EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

(Z)-4-dodecenal
(4Z)-dodecenal

Supplier Sponsors

Fragrance Demo Formulas
Name:(Z)-dodec-4-enal
CAS Number: 21944-98-9Picture of molecule3D/inchi
FDA UNII:IJA6BV46A7
Nikkaji Web:J1.520.586E
XlogP3-AA:4.10 (est)
Molecular Weight:182.30654000
Formula:C12 H22 O
NMR Predictor:Predict (works with chrome or firefox)
Also(can) Contains:dodecanal (aldehyde C-12 lauric) 3.00% to 4.00%
EFSA/JECFA Comments:
Known imputities: 1.06 % 4E-dodecenal, 3.66 % dodecanal (FL-no: 05.011), 1.29 % tetradecane (FL-no: 01.057).
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
JECFA Food Flavoring:1636 (Z)-4-dodecenal
FLAVIS Number:05.220 (Old)
DG SANTE Food Flavourings:05.220 (4Z)-dodecenal
FEMA Number:4036 (Z)-4-dodecenal
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):21944-98-9 ; (Z)-4-DODECENAL
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 94.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.84300 to 0.84900 @ 25.00 °C.
Pounds per Gallon - (est).: 7.015 to 7.065
Refractive Index:1.44300 to 1.44900 @ 20.00 °C.
Boiling Point: 254.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.016000 mmHg @ 25.00 °C. (est)
Flash Point: 228.00 °F. TCC ( 108.89 °C. )
logP (o/w): 4.831 (est)
Soluble in:
 alcohol
 water, 7.259 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: aldehydic
Odor Strength:medium ,
recommend smelling in a 1.00 % solution or less
aldehydic citrus fruity
Odor Description:at 1.00 % in dipropylene glycol. aldehydic citrus fruity
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
cis-4-DODECENAL 97.0% (sum of isomers
Parchem
(Z)-4-dodecen-1-al
Chemical Sources Association
Need This Item for Flavor/Food?: You can contact the Chemical Sources Association
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for (Z)-4-dodecenal usage levels up to:
  0.8000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 1.20 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 36 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 21
 average usual ppmaverage maximum ppm
baked goods: 0.100000.20000
beverages(nonalcoholic): 0.050000.10000
beverages(alcoholic): 0.080000.16000
breakfast cereal: 0.100000.20000
cheese: --
chewing gum: 4.000008.00000
condiments / relishes: --
confectionery froastings: 1.000002.00000
egg products: --
fats / oils: --
fish products: --
frozen dairy: 0.080000.16000
fruit ices: 0.080000.16000
gelatins / puddings: 0.050000.11000
granulated sugar: --
gravies: --
hard candy: 0.100000.20000
imitation dairy: --
instant coffee / tea: --
jams / jellies: 0.040000.08000
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: 0.100000.20000
soft candy: 0.100000.20000
soups: --
sugar substitutes: --
sweet sauces: --
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 0.050000.16000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): --
Edible ices, including sherbet and sorbet (03.0): 0.080000.16000
Processed fruit (04.1): 0.040000.08000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 0.100008.00000
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 0.100000.20000
Bakery wares (07.0): 0.100000.20000
Meat and meat products, including poultry and game (08.0): --
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): --
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): --
Foodstuffs intended for particular nutritional uses (13.0): --
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 0.050000.10000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 0.080000.16000
Ready-to-eat savouries (15.0): 0.100000.20000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 6, Revision 1 (FGE.06Rev1) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 06, Revision 2 (FGE.06Rev2): Straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters from chemical groups 1 and 4
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 06, Revision 3 (FGE.06Rev3): Straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters from chemical groups 1 and 4
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 06, Revision 4 (FGE.06Rev4): Straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids and esters from chemical groups 1, 3 and 4
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):21944-98-9
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6430180
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
(Z)-dodec-4-enal
Chemidplus:0021944989
 
