methyl 3-mercaptobutanoate
 
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IUPAC name :methyl 3-sulfanylbutanoate
InChI :InChI=1/C5H10O2S/c1-4(8)3-5(6)7-2/h4,8H,3H2,1-2H3
InChIKey :BHDKXXOGPCSBQI-UHFFFAOYAK
SMILES :CC(CC(=O)OC)S
cas number :54051-19-3
fema number :4167
jecfa number :1674
fl. number :12.290
molar refractivity :34.84 ± 0.3 cm3
parachor :305.0 ± 4.0 cm3
index of refraction :1.452 ± 0.02
surface tension :31.2 ± 3.0 dyne/cm
density :1.040 ± 0.06 g/cm3
polarizability :13.81 ± 0.5 10-24cm3
xlogp : 1.00
molecular weight : 134.1967000
formula :C5 H10 O2 S
 
 
fda reg :unspecified h. number :unspecified
 
organoleptics : 
odor description :
pungent onion
properties : 
appearence :colorless to pale yellow clear liquid
assay : 98.00 - 100.00 %   
Food Chemicals Codex Listed :No
specific gravity :1.05300 - 1.05700 @ 25.00 °C.
pounds per gallon - calc. : 8.762 to 8.795
refractive index :1.45300 - 1.45900 @ 20.00 °C.
boiling point : 171.00 - 172.00 °C. @ 760.00 mm Hg
boiling point : 75.00 °C. @ 16.00 mm Hg
logp : 1.22
safety : 
Oral Toxicity(LD50) : Not determined
Dermal Toxicity(LD50) : Not determined
  
flash point ( Deg. F. ) : 137.00  °F.  TCC  ( 58.33 °C. )
  
recommendation for methyl 3-mercaptobutanoate usage levels up to :
 not for fragrance use.
  
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
publication number : 22.
4167 average usual ppmaverage maximum ppm
baked goods : 0.500001.00000
beverages(nonalcoholic) : 0.200001.00000
beverages(alcoholic) : 0.200000.40000
breakfast cereal : --
cheese : --
chewing gum : 1.000002.00000
condiments / relishes : 0.200000.40000
confectionery froastings : --
egg products : --
fats / oils : --
fish products : --
frozen dairy : 0.300000.60000
fruit ices : --
gelatins / puddings : 0.300000.60000
granulated sugar : --
gravies : 0.200000.40000
hard candy : 0.400000.80000
imitation dairy : 0.200000.40000
instant coffee / tea : 0.200000.40000
jams / jellies : --
meat products : --
milk products : 0.200000.40000
nut products : --
other grains : --
poultry : --
processed fruits : --
processed vegetables : --
reconstituted vegetables : --
seasonings / flavors : --
snack foods : --
soft candy : 0.300000.60000
soups : 0.200000.40000
sugar substitutes : --
sweet sauces : --
safety links : 
chemidplus :54051-19-3
epa-srs :54051-19-3
  
other : 
 
references : 
jecfa number :1674
fl. number :12.290
pubchem :45645740
  
synonyms :
3-mercaptobutanoic acid methyl ester
 methyl 3-mercaptobutanoate
soluble in :
 alcohol
insoluble in :
 water
(odor and/or flavor) blends with :
 allyl disulfide
 allyl methyl disulfide
 allyl methyl trisulfide
 allyl propyl sulfide
 allyl sulfide
isoamyl mercaptan
 asafetida oil
2,3-butane diol
 butyl mercaptan
 cyclopentyl mercaptan
 diallyl tetrasulfide
 dicyclohexyl disulfide
 diethyl trisulfide
 dimethyl sulfide
(Z+E)-2,5-dimethyl-3-tetrahydrofuran thiol
 dipropyl disulfide
 dipropyl trisulfide
 ethyl 3-(furfuryl thio) propionate
 ethyl propyl disulfide
S-ethyl thioacetate
 furfuryl thiopropionate
 heptyl mercaptan
1-para-menthene-8-thiol
3-mercapto-2-methyl pentanol
(R*,S*)-2-mercapto-3-butanol
 methyl 2-methyl-3-furyl disulfide
 methyl 3-(methyl thio) propionate
2-methyl 5-(methyl thio) furan
 methyl propyl trisulfide
3-(methyl thio) hexanol
3-(methyl thio) propanol
2-methyl-1-butanol
 onion oil
 propenyl propyl disulfide
 propyl mercaptan
 propyl thioacetate
2,3,5-trithiahexane
(odor and/or flavor) used in :
 asafoetida
 chive
 durian
 garlic
 jackfruit
 leek
 onion
 savory
 scallion
 shallot
natural occurrence in :
found in nature



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