geranic oxide
limetol (Givaudan)

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  500913 Limetol

Name: 2-ethenyl-2,6,6-trimethyloxane CAS Number: 7392-19-0 3D/inchi Other(deleted CASRN): 13837-56-4 ECHA EINECS - REACH Pre-Reg: 230-983-3 FDA UNII: V3824Q785M Nikkaji Web: J100.127B CoE Number: 10976 XlogP3-AA: 2.40 (est) Molecular Weight: 154.25266000 Formula: C10 H18 O NMR Predictor: Predict (works with chrome, Edge or firefox) Category:flavor and fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search JECFA Food Flavoring: 1236 2,2,6-trimethyl-6-vinyltetrahydropyran DG SANTE Food Flavourings: 13.094 2,6,6-trimethoxy-2-vinyltetrahydropyran FEMA Number: 3735 2,2,6-trimethyl-6-vinyltetrahydropyran FDA: No longer provide for the use of these seven synthetic flavoring substances FDA Mainterm (SATF): 7392-19-0 ; 2,2,6-TRIMETHYL-6-VINYLTETRAHYDROPYRAN   Physical Properties: Appearance: colorless clear liquid (est) Assay: 99.00 to 100.00 sum of isomers Food Chemicals Codex Listed: No Boiling Point: 170.00 to 171.00 °C. @ 760.00 mm Hg Vapor Pressure: 1.904000 mmHg @ 25.00 °C. (est) Flash Point: 136.00 °F. TCC ( 57.78 °C. ) logP (o/w): 3.020 (est) Soluble in:   alcohol   water, 70.97 mg/L @ 25 °C (est) Insoluble in:   water Stability:   detergent   soap   Organoleptic Properties: Odor Type: herbal Odor Strength:medium , recommend smelling in a 10.00 % solution or less Substantivity:4 hour(s) at 20.00 % fresh camphoreous herbal rosemary Odor Description:at 10.00 % in dipropylene glycol. fresh camphor herbal rosemary Luebke, William tgsc, (1985) Odor sample from: Roure Bertrand Dupont Inc. sweet floral citrus woody cooling minty camphoreous Odor Description:Sweet, floral, citrus with woody, cooling, minty and camphoreous nuances Mosciano, Gerard P&F 18, No. 3, 53, (1993) Flavor Type: camphoreous sweet camphoreous woody cooling floral Taste Description: at 20.00 ppm. Sweet, camphoreous, woody, cooling, with floral nuances Mosciano, Gerard P&F 18, No. 3, 53, (1993) Odor and/or flavor descriptions from others (if found). Bedoukian Research 2,2,6-TRIMETHYL-6-VINYLTETRAHYDROPYRAN ≥95.0%, Kosher Odor Description:A fresh camphor, herbal, rosemary odor Blends well with marjoram and lavender; also can be used in bois de rose and geranium. Taste Description:herbal Used in berry, blueberry, tea and other floral flavors. Givaudan Limetol Odor Description:Fresh, Camphoraceous, Woody, Cineole-Lime Limetol is used where a lemon-woody note is desired. It also offers pine needle and lime nuances. Taste Description:sweet camphor woody cooling floral Indukern F&F LIMETOL Odor Description:CITRUS, FRESH, TERPENIC, MENTHOLATED Moellhausen LIMETOL Odor Description:Fresh, Camphoraceous, Woody, Cineole-Lime Taste Description:sweet camphor woody cooling floral   Cosmetic Information: CosIng: cosmetic data2 CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: BOC Sciences For experimental / research use only. 2,2,6-Trimethyl-6-vinyltetrahydropyran Givaudan Limetol Odor: Fresh, Camphoraceous, Woody, Cineole-Lime Use: Limetol is used where a lemon-woody note is desired. It also offers pine needle and lime nuances. Indukern F&F LIMETOL Odor: CITRUS, FRESH, TERPENIC, MENTHOLATED Lluch Essence LIMETOL Moellhausen LIMETOL Penta International 2,2,6-TRIMETHYL-6-VINYLTETRAHYDROPYRAN NATURAL Penta International 2,2,6-TRIMETHYL-6-VINYLTETRAHYDROPYRAN Santa Cruz Biotechnology For experimental / research use only. Limetol The Perfumers Apprentice Limetol (G) Odor: Fresh, Camphoraceous, Woody, Cineole-Lime-like Use: Used where a lemon-woody note is desired. Also gives a pine needle and lime nuance Vigon International Limetol Odor: Fresh, Camphoraceous, Woody, Cineole-Lime   Safety Information: European information : Most important hazard(s): Xi - Irritant R 10 - Flammable. R 38 - Irritating to skin. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: oral-rat LD50 [sex: M,F] 2700 - 2800 mg/kg (Sauer-Freeman, 1980) oral-mouse LD50 [sex: M,F] 4000 - 8000 mg/kg (Roure Bertrand Dupont, 1979) Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: flavor and fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for geranic oxide usage levels up to:   3.0000 % in the fragrance concentrate.   