References:
 (Z)-dodec-4-enal
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):6430180
Pubchem (sid):135263444
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
HMDB (The Human Metabolome Database):HMDB32247
FooDB:FDB009339
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
(Z)-8-
tetradecenal
FL/FR
aldehydic
aldehydic
citronellyl oxyacetaldehyde
FL/FR
dodecanal (aldehyde C-12 lauric)
FL/FR
3-
methyl-4-(1-methyl hexyl oxy) butyraldehyde
FR
3-
methyl-4-heptyl oxybutyraldehyde
FR
undecanal
FL/FR
(Z)-8-
undecenal
FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
citrus
agrestic specialty
FR
aldehydic nitrile
FR
citronitrile (Symrise)
FR
citrus limon peel oil expressed
FL/FR
citrus paradisi peel extract
FL/FR
curacao specialty
FR
4,7-
decadienal
FR
(Z)-4-
decenal
FL/FR
(Z)-7-
decenal
FR
(E)-4-
decenal
FL/FR
2-
dodecanone
FL/FR
lemon fragrance
FR
lemon oil c.p. california
FL/FR
lemon oil c.p. furocoumarin reduced
FL/FR
lemon oil replacer
FR
lemon specialty
FL/FR
mandarin specialty
FR
marine decadienal
FR
(Z+E)-2-
methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde
FL/FR
1-
methyl-4-methyl ethenyl cyclohexene sulfurized
FL/FR
orange fruit oil
FL/FR
blood
orange oil italy
FL/FR
tetrahydrocitral
FL/FR
creamy
3-
heptyl dihydro-5-methyl-2(3H)-furanone
FL/FR
fatty
(E)-2-
nonenal
FL/FR
floral
bursera graveolens wood oil
FL/FR
citronellal
FL/FR
citronellyl acetate
FL/FR
geranyl tiglate
FL/FR
neryl isovalerate
FL/FR
terpinyl formate
FL/FR
(E)-2,5,9-
trimethyl-4,9-decadien-1-al
FR
fruity
iso
amyl 2-methyl butyrate
FL/FR
iso
butyl 2-methyl butyrate
FL/FR
ethyl citronellate
FL/FR
ethyl isobutyrate
FL/FR
heptanal cyclic ethylene acetal
FR
methyl acetoacetate
FL/FR
iso
propyl isobutyrate
FL/FR
tropical specialty
FR
(E)-2-
undecenal
FL/FR
green
citrus carbaldehyde / methyl anthranilate schiff's base
FR
green carbaldehyde
FR
green carboxylate
FR
(Z)-3-
hexen-1-yl oxyacetaldehyde
FR
dextro-
limonene oxide
FL/FR
(2-
methoxy-1-methyl butyl) benzene
FR
herbal
2-
dodecenal
FL/FR
6-
methoxy-2,6-dimethyl octanal
FR
(1S,5R)-
myrtenyl acetate
FL/FR
waxy
aldenal C-9
FR
3-
decanone
FL/FR
woody
bamboo fragrance
FR
For Flavor
No flavor group found for these
bursera graveolens wood oil
FL/FR
beta-
cubebene
FL
3-
decanone
FL/FR
dihydronootkatone
FL
lemon specialty
FL/FR
3-
mercaptooctanal
FL
methyl acetoacetate
FL/FR
(Z+E)-2-
methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde
FL/FR
iso
propyl isobutyrate
FL/FR
(Z)-8-
tetradecenal
FL/FR
tetrahydrocitral
FL/FR
dextro-
limonene oxide
FL/FR
citrus
citrus
citronellyl oxyacetaldehyde
FL/FR
citrus limon peel oil expressed
FL/FR
citrus paradisi peel extract
FL/FR
(Z)-4-
decenal
FL/FR
dehydronootkatone
FL
lemon oil c.p. california
FL/FR
lemon oil c.p. furocoumarin reduced
FL/FR
1-
methyl-4-methyl ethenyl cyclohexene sulfurized
FL/FR
orange fruit oil
FL/FR
blood
orange oil italy
FL/FR
dusty
ethyl citronellate
FL/FR
ethereal
ethyl isobutyrate
FL/FR
fatty
2-
dodecanone
FL/FR
2-
dodecenal
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
floral
citronellal
FL/FR
citronellyl acetate
FL/FR
geranyl tiglate
FL/FR
fruity
iso
amyl 2-methyl butyrate
FL/FR
iso
butyl 2-methyl butyrate
FL/FR
3-
heptyl dihydro-5-methyl-2(3H)-furanone
FL/FR
neryl isovalerate
FL/FR
terpinyl formate
FL/FR
green
(E)-2-
heptenal
FL
(E,E)-2,4-
hexadienal
FL
(E)-2-
nonenal
FL/FR
ripe
(E)-4-
decenal
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
waxy
undecanal
FL/FR
(E)-2-
undecenal
FL/FR
woody
(1S,5R)-
myrtenyl acetate
FL/FR
 
Potential Uses:
FRcitrus
 
Occurrence (nature, food, other):note
 coriander leaf
Search Trop Picture
 
Synonyms:
(4Z)-dodec-4-enal
(Z)-dodec-4-enal
(Z)-4-dodecen-1-al
(4Z)-dodecenal
(4Z)-4-dodecenal
4-dodecenal, (4Z)-
 tangerinal
 

Articles:

 None found yet.
 
Notes:
Used as a food additive [EAFUS]
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2018 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy