EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

laevo-camphor
bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1S)-

Supplier Sponsors

Name:(1S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
CAS Number: 464-48-2Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:207-354-7
FDA UNII:213N3S8275
Beilstein Number:1907612
MDL:MFCD00064148
XlogP3-AA:2.20 (est)
Molecular Weight:152.23672000
Formula:C10 H16 O
NMR Predictor:Predict (works with chrome or firefox)
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:white crystals (est)
Assay: 97.00 to 100.00
Food Chemicals Codex Listed: No
Optical Rotation:-41.00 to -45.00
Melting Point: 178.00 to 180.00 °C. @ 760.00 mm Hg
Boiling Point: 207.42 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.040000 mmHg @ 20.00 °C.
Vapor Density:5.24 ( Air = 1 )
Flash Point: 149.00 °F. TCC ( 65.00 °C. )
logP (o/w): 2.089 (est)
Soluble in:
 alcohol
 water, 339.1 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: camphoreous
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
camphoreous
Odor Description:at 10.00 % in dipropylene glycol. camphor
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
L(-)-Camphor >96.0%(GC)
EMD Millipore
For experimental / research use only.
(1S)-(-)-Camphor
ExtraSynthese
For experimental / research use only.
(-)-Camphor (GC) ≥95%
Santa Cruz Biotechnology
For experimental / research use only.
(1S)-(-)-Camphor
Sigma-Aldrich: Aldrich
For experimental / research use only.
(1S)-(-)-Camphor 99%
TCI AMERICA
For experimental / research use only.
(-)-Camphor >96.0%(GC)
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 0.80 mg/kg
Journal of Pharmacology and Experimental Therapeutics. Vol. 1, Pg. 445, 1909.

intravenous-mouse LD50 320 mg/kg
Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02534

intravenous-mouse LD50 320 mg/kg
U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02534

oral-rat LDLo 800 ug/kg
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Journal of Pharmacology and Experimental Therapeutics. Vol. 1, Pg. 445, 1909.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
flavor and fragrance agents
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for laevo-camphor usage levels up to:
  5.0000 % in the fragrance concentrate.
 
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Camphor in flavourings and other food ingredients with flavouring properties - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food on a request from the Commission
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):464-48-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :10050
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 2717
WGK Germany:1
(1S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
Chemidplus:0000464482
EPA/NOAA CAMEO:hazardous materials
RTECS:EX1250000 for cas# 464-48-2
 
