EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

mesityl oxide
4-methyl-3-penten-2-one

Sponsors

Name:4-methylpent-3-en-2-one
CAS Number: 141-79-7Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:205-502-5
FDA UNII:77LAC84669
Nikkaji Web:J2.540B
Beilstein Number:1361550
MDL:MFCD00008900
CoE Number:11853
XlogP3-AA:1.40 (est)
Molecular Weight:98.14490000
Formula:C6 H10 O
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:1131 4-methyl-3-penten-2-one
FLAVIS Number:07.101 (Old)
DG SANTE Food Flavourings:07.101 4-methylpent-3-en-2-one
FEMA Number:3368 4-methyl-3-penten-2-one
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: 4-METHYL-3-PENTEN-2-ONE
 
Physical Properties:
Appearance:colorless to yellow oily liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.86200 to 0.86800 @ 25.00 °C.
Pounds per Gallon - (est).: 7.173 to 7.223
Refractive Index:1.44200 to 1.44700 @ 20.00 °C.
Melting Point: -53.00 °C. @ 760.00 mm Hg
Boiling Point: 126.76 °C. @ 760.00 mm Hg
Boiling Point: 41.00 °C. @ 23.00 mm Hg
Vapor Pressure:8.757000 mm/Hg @ 25.00 °C. (est)
Flash Point: 87.00 °F. TCC ( 30.56 °C. )
logP (o/w): 1.069 (est)
Soluble in:
 alcohol
 dipropylene glycol
 propylene glycol
 water, 28900 mg/L @ 20 °C (exp)
 
Organoleptic Properties:
Odor Type: vegetable
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
pungent earthy vegetable acrylate
Odor Description:at 10.00 % in propylene glycol. pungent earthy vegetable acrylic
musty earthy chemical nutty chocolate woody
Odor Description:at 1.00 %. musty, mildew, earthy, chemical, card board like with nutty, chocolate and woody nuances
Mosciano, Gerard, (2009)
Flavor Type: potato
potato raw potato baked potato raw vegetable nutty dirty
Taste Description: at 3.00 ppm. potato bin, raw and baked potato, jimica with raw vegetative, nutty and dirt like nuances
Mosciano, Gerard, (2009)
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Arkema
Mesityl Oxide
Odor: characteristic
Use: Mesityl oxide (MO) is a a-unsaturated ketone. It is mainly used in fine chemistry in the synthesis of vitamins, flavour and fragrances.
Penta International
MESITYL OXIDE NATURAL, Kosher
Penta International
MESITYL OXIDE, Kosher, Halal
Santa Cruz Biotechnology
For experimental / research use only.
Mesityl Oxide ≥89%
Sigma-Aldrich
4-Methyl-3-penten-2-one, ≥90%
Odor: vegetable; vanilla
Certified Food Grade Products
TCI AMERICA
For experimental / research use only.
4-Methyl-3-penten-2-one >95.0%(GC)
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 10 - Flammable.
R 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
S 01/02 - Keep locked up and out of the reach of children.
S 16 - Keep away from sources of ignition - No Smoking.
S 20/21 - When using do not eat, drink or smoke.
S 23 - Do not breath vapour.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rabbit LD50 1000 mg/kg
"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 6, Pg. 896, 1991.

oral-mouse LD50 710 mg/kg
"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 80, 1982.

intraperitoneal-mouse LD50 354 mg/kg
Shell Chemical Company. Unpublished Report. Vol. -, Pg. 6, 1961.

oral-mammal (species unspecified) LD50 710 mg/kg
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974.

oral-rat LD50 1120 mg/kg
"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 6, Pg. 896, 1991.

Dermal Toxicity:
subcutaneous-frog LDLo 1400 mg/kg
Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 56, Pg. 346, 1906.

skin-rabbit LD50 5150 mg/kg
Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 71, 1974.

subcutaneous-rabbit LDLo 840 mg/kg
Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 56, Pg. 346, 1906.

Inhalation Toxicity:
inhalation-mouse LC50 10000 mg/m3/2H
"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 80, 1982.

inhalation-guinea pig LCLo 500 ppm/8H
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Journal of Industrial Hygiene and Toxicology. Vol. 24, Pg. 46, 1942.

inhalation-human TCLo 25 ppm
SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE
Journal of Industrial Hygiene and Toxicology. Vol. 28, Pg. 262, 1946.

inhalation-rat LC50 9000 mg/m3/4H
"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 80, 1982.

 
Safety in Use Information:
Category: flavor and fragrance agents
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.34 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): ND (μg/capita/day)
Threshold of Concern:540 (μg/person/day)
Structure Class: II
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 6
 average usual ppmaverage maximum ppm
baked goods: -2.25000
beverages(nonalcoholic): --
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -0.75000
fruit ices: -0.75000
gelatins / puddings: -0.50000
granulated sugar: --
gravies: --
hard candy: -1.12000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: -0.40000
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 0.400000.40000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): --
Edible ices, including sherbet and sorbet (03.0): 0.750000.75000
Processed fruit (04.1): --
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 1.120001.12000
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): --
Bakery wares (07.0): 2.250002.25000
Meat and meat products, including poultry and game (08.0): --
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): --
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 0.500000.50000
Foodstuffs intended for particular nutritional uses (13.0): 0.500000.50000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): --
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): --
Ready-to-eat savouries (15.0): --
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

List of apha, beta-Unsaturated Aldehydes and Ketones representative of FGE.19 substances for Genotoxicity Testing [1] - Statement of the Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 204 (FGE.204): Consideration of genotoxicity data on representatives for 18 mono-unsaturated, aliphatic, a,-unsaturated ketones and precursors from chemical subgroup 1.2.1 of FGE.19 by EFSA
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 63, Revision 2 (FGE.63Rev2): Consideration of aliphatic secondary alcohols, ketones and related esters evaluated by JECFA (59th and 69th meetings) structurally related to saturated and unsaturated aliphatic secondary alcohols, ketones and esters of secondary alcohols and saturated linear or branched-chain carboxylic acids evaluated by EFSA in FGE.07Rev4
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 63, Revision 3 (FGE.63Rev3): aliphatic secondary alcohols, ketones and related esters evaluated by JECFA (59th and 69th meetings) structurally related to saturated and unsaturated aliphatic secondary alcohols, ketones and esters of secondary alcohols and saturated linear or branched-chain carboxylic acids evaluated by EFSA in FGE.07Rev4
View page or View pdf

EPI System: View
NIOSH International Chemical Safety Cards:search
NIOSH Pocket Guide:search
NLM Hazardous Substances Data Bank:Search
Cancer Citations:Search
Env. Mutagen Info. Center:Search
NLM Developmental and Reproductive Toxicity:Search
EPA Substance Registry Services (TSCA):141-79-7
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :8858
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 1229
WGK Germany:1
4-methylpent-3-en-2-one
Chemidplus:0000141797
EPA/NOAA CAMEO:hazardous materials
RTECS:141-79-7
 
References:
 4-methylpent-3-en-2-one
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:141-79-7
Pubchem (cid):8858
Pubchem (sid):134975574
Flavornet:141-79-7
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB31563
FooDB:FDB008178
Export Tariff Code:2914.19.0000
Haz-Map:View
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
Wikipedia:View
RSC Learn Chemistry:View
Formulations/Preparations:
•grade: technical •grades of purity: 97+%
 
Potential Blenders and core components note
For Odor
No odor group found for these
octanal propylene glycol acetal
FL/FR
balsamic
balsamic
betula pubescens bud oil
FL/FR
spruce needle absolute
FL/FR
valerian rhizome absolute
FL/FR
caramellic
iso
propenyl pyrazine
FL/FR
chocolate
2-
methyl butyraldehyde
FL/FR
citrus
alpha-
methylene citronellal
FR
neroli ketone
FR
earthy
bean pyrazine
FL/FR
floral
karo karounde absolute
FR
linalool
FL/FR
beta-
ocimene
FL/FR
orange leaf absolute
FL/FR
fruity
apple ketal
FL/FR
green acetate
FR
tropical thiazole
FL/FR
green
bergoxane
FR
2-sec-
butyl-3-methoxypyrazine
FL/FR
alpha-
elemol
FL/FR
fresh nitrile
FR
galbanum oil
FL/FR
galbanum oleoresin
FL/FR
galbanum resinoid
FL/FR
geranium thiazole
FL/FR
(Z)-4-
heptenal
FL/FR
(Z)-3-
hexen-1-yl (E)-crotonate
FL/FR
(E)-2-
hexen-1-yl salicylate
FR
4-
hexenol
FL/FR
para-
methyl hydratropaldehyde
FL/FR
2-
octen-1-ol
FL/FR
1-
penten-3-ol
FL/FR
terpinyl propionate
FL/FR
valerian rhizome oil CO2 extract china
FL/FR
herbal
bornyl salicylate
FR
(+)-alpha-
campholenic aldehyde
FL/FR
canarium luzonicum oil
FL/FR
iso
dihydrolavandulal
FL/FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
nonisyl formate
FR
3-
octyl acetate
FL/FR
tricyclo(5.2.1.02,6)dec-3-enyl acetate
FR
valerian rhizome oil
FL/FR
valerian rhizome oil china
FL/FR
wormwood oil america
FL/FR
melon
(Z)-6-
nonen-1-ol
FL/FR
(Z)-6-
nonenal
FL/FR
minty
iso
propyl tiglate
FL/FR
(-)-iso
pulegol
FL/FR
mossy
oakmoss absolute
FL/FR
musty
3-
acetyl-2,5-dimethyl furan
FL/FR
hazelnut pyrazine
FL/FR
menthofuran
FL/FR
nutty
2-
acetyl-3-ethyl pyrazine
FL/FR
4,5-
dimethyl-2-ethyl-3-thiazoline
FL/FR
orris
iso
eugenyl formate
FL/FR
spicy
iso
cyclogeraniol (IFF)
FR
2-
octanol
FL/FR
sulfurous
grapefruit menthane
FL/FR
3-(
methyl thio) hexanol
FL/FR
waxy
2-
tridecanone
FL/FR
For Flavor
No flavor group found for these
(E)-
aconitic acid
FL
bean pyrazine
FL/FR
betula pubescens bud oil
FL/FR
6,7-
dimethyl dihydrocyclopentapyrazine
FL
dimethyl dihydrocyclopentapyrazine
FL
alpha-
elemol
FL/FR
2-
ethyl-4,5-dimethyl oxazole
FL
iso
eugenyl formate
FL/FR
(Z)-3-
hexen-1-yl (E)-crotonate
FL/FR
(E)-4-
hexenal
FL
iso
mesityl oxide
FL
2-
methyl thiazole
FL
4-(
methyl thio) butanol
FL
octanal propylene glycol acetal
FL/FR
2-iso
propyl-3-(methyl thio) pyrazine
FL
alliaceous
alliaceous
3-
tetrahydrothiophenone
FL
tropical thiazole
FL/FR
balsamic
spruce needle absolute
FL/FR
bitter
cocoa pyrazines base (mixture of pyrazines)
FL
burnt
iso
propenyl pyrazine
FL/FR
camphoreous
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
citrus
linalool
FL/FR
cocoa
cocoa distillates
FL
coffee
difurfuryl ether
FL
fatty
2-
octen-1-ol
FL/FR
2-
tridecanone
FL/FR
floral
orange leaf absolute
FL/FR
fruity
apple ketal
FL/FR
valerian rhizome absolute
FL/FR
valerian rhizome oil
FL/FR
valerian rhizome oil china
FL/FR
valerian rhizome oil CO2 extract china
FL/FR
fusel
2-
methyl butyraldehyde
FL/FR
green
(+)-alpha-
campholenic aldehyde
FL/FR
canarium luzonicum oil
FL/FR
dihydroxyacetophenone (mixed isomers)
FL
galbanum oil
FL/FR
galbanum oleoresin
FL/FR
galbanum resinoid
FL/FR
geranium thiazole
FL/FR
(Z)-4-
heptenal
FL/FR
(E)-2-
heptenal
FL
2-
hexyl pyridine
FL
para-
methyl hydratropaldehyde
FL/FR
3-(5-
methyl-2-furyl) butanal
FL
2-
methyl-5-isopropyl pyrazine
FL
(Z)-6-
nonenal
FL/FR
oakmoss absolute
FL/FR
beta-
ocimene
FL/FR
2,4-
octadienal
FL
3-
octyl acetate
FL/FR
4-
penten-1-yl acetate
FL
1-
penten-3-ol
FL/FR
2-
propyl pyrazine
FL
iso
propyl tiglate
FL/FR
propylene glycol acetone ketal
FL
terpinyl propionate
FL/FR
herbal
iso
dihydrolavandulal
FL/FR
wormwood oil america
FL/FR
meaty
2,6-
dimethyl thiophenol
FL
metallic
4-
hexenol
FL/FR
3-(
methyl thio) hexanol
FL/FR
minty
(-)-iso
pulegol
FL/FR
musty
hazelnut pyrazine
FL/FR
menthofuran
FL/FR
propionaldehyde
FL
nutty
3-
acetyl-2,5-dimethyl furan
FL/FR
2-
acetyl-3-ethyl pyrazine
FL/FR
aconitic acid
FL
4,5-
dimethyl-2-ethyl-3-thiazoline
FL/FR
nutty thiazole
FL
spicy
2-
octanol
FL/FR
sulfurous
grapefruit menthane
FL/FR
methyl benzyl disulfide
FL
vegetable
2-sec-
butyl-3-methoxypyrazine
FL/FR
waxy
(Z)-6-
nonen-1-ol
FL/FR
 
