EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

leerall / methyl anthranilate schiff's base
lyrame (IFF)

Supplier Sponsors

Name:methyl 2-[[4-(4-hydroxy-4-methylpentyl)-1-cyclohex-3-enyl]methylideneamino]benzoate
CAS Number: 67634-12-2Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:266-816-6
Nikkaji Web:J333.247K
XlogP3-AA:3.40 (est)
Molecular Weight:343.46673000
Formula:C21 H29 N O3
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
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Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:bright yellow viscous liquid (est)
Food Chemicals Codex Listed: No
Specific Gravity:1.06270 to 1.07070 @ 25.00 °C.
Pounds per Gallon - (est).: 8.843 to 8.909
Refractive Index:1.52590 to 1.53540 @ 20.00 °C.
Boiling Point: 497.00 to 498.00 °C. @ 760.00 mm Hg
Flash Point:> 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w): 4.050
Shelf Life: 36.00 month(s) or longer if stored properly.
Storage:store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
 alcohol
 oils
 water, 0.2014 mg/L @ 25 °C (est)
Insoluble in:
 water
Stability:
 alcoholic lotion
 deo stick
 fabric softener
 shampoo
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:medium ,
recommend smelling in a 50.00 % solution or less
Substantivity:400 hour(s) at 100.00 %
fresh lily floral sweet orangeflower
Odor Description:at 50.00 % in dipropylene glycol. fresh lily floral sweet orangeblossom
Luebke, William tgsc, (1990)
Odor sample from: International Flavors & Fragrances Inc.
Odor and/or flavor descriptions from others (if found).
IFF
Lyrame Super
Odor Description:Tenacious floral absolute odor with a very sweet, orange blossom profile. Increases the substantivity of a fragrance and provides fixation and floralcy as well
Robertet
Schiff lyral
Odor Description:Floral, honey, orange flower
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Augustus Oils
Lyral – Ma Schiff Base
Services
Azelis UK
LYRAME SUPER
Services
BOC Sciences
For experimental / research use only.
Methyl Anthranilate / Lyral Schiff Base
Charabot
Schiff lyral
Odor: Floral, honey, orange flower
Ernesto Ventós
LYRAME SUPER IFF
Odor: FLORAL,FRUITY,MUGUET,ORANGE BLOSSOM
Ernesto Ventós
SCHIFF BASE, LYRAL
Odor: FLORAL,FRUITY,MUGUET,ORANGE BLOSSOM
IFF
Lyrame Super
Odor: Tenacious floral absolute odor with a very sweet, orange blossom profile. Increases the substantivity of a fragrance and provides fixation and floralcy as well
Indukern F&F
LYRAME SUPER
Odor: FLORAL, FRUITY, MUGUET, ORANGE BLOSSOM
M&U International
Lyrame Super
Penta International
METHYL ANTHRANILATE/LYRAL
Perfumery Laboratory
LIRAM SUPER ™ 50% in the IFG IFF (LYRAME SUPER ™ IFF)
Odor: A fresh, sweet scent of lily of the valley and orange blossoms
Robertet
Schiff lyral
Odor: Floral, honey, orange flower
Taytonn
Lyrame Super
Taytonn
Lyrame
Vigon International
LYRAL BASE
Vigon International
Methyl Anthranilate / Lyral Schiff Base
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
IFRA Critical Effect: Sensitization
IFRA fragrance material specification:
 The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes.
Recommendation for leerall / methyl anthranilate schiff's base usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for leerall / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):67634-12-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :106740
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
methyl 2-[[4-(4-hydroxy-4-methylpentyl)-1-cyclohex-3-enyl]methylideneamino]benzoate
Chemidplus:0067634122
 
