EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
BT
 

lilyall / methyl anthranilate schiff's base
verdantiol (Givaudan)

Sponsors

Fragrance Demo Formulas
Name: methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
CAS Number: 91-51-0Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 202-073-6
Nikkaji Web: J60.461E
XlogP3-AA: 5.50 (est)
Molecular Weight: 337.46259000
Formula: C22 H27 N O2
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
 
Physical Properties:
Appearance: yellow liquid to solid (est)
Assay: 98.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 1.03590 to 1.04210 25.00 °C.
Pounds per Gallon - (est).: 8.620 to 8.671
Refractive Index: 1.53560 to 1.54290 @ 20.00 °C.
Boiling Point: 471.82 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 0.001300 mm/Hg @ 20.00 °C.
Flash Point: > 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w): 7.660 (est)
Soluble in:
 alcohol
 water, 0.02806 mg/L @ 25 °C (est)
Insoluble in:
 water
Stability:
 beauty care
 fine fragrance
 household
 laundry care
 
Organoleptic Properties:
Odor Type: floral
Odor Strength: medium ,
recommend smelling in a 50.00 % solution or less
Substantivity: 400 hour(s) at 100.00 %
 fresh green orangeflower lily citrus muguet
Odor Description:
at 50.00 % in dipropylene glycol.
fresh green orangeflower lily citrus hydroxycitronellal
Luebke, William tgsc, (1986)
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
SCHIFF'S BASE LILIAL-METHYL ANTHRANILATE ≥90.0% (sum of isomers), Kosher
Odor Description: neroli, orange blossom
A very high quality product with subtle floral notes to enhance delicate fragrances.
Givaudan
Verdantiol
Odor Description: Linden-Orange Flower
Verdantiol offers an intense floral note to delicate flower type creations, such as neroli, orange blossom, narcissus and frangipani. Excellent fixative value on all supports.
Moellhausen
VERDANTIOL
Odor Description: fresh floral, sweet aromatic, citrusy; notes of muguet and neroli
Robertet
Schiff lilial
Odor Description: Floral, orange flower, lily of the valley
 
Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
A.C.S. International
Liliavert
Operational Capabilities
Apple Flavor & Fragrance
Lilial/MA schiffbase
BOC Sciences
For experimental / research use only.
Benzoic acid,2-[[3-[4-(1,1-dimethylethyl)phenyl]-2-methylpropylidene]amino]-, methyl ester
CG Herbals
Schiff's Base Lilianthral
Charabot
Schiff lilial
Odor: Floral, orange flower, lily of the valley
Ernesto Ventós
SCHIFF BASE EXTRA, LILIAL
Ernesto Ventós
SCHIFF BASE, LILIAL
Odor: FLORAL, DRY
Fleurchem
lilial / methyl anthranilate schiff's base
Givaudan
Verdantiol
Odor: Linden-Orange Flower
Use: Verdantiol offers an intense floral note to delicate flower type creations, such as neroli, orange blossom, narcissus and frangipani. Excellent fixative value on all supports.
Grau Aromatics
LILANATE 3275 P (LILIALMETHYLANTHRANILATE)
IFF
Lilianth
Odor: Fresh green orangeflower, lily, citrus, hydroxycitronellal like note
Indukern F&F
SCHIFF BASE LILIAL
Odor: FLORAL, DRY
Inoue Perfumery
LILYANTINE
Keva
VERANIOL L.S
Moellhausen
VERDANTIOL
Odor: fresh floral, sweet aromatic, citrusy; notes of muguet and neroli
Penta International
METHYL ANTHRANILATE/LILIAL
PerfumersWorld
Verdantiol
Robertet
Schiff lilial
Odor: Floral, orange flower, lily of the valley
SRS Aromatics
LILANATE 3275 P
Vigon International
Methyl Anthranilate / Lilial Schiff Base
Odor: Linden-Orange Flower
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 38 - Irritating to skin.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 24 - Avoid contact with skin.
S 37 - Wear suitable gloves.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
12% in petrolatum produced no irritation or sensitization in humans.
Oral/Parenteral Toxicity:
oral-rat LD50 3000 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 729, 1982.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 729, 1982.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
IFRA Critical Effect: Sensitization
IFRA fragrance material specification:
 The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes.
Recommendation for lilyall / methyl anthranilate schiff's base usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for lilyall / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 91-51-0
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 64807
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
Chemidplus: 0000091510
 
