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leafy oxime
stemone (Givaudan)

Supplier Sponsors

Fragrance Demo Formulas
Name:N-(5-methylheptan-3-ylidene)hydroxylamine
CAS Number: 22457-23-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:245-010-8
Beilstein Number:1923529
MDL:MFCD03938986
XlogP3-AA:2.50 (est)
Molecular Weight:143.22969000
Formula:C8 H17 O N
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 97.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.88600 to 0.89100 @ 25.00 °C.
Pounds per Gallon - (est).: 7.372 to 7.414
Specific Gravity:0.88500 to 0.89000 @ 25.00 °C.
Pounds per Gallon - est.: 7.364 to 7.406
Refractive Index:1.45000 to 1.45500 @ 20.00 °C.
Boiling Point: 220.84 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.041000 mm/Hg @ 25.00 °C. (est)
Flash Point: 203.00 °F. TCC ( 95.00 °C. )
logP (o/w): 2.512 (est)
Soluble in:
 alcohol
 water, 1014 mg/L @ 20 °C (exp)
Stability:
 cosmetics
 detergent
 soap
 
Organoleptic Properties:
Odor Type: green
Odor Strength:medium
Substantivity:16 hour(s) at 100.00 %
galbanum fig leafy green weedy cortex
Odor Description:at 100.00 %. galbanum fig leaf green weedy cortex
Luebke, William tgsc, (1986)
Odor sample from: Givaudan Corporation
Odor and/or flavor descriptions from others (if found).
Givaudan
Stemone®
Odor Description:Green, Natural, Leafy, Fresh, Powerful
Stemone imparts a natural and fresh nuance to fragrance notes such as lily-of-the-valley, narcissus, mandarin, fig leaves, grapefruit, black currant and tomato. It is an excellent modifier that strengthens and modernises green notes.
PerfumersWorld
Stemone
Odor Description:herbaceous citrusy lemon
Blends-well-with - +Galbanum +Pineapple
Pell Wall Perfumes
Stemone
Odor Description:Green-leafy, galbanum, fig, fresh, natural
Description from Givaudan: “Green, Natural, Leafy, Fresh, Powerful. Imparts a natural and fresh nuance to fragrance notes such as lily-of-the-valley, narcissus, mandarin, fig leaves, grapefruit, black currant and tomato. It is an excellent modifier that strengthens and modernises green notes.” Arcadi Boix Camps describes the scent of this material as “somewhere between galbanum and fig leaves absolute”
Prodasynth
OXYME EAC (SUM OF ISOMERS > 96%)
Odor Description:GREEN, POWERFUL, FRESH, IVY
Tadimety Aromatics
Tremone
Odor Description:Green, Natural, Leafy, Fresh
Nactis Flavours
HEPTOXIME
Odor Description:powerfull natural green and minty note, reminiscent of fig tree leaves
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: masking agents
perfuming agents
 
