EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

methyl (E,Z)-2,4-decadienoate
methyl (E)-2-(Z)-4-decadienoate

Sponsors

Name:methyl (2E,4Z)-deca-2,4-dienoate
CAS Number: 4493-42-9Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:224-787-7
FDA UNII:WX3M6126GD
Beilstein Number:1723201
XlogP3-AA:3.60 (est)
Molecular Weight:182.26286000
Formula:C11 H18 O2
NMR Predictor:Predict (works with chrome or firefox)
EFSA/JECFA Comments:
According to the JECFA: Min. assay value is "93 %" and secondary components "(E,E) methyl 2,4-decadienoate". CASrn in Register refers to the (2E,4Z)-enantiomer. Register name to be changed to Methyl (E,Z)-deca-2,4-dienoate. CASrn refers to (2E, 4Z)-isomer. Material in commerce is min. 93 % pure (2E,4Z)-isomer. Min. Purity > 95 % (sum of isomers: other isomer mainly (2E,4E)-isomer (< 5%))(EFFA, 2010a). Registed name to ge changed to Methyl (E,Z)-deca-2,4-dienoate.
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
JECFA Food Flavoring:1191 methyl (E)-2-(Z)-4-decadienoate
FLAVIS Number:09.639 (Old)
DG SANTE Food Flavourings:09.639 methyl (E,Z)-deca-2,4-dienoate
FEMA Number:3859 methyl (E)-2-(Z)-4-decadienoate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm: METHYL(E)-2-(Z)-4-DECADIENOATE
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 93.50 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity:0.91100 to 0.91800 @ 25.00 °C.
Pounds per Gallon - (est).: 7.580 to 7.639
Refractive Index:1.48600 to 1.49400 @ 20.00 °C.
Boiling Point: 105.00 °C. @ 2.00 mm Hg
Boiling Point: 246.00 to 247.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.028000 mm/Hg @ 25.00 °C. (est)
Flash Point: 230.00 °F. TCC ( 110.00 °C. )
logP (o/w): 3.986 (est)
Soluble in:
 alcohol
 water, 26.5 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: fruity
Odor Strength:medium
fruity waxy pear
Odor Description:at 100.00 %. fruity waxy pear
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
METHYL 2,4-DECADIENOATE
Odor Description:A fruity waxy pear-like odor with a slight lemon connotation
Used in various fragrance compositions for it\'s mild fruitiness.
 
Cosmetic Information:
None found
 
Suppliers:
Bedoukian Research
METHYL 2,4-DECADIENOATE
Odor: A fruity waxy pear-like odor with a slight lemon connotation
Use: Used in various fragrance compositions for it\'s mild fruitiness.
BOC Sciences
For experimental / research use only.
2,4-Decadienoic acid methyl ester
Carbosynth
For experimental / research use only.
Methyl-2-trans-4-cis-decadienoate
Parchem
methyl (E,Z)-2,4-decadienoate
Santa Cruz Biotechnology
For experimental / research use only.
(2E,4Z)-2,4-Decadienoic acid methyl ester
Chemical Sources Association
Need This Item for Flavor/Food?: You can contact the Chemical Sources Association
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for methyl (E,Z)-2,4-decadienoate usage levels up to:
  3.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.097 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 1.00 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 18
 average usual ppmaverage maximum ppm
baked goods: 1.0000010.00000
beverages(nonalcoholic): 0.200002.00000
beverages(alcoholic): 0.400004.00000
breakfast cereal: --
cheese: --
chewing gum: 10.0000050.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: --
fruit ices: 1.0000010.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: 2.0000020.00000
imitation dairy: --
instant coffee / tea: 0.400004.00000
jams / jellies: 2.0000020.00000
meat products: --
milk products: 1.0000010.00000
nut products: --
other grains: --
poultry: --
processed fruits: 0.400004.00000
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 2.0000020.00000
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(efsa):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 70 (FGE.70): Consideration of aliphatic, alicyclic, linear, alpha,beta-unsaturated, di- and trienals and related alcohols, acids and esters evaluated by JECFA (61st meeting)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 96 (FGE.96): Consideration of 88 flavouring substances considered by EFSA for which EU production volumes / anticipated production volumes have been submitted on request by DG SANCO. Addendum to FGE. 51, 52, 53, 54, 56, 58, 61, 62, 63, 64, 68, 69, 70, 71, 73, 76, 77, 79, 80, 83, 84, 85 and 87.
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):4493-42-9
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6436336
National Institute of Allergy and Infectious Diseases:Data
methyl (2E,4Z)-deca-2,4-dienoate
Chemidplus:0004493429
 
