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spirogalbanone (Givaudan)
4-penten-1-one, 1-spiro[4.5]dec-7-en-7-yl-

Sponsors

Fragrance Demo Formulas
Name:1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one
CAS Number: 224031-70-3Picture of molecule3D/inchi
Molecular Weight:218.33954000
Formula:C15 H22 O
NMR Predictor:Predict (works with chrome or firefox)
Name:1-(spiro[4.5]dec-6-en-7-yl)pent-4-en-1-one
CAS Number: 224031-71-4Picture of molecule3D/inchi
Molecular Weight:218.33954000
Formula:C15 H22 O
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
 
Physical Properties:
Appearance:pale yellow to yellow clear oily liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Boiling Point: 331.00 to 332.00 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.000153 mm/Hg @ 25.00 °C. (est)
Flash Point: 284.00 °F. TCC ( 140.10 °C. ) (est)
logP (o/w): 4.004 (est)
Soluble in:
 alcohol
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: green
Odor Strength:high ,
recommend smelling in a 1.00 % solution or less
green galbanum fruity pineapple
Odor Description:at 1.00 % in dipropylene glycol. green galbanum fruity pineapple
Odor and/or flavor descriptions from others (if found).
Givaudan
Spirogalbanone Pure
Odor Description:Green, Galbanum, Fruity, Pineapple, Powerful
Spirogalbanone is a powerful green galbanum note, accompanied by fruit facets. As such, Spirogalbanone has the same olfactive profile as classical green galbanum molecules but it differentiates itself thanks to its outstanding substantivity. In addition to its fresh green galbanum volume, its excellent stability allows for use in all applications, especially in those where performance and substantivity are sought.
Pell Wall Perfumes
Spirogalbanone
Odor Description:Green-galbanum, fruity-pineapple. Powerful and substantive
Arcadi Boix Camps wrote extensively, and enthusiastically, about Spirogalbanone in 2009. He points out that although the odour is very similar to that of materials such as Allyl Amyl Glycolate, Dynascone, Pharaone, Galbaniff and neobutenone it has the advantage that while the latter four last two or three days on a smelling strip, Spirogalbanone lasts about two weeks. This, he says, “is a supreme characteristic, a radical difference.” he goes on to point out that it “imparts an important synergistic effect” on those other materials, acting as a fixative for them. Furthermore he says it is “very clean and extremely diffusive” when compared to galbanum absolute or resinoid.
 
Cosmetic Information:
None found
 
Suppliers:
CG Herbals
Spirogalbanone
Odor: Green, Galbanum, Fruity, Pineapple
Use: Spirogalbanone is a powerful green galbanum note, accompanied by fruit facets. As such, Spirogalbanone has the same olfactive profile as classical green galbanum molecules but it differentiates itself thanks to its outstanding substantivity. In addition to its fresh green galbanum volume, its excellent stability allows for use in all applications, especially in those where performance and substantivity are sought.
Givaudan
Spirogalbanone Pure
Odor: Green, Galbanum, Fruity, Pineapple, Powerful
Use: Spirogalbanone is a powerful green galbanum note, accompanied by fruit facets. As such, Spirogalbanone has the same olfactive profile as classical green galbanum molecules but it differentiates itself thanks to its outstanding substantivity. In addition to its fresh green galbanum volume, its excellent stability allows for use in all applications, especially in those where performance and substantivity are sought.
Indukern F&F
SPIROGALBANONE
Odor: GREEN, GALBANUM, FRUITY, PINEAPPLE
Moellhausen
GALBASCONE PURE
Pell Wall Perfumes
Spirogalbanone 10%
Odor: Green-galbanum, fruity-pineapple. Powerful and substantive
Use: Very powerful material, manufactured by Givaudan, normally used in high dilution and therefore offered here at 10% in IPM for those who normally work in smaller quantities and also to make this relatively expensive material more affordable.
Pell Wall Perfumes
Spirogalbanone
Odor: Green-galbanum, fruity-pineapple. Powerful and substantive
Use: Arcadi Boix Camps wrote extensively, and enthusiastically, about Spirogalbanone in 2009. He points out that although the odour is very similar to that of materials such as Allyl Amyl Glycolate, Dynascone, Pharaone, Galbaniff and neobutenone it has the advantage that while the latter four last two or three days on a smelling strip, Spirogalbanone lasts about two weeks. This, he says, “is a supreme characteristic, a radical difference.” he goes on to point out that it “imparts an important synergistic effect” on those other materials, acting as a fixative for them. Furthermore he says it is “very clean and extremely diffusive” when compared to galbanum absolute or resinoid.
Vigon International
Spirogalbanone
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 5), H303
Skin corrosion/irritation (Category 3), H316
Skin sensitisation (Category 1), H317
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
GHS Label elements, including precautionary statements
 
Pictogramexclamation-mark.jpgenvironment.jpg
 
Signal word Danger
Hazard statement(s)
H303 - May be harmfulif swallowed
H316 - Causes mild skin irritation
H317 - May cause an allergic skin reaction
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statement(s)
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash skin thouroughly after handling.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 - IF ON SKIN: wash with plenty of soap and water.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P333 + P313 - IF SKIN irritation or rash occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P391 - Collect spillage. Hazardous to the aquatic environment
P501 - Dispose of contents/ container to an approved waste disposal plant.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for spirogalbanone (Givaudan) usage levels up to:
  0.5000 % in the fragrance concentrate.
 
