EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

alpha-methylene citronellal
bergamal (IFF)

Supplier Sponsors

Name:3,7-dimethyl-2-methylideneoct-6-enal
CAS Number: 22418-66-2Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:244-981-5
Nikkaji Web:J285.506B
XlogP3-AA:3.40 (est)
Molecular Weight:166.26366000
Formula:C11 H18 O
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 90.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.86800 to 0.87600 @ 20.00 °C.
Pounds per Gallon - est.: 7.231 to 7.298
Boiling Point: 244.31 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.031000 mm/Hg @ 25.00 °C. (est)
Flash Point: 181.00 °F. TCC ( 82.78 °C. )
logP (o/w): 3.345
Shelf Life: 24.00 month(s) or longer if stored properly.
Storage:store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
 alcohol
 water, 27.56 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: citrus
Odor Strength:medium
Substantivity:6 hour(s) at 100.00 %
petitgrain bergamot citrus fresh green woody
Odor Description:at 100.00 %. petitgrain bergamot citrus fresh green woody
Luebke, William tgsc, (1988)
Odor sample from: International Flavors & Fragrances Inc.
Odor and/or flavor descriptions from others (if found).
IFF
Bergamal
Odor Description:Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties
Taytonn
Bergamal
Odor Description:Aldehydic/ Aldehyde, Citronella, Citrus, Floral
Pell Wall Perfumes
Bergamal
Odor Description:aldehydic, verbena, bergamot
Also known as alpha-methylene citronellal, this IFF product is described by them as: “Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties.” Very useful to enhance bergamot and other citrus notes.
Perfumery Laboratory
BERGAMAL IFF
Odor Description:Refreshing, aldehyde, lemon verbena, with a clear note of bergamot
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Azelis UK
BERGAMAL
Services
Creatingperfume.com
Bergamal (IFF)
Odor: Petitgrain, bergamot, citrus, fresh, green, woody. Refreshing, aldehydic, lemon, verbena note with definite bergamot and dry orange
Ernesto Ventós
BERGAMAL IFF
IFF
Bergamal
Odor: Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties
Indukern F&F
BERGAMAL
Odor: ALDEHYDIC, FRESH, CITRUS, LEMON
Pell Wall Perfumes
Bergamal
Odor: aldehydic, verbena, bergamot
Use: Also known as alpha-methylene citronellal, this IFF product is described by them as: “Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties.” Very useful to enhance bergamot and other citrus notes.
Penta International
alpha-METHYLENE CITRONELLAL
Perfumery Laboratory
BERGAMAL IFF
Odor: Refreshing, aldehyde, lemon verbena, with a clear note of bergamot
Taytonn
Bergamal
Odor: Aldehydic/ Aldehyde, Citronella, Citrus, Floral
The John D. Walsh Company
Bergamal
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: fragrance agents
Recommendation for alpha-methylene citronellal usage levels up to:
  10.0000 % in the fragrance concentrate.
 
Recommendation for alpha-methylene citronellal flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):22418-66-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :90776
National Institute of Allergy and Infectious Diseases:Data
3,7-dimethyl-2-methylideneoct-6-enal
Chemidplus:0022418662
 
