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lilyall / methyl anthranilate schiff's base
verdantiol (Givaudan)

Sponsors

Fragrance Demo Formulas
Name:methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
CAS Number: 91-51-0Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:202-073-6
Nikkaji Web:J60.461E
XlogP3-AA:5.50 (est)
Molecular Weight:337.46259000
Formula:C22 H27 N O2
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:yellow liquid to solid (est)
Assay: 98.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.03590 to 1.04210 @ 25.00 °C.
Pounds per Gallon - (est).: 8.620 to 8.671
Refractive Index:1.53560 to 1.54290 @ 20.00 °C.
Boiling Point: 471.82 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.001300 mm/Hg @ 20.00 °C.
Flash Point:> 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w): 7.660 (est)
Soluble in:
 alcohol
 water, 0.02806 mg/L @ 25 °C (est)
Insoluble in:
 water
Stability:
 beauty care
 fine fragrance
 household
 laundry care
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:medium ,
recommend smelling in a 50.00 % solution or less
Substantivity:400 hour(s) at 100.00 %
fresh green orangeflower lily citrus muguet
Odor Description:at 50.00 % in dipropylene glycol. fresh green orangeflower lily citrus hydroxycitronellal
Luebke, William tgsc, (1986)
Odor sample from: The Good Scents Company
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
SCHIFF'S BASE LILIAL-METHYL ANTHRANILATE ≥90.0% (sum of isomers), Kosher
Odor Description:neroli, orange blossom
A very high quality product with subtle floral notes to enhance delicate fragrances.
Givaudan
Verdantiol
Odor Description:Linden-Orange Flower
Verdantiol offers an intense floral note to delicate flower type creations, such as neroli, orange blossom, narcissus and frangipani. Excellent fixative value on all supports.
Moellhausen
VERDANTIOL
Odor Description:fresh floral, sweet aromatic, citrusy; notes of muguet and neroli
Robertet
Schiff lilial
Odor Description:Floral, orange flower, lily of the valley
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
A.C.S. International
Liliavert
Operational Capabilities
Apple Flavor & Fragrance
Lilial/MA schiffbase
BOC Sciences
For experimental / research use only.
Benzoic acid,2-[[3-[4-(1,1-dimethylethyl)phenyl]-2-methylpropylidene]amino]-, methyl ester
CG Herbals
Schiff's Base Lilianthral
Charabot
Schiff lilial
Odor: Floral, orange flower, lily of the valley
Ernesto Ventós
SCHIFF BASE EXTRA, LILIAL
Ernesto Ventós
SCHIFF BASE, LILIAL
Odor: FLORAL, DRY
Fleurchem
lilial / methyl anthranilate schiff's base
Givaudan
Verdantiol
Odor: Linden-Orange Flower
Use: Verdantiol offers an intense floral note to delicate flower type creations, such as neroli, orange blossom, narcissus and frangipani. Excellent fixative value on all supports.
Grau Aromatics
LILANATE 3275 P (LILIALMETHYLANTHRANILATE)
IFF
Lilianth
Odor: Fresh green orangeflower, lily, citrus, hydroxycitronellal like note
Indukern F&F
SCHIFF BASE LILIAL
Odor: FLORAL, DRY
Inoue Perfumery
LILYANTINE
Keva
VERANIOL L.S
Moellhausen
VERDANTIOL
Odor: fresh floral, sweet aromatic, citrusy; notes of muguet and neroli
Penta International
METHYL ANTHRANILATE/LILIAL
PerfumersWorld
Verdantiol
Robertet
Schiff lilial
Odor: Floral, orange flower, lily of the valley
SRS Aromatics
LILANATE 3275 P
Vigon International
Methyl Anthranilate / Lilial Schiff Base
Odor: Linden-Orange Flower
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 38 - Irritating to skin.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 24 - Avoid contact with skin.
S 37 - Wear suitable gloves.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
12% in petrolatum produced no irritation or sensitization in humans.
Oral/Parenteral Toxicity:
oral-rat LD50 3000 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 729, 1982.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 729, 1982.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
IFRA Critical Effect: Sensitization
IFRA fragrance material specification:
 The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes.
Recommendation for lilyall / methyl anthranilate schiff's base usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for lilyall / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):91-51-0
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :64807
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
Chemidplus:0000091510
 
References:
 methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:91-51-0
Pubchem (cid):64807
Pubchem (sid):135021438
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2922.49.8050
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
adoxal (Givaudan)
FL/FR
citrus carbaldehyde
FR
decanal (aldehyde C-10)
FL/FR
9-
decenal
FL/FR
dodecanal (aldehyde C-12 lauric)
FL/FR
nonanal (aldehyde C-9)
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
anisic
para-
anisaldehyde
FL/FR
balsamic
amyris wood oil
FL/FR
siam
benzoin resinoid
FL/FR
benzyl salicylate
FL/FR
iso
butyl cinnamate
FL/FR
cinnamyl alcohol
FL/FR
clover nitrile
FR
ethyl cinnamate
FL/FR
fir balsam absolute
FR
3-
phenyl propyl alcohol
FL/FR
berry
raspberry ketone
FL/FR
raspberry ketone acetate
FL/FR
raspberry ketone methyl ether
FL/FR
citrus
lime oil distilled mexico
FL/FR
methyl indole-1-carboxylate
FR
clean
clean nitrile
FR
fatty
decanol
FL/FR
floral
alpha-
amyl cinnamaldehyde
FL/FR
iso
amyl salicylate
FL/FR
bois de rose oil brazil
FL/FR
4-iso
butyl cyclohexane propanal
FR
iso
butyl salicylate
FL/FR
citronellol
FL/FR
citronellyl acetate
FL/FR
coriander seed oil
FL/FR
corps popinal
FR
cuminyl acetaldehyde
FL/FR
cyclamen aldehyde
FL/FR
cyclamen homoaldehyde
FR
cyclohexyl ethyl alcohol
FL/FR
dihydrojasmone
FL/FR
dimethyl anthranilate
FL/FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
2,5-
dimethyl-2-indan methanol
FR
4-
ethyl cyclohexane propanal
FR
(E,E)-
farnesol
FL/FR
floral pyranol
FR
floral specialty
FR
gardenia oxide
FR
geraniol
FL/FR
geranyl acetate
FL/FR
heliotropin
FL/FR
heliotropyl acetone
FL/FR
heliotropyl diethyl acetal
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hyacinth ether
FR
hydroxycitronellal
FL/FR
hydroxycitronellal / methyl anthranilate schiff's base
FR
hydroxycitronellal diethyl acetal
FL/FR
hydroxycitronellal dimethyl acetal
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
hydroxycitronellal residue
FR
leerall
FR
calla
lily fragrance
FR
lily of the valley specialty
FR
lilyall substitute
FR
linalool
FL/FR
linalool oxide
FL/FR
magnolia cyclohexanol
FR
methoxycitronellal
FR
4-
methyl cyclohexane propanal
FR
methyl dihydrojasmonate
FL/FR
mimosa absolute france
FL/FR
muguet butanal
FR
muguet butanol
FR
muguet carbaldehyde
FR
muguet carboxaldehyde
FR
muguet ethanol
FR
muguet octadienol
FR
muguet specialty
FR
nerol
FL/FR
neroli oil CO2 extract
FL/FR
neroli oil morocco
FL/FR
nerolidol
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
ocean propanal / methyl anthranilate schiff's base
FR
octahydro-4,7-methano-1H-indene-5-acetaldehyde
FR
octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd
FR
orris pyridine 25% IPM
FR
peony alcohol
FR
petitgrain absolute morocco
FL/FR
petitgrain oil fractions
FR
phenethyl alcohol
FL/FR
phenethyl phenyl acetate
FL/FR
phenethyl salicylate
FL/FR
4-
propyl cyclohexane propanal
FR
rhodinol
FL/FR
rose butanoate
FL/FR
alpha-
terpinyl anthranilate
FL/FR
tetrahydrolinalool
FL/FR
verdyl acetate
FR
violet methyl carbonate
FR
fruity
allyl amyl glycolate
FR
dimethyl benzyl carbinyl isobutyrate
FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
(Z)-
leaf acetal
FL/FR
melon nonenoate
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
phenyl acetaldehyde ethylene glycol acetal
FR
violet leaf absolute
FL/FR
hay
hay absolute
FR
herbal
clary sage oil france
FL/FR
daucus carota fruit oil
FL/FR
linalyl acetate
FL/FR
pine hexanol
FR
marine
marine pyridine
FR
ozone propanal
FR
melon
watermelon ketone
FR
mossy
veramoss (IFF)
FR
naphthyl
beta-
naphthyl ethyl ether
FL/FR
powdery
para-
anisyl alcohol
FL/FR
spicy
iso
eugenyl acetate
FL/FR
terpenic
alpha-
terpineol
FL/FR
tonka
tonka bean absolute
FR
vanilla
ethyl vanillin
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
waxy
decyl acetate
FL/FR
1-
dodecanol
FL/FR
ethyl laurate
FL/FR
octanol
FL/FR
1-
undecanol
FL/FR
woody
amber dioxane
FR
cedryl methyl ether