References:
Leffingwell:Chirality or Article
 (1S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):10050
Pubchem (sid):135269914
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
KEGG (GenomeNet):C00809
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2914.21.2000
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
fenchone
FL/FR
laurel leaf concrete
FR
yarrow oil greece
FL/FR
yarrow oil hungary
FL/FR
achillea tenuifolia lam. flower oil iran
FR
tert-
butanol
FL/FR
laurel leaf absolute
FL/FR
6-
methyl-2-heptanone
FL/FR
2-
methyl-3-butanone
FL/FR
yarrow oil
FL/FR
anisic
anisic
bitter
fennel seed oil spain
FR
balsamic
balsam fir oleoresin
FL/FR
dextro-
borneol
FL/FR
dextro,laevo-
borneol
FL/FR
dextro,laevo-iso
borneol
FL/FR
laevo-
borneol
FL/FR
bornyl acetate
FL/FR
iso
bornyl acetate
FL/FR
laevo-
bornyl acetate
FL/FR
iso
bornyl formate
FL/FR
bornyl formate
FL/FR
iso
bornyl isobutyrate
FL/FR
iso
bornyl methyl ether
FL/FR
iso
bornyl propionate
FL/FR
dextro-
fenchone
FL/FR
fenchyl acetate
FL/FR
fir balsam absolute
FR
fir balsam absolute replacer
FL/FR
fir carboxylate
FR
fir needle oil canada
FL/FR
fir needle oil terpeneless canada
FL/FR
juniper berry oil terpeneless
FL/FR
pine needle absolute
FL/FR
spruce needle absolute
FL/FR
terpinyl benzoate
FR
camphoreous
3-
benzylidene-2-butanone
FL/FR
bornyl isobutyrate
FL/FR
butyrophenone
FL/FR
alpha-
campholenic alcohol
FL/FR
(±)-
camphor
FL/FR
dextro-
camphor
FL/FR
camphor tree bark oil
FL/FR
cyclademol
FR
beta-homo
cyclocitral
FL/FR
cyclohexanol
FL/FR
fenchol
FL/FR
laevo-
fenchone
FL/FR
herbal ethanone
FR
hinoki leaf oil
FR
thujyl alcohol
FL/FR
verbenone
FL/FR
earthy
2-
ethyl fenchol
FL/FR
(-)-alpha-
fenchol
FL/FR
ethereal
methyl ethyl ketone
FL/FR
fir needle
abies amabilis oil canada
FR
floral
iso
amyl salicylate
FL/FR
bois de rose oil peru
FL/FR
karo karounde absolute
FR
lavandula angustifolia flower oil
FL/FR
lavender oil
FL/FR
lavender oil france
FL/FR
lavender oil greece
FL/FR
linalool oxide (furanoid)
FL/FR
mimosa absolute morocco
FL/FR
nonisyl propionate
FR
terpinyl isobutyrate
FL/FR
fruity
cherry propanol
FL/FR
green
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
dicyclopentadiene propionate
FR
privet dioxane
FR
herbal
acorus calamus rhizome oil
FR
1-
allyl-2,2,7,7-tetramethyl cycloheptanol
FR
anethum graveolens herb oil
FL/FR
artemisia diffusa krasch. ex poljak oil iran
FR
artemisia vestita wall. leaf oil
FR
barosma betulina leaf oil
FL/FR
bornyl 2-methyl butyrate
FL/FR
bornyl butyrate
FL/FR
(-)-
bornyl isovalerate
FL/FR
bornyl salicylate
FR
beta-
bourbonene
FL/FR
carvacryl methyl ether
FL/FR
chamomile oil morocco
FR
1,8-
cineole
FL/FR
1,4-
cineole
FL/FR
dimethyl cyclormol (IFF)
FR
2,10-
epoxypinane
FR
freesia heptanol
FL/FR
geranic oxide
FL/FR
herbal acetal
FR
herbal dioxane
FR
herbal undecanol
FR
herbal undecanone
FR
hexanol
FL/FR
hop oil
FL/FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
hyssop oil
FL/FR
immortelle flower oil
FL/FR
juniparome (Takasago)
FR
lavandin concrete
FL/FR
abrialis
lavandin oil
FL/FR
spike
lavender absolute
FL/FR
spike
lavender oil
FL/FR
spike
lavender oil spain
FL/FR
linalyl acetate
FL/FR
melaleuca leucadendron var. cajuputi leaf oil
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