References:
Leffingwell:Chirality or Article
 3,7-dimethyl-2-methylideneoct-6-enal
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:22418-66-2
Pubchem (cid):90776
Pubchem (sid):135049242
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2912.19.0000
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
octanal propylene glycol acetal
FL/FR
aldehydic
aldehydic
dodecanal (aldehyde C-12 lauric)
FL/FR
green hexanal
FL/FR
undecanal
FL/FR
balsamic
betula pubescens bud oil
FL/FR
fir balsam absolute
FR
fir balsam concrete
FR
fir tree fragrance
FR
valerian rhizome absolute
FL/FR
citrus
bergamot acetoacetate
FR
bergamot oil bergaptene reduced italy
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
citronellal oxime
FR
(R)-
citronellyl nitrile
FR
iso
decyl acetate
FR
dihydromyrcenyl acetate
FR
lime oil distilled terpeneless
FL/FR
lime oil fractions
FR
limonene aldehyde
FR
litsea cubeba fruit oil
FL/FR
methyl heptenone
FL/FR
1-
methyl-4-methyl ethenyl cyclohexene sulfurized
FL/FR
myrcenyl acetate
FL/FR
neroli ketone
FR
petitgrain combava oil
FR
tangerine acetate
FR
alpha-
terpinyl methyl ether
FL/FR
earthy
octyl phenyl acetate
FL/FR
fatty
6-
methyl-5-hepten-2-one propylene glycol acetal
FL/FR
floral
bigarade oxide
FR
bois de rose oil brazil
FL/FR
cilantro herb oil egypt
FL/FR
citronellol
FL/FR
(S)-
citronellyl acetate
FL/FR
citronellyl anthranilate
FL/FR
citronellyl formate
FL/FR
coranol (Firmenich)
FR
dihydrocitronellyl ethyl ether
FR
dihydrolinalool
FL/FR
3,6-
dimethyl-3-octanol
FL/FR
ethyl ethyl anthranilate
FL/FR
ethyl linalool
FR
ethyl linalyl acetal
FR
ethyl linalyl acetate
FR
ethyl linalyl ether
FL/FR
glycoacetal
FR
ho leaf oil
FR
ho wood oil
FR
karo karounde absolute
FR
leerall
FR
linalool
FL/FR
linalool oxide
FL/FR
linalyl anthranilate
FL/FR
linalyl benzoate
FL/FR
linalyl butyrate
FL/FR
linalyl propionate
FL/FR
melaleuca ericifolia leaf oil
FR
(E)-
nerolidol
FL/FR
neryl isovalerate
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower water absolute
FL/FR
petitgrain cedrat oil
FL/FR
terpinyl isobutyrate
FL/FR
tetrahydrolinalool
FL/FR
tetrahydrolinalyl acetate
FR
fruity
apple ketal
FL/FR
iso
butyl 2-methyl butyrate
FL/FR
butyl anthranilate
FL/FR
cyclohexyl crotonate
FR
2-
cyclopentyl cyclopentanone
FL/FR
1,4-
dibutyl-6,8-dioxabicyclo(3.2.1)octane
FR
1,4-
diisopropyl-6,8-dioxabicyclo(3.2.1)octane
FR
(R)-gamma-
dodecalactone
FL/FR
ethyl methyl anthranilate
FL/FR
grapefruit acetal
FR
linalyl isobutyrate
FL/FR
methyl acetoacetate
FL/FR
nerolidyl isobutyrate
FR
ocimen-1-yl acetate
FR
green
bergoxane
FR
citral / diisotridecyl acetal
FR
citrus carbaldehyde / methyl anthranilate schiff's base
FR
alpha-
elemol
FL/FR
fresh nitrile
FR
galbanum oil
FL/FR
galbanum oleoresin
FL/FR
galbanum resinoid
FL/FR
green carboxylate
FR
1-
heptanol
FL/FR
(E)-2-
hexen-1-yl salicylate
FR
dextro-
limonene oxide
FL/FR
para-
methyl hydratropaldehyde
FL/FR
octanal diethyl acetal
FL/FR
octanal dimethyl acetal
FL/FR
(E)-2-
octen-1-ol
FL/FR
terpinyl propionate
FL/FR
valerian rhizome oil CO2 extract china
FL/FR
herbal
bergamot mint herb oil
FR
bornyl salicylate
FR
(+)-alpha-
campholenic aldehyde
FL/FR
canarium luzonicum oil
FL/FR
clary octenone
FR
cuminyl acetate
FL/FR
iso
dihydrolavandulal
FL/FR
2-
dodecenal
FL/FR
herbal carene
FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
linalyl acetate
FL/FR
linalyl formate
FL/FR
linalyl isovalerate
FL/FR
nonisyl formate
FR
3-
octyl acetate
FL/FR
petitgrain heptane
FR
terpineol acetate
FL/FR
tricyclo(5.2.1.02,6)dec-3-enyl acetate
FR
valerian rhizome oil
FL/FR
valerian rhizome oil china
FL/FR
melon
(Z)-6-
nonenal
FL/FR
minty
(-)-iso
pulegol
FL/FR
iso
pulegol
FL/FR
2,4,4,6-
tetramethyl cyclohexa-2,5-diene-1-one
FR
mossy
oakmoss absolute
FL/FR
orris
iso
eugenyl formate
FL/FR
pine
pine oil 85
FR
spicy
cubeb oil
FL/FR
iso
cyclogeraniol (IFF)
FR
2,5-
dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate + 1,4-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate
FR
2-
octanol
FL/FR
black
pepper oil CO2 extract
FL/FR
zanthoxylum piperitum fruit absolute CO2 extract
FL/FR
terpenic
juniper branch oil
FR
alpha-
phellandrene
FL/FR
waxy
decanal dimethyl acetal
FL/FR
woody
bruyere root absolute
FR
alpha-
farnesene
FL/FR
alpha-
farnesene isomer
FL/FR
frankincense resinoid replacer
FR
humulus lupulus extract
FL/FR
moss naphthaleneol
FR
(±)-
tetrahydronootkatone
FL/FR
xanthoxylum alatum roxb. oil
FR
For Flavor
No flavor group found for these
betula pubescens bud oil
FL/FR
cuminyl acetate
FL/FR
2-
cyclopentyl cyclopentanone
FL/FR
decanal dimethyl acetal
FL/FR
(R)-gamma-
dodecalactone
FL/FR
alpha-
elemol
FL/FR
ethyl ethyl anthranilate
FL/FR
ethyl linalyl ether
FL/FR
ethyl methyl anthranilate
FL/FR
iso
eugenyl formate
FL/FR
linalyl formate
FL/FR
methyl acetoacetate
FL/FR
6-
methyl-5-hepten-2-one propylene glycol acetal
FL/FR
octanal propylene glycol acetal
FL/FR
octyl phenyl acetate
FL/FR
terpineol acetate
FL/FR
terpinyl isobutyrate
FL/FR
(±)-
tetrahydronootkatone
FL/FR
dextro-
limonene oxide
FL/FR
camphoreous
camphoreous
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
citrus
bergamot oil bergaptene reduced italy
FL/FR
citral diethyl acetal
FL/FR
citral dimethyl acetal
FL/FR
lime oil distilled terpeneless
FL/FR
linalool
FL/FR
litsea cubeba fruit oil
FL/FR
1-
methyl-4-methyl ethenyl cyclohexene sulfurized
FL/FR
myrcenyl acetate
FL/FR
petitgrain cedrat oil
FL/FR
fatty
2-
dodecenal
FL/FR
(E)-2-
octen-1-ol
FL/FR
floral
bois de rose oil brazil
FL/FR
citronellol
FL/FR
(S)-
citronellyl acetate
FL/FR
dihydrolinalool
FL/FR
linalyl acetate
FL/FR
linalyl anthranilate
FL/FR
linalyl benzoate
FL/FR
linalyl butyrate
FL/FR
linalyl isobutyrate
FL/FR
orange leaf absolute
FL/FR
bitter
orangeflower water absolute
FL/FR
tetrahydrolinalool
FL/FR
fruity
apple ketal
FL/FR
iso
butyl 2-methyl butyrate
FL/FR
butyl anthranilate
FL/FR
citronellyl anthranilate
FL/FR
citronellyl formate
FL/FR
linalyl isovalerate
FL/FR
neryl isovalerate
FL/FR
valerian rhizome absolute
FL/FR
valerian rhizome oil
FL/FR
valerian rhizome oil china
FL/FR
valerian rhizome oil CO2 extract china
FL/FR
green
(+)-alpha-
campholenic aldehyde
FL/FR
canarium luzonicum oil
FL/FR
alpha-
farnesene
FL/FR
alpha-
farnesene isomer
FL/FR
galbanum oil
FL/FR
galbanum oleoresin
FL/FR
galbanum resinoid
FL/FR
linalool oxide
FL/FR
methyl heptenone
FL/FR
para-
methyl hydratropaldehyde
FL/FR
(E)-
nerolidol
FL/FR
(Z)-6-
nonenal
FL/FR
oakmoss absolute
FL/FR
octanal diethyl acetal
FL/FR
octanal dimethyl acetal
FL/FR
3-
octyl acetate
FL/FR
terpinyl propionate
FL/FR
herbal
cilantro herb oil egypt
FL/FR
iso
dihydrolavandulal
FL/FR
3,6-
dimethyl-3-octanol
FL/FR
green hexanal
FL/FR
linalyl propionate
FL/FR
minty
iso
pulegol
FL/FR
(-)-iso
pulegol
FL/FR
nutty
peanut oxazole
FL
soapy
dodecanal (aldehyde C-12 lauric)
FL/FR
solvent
1-
heptanol
FL/FR
spicy
cubeb oil
FL/FR
2-
octanol
FL/FR
black
pepper oil CO2 extract
FL/FR
zanthoxylum piperitum fruit absolute CO2 extract
FL/FR
terpenic
alpha-
phellandrene
FL/FR
waxy
undecanal
FL/FR
woody
humulus lupulus extract
FL/FR
alpha-
terpinyl methyl ether
FL/FR
 
Potential Uses:
FRaldehydic
FRbergamot
FRcitrus
FRclary sage oil replacer
 dry
FRgreen
FRlemon
FRmagnolia
FRmandarin
FRorange
FL/FRorange bitter orange peel
FRpetitgrain
FRverbena
FRwoody
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 bergamal (IFF)
3,7-dimethyl-2-methylene oct-6-enal
3,7-dimethyl-2-methylene octa-6-enal
3,7-dimethyl-2-methylene-6-octen-1-al
3,7-dimethyl-2-methylene-6-octenal
3,7-dimethyl-2-methylene-oct-6-enal
3,7-dimethyl-2-methyleneoct-6-enal
3,7-dimethyl-2-methyleneocta-6-enal
3,7-dimethyl-2-methylideneoct-6-enal
alpha-methylene citronellal
a-methylenecitronellal
6-octenal, 3,7-dimethyl-2-methylene-
 

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