EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

alpha-amyl cinnamaldehyde / methyl anthranilate schiff's base
jasmea (IFF)

Supplier Sponsors

Fragrance Demo Formulas
Name:methyl 2-[[(2E)-2-(phenylmethylidene)octylidene]amino]benzoate
CAS Number: 67924-13-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:267-798-2
Nikkaji Web:J317.231G
XlogP3-AA:6.50 (est)
Molecular Weight:349.47359000
Formula:C23 H27 N O2
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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Pubchem Patents:Search
 
Physical Properties:
Appearance:yellow waxy solid (est)
Assay: 98.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.04790 to 1.05590 @ 25.00 °C.
Pounds per Gallon - (est).: 8.720 to 8.786
Refractive Index:1.56530 to 1.57310 @ 20.00 °C.
Boiling Point: 497.00 to 498.00 °C. @ 760.00 mm Hg
Flash Point:> 200.00 °F. TCC ( > 93.33 °C. )
logP (o/w): 8.649 (est)
Shelf Life: 36.00 month(s) or longer if stored properly.
Soluble in:
 alcohol
 water, 0.009603 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items:note
hexyl cinnamaldehyde / methyl anthranilate schiff's base
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:medium ,
recommend smelling in a 50.00 % solution or less
Substantivity:308 hour(s) at 100.00 %
fresh floral fatty waxy
Odor Description:at 50.00 % in dipropylene glycol. fresh floral fatty waxy
Luebke, William tgsc, (1982)
Odor sample from: Nickstadt Moeller, Inc.
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
BOC Sciences
For experimental / research use only.
Jasmea
U. K. Aromatics and Chemicals
JASMA FLOR
Odor: Sweet,floral orange blossom, gardenia, tuberose, heavy floras
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
IFRA Critical Effect: Sensitization
IFRA fragrance material specification:
 The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes.
Recommendation for alpha-amyl cinnamaldehyde / methyl anthranilate schiff's base usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for alpha-amyl cinnamaldehyde / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):67924-13-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6437178
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
methyl 2-[[(2E)-2-(phenylmethylidene)octylidene]amino]benzoate
Chemidplus:0067924134
 
