EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

amber dodecane
madrox (Givaudan)

Sponsors

Fragrance Demo Formulas
Name:1-methoxy-1-methylcyclododecane
CAS Number: 37514-30-0Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:253-534-3
Nikkaji Web:J182.743J
Beilstein Number:2238172
XlogP3-AA:5.30 (est)
Molecular Weight:212.37636000
Formula:C14 H28 O
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
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Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.92100 @ 25.00 °C.
Refractive Index:1.48000 @ 20.00 °C.
Boiling Point: 248.00 to 249.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.008000 mm/Hg @ 20.00 °C.
Flash Point:> 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w): 5.537 (est)
Soluble in:
 alcohol
 water, 0.4763 mg/L @ 25 °C (est)
Stability:
 alcoholic - good
 antiperspirant spray - moderate
 APC (pH = 10) - good
 candles - untested
 damp fabric - moderate
 dry fabric - moderate
 liquid bleach - poor
 pH = 2 - moderate
 powder detergent - good
 powder detergent + activator - moderate
 soap - good
 toiletries - good
Similar Items:note
methyl cyclododecyl ether
 
Organoleptic Properties:
Odor Type: woody
Odor Strength:medium
Substantivity:28 hour(s) at 100.00 %
woody celery musk ambergris woody old wood
Odor Description:at 100.00 %. woody celery musk ambergris old wood
Luebke, William tgsc, (1986)
Odor sample from: Givaudan Corporation
Odor and/or flavor descriptions from others (if found).
Givaudan
Madrox®
Odor Description:Woody, Tobacco, Ambery, Warm
Madrox is extremely useful in woody fougère and chypre type compositions, where it imparts an interesting ambergris note. Used as a main constituent, it blends the top notes and strengthens the body of a fragrance.
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
BOC Sciences
For experimental / research use only.
1-Methoxy-1-methylcyclododecane
CG Herbals
Madrox
Odor: Woody, Tobacco, Ambery, Warm
Use: Madrox is extremely useful in woody fougere and chypre type compositions, where it imparts an interesting ambergris note. Used as a main constituent, it blends the top notes and strengthens the body of a fragrance.
Givaudan
Madrox®
Odor: Woody, Tobacco, Ambery, Warm
Use: Madrox is extremely useful in woody fougère and chypre type compositions, where it imparts an interesting ambergris note. Used as a main constituent, it blends the top notes and strengthens the body of a fragrance.
Indukern F&F
MADROX
Penta International
1-METHYLCYCLODODECYL METHYL ETHER
 
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 81S, 1992.

Dermal Toxicity:
skin-rabbit LDLo 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 81S, 1992.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for amber dodecane usage levels up to:
  10.0000 % in the fragrance concentrate.
 
Recommendation for amber dodecane flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):37514-30-0
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :161949
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
1-methoxy-1-methylcyclododecane
Chemidplus:0037514300
 
