EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

cinnamyl benzoate
3-phenyl-2-propenyl benzoate

Sponsors

Name:3-phenylprop-2-enyl benzoate
CAS Number: 5320-75-2Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:226-180-2
Nikkaji Web:J89.936D
MDL:MFCD00475021
CoE Number:743
XlogP3:4.60 (est)
Molecular Weight:238.28598000
Formula:C16 H14 O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome or firefox)
Also(can) Contains:(E)-cinnamyl benzoate
 (Z)-cinnamyl benzoate
EFSA/JECFA Comments:
Mixture of (Z)- and (E)- isomers (EFFA, 2010a). Composition of stereoisomeric mixture to be specified.
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:760 cinnamyl benzoate
FLAVIS Number:09.780 (Old)
DG SANTE Food Flavourings:09.780 cinnamyl benzoate
FEMA Number:4703 cinnamyl benzoate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: CINNAMYL BENZOATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
 
Physical Properties:
Appearance:white crystalline powder (est)
Assay: 98.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Melting Point: 31.00 to 33.00 °C. @ 760.00 mm Hg
Boiling Point: 209.00 °C. @ 13.00 mm Hg
Boiling Point: 335.00 °C. @ 760.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.000040 mm/Hg @ 25.00 °C.
Flash Point: 348.00 °F. TCC ( 175.56 °C. )
logP (o/w): 4.420 (est)
Soluble in:
 alcohol
 water, 5.8 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: balsamic
Odor Strength:medium
balsamic spicy buttery fruity
Odor Description:at 100.00 %. balsam spicy buttery fruity
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Beijing Lys Chemicals
Cinnamyl benzoate
BOC Sciences
For experimental / research use only.
Cinnamyl Benzoate
Fleurchem
cinnamyl benzoate natural
Inoue Perfumery
CINNAMYL BENZOATE
M&U International
NAT. CINNAMYL BENZOATE
Penta International
CINNAMYL BENZOATE, Kosher
Sigma-Aldrich
Cinnamyl benzoate, ≥98%, FG
Certified Food Grade Products
Synerzine
Cinnamyl Benzoate
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
5 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50 4000 mg/kg
Food and Cosmetics Toxicology. Vol. 14, Pg. 717, 1976.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
maximum skin levels for fine fragrances:
  0.1000 % and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey). (IFRA, 2001)
Recommendation for cinnamyl benzoate usage levels up to:
  3.0000 % in the fragrance concentrate.
use level in formulae for use in cosmetics:
  0.5000 %
Dermal Systemic Exposure in Cosmetic Products:
 0.0127 mg/kg/day (IFRA, 2001)
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 1.20 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 1.00 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 25
 average usual ppmaverage maximum ppm
baked goods: 15.2000024.30000
beverages(nonalcoholic): 3.630007.13000
beverages(alcoholic): 2.000004.00000
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: 5.0000010.00000
fruit ices: --
gelatins / puddings: 10.0000020.00000
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: 2.000005.00000
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 9.0000018.00000
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 214: alpha,beta-Unsaturated aldehydes and precursors from chemical subgroup 3.1 of FGE.19: Cinnamyl derivatives[1]
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 68 (FGE.68): Consideration of cinnamyl alcohol and related flavouring agents evaluated by JECFA (55th meeting) evaluated by EFSA in FGE.15Rev1 (2008)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 96 (FGE.96): Consideration of 88 flavouring substances considered by EFSA for which EU production volumes / anticipated production volumes have been submitted on request by DG SANCO. Addendum to FGE. 51, 52, 53, 54, 56, 58, 61, 62, 63, 64, 68, 69, 70, 71, 73, 76, 77, 79, 80, 83, 84, 85 and 87.
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):5320-75-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :316771
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
3-phenylprop-2-enyl benzoate
Chemidplus:0005320752
 