Potential Uses:
FLvegetable
 
Occurrence (nature, food, other):note
 cayenne fruit
Search Trop Picture
 cedarwood oil lebanon @ >0.10%
Data GC Search Trop Picture
 coffee
Search PMC Picture
 osmanthus absolute @ trace%
Data GC Search Trop Picture
 pepper bell pepper fruit
Search Trop Picture
 
Synonyms:
isobutenyl methyl ketone
2,2-dimethyl vinyl methyl ketone
2,2-dimethylvinyl methyl ketone
3-isohexen-2-one
 mesityl oxide
 mesityl oxide natural
 mesityloxyde
 methyl 2-methyl-1-propenyl ketone
 methyl 2,2-dimethyl vinyl ketone
 methyl 2,2-dimethylvinyl ketone
 methyl isobutenyl ketone
4-methyl pent-3-en-2-one
2-methyl-2-penten-4-one
4-methyl-3-penten-2-one
4-methyl-3-pentene-2-one
2-methyl-4-oxo-2-pentene
4-methyl-pent-3-en-2-one
4-methylpent-3-en-2-one
3-penten-2-one, 4-methyl-
isopropylidene acetone
isopropylideneacetone
 

Articles:

PubMed:A quick, simple, robust method to measure the acidity of ionic liquids.
PubMed:Determination of residual acetone and acetone related impurities in drug product intermediates prepared as Spray Dried Dispersions (SDD) using gas chromatography with headspace autosampling (GCHS).
PubMed:Integration of stable isotope and trace contaminant concentration for enhanced forensic acetone discrimination.
PubMed:Evaluation of electroosmotic markers in aqueous and nonaqueous capillary electrophoresis.
PubMed:On the adsorption/reaction of acetone on pure and sulfate-modified zirconias.
PubMed:Morphology control in mesoporous carbon films using solvent vapor annealing.
PubMed:Determination of effective mobilities of EOF markers in BGE containing sulfated β-cyclodextrin by a two-detector method.
PubMed:Roles of acetone and diacetone alcohol in coordination and dissociation reactions of uranyl complexes.
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PubMed:A systematic study on the activation of simple polyethers by MoCl5 and WCl6.
PubMed:Synthesis of modified homo-N-nucleosides from the reactions of mesityl nitrile oxide with 9-allylpurines and their influence on lipid peroxidation and thrombin inhibition.
PubMed:Application of artificial neural networks in the prediction of product distribution in electrophoretically mediated microanalysis.
PubMed:Acetone reactions over the surfaces of polycrystalline UO2: a kinetic and spectroscopic study.
PubMed:Function-oriented synthesis applied to the anti-botulinum natural product toosendanin.
PubMed:Structural and formulation factors influencing pyridinium lipid-based gene transfer.
PubMed:Gas chromatography-olfactometry analysis of the volatile compounds of two commercial Irish beef meats.
PubMed:Speciation of vanadium in soil.
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PubMed:Surprising structural lability of a cysteine-S-conjugate precursor of 4-methyl-4-sulfanylpentan-2-one, a varietal aroma in wine of Vitis vinifera L. cv. Sauvignon blanc.
PubMed:Origins of selectivity for the [2+2] cycloaddition of alpha,beta-unsaturated ketones within a porous self-assembled organic framework.
PubMed:Photochemistry of the indoor air pollutant acetone on Degussa P25 TiO2 studied by chemical ionization mass spectrometry.
PubMed:[Sensory evaluation test: odor component analysis and endotoxin content of Krestin and Carbocrin (generic drug) to compare palatability].
PubMed:Two-dimensional capillary electrophoresis using tangentially connected capillaries.
PubMed:On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis.
PubMed:A new approach to promoting sluggish Diels-Alder reactions: dihapto-coordination of the diene.
PubMed:An experimental study of the gas-phase reaction of the NO3 radical with alpha,beta-unsaturated carbonyl compounds.
PubMed:Refined Synthesis of 2,3,4,5-Tetrahydro-1,3,3-trimethyldipyrrin, a Deceptively Simple Precursor to Hydroporphyrins.
PubMed:Proline-coated column for the capillary electrochromatographic separation of amino acids by in-column derivatization.
PubMed:The strongest isolable acid.
PubMed:Analysis of a model reaction system containing cysteine and (E)-2-methyl-2-butenal, (E)-2-hexenal, or mesityl oxide.
PubMed:Volatile compounds emitted by sclerotia of Sclerotinia minor, Sclerotinia sclerotiorum, and Sclerotium rolfsii.
PubMed:Reaction of Resorcinol with alpha,beta-Unsaturated Ketones.
PubMed:Medium-throughput pKa screening pharmaceuticals by pressure-assisted capillary electrophoresis.