References:
 methyl (2E,4Z)-deca-2,4-dienoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:4493-42-9
Pubchem (cid):6436336
Pubchem (sid):135036227
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2009
(IUPAC):Atomic Weights of the Elements 2009 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS):View
HMDB (The Human Metabolome Database):HMDB34730
FooDB:FDB013268
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
fatty
allyl octanoate
FL/FR
iso
butyl undecylenate
FL/FR
floral
citronellyl propionate
FL/FR
gelsone (IFF)
FL/FR
(E)-
geranyl acetone
FL/FR
geranyl hexanoate
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
methyl citronellate
FL/FR
octyl acetate
FL/FR
fruity
allyl 10-undecenoate
FL/FR
allyl heptanoate
FL/FR
iso
amyl isobutyrate
FL/FR
iso
amyl octanoate
FL/FR
decyl butyrate
FL/FR
ethyl (E)-2-decenoate
FL/FR
ethyl (E)-4-octenoate
FR
ethyl hexanoate
FL/FR
3-
hexanone
FL/FR
(Z)-3-
hexen-1-yl 2-methyl-2-pentenoate
FR
hexyl propionate
FL/FR
3-
mercaptohexyl acetate
FL/FR
methyl 2-octenoate
FL/FR
methyl nonanoate
FL/FR
(E)-2-
nonen-1-yl acetate
FL/FR
(Z)-3-
octen-1-yl propionate
FL/FR
octyl butyrate
FL/FR
2-
undecanone
FL/FR
green
ethyl (E,Z)-2,4-decadienoate
FL/FR
ethyl (E)-4-decenoate
FL/FR
(E)-2-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl hexanoate
FL/FR
(E)-2-
hexen-1-yl isovalerate
FL/FR
(Z)-3-
hexen-1-yl propionate
FL/FR
hexyl 2-methyl butyrate
FL/FR
hexyl phenyl acetate
FL/FR
(E,Z)-3,6-
nonadien-1-yl acetate
FL/FR
3,6-
nonadien-1-yl acetate
FL/FR
3-
octyl formate
FL/FR
herbal
butyl levulinate
FL/FR
musk
iso
ambrettolide
FL/FR
musk propanoate
FR
vegetable
1-
furfuryl pyrrole
FL/FR
waxy
allyl nonanoate
FL/FR
3-
decanone
FL/FR
dihydrocitronellyl acetate
FL/FR
ethyl decanoate
FL/FR
ethyl palmitate
FL/FR
heptyl octanoate
FL/FR
methyl butyl phenyl acetate
FL/FR
(E)-2-
octen-1-yl butyrate
FL/FR
octyl 2-methyl butyrate
FL/FR
propyl decanoate
FL/FR
(E)-2-
tridecen-1-yl acetate
FL/FR
For Flavor
No flavor group found for these
allyl 10-undecenoate
FL/FR
iso
butyl undecylenate
FL/FR
3-
decanone
FL/FR
dihydrocitronellyl acetate
FL/FR
hexyl propionate
FL/FR
methyl 2-octenoate
FL/FR
4-
methyl pentyl 4-methyl valerate
FL
(E)-2-
octen-1-yl butyrate
FL/FR
propyl decanoate
FL/FR
(E)-2-
tridecen-1-yl acetate
FL/FR
coconut
coconut
(R)-
massoia lactone
FL
fatty
allyl octanoate
FL/FR
ethyl (E)-4-decenoate
FL/FR
floral
citronellyl propionate
FL/FR
(E)-
geranyl acetone
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
methyl citronellate
FL/FR
fruity
allyl heptanoate
FL/FR
iso
amyl isobutyrate
FL/FR
iso
amyl octanoate
FL/FR
decyl butyrate
FL/FR
ethyl (E)-2-decenoate
FL/FR
ethyl hexanoate
FL/FR
geranyl hexanoate
FL/FR
3-
hexanone
FL/FR
hexyl phenyl acetate
FL/FR
(Z)-3-
octen-1-yl propionate
FL/FR
green
ethyl (E,Z)-2,4-decadienoate
FL/FR
gelsone (IFF)
FL/FR
(E)-2-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl hexanoate
FL/FR
(E)-2-
hexen-1-yl isovalerate
FL/FR
(Z)-3-
hexen-1-yl propionate
FL/FR
(E)-3-
hexenoic acid
FL
hexyl 2-methyl butyrate
FL/FR
methyl 2-undecynoate
FL
3,6-
nonadien-1-yl acetate
FL/FR
(E,Z)-3,6-
nonadien-1-yl acetate
FL/FR
herbal
butyl levulinate
FL/FR
leafy
methyl butyl phenyl acetate
FL/FR
musk
iso
ambrettolide
FL/FR
tropical
3-
mercaptohexyl acetate
FL/FR
vegetable
1-
furfuryl pyrrole
FL/FR
waxy
allyl nonanoate
FL/FR
ethyl decanoate
FL/FR
ethyl palmitate
FL/FR
heptyl octanoate
FL/FR
(E)-2-
nonen-1-yl acetate
FL/FR
octyl 2-methyl butyrate
FL/FR
octyl acetate
FL/FR
octyl butyrate
FL/FR
3-
octyl formate
FL/FR
2-
undecanone
FL/FR
winey
methyl nonanoate
FL/FR
 
Potential Uses:
FRfruit
FRpear
 waxy
 
Occurrence (nature, food, other):note
 maxillaria variabilis
Search Trop Picture
 pear fruit
Search Trop Picture
 
Synonyms:
2,4-decadienoic acid, methyl ester, (2E,4Z)-
2,4-decadienoic acid, methyl ester, (E,Z)-
 methyl (2E,4Z)-2,4-decadienoate
 methyl (2E,4Z)-deca-2,4-dienoate
 methyl (E,Z)-deca-2,4-dienoate
 methyl (E)-2-(Z)-4-decadienoate
(E,Z)-methyl 2,4-decadienoate
 methyl pear decadienoate
 methyl trans-2,cis-4-decadienoate
 
 
Notes:
Found in pears and spineless monkey orange. Flavour for candies etc
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