EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

benzyl crotonate
benzyl 2-butenoate

Supplier Sponsors

Name:benzyl but-2-enoate
CAS Number: 65416-24-2Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:265-764-1
FDA UNII:IIG3KVS651
XlogP3:2.80 (est)
Molecular Weight:176.21504000
Formula:C11 H12 O2
NMR Predictor:Predict (works with chrome or firefox)
Category:flavoring agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
FLAVIS Number:09.314 (Old)
DG SANTE Food Flavourings:09.314 benzyl crotonate
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.02900 to 1.03500 @ 25.00 °C.
Pounds per Gallon - (est).: 8.562 to 8.612
Refractive Index:1.51500 to 1.52100 @ 20.00 °C.
Boiling Point: 249.00 to 250.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.021000 mm/Hg @ 25.00 °C. (est)
Flash Point: 262.00 °F. TCC ( 127.78 °C. )
logP (o/w): 2.617 (est)
Soluble in:
 alcohol
 water, 212.3 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items:note
allyl crotonate
isoamyl crotonate
apple crotonate
butyl (E)-2-crotonate
citronellyl crotonate
cyclohexyl crotonate
dimethyl benzyl carbinyl crotonate
ethyl (E)-2-crotonate
ethyl crotonate
fig crotonate
geranyl crotonate
heptyl crotonate
(Z)-3-hexen-1-yl (E)-crotonate
(E)-3-hexen-1-yl crotonate
hexyl (E)-crotonate
octyl crotonate
phenethyl crotonate
3-phenyl propyl crotonate
plum crotonate
isopropyl (E)-crotonate
propyl crotonate
isopropyl 3-methyl thiocrotonate
 
Organoleptic Properties:
Odor Type: herbal
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
warm herbal spicy balsamic
Odor Description:at 10.00 % in dipropylene glycol. warm herbal spicy
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Benzyl Crotonate
Grau Aromatics
BENZYL-CROTONATE
NI, Kosher
Inoue Perfumery
BENZYL CROTONATE
Penta International
BENZYL CROTONATE
SRS Aromatics
BENZYL CROTONATE
Odor: Warm, Herbal, Spicy
Synerzine
Benzyl Crotonate
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavoring agents
Recommendation for benzyl crotonate usage levels up to:
 not for fragrance use.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.37 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 3900 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 7.0000035.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 5.0000025.00000
Edible ices, including sherbet and sorbet (03.0): 10.0000050.00000
Processed fruit (04.1): 7.0000035.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 10.0000050.00000
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.0000025.00000
Bakery wares (07.0): 10.0000050.00000
Meat and meat products, including poultry and game (08.0): 2.0000010.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.0000010.00000
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.0000025.00000
Foodstuffs intended for particular nutritional uses (13.0): 10.0000050.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 5.0000025.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.0000050.00000
Ready-to-eat savouries (15.0): 20.00000100.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.0000025.00000
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) on a request from the Commission related to Flavouring Group Evaluation 20 (FGE.20): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical group 23
View page or View pdf

Flavouring Group Evaluation 52 (FGE.52): Consideration of hydroxy- and alkoxy-substituted benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters evaluated by EFSA in FGE.20 (2005) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf

Flavouring Group Evaluation 54 (FGE.54)[1] - Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20 (2005) - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf

Flavouring Group Evaluation 20, Revision 1 (FGE.20Rev1): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters from chemical group 23
View page or View pdf

Flavouring Group Evaluation 54, Revision 1 (FGE.54Rev1): Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20Rev1 (2009)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 20, Revision 4 (FGE.20Rev4): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):65416-24-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :97885
National Institute of Allergy and Infectious Diseases:Data
benzyl but-2-enoate
Chemidplus:0065416242
 