References:
 methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 91-51-0
Pubchem (cid): 64807
Pubchem (sid): 135021438
 
Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2922.49.8050
ChemSpider: View
 
Potential Blenders and core components note
For Odor
aldehydic
citrus carbaldehyde
FR
balsamic
clover nitrile
FR
fir balsam absolute
FR
citrus
methyl indole-1-carboxylate
FR
clean
clean nitrile
FR
floral
4-iso
butyl cyclohexane propanal
FR
corps popinal
FR
cyclamen homoaldehyde
FR
2,5-
dimethyl-2-indan methanol
FR
4-
ethyl cyclohexane propanal
FR
floral pyranol
FR
floral specialty
FR
gardenia oxide
FR
heliotropyl diethyl acetal
FR
hyacinth ether
FR
hydroxycitronellal / methyl anthranilate schiff's base
FR
hydroxycitronellal residue
FR
leerall
FR
calla
lily fragrance
FR
lily of the valley specialty
FR
lilyall substitute
FR
magnolia cyclohexanol
FR
methoxycitronellal
FR
4-
methyl cyclohexane propanal
FR
muguet butanal
FR
muguet butanol
FR
muguet carbaldehyde
FR
muguet carboxaldehyde
FR
muguet ethanol
FR
muguet octadienol
FR
muguet specialty
FR
ocean propanal / methyl anthranilate schiff's base
FR
octahydro-4,7-methano-1H-indene-5-acetaldehyde
FR
octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd
FR
orris pyridine 25% IPM
FR
peony alcohol
FR
petitgrain oil fractions
FR
4-
propyl cyclohexane propanal
FR
verdyl acetate
FR
violet methyl carbonate
FR
fruity
allyl amyl glycolate
FR
dimethyl benzyl carbinyl isobutyrate
FR
green
phenyl acetaldehyde ethylene glycol acetal
FR
hay
hay absolute
FR
herbal
pine hexanol
FR
marine
marine pyridine
FR
ozone propanal
FR
melon
watermelon ketone
FR
mossy
veramoss (IFF)
FR
tonka
tonka bean absolute
FR
woody
amber dioxane
FR
cedryl methyl ether
FR
patchouli ethanone
FR
santall
FR
tobacarol (IFF)
FR
woody acetate
FR
(Z)-
woody amylene
FR
For Flavor
 
Potential Uses:
 floralFR
 frangipanni plumeriaFR
 lilyFR
 narcissus narcisseFR
 neroliFR
 orange blossomFR
 
Occurrence (nature, food, other): note
 not found in nature
 
Synonyms:
 anthranilic acid, N-(3-(p-tert-butylphenyl)-2-methylpropylidene)-, methyl ester
 benzoic acid, 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)-, methyl ester
p-tert-butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base
para-tert-butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base
 lilanate 3275 P (Grau)
 lilial/ma schiffbase
 lilianth (IFF)
 liliavert (A.C.S. International)
 lilyall / methyl anthranilate schiff's base
 lilyantine
 maranthra
 methyl 2-((3-(4-(1,1-dimethyl ethyl)phenyl)-2-methyl propylidene)amino) benzoate
 methyl 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)benzoate
 methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
 methyl anthranilate / lilial
 methyl anthranilate / lilyall schiff's base
 methyl-N-(p-tert-butyl-a-methylhydrocinnamylidene) anthranilate
 methyl-N-(p-tert-butyl-alpha-methylhydrocinnamylidene) anthranilate
 methyl-N-(para-tert-butyl-alpha-methyl hydrocinnamylidene) anthranilate
 schiff base lilial
 schiff's base lilial-methyl anthranilate
 schiff's base lilianthral
 verdantiol (Givaudan)
 

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