Recommendation for spirogalbanone (Givaudan) flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):224031-70-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one
Chemidplus:224031703
1-(spiro[4.5]dec-6-en-7-yl)pent-4-en-1-one
Chemidplus:224031714
 
References:
 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one
NIST Chemistry WebBook:Search Inchi
Pubchem (sid):135326225
 1-(spiro[4.5]dec-6-en-7-yl)pent-4-en-1-one
NIST Chemistry WebBook:Search Inchi
Pubchem (sid):3820329
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
balsamic
cotinus coggygria branch/leaf oil
FL/FR
cheesy
heptanoic acid
FL/FR
chemical
propyl propionate
FL/FR
ethereal
propyl valerate
FL/FR
fatty
allyl decanoate
FL/FR
allyl octanoate
FL/FR
methyl 2-hexenoate
FL/FR
floral
geranyl valerate
FL/FR
fruity
allyl 3,5,5-trimethyl hexanoate
FL/FR
allyl amyl glycolate
FR
allyl cinnamate
FL/FR
allyl cyclohexyl acetate
FL/FR
allyl cyclohexyl butyrate
FL/FR
allyl heptanoate
FL/FR
amyl propionate
FL/FR
iso
butyl hexanoate
FL/FR
butyl valerate
FL/FR
ethyl 3-(2-furyl) propanoate
FL/FR
ethyl 3-hexenoate
FL/FR
ethyl 3-methyl valerate
FL/FR
ethyl 5-hydroxyoctanoate
FL/FR
ethyl butyrate
FL/FR
ethyl cyclohexane propionate
FL/FR
ethyl heptanoate
FL/FR
ethyl hexanoate
FL/FR
ethyl-2-cyclopentenyl acetate
FR
methyl hexanoate
FL/FR
methyl isovalerate
FL/FR
iso
propyl hexanoate
FL/FR
iso
propyl isobutyrate
FL/FR
green
S-sec-
butyl thioisovalerate
FL/FR
galbanum oxyacetate
FR
galbascone (IFF)
FR
3-
hexenyl 2-methyl butyrate
FL/FR
leafy oxime
FR
neogall
FR
pineapple heptadienone 10%
FR
iso
propyl 3-methyl thiocrotonate
FL/FR
iso
propyl thioisovalerate
FL/FR
(E,E)-
sorbyl isobutyrate
FL/FR
sorbyl isobutyrate
FL/FR
herbal
herbal undecanone
FR
nutty
2-
methyl-3-ethoxypyrazine
FL/FR
sulfurous
ethyl methyl mercaptopropionate
FL/FR
tropical
cis-
galbanum oxathiane
FL/FR
pina colada fragrance
FR
tropical 3-thiobutyrate
FL/FR
2-
tropical oxathiane
FL/FR
waxy
ethyl octanoate
FL/FR
For Flavor
No flavor group found for these
allyl 3,5,5-trimethyl hexanoate
FL/FR
allyl cinnamate
FL/FR
allyl cyclohexyl butyrate
FL/FR
amyl propionate
FL/FR
S-sec-
butyl thioisovalerate
FL/FR
cotinus coggygria branch/leaf oil
FL/FR
ethyl 3-methyl valerate
FL/FR
ethyl 5-hydroxyoctanoate
FL/FR
ethyl cyclohexane propionate
FL/FR
geranyl valerate
FL/FR
methyl 2-hexenoate
FL/FR
2-
methyl-3-ethoxypyrazine
FL/FR
iso
propyl 3-methyl thiocrotonate
FL/FR
iso
propyl hexanoate
FL/FR
iso
propyl isobutyrate
FL/FR
iso
propyl thioisovalerate
FL/FR
propyl valerate
FL/FR
(E,E)-
sorbyl isobutyrate
FL/FR
2-
tropical oxathiane
FL/FR
sorbyl isobutyrate
FL/FR
fatty
fatty
allyl octanoate
FL/FR
fruity
allyl cyclohexyl acetate
FL/FR
allyl decanoate
FL/FR
allyl heptanoate
FL/FR
iso
butyl hexanoate
FL/FR
butyl valerate
FL/FR
ethyl 3-(2-furyl) propanoate
FL/FR
ethyl 3-hexenoate
FL/FR
ethyl butyrate
FL/FR
ethyl heptanoate
FL/FR
ethyl hexanoate
FL/FR
methyl hexanoate
FL/FR
methyl isovalerate
FL/FR
green
cis-
galbanum oxathiane
FL/FR
3-
hexenyl 2-methyl butyrate
FL/FR
sulfurous
ethyl methyl mercaptopropionate
FL/FR
tropical 3-thiobutyrate
FL/FR
tropical
propyl propionate
FL/FR
waxy
ethyl octanoate
FL/FR
heptanoic acid
FL/FR
 
Potential Uses:
FRgreen
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
4-penten-1-one, 1-spiro[4.5]dec-7-en-7-yl-
1-spiro(4.5)-6-decen-7-yl-4-penten-1-one and 1-spiro(4.5)-7-decen-7-yl-4-penten-1-one
1-spiro(4.5)-7-decen-7-yl-4-penten-1-one and 1-spiro(4.5)-6-decen-7-yl-4-penten-1-one
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one
 

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