References:
 1-methoxy-1-methylcyclododecane
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:37514-30-0
Pubchem (cid):161949
Pubchem (sid):135117566
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
amber romance fragrance
FR
(Z)-iso
ambrettolide
FR
aldehydic
aldehydic
dodecanal (aldehyde C-12 lauric)
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
amber
acetoxymethyl isolongifolene
FR
amber acetate
FR
amber butanol
FR
amber cyclohexanol
FR
amber decane
FR
amber furan
FR
amber naphthofuran
FL/FR
ambergris naphthol
FR
ambergris specialty
FR
ambrein
FR
ambrette seed absolute
FL/FR
ambrette seed oil CO2 extract
FL/FR
ambrette seed oil replacer
FR
ambroxan
FL/FR
ambroxide
FL/FR
angelica root oil
FL/FR
cistus ladaniferus resin
FR
cistus ladaniferus resinoid
FR
formoxymethyl isolongifolene
FR
(cis+trans)-6,6a,7,8,9,9a-
hexahydro-7,7,8,9,9-pentamethyl-5H-cyclopenta[H]quinazoline
FR
hydroxymethyl isolongifolene 50% in dpg
FR
labdanum absolute
FL/FR
labdanum gum extract ethyl ester
FR
labdanum oil
FL/FR
muscomer
FR
animal
ambergris tincture replacer
FR
animal carbolactone
FR
animal specialty
FR
costus valerolactone
FR
indole
FL/FR
2-
methyl-4-(camphenyl-8) cyclohexanone
FR
anisic
ambrette seed oil
FL/FR
balsamic
amyris wood oil
FL/FR
siam
benzoin resinoid
FL/FR
cistus leaf oil
FR
myrrh resin
FL/FR
opoponax absolute (commiphora erythraea var. glabrescens engle)
FL/FR
opoponax resinoid (commiphora erythraea var. glabrescens engle)
FR
styrax oil (liquidambar styraciflua)
FL/FR
styrax resinoid (liquidambar styraciflua)
FL/FR
berry
raspberry ketone
FL/FR
camphoreous
verbenone
FL/FR
caramellic
ethyl maltol
FL/FR
fenugreek absolute
FL/FR
immortelle absolute
FL/FR
maltol
FL/FR
coconut
gamma-
nonalactone (aldehyde C-18 (so-called))
FL/FR
gamma-
octalactone
FL/FR
fatty
decanol
FL/FR
floral
acetophenone
FL/FR
iso
amyl salicylate
FL/FR
bois de rose oil brazil
FL/FR
boronia butenal
FR
iso
butyl salicylate
FL/FR
cyclamen aldehyde
FL/FR
dihydrojasmone
FL/FR
floral pyranol
FR
heliotropyl acetone
FL/FR
hexahydrofarnesyl acetone
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
iso
jasmone
FL/FR
(Z)-
jasmone
FL/FR
lilyall
FR
laevo-
linalool
FL/FR
methyl dihydrojasmonate
FL/FR
beta-iso
methyl ionone
FL/FR
nerolidol
FL/FR
nonanol
FL/FR
ocean propanal
FL/FR
2-
pentadecanone
FL/FR
phenethyl phenyl acetate
FL/FR
fruity
cyclohexanone diethyl acetal
FL/FR
gamma-
decalactone
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
valeriana officinalis root extract
FL/FR
green
iso
butyl benzyl carbinol
FL/FR
diphenyl oxide
FL/FR
galbanum oil
FL/FR
methyl heptine carbonate
FL/FR
(E,Z)-2,6-
nonadien-1-ol
FL/FR
violet leaf absolute
FL/FR
hay
beeswax absolute
FL/FR
hay absolute
FR
herbal
apium graveolens seed oil india
FL/FR
3-
butyl phthalide
FL/FR
3-
butylidene phthalide
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
celery ketone
FL/FR
celery leaf oil
FL/FR
celery seed oil CO2 extract
FL/FR
celery undecene
FR
daucus carota fruit oil
FL/FR
levisticum officinale herb oil
FL/FR
levisticum officinale root absolute
FL/FR
curled
parsley seed oil
FL/FR
3-
propylidene phthalide
FL/FR
melon
melon heptenal
FL/FR
(Z)-6-
nonenal
FL/FR
watermelon ketone
FR
mossy
veramoss (IFF)
FR
musk
musk dimethyl indane
FL/FR
musk indane
FR
musk lactone
FR
musk methyl ketone
FR
6,7,8,9-
tetrahydro-7,7,8,9,9-pentamethyl-5H-cyclopenta[H]quinazoline
FR
spicy
iso
butyl angelate
FL/FR
cassia bark oil china
FL/FR
black
currant bud absolute
FL/FR
N,N-
diethyl octanamide
FR
iso
eugenyl acetate
FL/FR
levisticum officinale root oil
FL/FR
machilus kusanoi wood oil
FR
terpenic
angelica seed oil
FL/FR
frankincense oil
FL/FR
tonka
saffron resinoid
FL/FR
tonka bean absolute
FR
tonka undecanone
FR
whiskey lactone
FL/FR
vanilla
propenyl guaethol
FL/FR
waxy
1-
dodecanol
FL/FR
ethyl laurate
FL/FR
woody
acetyl cedrene
FR
amber carbinol
FR
amber decatriene
FR
amber dioxane
FR
amber formate
FR
amber pentadecane
FR
ambrene acetal
FR
atlas
cedarwood absolute
FR
atlas
cedarwood oil
FR
alpha-
cedrene epoxide