References:
 benzyl but-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:65416-24-2
Pubchem (cid):97885
Pubchem (sid):135052312
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.19.7000
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
arnica montana flower extract
FL/FR
amber
amber
labdanum oil
FL/FR
anise
sweet
fennel seed oil
FL/FR
balsamic
artemisia annua herb oil bulgaria
FL/FR
sumatra
benzoin absolute
FL/FR
benzoin absolute replacer
FL/FR
siam
benzoin CO2 extract
FL/FR
alpha-
bisabolene
FL/FR
cinnamyl alcohol
FL/FR
cinnamyl benzoate
FL/FR
copaiba balsam oil
FL/FR
ethyl cinnamate
FL/FR
myrrh oil CO2 extract
FL/FR
opoponax oil (balsamodendron kafal)
FL/FR
opoponax oil (commiphora erythraea var. glabrescens engle)
FL/FR
3-
phenyl propyl acetate
FL/FR
3-
phenyl propyl cinnamate
FL/FR
cheesy
2-
heptanone
FL/FR
earthy
3-
octen-2-one
FL/FR
pinus sylvestris leaf absolute
FL/FR
fatty
perillaldehyde propylene glycol acetal
FL/FR
floral
coriander seed oil
FL/FR
geranium oil africa
FL/FR
(Z)-
jasmone
FL/FR
(Z)-
rose oxide
FL/FR
terpinyl isobutyrate
FL/FR
green
holy
basil leaf oil
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
black
currant bud absolute replacer
FL/FR
herbal
carum carvi fruit oil
FL/FR
carvacryl methyl ether
FL/FR
celery ketone
FL/FR
dehydroxylinalool oxide
FL/FR
lavender absolute bulgaria
FL/FR
lavender absolute france
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
T-
muurolol
FL/FR
3-
nonanol
FL/FR
3-
octanon-1-ol
FL/FR
origanum oil
FL/FR
curled
parsley leaf oil
FL/FR
minty
betula lenta bark oil america
FL/FR
ethyl salicylate
FL/FR
peppermint oil special fractions
FL/FR
spicy
bay leaf oil terpeneless
FL/FR
benzyl isoeugenol
FL/FR
carrot weed oil
FL/FR
carvacryl ethyl ether
FL/FR
(Z)-
cinnamyl acetate
FL/FR
clove bud oleoresin
FL/FR
(-)-
cubenol
FL/FR
cuminyl alcohol
FL/FR
black
currant bud absolute
FL/FR
eugenyl benzoate
FL/FR
ginger root absolute
FL/FR
mace oil CO2 extract
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
nutmeg absolute
FL/FR
nutmeg oil CO2 extract
FL/FR
origanum majorana oil
FL/FR
origanum majorana oil CO2 extract
FL/FR
white
pepper oil
FL/FR
black
pepper oil CO2 extract
FL/FR
black
pepper oleoresin
FL/FR
saffron oil CO2 extract
FL/FR
spicy acetoacetate
FL/FR
annus
wormwood oil vietnam
FL/FR
woody
frankincense resinoid
FL/FR
kaempferia galanga rhizome oil
FL/FR
sandalwood oil
FL/FR
(±)-
tetrahydronootkatone
FL/FR
For Flavor
No flavor group found for these
arnica montana flower extract
FL/FR
artemisia annua herb oil bulgaria
FL/FR
holy
basil leaf oil
FL/FR
alpha-
bisabolene
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
carvacryl ethyl ether
FL/FR
carvacryl methyl ether
FL/FR
(Z)-
cinnamyl acetate
FL/FR
cinnamyl benzoate
FL/FR
(±)-(cis+trans)-1,2-
dihydroperillaldehyde
FL
eugenyl benzoate
FL/FR
fleabane oil (erigeron canadensis)
FL
2-
heptyl cyclopropane carboxylic acid
FL
T-
muurolol
FL/FR
3-
nonanol
FL/FR
3-
octanon-1-ol
FL/FR
perillaldehyde propylene glycol acetal
FL/FR
pinus sylvestris leaf absolute
FL/FR
terpinyl isobutyrate
FL/FR
(±)-
tetrahydronootkatone
FL/FR
hexyl 3-mercaptobutanoate
FL
amber
amber
labdanum oil
FL/FR
anise
sweet
fennel seed oil
FL/FR
balsamic
benzoin absolute replacer
FL/FR
copaiba balsam oil
FL/FR
ethyl cinnamate
FL/FR
myrrh oil CO2 extract
FL/FR
opoponax oil (balsamodendron kafal)
FL/FR
opoponax oil (commiphora erythraea var. glabrescens engle)
FL/FR
3-
phenyl propyl acetate
FL/FR
buttery
bovolide
FL
camphoreous
kaempferia galanga rhizome oil
FL/FR
cheesy
2-
heptanone
FL/FR
creamy
3-
octen-2-one
FL/FR
floral
geranium oil africa
FL/FR
fruity
black
currant bud absolute replacer
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
green
carrot weed oil
FL/FR
celery distillates
FL
celery ketone
FL/FR
cinnamyl alcohol
FL/FR
(Z)-
rose oxide
FL/FR
herbal
carum carvi fruit oil
FL/FR
coriander seed oil
FL/FR
lavender absolute bulgaria
FL/FR
lavender absolute france
FL/FR
oregano oleoresin
FL
origanum majorana oil
FL/FR
origanum majorana oil CO2 extract
FL/FR
origanum oil
FL/FR
curled
parsley leaf oil
FL/FR
curled
parsley oleoresin
FL
minty
betula lenta bark oil america
FL/FR
ethyl salicylate
FL/FR
peppermint oil special fractions
FL/FR
spicy
bay leaf oil terpeneless
FL/FR
sweet
bay oleoresin
FL
sumatra
benzoin absolute
FL/FR
siam
benzoin CO2 extract
FL/FR
benzyl isoeugenol
FL/FR
clove bud oleoresin
FL/FR
(-)-
cubenol
FL/FR
cuminyl alcohol
FL/FR
black
currant bud absolute
FL/FR
galangal root oleoresin
FL
ginger root absolute
FL/FR
mace oil CO2 extract
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
nutmeg absolute
FL/FR
nutmeg oil CO2 extract
FL/FR
white
pepper oil
FL/FR
black
pepper oil CO2 extract
FL/FR
black
pepper oleoresin
FL/FR
3-
phenyl propyl cinnamate
FL/FR
saffron oil CO2 extract
FL/FR
spicy acetoacetate
FL/FR
annus
wormwood oil vietnam
FL/FR
woody
dehydroxylinalool oxide
FL/FR
frankincense resinoid
FL/FR
(Z)-
jasmone
FL/FR
sandalwood oil
FL/FR
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 papaya fruit - 0.0001 mg/kg
Search Trop Picture
 
Synonyms:
 benzyl 2-butenoate
 benzyl but-2-enoate
 benzyl-crotonate
2-butenoic acid, phenylmethyl ester
 phenylmethyl but-2-enoate
 
 
Notes:
None found
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