2-
methyl butyl salicylate
FL/FR
methyl cyclogeranate (Firmenich)
FR
myrtenol
FL/FR
myrtle oil
FL/FR
niaouli oil
FR
3-
octanon-1-ol
FL/FR
origanum oil
FL/FR
origanum oil greece
FL/FR
curled
parsley leaf oil
FL/FR
alpha-
pinene
FL/FR
pinocarveol
FL/FR
piperitone
FL/FR
rosemary absolute
FL/FR
rosemary oil egypt
FL/FR
rosemary oil morocco
FL/FR
rosemary oil spain
FL/FR
sabinene hydrate
FL/FR
safranal
FL/FR
sage absolute spain
FL/FR
tea leaf absolute
FL/FR
white
thyme oil
FL/FR
thyme oil (thymus zygis gracillis) spain
FL/FR
thymol
FL/FR
thymyl methyl ether
FL/FR
tricyclodecenyl propionate
FR
mentholic
laevo-
menthol
FL/FR
(±)-iso
menthone
FL/FR
peppermint cyclohexanone
FL/FR
iso
pulegyl acetate
FL/FR
minty
artemisia deserti krasch. oil iran
FR
dextro-
dihydrocarvone
FL/FR
(-)-
menthone
FL/FR
pennyroyal oil
FL/FR
(R)-(+)-
pulegone
FR
naphthyl
para-
methyl anisole
FL/FR
ortho-
methyl anisole
FL/FR
1-
methyl naphthalene
FL/FR
phenolic
methyl benzoate
FL/FR
pine
fir balsam oleoresin canada
FL/FR
spicy
ayou wood oil
FR
carvacrol
FL/FR
caryophyllene
FL/FR
black
currant bud absolute
FL/FR
elettaria cardamomum seed oil
FL/FR
galangal root oil
FL/FR
laurel berry absolute
FL/FR
laurus nobilis fruit oil
FL/FR
laurus nobilis leaf oil
FL/FR
laurus nobilis leaf oil turkey
FL/FR
marjoram oil (thymus mastichina) spain
FL/FR
myrtenal
FL/FR
origanum majorana oil
FL/FR
origanum majorana oil cuba
FL/FR
black
pepper oil CO2 extract
FL/FR
white
sassafras oil
FL/FR
laevo-
verbenone
FL/FR
zvoulimba leaf oil
FR
sulfurous
grapefruit menthane
FL/FR
terpenic
juniperus communis fruit oil
FL/FR
thujonic
armoise oil
FR
cedarleaf oil terpeneless
FR
sage oil (salvia lavandulifolia vahl.) spain
FL/FR
common
tansy flower oil argentina
FL/FR
woody
abies grandis oil canada
FR
abies lasiocarpa oil canada
FR
iso
bornyl isovalerate
FL/FR
bornyl valerate
FL/FR
2-tert-
butyl cyclohexanone
FR
(+)-
camphene
FL/FR
(-)-
camphene
FL/FR
camphene
FL/FR
dihydro-alpha-terpinyl acetate
FR
hinoki root oil
FR
juniper needle oil
FR
longifolene
FL/FR
orris hexanone
FR
patchouli absolute
FR
patchouli ethanol
FR
patchouli hexanol
FR
patchouli oil
FL/FR
cis-2-
pinanol
FR
iso
pinocamphone
FL/FR
sabinene
FL/FR
sandal glycol acetal
FR
sandalwood oil
FL/FR
spruce needle oil canada
FL/FR
zedoary bark oil
FL/FR
For Flavor
No flavor group found for these
balsam fir oleoresin
FL/FR
3-
benzylidene-2-butanone
FL/FR
dextro-
borneol
FL/FR
dextro,laevo-
borneol
FL/FR
bornyl 2-methyl butyrate
FL/FR
bornyl butyrate
FL/FR
bornyl formate
FL/FR
bornyl isobutyrate
FL/FR
(-)-
bornyl isovalerate
FL/FR
iso
bornyl methyl ether
FL/FR
beta-
bourbonene
FL/FR
tert-
butanol
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
butyrophenone
FL/FR
(-)-
camphene
FL/FR
(+)-
camphene
FL/FR
alpha-
campholenic alcohol
FL/FR
carvacryl methyl ether
FL/FR
cyclohexanol
FL/FR
2,6-
dimethyl-1,5,7-octatrien-3-ol
FL
epoxyoxophorone
FL
fenchone
FL/FR
fir balsam oleoresin canada
FL/FR
fir needle oil canada
FL/FR
laurel berry absolute
FL/FR
laurus nobilis fruit oil
FL/FR
laurus nobilis leaf oil
FL/FR
laurus nobilis leaf oil turkey
FL/FR
linalool oxide (furanoid)
FL/FR
melaleuca leucadendron var. cajuputi leaf oil
FL/FR
2-
methyl butyl salicylate
FL/FR
3-
methyl cyclohexanone
FL
6-