References:
 methyl 2-[[(2E)-2-(phenylmethylidene)octylidene]amino]benzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:67924-13-4
Pubchem (cid):6437178
Pubchem (sid):135062848
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
adoxal (Givaudan)
FL/FR
aldehydic fragrance
FR
citronellyl oxyacetaldehyde
FL/FR
9-
decenal
FL/FR
mandarine undecenal
FL/FR
(Z)-8-
undecenal
FR
balsamic
cinnamyl formate
FL/FR
citrus
citral / methyl anthranilate schiff's base
FR
citronellyl nitrile
FR
(Z)-4-
decenal
FL/FR
alpha-
terpinyl methyl ether
FL/FR
2-
tetradecenal
FL/FR
10-
undecen-1-ol
FL/FR
clean
clean nitrile
FR
coumarinic
tonka ketone
FR
creamy
creamy lactone
FL/FR
earthy
methyl undecylenate
FL/FR
fatty
allyl octanoate
FL/FR
(Z)-
dairy lactone
FL/FR
(E,E)-2,4-
decadien-1-ol
FL/FR
2,4-
decadien-1-ol
FL/FR
decane nitrile
FR
decanol
FL/FR
(E)-2-
decen-1-ol
FL/FR
2-
decen-1-ol
FL/FR
(E)-2-
decenal
FL/FR
4-
ethyl octanoic acid
FL/FR
ethyl undecylenate
FL/FR
hexyl pivalate
FR
delta-
juniper lactone
FL/FR
methyl 10-undecenoate
FL/FR
4-
methyl octanoic acid
FL/FR
octanoic acid
FL/FR
(Z)-
oleic acid
FL/FR
(E,Z,Z)-2,4,7-
tridecatrienal
FL/FR
undecanal propylene glycol acetal
FL/FR
fermented
methyl decanoate
FL/FR
floral
acetyl tetralin
FR
benzyl lactate
FL/FR
champaca absolute
FR
citronellyl butyrate
FL/FR
citronellyl hexanoate
FL/FR
citronellyl propionate
FL/FR
(E)-
citronellyl tiglate
FL/FR
cyclamen aldehyde / methyl anthranilate schiff's base
FR
cyclohexyl ethyl alcohol
FL/FR
decanal / methyl anthranilate schiff's base
FR
3-
decanol
FL/FR
decyl formate
FR
dihydrojasmone
FL/FR
ethyl anthranilate
FL/FR
(±)-4-
ethyl octanal
FL/FR
gardenia concrete
FR
hexyl 2-furoate
FL/FR
honeysuckle absolute
FR
hydroxycitronellal / methyl anthranilate schiff's base
FR
jasmin concrete
FR
jasmin concrete morocco
FR
iso
jasmone
FL/FR
leerall / methyl anthranilate schiff's base
FR
lily of the valley absolute
FR
lilyall / methyl anthranilate schiff's base
FR
linalyl anthranilate
FL/FR
methyl citronellate
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
methyl ionyl acetate
FL/FR
alpha-
naphthyl methyl ketone
FL/FR
beta-
naphthyl methyl ketone
FL/FR
neroli oil bigarde
FL/FR
neroli oil CO2 extract
FL/FR
nerolin fragarol
FL/FR
nonanal / methyl anthranilate schiff's base
FR
nonanol
FL/FR
3-
nonanon-1-yl acetate
FL/FR
ocean propanal / methyl anthranilate schiff's base
FR
bitter
orangeflower absolute morocco
FL/FR
orris rhizome concrete butter (iris pallida)
FL/FR
petitgrain bigarade oil
FL/FR
phenethyl hexanoate
FL/FR
1-
phenyl propyl butyrate
FL/FR
2-
phenyl propyl isobutyrate
FL/FR
4-
phenyl-3-buten-2-ol
FL/FR
propyl anthranilate
FL/FR
iso
propyl benzoate
FL/FR
rose undecene
FR
surfleurs d'oranger oil
FL/FR
alpha-
terpinyl anthranilate
FL/FR
terpinyl valerate
FL/FR
tetrahydroionyl acetate
FR
fruity
benzaldehyde / methyl anthranilate schiff's base
FR
berry hexanoate
FR
iso
butyl anthranilate
FL/FR
iso
butyl furyl propionate
FL/FR
citronellyl isobutyrate
FL/FR
cyclohexyl anthranilate
FL/FR
beta-
damascone
FL/FR
(Z)-beta-
damascone
FL/FR
(E)-beta-
damascone
FL/FR
ethyl levulinate
FL/FR
heptyl isobutyrate
FL/FR
methyl (Z)-3-hexenoate
FL/FR
methyl anthranilate
FL/FR
methyl heptanoate
FL/FR
methyl isobutyrate
FL/FR
(E)-7-
methyl-3-octen-2-one
FL/FR
2-
nonanone propylene glycol acetal
FL/FR
4-(para-
tolyl)-2-butanone
FL/FR
tropical ionone
FL/FR
green
3,7-
dimethyl-6-octenoic acid
FL/FR
(Z)-3-
hepten-1-ol
FL/FR
(Z)-4-
heptenal diethyl acetal
FL/FR
heptyl formate
FL/FR
(Z)-3-
hexen-1-yl isovalerate
FL/FR
nerol oxide
FL/FR
herbal
butyl levulinate
FL/FR
chamomile isobutyrate
FR
chamomile propionate
FR
naphthyl
beta-
naphthyl ethyl ether
FL/FR
beta-
naphthyl methyl ether
FL/FR
oily
amyl laurate
FL/FR
petal pyranone
FL/FR
powdery
alpha-
methyl ionone
FL/FR
soapy
benzyl laurate
FL/FR
ethyl undecanoate
FL/FR
spicy
para-
anisyl formate
FL/FR
tonka
6-
amyl-alpha-pyrone
FL/FR
waxy
(Z)-4-
decen-1-ol
FL/FR
1-
dodecanol
FL/FR
ethyl laurate
FL/FR
hexadecanol
FL/FR
methyl myristate
FL/FR
methyl palmitate
FL/FR
methyl undecanoate
FR
myristic acid
FL/FR
2,4-
nonadien-1-ol
FL/FR
palmitic acid
FR
tetradecanal
FL/FR
2-
tridecanone
FL/FR
woody
2-
decalinyl acetate
FR
labdanum ethanone
FR
mimosa concrete morocco
FL/FR
For Flavor
No flavor group found for these
amyl laurate
FL/FR
benzyl lactate
FL/FR
3-
decanol
FL/FR
(E)-2-
decen-1-ol
FL/FR
(Z)-4-
decen-1-ol
FL/FR
9-
decenal
FL/FR
(±)-4-
ethyl octanal
FL/FR
(Z)-3-
hepten-1-ol
FL/FR
mandarine undecenal
FL/FR
methyl myristate
FL/FR
methyl palmitate
FL/FR
alpha-
naphthyl methyl ketone
FL/FR
2-
nonanone propylene glycol acetal
FL/FR
1-
phenyl propyl butyrate
FL/FR
2-
phenyl propyl isobutyrate
FL/FR
propyl anthranilate
FL/FR
iso
propyl benzoate
FL/FR
surfleurs d'oranger oil
FL/FR
alpha-
terpinyl anthranilate
FL/FR
2-
tetradecenal
FL/FR
undecanal propylene glycol acetal
FL/FR
10-
undecen-1-ol
FL/FR
iso
butyl furyl propionate
FL/FR
beta-
damascone
FL/FR
berry
berry
heptyl isobutyrate
FL/FR
bitter
(E,Z,Z)-2,4,7-
tridecatrienal
FL/FR
citrus
citronellyl oxyacetaldehyde
FL/FR
(Z)-4-
decenal
FL/FR
petitgrain bigarade oil
FL/FR
creamy
6-
amyl-alpha-pyrone
FL/FR
creamy lactone
FL/FR
ethereal
benzyl laurate
FL/FR
methyl isobutyrate
FL/FR
fatty
allyl octanoate
FL/FR
(Z)-
dairy lactone
FL/FR
2,4-
decadien-1-ol
FL/FR
(E,E)-2,4-
decadien-1-ol
FL/FR
4-
ethyl octanoic acid
FL/FR
ethyl undecylenate
FL/FR
heptyl formate
FL/FR
delta-
juniper lactone
FL/FR
methyl decanoate
FL/FR
4-
methyl octanoic acid
FL/FR
(E)-7-
methyl-3-octen-2-one
FL/FR
2,4-
nonadien-1-ol
FL/FR
(Z)-
oleic acid
FL/FR
tetradecanal
FL/FR
2-
tridecanone
FL/FR
floral
citronellyl hexanoate
FL/FR
citronellyl propionate
FL/FR
dihydrojasmone
FL/FR
3,7-
dimethyl-6-octenoic acid
FL/FR
linalyl anthranilate
FL/FR
methyl citronellate
FL/FR
alpha-iso
methyl ionone (90% min.)
FL/FR
beta-
naphthyl methyl ketone
FL/FR
neroli oil bigarde
FL/FR
neroli oil CO2 extract
FL/FR
bitter
orangeflower absolute morocco
FL/FR
orris rhizome concrete butter (iris pallida)
FL/FR
tropical ionone
FL/FR
fruity
iso
butyl anthranilate
FL/FR
citronellyl butyrate
FL/FR
citronellyl isobutyrate
FL/FR
cyclohexyl anthranilate
FL/FR
(E)-beta-
damascone
FL/FR
(Z)-beta-
damascone
FL/FR
ethyl anthranilate
FL/FR
ethyl levulinate
FL/FR
methyl (Z)-3-hexenoate
FL/FR
methyl anthranilate
FL/FR
methyl heptanoate
FL/FR
alpha-
methyl ionone
FL/FR
nerolin fragarol
FL/FR
3-
nonanon-1-yl acetate
FL/FR
terpinyl valerate
FL/FR
4-(para-
tolyl)-2-butanone
FL/FR
green
(E)-
citronellyl tiglate
FL/FR
cyclohexyl ethyl alcohol
FL/FR
(Z)-4-
heptenal diethyl acetal
FL/FR
(Z)-3-
hexen-1-yl isovalerate
FL/FR
hexyl 2-furoate
FL/FR
iso
jasmone
FL/FR
nerol oxide
FL/FR
herbal
butyl levulinate
FL/FR
naphthyl
beta-
naphthyl methyl ether
FL/FR
oily
petal pyranone
FL/FR
powdery
beta-
naphthyl ethyl ether
FL/FR
soapy
1-
dodecanol
FL/FR
octanoic acid
FL/FR
spicy
para-
anisyl formate
FL/FR
cinnamyl formate
FL/FR
waxy
adoxal (Givaudan)
FL/FR
decanol
FL/FR
2-
decen-1-ol
FL/FR
(E)-2-
decenal
FL/FR
ethyl laurate
FL/FR
ethyl undecanoate
FL/FR
hexadecanol
FL/FR
methyl 10-undecenoate
FL/FR
methyl undecylenate
FL/FR
myristic acid
FL/FR
nonanol
FL/FR
phenethyl hexanoate
FL/FR
4-
phenyl-3-buten-2-ol
FL/FR
woody
methyl ionyl acetate
FL/FR
mimosa concrete morocco
FL/FR
alpha-
terpinyl methyl ether
FL/FR
 
Potential Uses:
FRcologne
FLfat
FRgardenia
FRjasmin
FRjonquil
FRlilac
FRlily of the valley
FRrose
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
alpha-amyl cinnamaldehyde / methyl anthranilate schiff's base
alpha-amylcinnamaldehyde / methyl anthranilate schiff's base
 benzoic acid, 2-((2-(phenylmethylene)octylidene)amino)-, methyl ester
 jasma flor (U. K. Aromatics)
 jasmea (IFF)
 methyl 2-((-2-pentyl-3-phenyl-2-propenylidene)amino)-1-benzene carboxylate
 methyl 2-((2-(phenyl methylene)octylidene)amino) benzoate
 methyl 2-((2-(phenylmethylene)octylidene)amino)benzoate
 methyl 2-[[(2E)-2-(phenylmethylidene)octylidene]amino]benzoate
 methyl anthranilate / alpha-amyl cinnamaldehyde schiff's base
 methyl-2-phenyl methylene octylidene aminobenzoate
alpha-pentyl cinnamaldehyde / methyl anthranilate schiff's base
alpha-pentylcinnamaldehyde / methyl anthranilate schiff's base
 seringone
 

Articles:

 None found yet.
 
Notes:
rose accord: 0.01 - dihydromyrcenol 0.05 - benzyl propionate 0.05 - linalyl acetate 0.05 - phenethyl alcohol 0.01 - aldehyde C-14 10% 0.20 - amyl cinnamaldehyde 0.01 - ma/hy shiff 0.05 - naphthyl ethyl ether 0.01 - aldehyde C-16 10% 0.05 - geraniol
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