Suppliers:
Augustus Oils
Stemone
Services
Ernesto Ventós
HEPTOXIME (STEMONE)
Ernesto Ventós
HEPTOXIME PCAS
Ernesto Ventós
HEPTOXIME PCAS
Odor: GREEN, POWERFUL, FRESH
Givaudan
Stemone®
Odor: Green, Natural, Leafy, Fresh, Powerful
Use: Stemone imparts a natural and fresh nuance to fragrance notes such as lily-of-the-valley, narcissus, mandarin, fig leaves, grapefruit, black currant and tomato. It is an excellent modifier that strengthens and modernises green notes.
Global Essence
Heptoxime
Indukern F&F
STEMONE
Odor: GREEN, FRESH, LEAF, HERBAL
M&U International
STEMONE
Moellhausen
STEMONE
Odor: herbaceous, citrus, lemon
Flavor: lemon
Nactis Flavours
HEPTOXIME
Odor: powerfull natural green and minty note, reminiscent of fig tree leaves
PCAS
Heptoxime
PCW France
Stigemone
Steps to a fragranced product
Pell Wall Perfumes
Stemone
Odor: Green-leafy, galbanum, fig, fresh, natural
Use: Description from Givaudan: “Green, Natural, Leafy, Fresh, Powerful. Imparts a natural and fresh nuance to fragrance notes such as lily-of-the-valley, narcissus, mandarin, fig leaves, grapefruit, black currant and tomato. It is an excellent modifier that strengthens and modernises green notes.” Arcadi Boix Camps describes the scent of this material as “somewhere between galbanum and fig leaves absolute”
Penta International
5-METHYL-3-HEPTANONE OXIME, Kosher
PerfumersWorld
Stemone 10% in DPG
PerfumersWorld
Stemone
Odor: herbaceous citrusy lemon
Use: Blends-well-with - +Galbanum +Pineapple
Perfumery Laboratory
STEMON® G 10% in DPG (STEMONE® G 10% DPG)
Odor: Peach tree leaves
Prasad Organics
Greenone
Prodasynth
OXYME EAC
(SUM OF ISOMERS > 96%)
Odor: GREEN, POWERFUL, FRESH, IVY
Santa Cruz Biotechnology
For experimental / research use only.
Stemone
Sigma-Aldrich: Aldrich
For experimental / research use only.
vMethyl-3-heptanone Oxime
Tadimety Aromatics
Tremone
Odor: Green, Natural, Leafy, Fresh
The Perfumers Apprentice
Stemone
Odor: Green, Natural, Leafy, Fresh, Powerful
Use: gives a natural and fresh nuance to fragrance notes such as lily-of-the-valley, narcissus, mandarin, fig leaves, grapefruit, black currant and tomato. It is an excellent modifier that strengthens and modernises green notes.
Vigon International
Methyl-5 3-Heptanone Oxime (Stemone )
Odor: Green, Natural, Leafy, Fresh, Powerful
Zanos
Tremone
Odor: Green, natural leafy fresh
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 3800 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 87S, 1992.

Dermal Toxicity:
skin-rabbit LD50 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 87S, 1992.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for leafy oxime usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Recommendation for leafy oxime flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):22457-23-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :90787
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
N-(5-methylheptan-3-ylidene)hydroxylamine
Chemidplus:0022457234
 