methyl-2-heptanone
FL/FR
2-
methyl-3-butanone
FL/FR
3-
octanon-1-ol
FL/FR
(Z,Z)-
photocitral A
FL
pine needle absolute
FL/FR
iso
pinocamphone
FL/FR
white
sassafras oil
FL/FR
terpinyl isobutyrate
FL/FR
laevo-
verbenone
FL/FR
verbenone
FL/FR
yarrow oil
FL/FR
yarrow oil greece
FL/FR
yarrow oil hungary
FL/FR
laurel leaf absolute
FL/FR
thujyl alcohol
FL/FR
balsamic
balsamic
laevo-
bornyl acetate
FL/FR
iso
bornyl isobutyrate
FL/FR
iso
bornyl propionate
FL/FR
fir balsam absolute replacer
FL/FR
fir needle oil terpeneless canada
FL/FR
spruce needle absolute
FL/FR
camphoreous
dextro,laevo-iso
borneol
FL/FR
laevo-
borneol
FL/FR
bornyl acetate
FL/FR
camphene
FL/FR
(±)-
camphor
FL/FR
camphor tree bark oil
FL/FR
(-)-alpha-
fenchol
FL/FR
fenchol
FL/FR
laevo-
fenchone
FL/FR
geranic oxide
FL/FR
6-
hydroxydihydrotheaspirane (mixture of isomers)
FL/FR
ortho-
methyl anisole
FL/FR
pinocarveol
FL/FR
chemical
methyl ethyl ketone
FL/FR
citrus
freesia heptanol
FL/FR
cooling
1,4-
cineole
FL/FR
beta-homo
cyclocitral
FL/FR
dextro-
fenchone
FL/FR
spike
lavender oil
FL/FR
laevo-
menthol
FL/FR
sabinene hydrate
FL/FR
earthy
2-
ethyl fenchol
FL/FR
floral
bois de rose oil peru
FL/FR
linalyl acetate
FL/FR
mimosa absolute morocco
FL/FR
fruity
cherry propanol
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
green
iso
amyl salicylate
FL/FR
dextro-
dihydrocarvone
FL/FR
hexanol
FL/FR
iso
phorone
FL
herbal
anethum graveolens herb oil
FL/FR
barosma betulina leaf oil
FL/FR
hop oil
FL/FR
hyssop oil
FL/FR
immortelle flower oil
FL/FR
lavandin concrete
FL/FR
abrialis
lavandin oil
FL/FR
lavandula angustifolia flower oil
FL/FR
spike
lavender absolute
FL/FR
lavender oil
FL/FR
lavender oil france
FL/FR
lavender oil greece
FL/FR
spike
lavender oil spain
FL/FR
origanum majorana oil
FL/FR
origanum oil
FL/FR
origanum oil greece
FL/FR
curled
parsley leaf oil
FL/FR
rosemary absolute
FL/FR
rosemary oil egypt
FL/FR
rosemary oil morocco
FL/FR
rosemary oil spain
FL/FR
sage absolute spain
FL/FR
sage oil (salvia lavandulifolia vahl.) spain
FL/FR
white
thyme oil
FL/FR
thyme oil (thymus zygis gracillis) spain
FL/FR
medicinal
dextro-
camphor
FL/FR
mentholic
peppermint cyclohexanone
FL/FR
minty
1,8-
cineole
FL/FR
(-)-
menthone
FL/FR
(±)-iso
menthone
FL/FR
myrtenal
FL/FR
myrtenol
FL/FR
pennyroyal oil
FL/FR
piperitone
FL/FR
musty
thymyl methyl ether
FL/FR
naphthyl
para-
methyl anisole
FL/FR
1-
methyl naphthalene
FL/FR
phenolic
methyl benzoate
FL/FR
thymol
FL/FR
spicy
carvacrol
FL/FR
caryophyllene
FL/FR
cubeb oleoresin
FL
black
currant bud absolute
FL/FR
elettaria cardamomum seed oil
FL/FR
galangal root oil
FL/FR
marjoram oil (thymus mastichina) spain
FL/FR
myrtle oil
FL/FR
origanum majorana oil cuba
FL/FR
black
pepper oil CO2 extract
FL/FR
sulfurous
grapefruit menthane
FL/FR
tea
tea leaf absolute
FL/FR
terpenic
juniperus communis fruit oil
FL/FR
thujonic
common
tansy flower oil argentina
FL/FR
woody
iso
bornyl acetate
FL/FR
iso
bornyl formate
FL/FR
iso
bornyl isovalerate
FL/FR
bornyl valerate
FL/FR
fenchyl acetate
FL/FR
juniper berry oil terpeneless
FL/FR
longifolene
FL/FR
patchouli oil
FL/FR
alpha-
pinene
FL/FR
iso
pulegyl acetate
FL/FR
sabinene
FL/FR
safranal
FL/FR
sandalwood oil
FL/FR
spruce needle oil canada
FL/FR
zedoary bark oil
FL/FR
 