References:
 methyl 2-[[4-(4-hydroxy-4-methylpentyl)-1-cyclohex-3-enyl]methylideneamino]benzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:67634-12-2
Pubchem (cid):106740
Pubchem (sid):135062609
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
citronellyl oxyacetaldehyde
FL/FR
lily pentanal
FR
muguet undecadienal
FR
nonanal (aldehyde C-9)
FL/FR
animal
para-
cresyl isobutyrate
FL/FR
para-
cresyl phenyl acetate
FL/FR
balsamic
linalyl cinnamate
FL/FR
citrus
benzyl anthranilate
FR
citral / methyl anthranilate schiff's base
FR
citrus ocimenol
FR
curacao specialty
FR
(Z)-4-
decenal
FL/FR
2-
dodecanone
FL/FR
mandarin oil italy
FL/FR
methyl indole-1-carboxylate
FR
myrmac aldehyde
FR
petitgrain specialty
FR
alpha-
terpinyl methyl ether
FL/FR
tetrahydromyrcenol
FR
clean
clean nitrile
FR
coumarinic
tonka ketone
FR
fatty
decanol
FL/FR
floral
acetyl tetralin
FR
aeolanthus graveolens oil
FR
alpha-
amyl cinnamaldehyde dimethyl acetal
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
4-iso
butyl cyclohexane propanal
FR
champaca absolute
FR
citronellyl (R)-lactate
FR
citronellyl ethoxalate
FR
citrus propanol
FR
corps popinal
FR
cumin carbinol
FR
cuminyl acetaldehyde
FL/FR
cyclamen aldehyde / methyl anthranilate schiff's base
FR
cyclamen homoaldehyde
FR
cyclohexyl ethyl alcohol
FL/FR
cyclohexyl propanol
FR
2-
decalinol
FR
decanal / methyl anthranilate schiff's base
FR
2-
decanone
FL/FR
(Z)-4-
decen-1-yl acetate
FL/FR
decyl formate
FR
2,5-
dimethyl-2-indan methanol
FR
ethyl anthranilate
FL/FR
4-
ethyl cyclohexane propanal
FR
ethyl linalyl acetal
FR
(E,E)-
farnesol
FL/FR
farnesol
FL/FR
floral butanal
FR
floral pyranol
FR
floral specialty
FR
pink
frangipani absolute
FR
freesia acetate
FR
gardenia decalone
FR
ginger lily fragrance
FR
hawthorn ethanol
FR
(Z)-4-
hepten-2-yl salicylate
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
hydrangea fragrance
FR
3-(4-
hydroxy-4-methyl cyclohexyl) butanal
FR
hydroxycitronellal
FL/FR
hydroxycitronellal / methyl anthranilate schiff's base
FR
hydroxycitronellal diethyl acetal
FL/FR
hydroxycitronellal dimethyl acetal
FL/FR
hydroxycitronellal distillation residue distillates
FR
hydroxycitronellal nitrile
FR
hydroxycitronellal propylene glycol acetal
FL/FR
hydroxycitronellal residue
FR
hydroxycitronellol
FL/FR
jasimia
FR
leerall
FR
lily flower absolute
FR
calla
lily fragrance
FR
lily fragrance
FR
water
lily fragrance
FR
lily of the valley fragrance
FR
lily of the valley specialty
FR
lily propanol
FR
lilyall
FR
lilyall / methyl anthranilate schiff's base
FR
lilyall substitute
FR
linalyl anthranilate
FL/FR
linalyl benzoate
FL/FR
linalyl propionate
FL/FR
lotus fragrance
FR
magnolia cyclohexanol
FR
magnolia decadienal
FR
methoxycitronellal
FR
4-
methyl cyclohexane propanal
FR
2-
methyl octanal
FL/FR
1-
methyl-3-(2-methyl propyl) cyclohexanol
FR
4-(4-
methyl-4-hydroxyamyl)-delta3-cyclohexenecarboxaldehyde
FR
3-
methyl-6-ethyl-5-octen-1-ol
FR
muguet butanal
FR
muguet butanol
FR
muguet carbaldehyde
FR
muguet carbinol
FL/FR
muguet carboxaldehyde
FR
muguet ethanol
FR
muguet nitrile
FR
muguet octadienol
FR
muguet propanol
FR
cis-
muguet shiseol
FL/FR
muguet shiseol
FL/FR
muguet specialty
FR
beta-
naphthyl methyl ketone
FL/FR
alpha-
naphthyl methyl ketone
FL/FR
neroli absolute
FL/FR
neroli extract
FL/FR
neroli oil
FL/FR
neroli oil bigarde
FL/FR
nerolin fragarol
FL/FR
nonanal / methyl anthranilate schiff's base
FR
ocean propanal / methyl anthranilate schiff's base
FR
octahydro-4,7-methano-1H-indene-5-acetaldehyde
FR
octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd
FR
bitter
orangeflower absolute morocco
FL/FR
orchid specialty
FR
2-
pentyl-2-cyclohexen-1-one
FR
petitgrain absolute morocco
FL/FR
petitgrain bigarade oil
FL/FR
petitgrain oil fractions
FR
petitgrain oil replacer
FR
phenyl glycol diacetate
FR
propyl anthranilate
FL/FR
4-
propyl cyclohexane propanal
FR
rose absolute pentanol
FR
surfleurs d'oranger oil
FL/FR
alpha-
terpinyl anthranilate
FL/FR
tetrahydrolinalool
FL/FR
(S,E)-3,7,11-
trimethyldodeca-6,10-dienal
FR
ylang ylang flower oil
FL/FR
ylang ylang flower oil CO2 extract
FL/FR
ylang ylang flower oil fractions
FR
ylang ylang flower oil I
FL/FR
ylang ylang flower oil II
FL/FR
ylang ylang oil III fractions
FR
ylang ylang oil replacer
FR
ylang ylang specialty
FR
fruity
cyclohexyl anthranilate
FL/FR
methyl anthranilate
FL/FR
green
nerol oxide
FL/FR
phenyl acetaldehyde diethyl acetal
FL/FR
violet decenol
FR
herbal
dimethyl benzyl carbinyl formate
FL/FR
marine
ozone propanal
FR
muguet
4-iso
butyl 1-(3-methoxy-2-propen-1-yl) benzene
FR
4-
ethyl 1-(3-methoxy-2-propen-1-yl) benzene
FR
4-
methyl 1-(3-methoxy-2-propen-1-yl) benzene
FR
4-
propyl 1-(3-methoxy-2-propen-1-yl) benzene
FR
naphthyl
beta-
naphthyl ethyl ether
FL/FR
beta-
naphthyl methyl ether
FL/FR
waxy
3-
decanone
FL/FR
woody
amber dioxane
FR
hydroxycitronellal diisotridecyl acetal
FR
labdanum ethanone
FR
For Flavor
No flavor group found for these
alpha-
amyl cinnamaldehyde dimethyl acetal
FL/FR
3-
decanone
FL/FR
(Z)-4-
decen-1-yl acetate
FL/FR
dimethyl benzyl carbinyl formate
FL/FR
(E,E)-
farnesol
FL/FR
hydroxycitronellal propylene glycol acetal
FL/FR
2-
methyl octanal
FL/FR
alpha-
naphthyl methyl ketone
FL/FR
phenyl acetaldehyde diethyl acetal
FL/FR
propyl anthranilate
FL/FR
surfleurs d'oranger oil
FL/FR
alpha-
terpinyl anthranilate
FL/FR
alpha-
butyl cinnamaldehyde
FL/FR
aldehydic
aldehydic
nonanal (aldehyde C-9)
FL/FR
aromatic
para-
cresyl isobutyrate
FL/FR
citrus
citronellyl oxyacetaldehyde
FL/FR
(Z)-4-
decenal
FL/FR
mandarin oil italy
FL/FR
petitgrain bigarade oil
FL/FR
fatty
2-
dodecanone
FL/FR
fermented
2-
decanone
FL/FR
floral
farnesol
FL/FR
linalyl anthranilate
FL/FR
muguet carbinol
FL/FR
muguet shiseol
FL/FR
cis-
muguet shiseol
FL/FR
beta-
naphthyl methyl ketone
FL/FR
neroli absolute
FL/FR
neroli extract
FL/FR
neroli oil
FL/FR
neroli oil bigarde
FL/FR
bitter
orangeflower absolute morocco
FL/FR
petitgrain absolute morocco
FL/FR
tetrahydrolinalool
FL/FR
ylang ylang flower oil
FL/FR
ylang ylang flower oil CO2 extract
FL/FR
ylang ylang flower oil I
FL/FR
ylang ylang flower oil II
FL/FR
fruity
cyclohexyl anthranilate
FL/FR
ethyl anthranilate
FL/FR
linalyl benzoate
FL/FR
linalyl cinnamate
FL/FR
methyl anthranilate
FL/FR
nerolin fragarol
FL/FR
green
cuminyl acetaldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
nerol oxide
FL/FR
herbal
linalyl propionate
FL/FR
melon
hydroxycitronellal diethyl acetal
FL/FR
naphthyl
beta-
naphthyl methyl ether
FL/FR
phenolic
para-
cresyl phenyl acetate
FL/FR
powdery
hydroxycitronellol
FL/FR
beta-
naphthyl ethyl ether
FL/FR
waxy
decanol
FL/FR
hydroxycitronellal
FL/FR
hydroxycitronellal dimethyl acetal
FL/FR
woody
alpha-
terpinyl methyl ether
FL/FR
 
Potential Uses:
FRcitrus
FRfloral
FRgreenhouse
FRlily
FRlily of the valley
FRmagnolia
FRneroli
FRorange blossom
FRtuberose
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 benzoic acid, 2-(((4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylene)amino)-, methyl ester
 benzoic acid, 2-(((4-(4-hydroxy-4-methylpentyl)-3-cyclohexenyl)methylene)amino)-, methyl ester
 benzoic acid, 2-((4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylene)amino-, methyl ester
2-(((4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylene)amino)benzoic acid, methyl ester
 leerall / methyl anthranilate schiff's base
 lyrame (IFF)
 lyrame super (IFF)
 lyrantion (Quest)
 lyrantion 50%DPG (Quest)
 methyl 2-(((4-(4-hydroxy-4-methyl pentyl)-3-cyclohexenyl)methylene)amino) benzoate
 methyl 2-(((4-(4-hydroxy-4-methylpentyl)-3-cyclohexenyl)methylene)amino)benzoate
 methyl 2-(((E)-1-(4-(4-hydroxy-4-methyl pentyl)-3-cyclohexenyl)methylidene)amino)-1-benzene
 methyl 2-[[4-(4-hydroxy-4-methylpentyl)-1-cyclohex-3-enyl]methylideneamino]benzoate
 methyl anthranilate / leerall schiff's base
 methyl anthranilate / lyral
 methyl anthranilate / lyral schiff base
 methyl anthranilate / lyral schiff base 50% in DEP
 methyl hydroxymethyl pentyl cyclohexenyl methylene aminobenzoate
 methyl N-((4-(4-hydroxy-4-methyl pentyl)-3-cyclohexen-1-yl)methylidene) anthranilate
 methyl N-((4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylidene)anthranilate
 schiff lyral
 schiff's base lyrama super
 

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