References:
 N-(5-methylheptan-3-ylidene)hydroxylamine
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:22457-23-4
Pubchem (cid):90787
Pubchem (sid):135049380
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
adoxal (Givaudan)
FL/FR
citrus carbaldehyde
FR
decanal (aldehyde C-10)
FL/FR
9-
decenal
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
amber
angelica root oil
FL/FR
balsamic
2-
acetyl furan
FL/FR
iso
amyl benzoate
FL/FR
benzyl benzoate
FL/FR
benzyl salicylate
FL/FR
iso
bornyl acetate
FL/FR
laevo-
bornyl acetate
FL/FR
cinnamyl alcohol
FL/FR
clover nitrile
FR
cotinus coggygria branch/leaf oil
FL/FR
ethyl cinnamate
FL/FR
fir needle oil siberia
FL/FR
citrus
bergamot oil bergaptene reduced italy
FL/FR
citral
FL/FR
grapefruit oil c.p. california
FL/FR
grapefruit pentanol
FR
lemon oil c.p. california
FL/FR
lemongrass oil
FL/FR
lime oil distilled mexico
FL/FR
litsea cubeba fruit oil
FL/FR
methyl heptenone
FL/FR
blood
orange oil italy
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
tetrahydromyrcenol
FR
earthy
methyl undecylenate
FL/FR
floral
iso
amyl salicylate
FL/FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
benzyl isobutyrate
FL/FR
bois de rose oil brazil
FL/FR
iso
butyl salicylate
FL/FR
citronellyl acetate
FL/FR
coriander seed oil
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
dimethyl benzyl carbinol
FL/FR
floral pyranol
FR
gardenia oxide
FR
geraniol
FL/FR
geranyl acetate
FL/FR
heliotropyl diethyl acetal
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
ho leaf oil
FR
hyacinth ether
FR
leerall
FR
linalool
FL/FR
laevo-
linalool
FL/FR
linalool oxide
FL/FR
methyl dihydrojasmonate
FL/FR
mimosa absolute france
FL/FR
muguet carboxaldehyde
FR
muguet octadienol
FR
nerol
FL/FR
nerolidol
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
orris pyridine 25% IPM
FR
peony alcohol
FR
petitgrain oil paraguay
FL/FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
rhodinol
FL/FR
rose butanoate
FL/FR
tetrahydrolinalool
FL/FR
violet methyl carbonate
FR
fruity
allyl amyl glycolate
FR
allyl cyclohexyl propionate
FL/FR
allyl hexanoate
FL/FR
bitter
almond oil
FL/FR
iso
amyl acetate
FL/FR
benzaldehyde
FL/FR
benzyl propionate
FL/FR
diethyl malonate
FL/FR
green acetate
FR
hexyl acetate
FL/FR
methyl 2-methyl valerate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
bean hexene
FR
S-sec-
butyl thioisovalerate
FL/FR
cortex pyridine
FL/FR
galbanum oil
FL/FR
galbanum oxyacetate
FR
galbascone (IFF)
FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(Z)-3-
hexen-1-yl formate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl tiglate
FL/FR
(Z)-
leaf acetal
FL/FR
melon nonenoate
FL/FR
nerol oxide
FL/FR
(E,Z)-2,6-
nonadien-1-ol
FL/FR
(E,Z)-2,6-
nonadienal
FL/FR
phenyl acetaldehyde
FL/FR
3-
phenyl propionaldehyde
FL/FR
iso
propyl 3-methyl thiocrotonate
FL/FR
iso
propyl thioisovalerate
FL/FR
spirogalbanone (Givaudan)
FR
styralyl acetate
FL/FR
violet leaf absolute
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
clary sage oil france
FL/FR
daucus carota fruit oil
FL/FR
eucalyptus globulus oil
FL/FR
herbal undecanone
FR
lavender absolute bulgaria
FL/FR
linalyl acetate
FL/FR
nopyl acetate
FR
alpha-
terpinyl acetate
FL/FR
marine
marine pyridine
FR
melon
melon heptenal
FL/FR
watermelon ketone
FR
phenolic
methyl benzoate
FL/FR
powdery
para-
anisyl acetate
FL/FR
terpenic
frankincense oil
FL/FR
juniperus communis fruit oil
FL/FR
alpha-
terpineol
FL/FR
tropical
cis-
galbanum oxathiane
FL/FR
2-
tropical oxathiane
FL/FR
waxy
ethyl laurate
FL/FR
woody
amber carbinol
FR
patchouli ethanone
FR
spruce needle oil canada
FL/FR
thuja occidentalis leaf oil
FL/FR
vetiver oil haiti
FL/FR
woody acetate
FR
(Z)-
woody amylene
FR
woody propanol
FR
For Flavor
No flavor group found for these
S-sec-
butyl thioisovalerate