Potential Uses:
FLabsinthe
FRacacia
FRagate
FRagrumen aldehyde
FL/FRajowan
FRallspice
FRallspice
FRalpine bouquet
FL/FRangelica
FRarnica flower
FRash mountain ash berry
FRbasil oil replacer
FRbay rum
FRbayberry
FRbayberry
FRblue grass
 boldus oil replacer
FLbuchu leaf
FL/FRcajeput
FRcalamus oil replacer
FL/FRcamphor tree bark
FLcapsicum
FL/FRcaraway seed
FRcardamom oil replacer
FRcarnation
FLcarrot
FL/FRcarrot seed
FRcassia
FRcassia blossom
FRcelery
FRchamomile
FLchervil
FRchrysanthemum
FL/FRcilantro
FRcinnamon
FRclary sage oil replacer
FRclove
FL/FRcopaiba balsam
FL/FRcoriander
FRcountry meadow
FRcranberry
FL/FRcroton eluteria bark
FL/FRcubeb
FRcumin oil replacer
FL/FRcurrant bud absolute replacer
FL/FRcurry leaf
FRcypress oil replacer
FRdeertongue absolute replacer
FL/FRdill weed
FRdogwood
FRelder flower
FReucalyptus oil replacer
FRfennel
FRfig
FRflouve
FRforest
FL/FRgalangal root
FRgenet
FRgeranium
FLgin
FRginger
FRginger white ginger
FRgingerbread
FRgingergrass
FRgraham cracker
FL/FRguaiacwood
FRhabuba
FRheather
FRherbal
FRhinoki oil replacer
FRhollyberry
FRhop
FL/FRhyssop
FRivy
FRjonquil
FRlavandin
FRlavender
FL/FRlavender flower
FL/FRlavender spike lavender
FL/FRlovage root
FRmace
FRmaja
FL/FRmarigold
FL/FRmarjoram
FRmelissa oil replacer
FRmimosa
FLmustard
FRmyrrh
FRmyrtle oil replacer
FRniaouli
FRnutmeg
FRoregano
FRosmanthus
FL/FRparsley leaf
 parsnip
FRpepper
FL/FRpepper black pepper
 pepper chili pepper
FLpepper tabasco pepper
FL/FRpepper tree berry
FRpine forest
FL/FRpine needle
FRpizza
FRpumpkin pie
FRreseda
FRroot beer
FRrose dog rose
FRrose moss rose
FRrosemary
FL/FRrue
FRsaffron
FLsarsaparilla
FRsassafras
FL/FRsavin
FL/FRsnake root
FRspice
FRspicewood
FRspikenard oil replacer
FRspruce
FRsweet grass
FL/FRtansy oil replacer
FLtea
FLtea black tea
FLtea black tea
 tea china
FRtea green tea
FLtea herbal tea
FLtea lemon tea
FRthyme oil white replacer
FRtolu balsam
FL/FRvalerian
FLwasabi
 watercress nasturtium
FRwitch hazel
FRwoodruff
FLworcestershire sauce
FRwormwood oil replacer
FL/FRyerba mate
FRyew
 
Occurrence (nature, food, other):note
 armoise
Search Trop Picture
 matricaria parthenium
Search Trop Picture
 salvia grandiflora
Search Trop Picture
 
Synonyms:
(-)-alcanfor
 bicyclo(2.2.1)heptan-2-one, 1,7,7-trimethyl-, (1S,4S)-
 bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1S)-
(-)-bornan-2-one
(-)-2-bornanone
(1S,4S)-(-)-camphor
(1S)-camphor
(1S)-(-)-camphor
L-camphor
laevo-(-)-camphor
 camphor, (1S,4S)-(-)-
 camphor, L-, (-)-
(1S,4R)-(-)-1,3,3-trimethyl bicyclo(2.2.1)heptan-2-one
(1S,4S)-1,7,7-trimethyl bicyclo(2.2.1)heptan-2-one
(1S)-1,7,7-trimethyl bicyclo(2.2.1)heptan-2-one
(1S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
 
 
Notes:
None found
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