FR
guaiacwood oil
FL/FR
patchouli ethanone
FR
santall
FR
tobacarol (IFF)
FR
woody acetate
FR
(Z)-
woody amylene
FR
For Flavor
No flavor group found for these
9-
decenal
FL/FR
(E,E)-
farnesol
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
alpha-
terpinyl anthranilate
FL/FR
aldehydic
aldehydic
nonanal (aldehyde C-9)
FL/FR
1-
undecanol
FL/FR
balsamic
siam
benzoin resinoid
FL/FR
benzyl salicylate
FL/FR
iso
butyl cinnamate
FL/FR
ethyl cinnamate
FL/FR
berry
heliotropyl acetone
FL/FR
raspberry ketone
FL/FR
raspberry ketone acetate
FL/FR
raspberry ketone methyl ether
FL/FR
cherry
heliotropin
FL/FR
citrus
lime oil distilled mexico
FL/FR
linalool
FL/FR
nerol
FL/FR
alpha-
terpineol
FL/FR
cooling
iso
butyl salicylate
FL/FR
creamy
para-
anisaldehyde
FL/FR
fatty
(Z)-3-
hexen-1-yl benzoate
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
floral
bois de rose oil brazil
FL/FR
citronellol
FL/FR
citronellyl acetate
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
geraniol
FL/FR
linalyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
neroli oil CO2 extract
FL/FR
neroli oil morocco
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
petitgrain absolute morocco
FL/FR
phenethyl alcohol
FL/FR
rhodinol
FL/FR
tetrahydrolinalool
FL/FR
fruity
para-
anisyl alcohol
FL/FR
dimethyl anthranilate
FL/FR
rose butanoate
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
iso
amyl salicylate
FL/FR
cinnamyl alcohol
FL/FR
cuminyl acetaldehyde
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
geranyl acetate
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
2,4-
ivy carbaldehyde
FL/FR
(Z)-
leaf acetal
FL/FR
linalool oxide
FL/FR
melon nonenoate
FL/FR
nerolidol
FL/FR
phenyl acetaldehyde dimethyl acetal
FL/FR
violet leaf absolute
FL/FR
herbal
clary sage oil france
FL/FR
coriander seed oil
FL/FR
daucus carota fruit oil
FL/FR
honey
phenethyl phenyl acetate
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
phenethyl salicylate
FL/FR
melon
hydroxycitronellal diethyl acetal
FL/FR
powdery
beta-
naphthyl ethyl ether
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
1-
dodecanol
FL/FR
spicy
iso
eugenyl acetate
FL/FR
3-
phenyl propyl alcohol
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
vanilla
ethyl vanillin
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
waxy
adoxal (Givaudan)
FL/FR
decanal (aldehyde C-10)
FL/FR
decanol
FL/FR
decyl acetate
FL/FR
ethyl laurate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hydroxycitronellal
FL/FR
hydroxycitronellal dimethyl acetal
FL/FR
mimosa absolute france
FL/FR
octanol
FL/FR
woody
amyris wood oil
FL/FR
guaiacwood oil
FL/FR
 
Potential Uses:
FRfloral
FRfrangipani plumeria
FRlily
FRnarcissus
FRneroli
FRorange blossom
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 anthranilic acid, N-(3-(p-tert-butylphenyl)-2-methylpropylidene)-, methyl ester
 benzoic acid, 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)-, methyl ester
p-tert-butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base
para-tert-butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base
 lilanate 3275 P (Grau)
 lilial/ma schiffbase
 lilianth (IFF)
 liliavert (A.C.S. International)
 lilyall / methyl anthranilate schiff's base
 lilyantine
 maranthra
 methyl 2-((3-(4-(1,1-dimethyl ethyl)phenyl)-2-methyl propylidene)amino) benzoate
 methyl 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)benzoate
 methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
 methyl anthranilate / lilial
 methyl anthranilate / lilyall schiff's base
 methyl-N-(p-tert-butyl-a-methylhydrocinnamylidene) anthranilate
 methyl-N-(p-tert-butyl-alpha-methylhydrocinnamylidene) anthranilate
 methyl-N-(para-tert-butyl-alpha-methyl hydrocinnamylidene) anthranilate
 schiff base lilial
 schiff's base lilial-methyl anthranilate
 schiff's base lilianthral
 verdantiol (Givaudan)
 

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