FR
cedryl methyl ether
FR
cistus ladaniferus gum
FR
cistus twig/leaf absolute
FR
cistus twig/leaf oil
FL/FR
frankincense resinoid
FL/FR
guaiacwood oil
FL/FR
gurjun balsam oil
FR
hydroxyambran
FR
incense specialty
FR
labdanum concrete
FR
iso
longifolene ketone
FR
2-
methoxy-4-vinyl phenol
FL/FR
methyl 2,6,10-trimethyl cyclododeca-2,5,9-trienyl ketone
FR
methyl cedryl ketone
FL/FR
patchouli ethanone
FR
patchouli oil
FL/FR
sandal pentenol
FL/FR
santall
FR
sclareolide
FL/FR
spruce needle oil canada
FL/FR
timber propanol
FR
tobacarol (IFF)
FR
tobacco nonene
FR
verdoxan
FR
woody acetate
FR
woody cyclohexanone
FR
woody dioxolane
FR
woody dodecane
FR
woody ether
FR
woody nonane (ethoxy)
FR
For Flavor
No flavor group found for these
ambrette seed oil
FL/FR
ambroxide
FL/FR
3-
butyl phthalide
FL/FR
cistus twig/leaf oil
FL/FR
cyclohexanone diethyl acetal
FL/FR
beta-iso
methyl ionone
FL/FR
sandal pentenol
FL/FR
verbenone
FL/FR
amber
amber
amber naphthofuran
FL/FR
ambrette seed oil CO2 extract
FL/FR
angelica seed oil
FL/FR
iso
butyl benzyl carbinol
FL/FR
labdanum absolute
FL/FR
labdanum oil
FL/FR
animal
indole
FL/FR
apple
(E,Z)-2,6-
nonadien-1-ol
FL/FR
balsamic
siam
benzoin resinoid
FL/FR
myrrh resin
FL/FR
opoponax absolute (commiphora erythraea var. glabrescens engle)
FL/FR
styrax oil (liquidambar styraciflua)
FL/FR
styrax resinoid (liquidambar styraciflua)
FL/FR
berry
heliotropyl acetone
FL/FR
raspberry ketone
FL/FR
brown
beeswax absolute
FL/FR
caramellic
ethyl maltol
FL/FR
fenugreek absolute
FL/FR
maltol
FL/FR
celery
3-
butylidene phthalide
FL/FR
citrus
laevo-
linalool
FL/FR
coconut
gamma-
nonalactone (aldehyde C-18 (so-called))
FL/FR
cooling
iso
butyl salicylate
FL/FR
creamy
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
fatty
2-
pentadecanone
FL/FR
10-
undecenal (aldehyde C-11 undecylenic)
FL/FR
floral
bois de rose oil brazil
FL/FR
dihydrojasmone
FL/FR
methyl dihydrojasmonate
FL/FR
ocean propanal
FL/FR
fruity
gamma-
decalactone
FL/FR
valeriana officinalis root extract
FL/FR
green
iso
amyl salicylate
FL/FR
angelica root oil
FL/FR
iso
butyl angelate
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
celery ketone
FL/FR
cyclamen aldehyde
FL/FR
diphenyl oxide
FL/FR
galbanum oil
FL/FR
hexahydrofarnesyl acetone
FL/FR
immortelle absolute
FL/FR
iso
jasmone
FL/FR
melon heptenal
FL/FR
methyl heptine carbonate
FL/FR
nerolidol
FL/FR
(Z)-6-
nonenal
FL/FR
3-
propylidene phthalide
FL/FR
violet leaf absolute
FL/FR
herbal
apium graveolens seed oil india
FL/FR
celery leaf oil
FL/FR
celery seed oil CO2 extract
FL/FR
daucus carota fruit oil
FL/FR
curled
parsley seed oil
FL/FR
honey
phenethyl phenyl acetate
FL/FR
lactonic
gamma-
octalactone
FL/FR
musk
musk dimethyl indane
FL/FR
powdery
acetophenone
FL/FR
smoky
2-
methoxy-4-vinyl phenol
FL/FR
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
1-
dodecanol
FL/FR
spicy
cassia bark oil china
FL/FR
black
currant bud absolute
FL/FR
iso
eugenyl acetate
FL/FR
levisticum officinale herb oil
FL/FR
levisticum officinale root absolute
FL/FR
levisticum officinale root oil
FL/FR
sweet
saffron resinoid
FL/FR
vanilla
propenyl guaethol
FL/FR
waxy
decanol
FL/FR
ethyl laurate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
2-
methyl undecanal (aldehyde C-12 mna)
FL/FR
nonanol
FL/FR
woody
ambrette seed absolute
FL/FR
ambroxan
FL/FR
amyris wood oil
FL/FR
frankincense oil
FL/FR
frankincense resinoid
FL/FR
guaiacwood oil
FL/FR
(Z)-
jasmone
FL/FR
methyl cedryl ketone
FL/FR
patchouli oil
FL/FR
sclareolide
FL/FR
spruce needle oil canada
FL/FR
whiskey lactone
FL/FR
 
Potential Uses:
FRamber
FRambergris
FRfern
FRlabdanum
FRmoss
FRmusk
FRtobacco
FRwoody
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 amber dodecane
 cyclododecane, 1-methoxy-1-methyl-
 madrox (Givaudan)
1-methoxy-1-methyl cyclododecane
1-methoxy-1-methylcyclododecane
 methyl 1-methylcyclododecyl ether
1-methyl cyclododecyl methyl ether
1-methyl-1-methoxycyclododecane
1-methylcyclododecyl methyl ether
 

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