References:
 3-phenylprop-2-enyl benzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:5320-75-2
Pubchem (cid):316771
Pubchem (sid):136172
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB29700
FooDB:FDB000890
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
cinnamyl valerate
FL/FR
amber
amber
labdanum oil
FL/FR
balsamic
artemisia annua herb oil bulgaria
FL/FR
sumatra
benzoin absolute
FL/FR
sumatra
benzoin resinoid
FL/FR
alpha-
bisabolene
FL/FR
butyl benzoate
FL/FR
iso
butyl cinnamate
FL/FR
cinnamyl alcohol
FL/FR
cinnamyl butyrate
FL/FR
(E)-
cinnamyl butyrate
FL/FR
cinnamyl cinnamate
FL/FR
cinnamyl formate
FL/FR
copaiba balsam oil
FL/FR
ethyl cinnamate
FL/FR
frankincense absolute
FL/FR
(Z)-3-
hexen-1-yl cinnamate
FR
hexyl cinnamate
FR
linalyl cinnamate
FL/FR
myrrh oil CO2 extract
FL/FR
myrrh resinoid
FR
octyl benzoate
FR
octyl cinnamate
FR
opoponax oil (balsamodendron kafal)
FL/FR
opoponax oil (commiphora erythraea var. glabrescens engle)
FL/FR
opoponax resinoid (balsamodendron kafal)
FR
peru balsam oil
FL/FR
peru balsam resinoid
FL/FR
2-
phenoxyethyl formate
FR
3-
phenyl propyl acetate
FL/FR
3-
phenyl propyl cinnamate
FL/FR
phenyl salicylate
FR
black
poplar bud oleoresin
FL/FR
prenyl benzoate
FL/FR
propyl cinnamate
FL/FR
terpinyl butyrate
FL/FR
tetrahydrofurfuryl cinnamate
FL/FR
tolu balsam oil
FL/FR
buttery
acetyl isobutyryl
FL/FR
apple butter fragrance
FR
iso
butyl lactate
FL/FR
caramellic
alpha,alpha-
dimethyl anisyl acetone
FL/FR
mesitene lactone
FR
cheesy
butyric acid
FL/FR
creamy
2,3-
butane diol
FR
earthy
pinus sylvestris leaf absolute
FL/FR
fatty
butyl undecylenate
FL/FR
floral
alpha-
amyl cinnamyl acetate
FL/FR
benzyl acetone
FL/FR
benzyl lactate
FL/FR
cinnamyl phenyl acetate
FL/FR
fruity
1-
acetoxyacetone
FL/FR
cinnamyl hexanoate
FL/FR
cinnamyl isobutyrate
FL/FR
ethyl lactate
FL/FR
2-
methyl butyl butyrate
FL/FR
3-
phenyl propyl isobutyrate
FL/FR
prenyl isobutyrate
FL/FR
strawberry furanone butyrate
FL/FR
xanthoxylum fruit oil
FR
minty
ethyl salicylate
FL/FR
spicy
alpha-
amyl cinnamyl alcohol
FL/FR
amyl isoeugenol
FR
bay leaf oil terpeneless
FL/FR
benzyl isoeugenol
FL/FR
(Z)-
cinnamyl acetate
FL/FR
cinnamyl acetate
FL/FR
cinnamyl isovalerate
FL/FR
cinnamyl propionate
FL/FR
clove bud oleoresin
FL/FR
eugenyl benzoate
FL/FR
mace oil CO2 extract
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
myrcene
FR
nutmeg absolute
FL/FR
nutmeg oil CO2 extract
FL/FR
(E)-
propyl 2-furan acrylate
FL/FR
spicy acetoacetate
FL/FR
annus
wormwood oil vietnam
FL/FR
terpenic
cypress leaf oil
FR
tonka
dihydrocoumarin replacer
FR
tonka undecanone
FR
woody
agarwood specialty
FR
bruyere root absolute
FR
cinnamyl tiglate
FL/FR
guaiacwood oil 20% in gurjun balsam oil
FR
kaempferia galanga rhizome oil
FL/FR
santalyl butyrate
FL/FR
woody octene
FR
For Flavor
No flavor group found for these
1-
acetoxyacetone
