EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

dextro,laevo-menthone glycerine acetal
DL-menthone glycerol ketal

Supplier Sponsors

CAS Number: 63187-91-7Picture of molecule3D/inchi
FDA UNII: 7QQ1EE6RCP
Nikkaji Web:J1.087.004F
MDL:MFCD06409992
XlogP3-AA:2.50 (est)
Molecular Weight:228.33188000
Formula:C13 H24 O3
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:446 DL-menthone 1,2-glycerol ketal
DG SANTE Food Flavourings:06.120 DL-menthone 1,2-glycerol ketal
FEMA Number:3808 DL-menthone glycerol ketal
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):63187-91-7 ; MENTHONE 1,2-GLYCEROL KETAL
 
Physical Properties:
Appearance:colorless clear viscous liquid (est)
Assay: 98.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.03000 @ 25.00 °C.
Refractive Index:1.47300 to 1.48000 @ 20.00 °C.
Optical Rotation:-29.00 to -23.00
Boiling Point: 322.00 to 323.00 °C. @ 760.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.000021 mmHg @ 25.00 °C. (est)
Flash Point: 319.00 °F. TCC ( 159.44 °C. )
logP (o/w): 3.036 (est)
Soluble in:
 olive oil
 water
 water, 27.28 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor Type: odorless
Odor Strength:none
Odor Description:at 100.00 %. odorless
Flavor Type: cooling
cooling
Taste Description: cooling
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: refreshing agents
 
Suppliers:
Apple Flavor & Fragrance
l-Menthone 1,2-glyceryl ketal
BOC Sciences
For experimental / research use only.
6-Isopropyl-9-methyl-1,4-dioxaspiro[4.5]decane-2-methanol 95%
Nectar Lifesciences
Menthone Glycerol Ketal
OQEMA
Menthone-1,2-Glycerol Ketal
Penta International
L-MENTHONE-1,2-GLYCERYL KETAL
Shanghai Vigen Fine Chemical
l-Menthone-1,2-glyceryl Ketal
Symrise
Frescolat® MGA
Odor: characteristic
Use: Frescolat® products provide a pleasant, long-lasting freshness and cooling effect on the skin. Frescolat® MGA is an oil-soluble cooling ingredient.
Synerzine
L-MENTHONE 1,2-GLYCEROL KETAL
Vigon International
Frescolat MGA (Menthone Glyceryl Acetal)
WholeChem
L-Menthone 1,2-glyceryl ketal
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 17
Click here to view publication 17
 average usual ppmaverage maximum ppm
baked goods: 50.0000080.00000
beverages(nonalcoholic): 10.0000015.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: 500.00000800.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: --
fruit ices: --
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 50.0000080.00000
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):63187-91-7
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :162184
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
(9-methyl-6-propan-2-yl-1,4-dioxaspiro[4.5]decan-2-yl)methanol
Chemidplus:0063187917
 
References:
Leffingwell:Chirality or Article
 (9-methyl-6-propan-2-yl-1,4-dioxaspiro[4.5]decan-2-yl)methanol
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):162184
Pubchem (sid):135116907
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
HMDB (The Human Metabolome Database):HMDB32367
FooDB:FDB014990
ChemSpider:View
 
