.04%
Data GC Search Trop Picture
 grapefruit oil CO2 extract @ 0.31%
Data GC Search Trop Picture
 lemon petiole
Search Trop Picture
 mandarin oil uruguay @ 0.01-0.02%
Data GC Search Trop Picture
 orange fruit
Search Trop Picture
 orange oil terpeneless @ 1.30%
Data GC Search Trop Picture
 orange peel oil sweet c.p. blond italy @ 0.017%
Data GC Search Trop Picture
 orange peel oil sweet c.p. blond italy @ 0.030%
Data GC Search Trop Picture
 orange peel oil sweet c.p. blond italy @ 0.030%
Data GC Search Trop Picture
 orange peel oil sweet c.p. blond italy @ 0.044%
Data GC Search Trop Picture
 orange peel oil sweet c.p. blond italy @ 0.050%
Data GC Search Trop Picture
 orange peel oil sweet c.p. florida @ 0.02%
Data GC Search Trop Picture
 orange peel oil sweet c.p. valencia @ 0.03%
Data GC Search Trop Picture
 orange pericarp
Search Trop Picture
 petitgrain mandarin oil @ 1.60%
Data GC Search Trop Picture
 see sinensal, alpha-
 
Synonyms:
2,6-dimethyl-10-methylene dodeca-2,6,11-trien-1-al
2,6-dimethyl-10-methylene-2,6,11-dodecatrien-1-al
2,6-dimethyl-10-methylene-2,6,11-dodecatrienal
2,6-dimethyl-10-methylenedodeca-2,6,11-trien-1-al
(2E,6E)-2,6-dimethyl-10-methylidenedodeca-2,6,11-trienal
2,6,11-dodecatrienal, 2,6-dimethyl-10-methylene-
 sinensal 18/20% ex orange (natural)
beta-sinensal natural
 sinensal natural, mixture of alpha & beta
 sinensals
 

Articles:

US Patents:3,963,783 - 4-Methyl-8-vinyl-4,7- and -4,8-nonadienals
PubMed:Repellent effect of santalol from sandalwood oil against Tetranychus urticae (Acari: Tetranychidae).
US Patents:3,974,225 - Process for the preparation of unsaturated aldehydes
PubMed:Acaricidal and oviposition deterring effects of santalol identified in sandalwood oil against two-spotted spider mite, Tetranychus urticae Koch (Acari: Tetranychidae).
US Patents:3,979,425 - Process for the preparation of unsaturated aldehydes
PubMed:California Lomatiums, Part X. Comparison of composition of the hydrodistilled oils from two subspecies of Lomatium mohavense.
PubMed:Citrus fruit flavor and aroma biosynthesis: isolation, functional characterization, and developmental regulation of Cstps1, a key gene in the production of the sesquiterpene aroma compound valencene.
PubMed:Identification of aroma active compounds in orange essence oil using gas chromatography-olfactometry and gas chromatography-mass spectrometry.
PubMed:Volatile constituents of redblush grapefruit (Citrus paradisi) and pummelo (Citrus grandis) peel essential oils from Kenya.
 
Notes:
Constit. of orange oil (Citrus sinensis) and mandarin oil (Citrus reticulata). Flavour ingredient Used as a food additive [EAFUS]
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