PubMed:Spectrophotometric determination of ferbam (iron(III) dimethyldithiocarbamate) in commercial sample and wheat grains using 4,7-diphenyl-1,10-phenanthroline after extraction into mesityl oxide.
PubMed:Quantitative determination of sulfur containing wine odorants at sub-ppb levels. 1. Synthesis of the deuterated analogues.
PubMed:Preparation and evaluation of an imidazole-coated capillary column for the electrophoretic separation of aromatic acids.
PubMed:Isotope effects and syn selectivity in the ene reaction of triazolinedione with conjugated enones: aziridinium imide or an open intermediate mechanism?
PubMed:Olfactory and quantitative analysis of aroma compounds in elder flower (Sambucus nigra L.) drink processed from five cultivars.
PubMed:A robust method for determining DNA binding constants using capillary zone electrophoresis.
PubMed:A strategy for the mapping of N-glycans by high-performance capillary electrophoresis.
PubMed:The analysis of multiple phosphoseryl-containing casein peptides using capillary zone electrophoresis.
PubMed:Optimization of resolution in capillary zone electrophoresis: combined effect of applied voltage and buffer concentration.
PubMed:Adrenal-dependent leucopenia after short-term exposure to various airborne irritants in rats.
PubMed:Low-dose-rate effect of tritium beta-rays on transfection activity of phage DNA related to an oxidative species different from .OH, HO2. O2-., and H2O2.
PubMed:2,4-Diamino-5-benzylpyrimidines and analogues as antibacterial agents. 12. 1,2-Dihydroquinolylmethyl analogues with high activity and specificity for bacterial dihydrofolate reductase.
PubMed:Second derivative spectrophotometric determination of iron by extraction of the ferroin-perchlorate ion-association complex into mesityl oxide.
PubMed:Mutagen production by chlorination of methylated alpha,beta-unsaturated ketones.
PubMed:Quantitative evaluation of sensory irritating and neurobehavioural properties of aliphatic ketones in mice.
PubMed:Extraction of zinc, cadmium and mercury salicylates.
PubMed:Biotransformation of monoterpenes by Mentha cell lines.
PubMed:Selective extractive separation of zinc, cadmium and lead from iodide media with mesityl oxide.
PubMed:Extraction and separation of bismuth(III).
PubMed:[Effect of 4-methyl-3-penten-2-one (1-phthalazinyl) hydrazone (budralazine) on intra- and extracranial circulation in cats (author's transl)].
PubMed:Solvent extraction separation of hafnium with 4-methyl-3-pentene-2-one.
PubMed:[Styrene migration into wine contained in polyester resin tanks].
PubMed:Extraction and spectrophotometric determination of cobalt(II) with thiobenzoylacetone and simultaneous determination of cobalt and nickel.
PubMed:Reaction of glutathione with conjugated carbonyls.
PubMed:Solvent extraction of tellurium(IV) with mesityl oxide. Direct nephelometric determination.
PubMed:beta-Methyl-delta-keto-Delta(alphabeta)-hexenoic acid and mesityl oxide as acetyl donors in the enzymic synthesis of acetylcholine.
PubMed:Hygienic guide series: mesityl oxide.
PubMed:Liquid-liquid extraction of tungsten(VI) with mesityl oxide application to an alloy steel.
PubMed:Separation of zirconium by thin-layer chromatography.
PubMed:[Reaction of phosphatides containing ethanolamine with an alpha,beta-unsaturated ketone (mesityl oxide)].
PubMed:Catty odours in food: their production in meat stores from mesityl oxide in paint solvents.
PubMed:Catty odours in food: their production in meat stores from mesityl oxide in paint solvents.
PubMed:Catty odours in food: the reaction between mesityl oxide and sulphur compounds in foodstuffs.
PubMed:The effect of crotonylidene isonicotinic acid hydrazone (CIH) and mesityl oxide hydrazone (MIH) in experimental tuberculosis.
PubMed:The sulphonation of mesityl oxide.
PubMed:The isolation and purification of two isomers of mesityl oxide.
PubMed:Acid-base catalysis in non-aqueous solvents; the isomerisation of methyl mesityl oxide oxalate in chlorobenzene solution at 99 degrees.
 
Notes:
solvent for extraction of nitrocellulose, many resins, & tellurium. superlist note chemical remains on mtl because of additional testing actions (see oecd/sids listing) Flavouring ingredient. Constit. of Capsicum spp., Osmanthus fragrans (sweet osmanthus) and other plants
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