Potential Blenders and core components note
For Odor
balsamic
iso
bornyl formate
FL/FR
dextro-
fenchone
FL/FR
camphoreous
beta-homo
cyclocitral
FL/FR
fenchol
FL/FR
laevo-
fenchone
FL/FR
citrus
ocimene quintoxide
FL/FR
earthy
(-)-alpha-
fenchol
FL/FR
ethereal
cyclohexyl formate
FL/FR
floral
iso
butyl salicylate
FL/FR
dihydrocarvyl acetate
FL/FR
fruity
cyclohexyl acetate
FL/FR
pineapple pentenoate
FL/FR
tropical trithiane
FL/FR
vanilla carboxylate
FL/FR
green
manzanate (Givaudan)
FL/FR
3,5,5-
trimethyl hexanol
FL/FR
herbal
1,4-
cineole
FL/FR
1,8-
cineole
FL/FR
geranic oxide
FL/FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
hyssop oil
FL/FR
jambu oleoresin
FL/FR
spike
lavender oil
FL/FR
myrtenol
FL/FR
sabinene hydrate
FL/FR
theaspirane
FL/FR
medicinal
meta-
dimethyl hydroquinone
FL/FR
mentholic
cornmint oil china
FL/FR
cornmint oil terpeneless
FL/FR
dextro-neo
menthol
FL/FR
(±)-
menthol
FL/FR
laevo-
menthol
FL/FR
dextro,laevo-
menthol
FL/FR
(±)-iso
menthone
FL/FR
laevo-
menthyl acetate
FL/FR
menthyl acetate
FL/FR
peppermint cyclohexanone
FL/FR
minty
betula lenta bark oil america
FL/FR
cornmint oil japan
FL/FR
(±)-
menthone
FL/FR
(-)-
menthone
FL/FR
homo
menthyl acetate
FL/FR
laevo-
menthyl lactate
FL/FR
pennyroyal oil fractions
FL/FR
peppermint absolute
FL/FR
peppermint oil america
FL/FR
peppermint oil idaho
FL/FR
iso
pulegol
FL/FR
spearmint oil america
FL/FR
WS-23
FL/FR
naphthyl
para-
methyl anisole
FL/FR
spicy
4-
carvomenthenol
FL/FR
myrtenal
FL/FR
sulfurous
mango thiol
FL/FR
woody
(+)-
camphene
FL/FR
camphene
FL/FR
For Flavor
No flavor group found for these
(+)-
camphene
FL/FR
camphoreous
camphoreous
camphene
FL/FR
(-)-alpha-
fenchol
FL/FR
fenchol
FL/FR
laevo-
fenchone
FL/FR
geranic oxide
FL/FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
chemical
meta-
dimethyl hydroquinone
FL/FR
cooling
(2S,5R)-N-[4-(2-
amino-2-oxoethyl)phenyl]-5-methyl-2-(propan-2-yl)cyclohexanecarboxamide
FL
iso
butyl salicylate
FL/FR
4-
carvomenthenol
FL/FR
1,4-
cineole
FL/FR
beta-homo
cyclocitral
FL/FR
1,3-
dihydroxyacetone (dimer)
FL
dextro-
fenchone
FL/FR
1-(2-
hydroxy-4-methyl cyclohexyl) ethanone
FL
jambu oleoresin
FL/FR
spike
lavender oil
FL/FR
manzanate (Givaudan)
FL/FR
iso
menthol
FL
laevo-
menthol
FL/FR
dextro,laevo-
menthol
FL/FR
laevo-
menthone 1,2-glycerol ketal
FL
menthyl acetate
FL/FR
homo
menthyl acetate
FL/FR
laevo-
menthyl lactate
FL/FR
mono
menthyl succinate
FL
2-(4-
methylphenoxy)-N-(1H-pyrazol-3-yl)-N-(thiophen-2-ylmethyl)acetamide
FL
peppermint oil america
FL/FR
N-(2-(
pyridin-2-yl)ethyl)-3-para-menthane carboxamide
FL
sabinene hydrate
FL/FR
theaspirane
FL/FR
WS-12
FL
WS-3
FL
WS-5
FL
earthy
panax quinquefolius root extract
FL
floral
dihydrocarvyl acetate
FL/FR
fruity
pineapple pentenoate
FL/FR
tropical trithiane
FL/FR
vanilla carboxylate
FL/FR
green
cyclohexyl formate
FL/FR
ocimene quintoxide
FL/FR
iso
phorone
FL
3,5,5-
trimethyl hexanol
FL/FR
herbal
hyssop oil
FL/FR
mentholic
cornmint oil terpeneless
FL/FR
(±)-
menthol
FL/FR
dextro-neo
menthol
FL/FR
peppermint cyclohexanone
FL/FR
minty
betula lenta bark oil america
FL/FR
1,8-
cineole
FL/FR
cornmint oil china
FL/FR
cornmint oil japan
FL/FR
limonene glycol
FL
(±)-iso
menthone
FL/FR
(±)-
menthone
FL/FR
(-)-
menthone
FL/FR
laevo-
menthyl acetate
FL/FR
myrtenal
FL/FR
myrtenol
FL/FR
pennyroyal oil fractions
FL/FR
peppermint absolute
FL/FR
peppermint oil idaho
FL/FR
iso
pulegol
FL/FR
spearmint oil america
FL/FR
WS-23
FL/FR
naphthyl
para-
methyl anisole
FL/FR
solvent
cyclohexyl acetate
FL/FR
sulfurous
mango thiol
FL/FR
terpenic
para-
menthatriene
FL
woody
iso
bornyl formate
FL/FR
 
Potential Uses:
FRmint
 refreshing agents
FRspice
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
1,4-dioxaspiro(4.5)decane-2-methanol, 9-methyl-6-(1-methylethyl)-
1,4-dioxaspiro[4.5]decane-2-methanol, 9-methyl-6-(1-methylethyl)-
 frescolat MGA (Symrise)
 frescolat racemic MGA
 koolada-07 synthetic
dextro,laevo-menthone 1,2-glycerol ketal
DL-menthone 1,2-glycerol ketal
DL-menthone glycerine acetal
L-menthone glycerine acetal
DL-menthone glycerol ketal
L-menthone-1,2-glycerol ketal
L-menthone-1,2-glyceryl ketal
dextro,laevo-9-methyl-6-(1-methyl ethyl)-1,4-dioxaspiro(4.5)decane-2-methanol
DL-9-methyl-6-(1-methyl ethyl)-1,4-dioxaspiro(4.5)decane-2-methanol
9-methyl-6-(1-methylethyl)-1,4-dioxaspiro(4.5)decane-2-methanol
[9-methyl-6-(methylethyl)-1,4-dioxaspiro[4.5]dec-2-yl]methan-1-ol
(9-methyl-6-propan-2-yl-1,4-dioxaspiro[4.5]decan-2-yl)methanol
6-isopropyl-9-methyl-1,4-dioxaspiro(4.5)decane-2-methanol
dextro,laevo-6-6-isopropyl-9-methyl-1,4-dioxaspiro(4.5)decane-2-methanol
DL-6-6-isopropyl-9-methyl-1,4-dioxaspiro(4.5)decane-2-methanol
(6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]dec-2-yl)methanol
6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decane-2-methanol
 rightcool menthyl glycerin acetal
 
 
Notes:
Flavour enhancer for chewing gum and other low moisture foods
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