FL/FR
cotinus coggygria branch/leaf oil
FL/FR
9-
decenal
FL/FR
iso
propyl 3-methyl thiocrotonate
FL/FR
iso
propyl thioisovalerate
FL/FR
2-
tropical oxathiane
FL/FR
aldehydic
aldehydic
nonanal (aldehyde C-9)
FL/FR
octanal (aldehyde C-8)
FL/FR
apple
(E,Z)-2,6-
nonadien-1-ol
FL/FR
balsamic
benzyl benzoate
FL/FR
benzyl salicylate
FL/FR
laevo-
bornyl acetate
FL/FR
ethyl cinnamate
FL/FR
fir needle oil siberia
FL/FR
citrus
bergamot oil bergaptene reduced italy
FL/FR
citral
FL/FR
grapefruit oil c.p. california
FL/FR
lemon oil c.p. california
FL/FR
lemongrass oil
FL/FR
lime oil distilled mexico
FL/FR
laevo-
linalool
FL/FR
linalool
FL/FR
litsea cubeba fruit oil
FL/FR
nerol
FL/FR
blood
orange oil italy
FL/FR
sweet
orange peel oil c.p. brazil
FL/FR
alpha-
terpineol
FL/FR
cooling
iso
butyl salicylate
FL/FR
creamy
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
fatty
(Z)-3-
hexen-1-yl benzoate
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
floral
bois de rose oil brazil
FL/FR
citronellyl acetate
FL/FR
geraniol
FL/FR
linalyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
neryl acetate
FL/FR
ocean propanal
FL/FR
phenethyl alcohol
FL/FR
rhodinol
FL/FR
tetrahydrolinalool
FL/FR
fruity
allyl cyclohexyl propionate
FL/FR
allyl hexanoate
FL/FR
bitter
almond oil
FL/FR
iso
amyl acetate
FL/FR
iso
amyl benzoate
FL/FR
para-
anisyl acetate
FL/FR
benzaldehyde
FL/FR
benzyl acetate
FL/FR
benzyl alcohol
FL/FR
benzyl isobutyrate
FL/FR
benzyl propionate
FL/FR
diethyl malonate
FL/FR
hexyl acetate
FL/FR
methyl 2-methyl valerate
FL/FR
rose butanoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
styralyl acetate
FL/FR
green
acetaldehyde ethyl phenethyl acetal
FL/FR
iso
amyl salicylate
FL/FR
angelica root oil
FL/FR
cinnamyl alcohol
FL/FR
cortex pyridine
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
galbanum oil
FL/FR
cis-
galbanum oxathiane
FL/FR
geranyl acetate
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl formate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl tiglate
FL/FR
(Z)-
leaf acetal
FL/FR
linalool oxide
FL/FR
melon heptenal
FL/FR
melon nonenoate
FL/FR
methyl heptenone
FL/FR
nerol oxide
FL/FR
nerolidol
FL/FR
(E,Z)-2,6-
nonadienal
FL/FR
3-
phenyl propionaldehyde
FL/FR
violet leaf absolute
FL/FR
herbal
anthemis nobilis flower oil roman
FL/FR
clary sage oil france
FL/FR
coriander seed oil
FL/FR
daucus carota fruit oil
FL/FR
eucalyptus globulus oil
FL/FR
lavender absolute bulgaria
FL/FR
petitgrain oil paraguay
FL/FR
honey
phenethyl acetate
FL/FR
phenyl acetaldehyde
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
nutty
2-
acetyl furan
FL/FR
phenolic
methyl benzoate
FL/FR
terpenic
juniperus communis fruit oil
FL/FR
waxy
adoxal (Givaudan)
FL/FR
decanal (aldehyde C-10)
FL/FR
ethyl laurate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
methyl undecylenate
FL/FR
mimosa absolute france
FL/FR
woody
iso
bornyl acetate
FL/FR
frankincense oil
FL/FR
spruce needle oil canada
FL/FR
alpha-
terpinyl acetate
FL/FR
thuja occidentalis leaf oil
FL/FR
vetiver oil haiti
FL/FR
 
Potential Uses:
 cortex
FRcurrant black currant
FRfig
FRgalbanum
FRgrapefruit
FRgreen
FRgreen leaf
FRlily of the valley
FRmandarin
 modifier
FRnarcissus
 natural
FLtomato
 weedy
FRwoody
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 ethyl 2-methyl butyl ketoxime
 ethyl 2-methylbutyl ketoxime
 ethyl 2-methylbutyl ketoxine
 greenone
3-heptanone, 5-methyl-, oxime
 heptoxime (Synarome)
N-hydroxy-5-methylheptan-3-imine
 leafy oxime
5-methyl heptan-3-one oxime
 methyl heptanone oxime
5-methyl-3-heptanone oxime
 methyl-5 3-heptanone oxime
3-methyl-5-heptanone oxime
5-methylheptan-3-one oxime
N-(5-methylheptan-3-ylidene)hydroxylamine
 stemone (Givaudan)
 tremone (Tadimety)
 vertone
 

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