FL/FR
artemisia annua herb oil bulgaria
FL/FR
benzyl lactate
FL/FR
alpha-
bisabolene
FL/FR
butyl benzoate
FL/FR
(Z)-
cinnamyl acetate
FL/FR
(E)-
cinnamyl butyrate
FL/FR
cinnamyl hexanoate
FL/FR
cinnamyl phenyl acetate
FL/FR
cinnamyl tiglate
FL/FR
cinnamyl valerate
FL/FR
alpha,alpha-
dimethyl anisyl acetone
FL/FR
ethyl butyryl lactate
FL
eugenyl benzoate
FL/FR
methyl furfuracrylate
FL
pinus sylvestris leaf absolute
FL/FR
black
poplar bud oleoresin
FL/FR
prenyl benzoate
FL/FR
prenyl isobutyrate
FL/FR
santalyl butyrate
FL/FR
terpinyl butyrate
FL/FR
tetrahydrofurfuryl cinnamate
FL/FR
amber
amber
labdanum oil
FL/FR
balsamic
sumatra
benzoin resinoid
FL/FR
iso
butyl cinnamate
FL/FR
copaiba balsam oil
FL/FR
ethyl cinnamate
FL/FR
myrrh oil CO2 extract
FL/FR
opoponax oil (balsamodendron kafal)
FL/FR
opoponax oil (commiphora erythraea var. glabrescens engle)
FL/FR
peru balsam oil
FL/FR
peru balsam resinoid
FL/FR
3-
phenyl propyl acetate
FL/FR
tolu balsam oil
FL/FR
buttery
iso
butyl lactate
FL/FR
camphoreous
kaempferia galanga rhizome oil
FL/FR
caramellic
3-
methyl butyl 2-furyl butyrate
FL
creamy
acetyl isobutyryl
FL/FR
earthy
alpha-
amyl cinnamyl acetate
FL/FR
fatty
2,4-
undecadienal
FL
floral
cinnamyl propionate
FL/FR
fruity
benzyl acetone
FL/FR
cinnamyl isobutyrate
FL/FR
cinnamyl isovalerate
FL/FR
ethyl lactate
FL/FR
linalyl cinnamate
FL/FR
2-
methyl butyl butyrate
FL/FR
3-
phenyl propyl isobutyrate
FL/FR
(E)-
propyl 2-furan acrylate
FL/FR
propyl cinnamate
FL/FR
strawberry furanone butyrate
FL/FR
green
cinnamyl alcohol
FL/FR
medicinal
frankincense absolute
FL/FR
minty
ethyl salicylate
FL/FR
nutty
furfural acetone
FL
sour
butyric acid
FL/FR
spicy
alpha-
amyl cinnamyl alcohol
FL/FR
bay leaf oil terpeneless
FL/FR
sumatra
benzoin absolute
FL/FR
benzyl isoeugenol
FL/FR
cinnamyl acetate
FL/FR
cinnamyl cinnamate
FL/FR
cinnamyl formate
FL/FR
clove bud oleoresin
FL/FR
galangal root oleoresin
FL
mace oil CO2 extract
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
nutmeg absolute
FL/FR
nutmeg oil CO2 extract
FL/FR
3-
phenyl propyl cinnamate
FL/FR
spicy acetoacetate
FL/FR
annus
wormwood oil vietnam
FL/FR
waxy
butyl undecylenate
FL/FR
winey
cinnamyl butyrate
FL/FR
 
Potential Uses:
FRbalsam
 fixer
FRjasmin
FRoriental
FRrose
FRsandalwood
 
Occurrence (nature, food, other):note
 benzoin siam
Search PMC Picture
 champaca concrete @ 0.05%
Data GC Search Trop Picture
 
Synonyms:
 benzoic acid cinnamyl ester
 benzoic acid, cinnamyl ester
 cinnamyl alcohol benzoate
 cinnamyl alcohol, benzoate
 cinnamyl benzoate natural
3-phenyl allyl benzoate
3-phenyl-2-propen-1-ol benzoate
3-phenyl-2-propen-1-yl benzoate
3-phenyl-2-propenyl benzoate
3-phenylprop-2-enyl benzoate
2-propen-1-ol, 3-phenyl-, benzoate
 
 
Notes:
Flavouring ingredient Used as a food additive [EAFUS]
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