Maximised Survey-derived Daily Intakes (MSDI-EU): 0.024 (μg/capita/day) Maximised Survey-derived Daily Intakes (MSDI-USA): 8.00 (μg/capita/day) Structure Class: II Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library publication number: 13. Update in publication number(s): 14 Click here to view publication 13   average usual ppm average maximum ppm baked goods: - - beverages(nonalcoholic): - 0.50000 beverages(alcoholic): - - breakfast cereal: - - cheese: - - chewing gum: - - condiments / relishes: - - confectionery froastings: - 1.00000 egg products: - - fats / oils: - - fish products: - - frozen dairy: - - fruit ices: - - gelatins / puddings: - 2.00000 granulated sugar: - - gravies: - - hard candy: - - imitation dairy: - - instant coffee / tea: - - jams / jellies: - - meat products: - - milk products: - - nut products: - - other grains: - - poultry: - - processed fruits: - - processed vegetables: - - reconstituted vegetables: - - seasonings / flavors: - - snack foods: - - soft candy: - 0.50000 soups: - - sugar substitutes: - - sweet sauces: - -   Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 23 (FGE.23): Aliphatic, alicyclic and aromatic ethers including anisole derivatives From chemical groups 15, 16 and 26 (Commission Regulation (EC) No 1565/2000 of 18 July 2000 View page or View pdf Flavouring Group Evaluation 59 (FGE.59): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 (2006) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf Flavouring Group Evaluation 23, Revision 1 (FGE.23Rev1): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 26 and 30[1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf Flavouring Group Evaluation 33 (FGE.33)[1] - Six Tetrahydrofuran Derivatives from Chemical Groups 13, 14, 16 and 26 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010) View page or View pdf EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):7392-19-0 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :522514 National Institute of Allergy and Infectious Diseases:Data WISER:UN 1993 WGK Germany:2 2-ethenyl-2,6,6-trimethyloxane Chemidplus:0007392190   References:   2-ethenyl-2,6,6-trimethyloxane NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 7392-19-0 Pubchem (cid): 522514 Pubchem (sid): 135264600   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements FDA Substances Added to Food (formerly EAFUS): View CHEBI: View HMDB (The Human Metabolome Database): HMDB37133 FooDB: FDB016128 Export Tariff Code: 2932.99.6560 Typical G.C. VCF-Online: VCF Volatile Compounds in Food ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these fenchone FL/FR laurel leaf absolute FL/FR 2- methyl-3-butanone FL/FR balsamic balsamic laevo- borneol FL/FR dextro,laevo-iso borneol FL/FR dextro,laevo- borneol FL/FR bornyl acetate FL/FR iso bornyl acetate FL/FR iso bornyl formate FL/FR iso bornyl methyl ether FL/FR iso bornyl propionate FL/FR dextro- fenchone FL/FR camphoreous 3- benzylidene-2-butanone FL/FR bornyl isobutyrate FL/FR butyrophenone FL/FR dextro- camphor FL/FR (±)- camphor FL/FR camphor tree bark oil FL/FR beta-homo cyclocitral FL/FR 2,6- dimethyl-3-oxatricyclo(4.2.1.0*2,4*)nonane FR fenchol FL/FR laevo- fenchone FL/FR herbal ethanone FR hinoki leaf oil FR thujyl alcohol FL/FR verbenone FL/FR citrus bergamot oil italy FL/FR bergamot oil ivory coast FL/FR bergamot oil terpeneless FL/FR (S)-(-)- citronellal FL/FR citrus ocimenol FR citrus woody floral fragrance FR ocimene quintoxide FL/FR tetrahydromyrcenyl acetate FR earthy (-)-alpha- fenchol FL/FR 2- octanone FL/FR floral iso amyl salicylate FL/FR anise indene FR bigarade oxide FR bois de rose oil peru FL/FR cilantro herb oil egypt FL/FR citronellyl acetate FL/FR coriander oil fractions FL/FR cyclohexyl ethyl acetate FL/FR 2- decalinol FR dihydrolinalool FL/FR dihydromyrcene FR gardenia amide FR geranium oil china FL/FR geranyl tiglate FL/FR ho leaf oil FR (Z)- jasmone FL/FR karo karounde absolute FR lavandula angustifolia flower oil FL/FR lavender oil france FL/FR menthadienyl formate FR (E)- nerolidol FL/FR nerolidol FL/FR nonisyl propionate FR petitgrain bigarade oil FL/FR prenyl salicylate FL/FR fruity 3- allyl oxy-1,4-dimethyl bicyclo(3.2.1)octane FR 3- benzyl-4-heptanone FL/FR linalyl isobutyrate FL/FR ocimen-1-yl acetate FR green agrumen aldehyde FR cilantro leaf oil FL/FR iso cyclocitral (IFF) FL/FR geranium absolute FL/FR 3,6- ivy carbaldehyde FL/FR 2,4- ivy carbaldehyde FL/FR 3,5- ivy carbaldehyde FL/FR ivy carbaldehyde FL/FR para- methyl hydratropaldehyde FL/FR herbal 6- acetoxydihydrotheaspirane FL/FR acorus calamus rhizome oil FR 1- allyl-2,2,7,7-tetramethyl cycloheptanol FR bornyl butyrate FL/FR beta- bourbonene FL/FR alpha- cadinol FL/FR 1,4- cineole FL/FR (R)-(+)- citronellal FL/FR citrus ocimenol acetate FR coriander oleoresin FL/FR iso dihydrolavandulol FR (Z)-iso dihydrolavandulyl acetate FR dihydroterpinyl acetate FL/FR dimethyl cyclormol (IFF) FR eucalyptus citriodora oil FR eucalyptus radiata leaf/stem oil FR freesia heptanol FL/FR guava leaf oil cuba FR cis- herbal cyclohexane FR herbal dioxane FR herbal undecanol FR herbal undecanone FR 6- hydroxydihydrotheaspirane (mixture of isomers) FL/FR hyssop oil FL/FR immortelle flower oil FL/FR jambu oleoresin FL/FR laurus nobilis leaf oil FL/FR spike lavender oil FL/FR methyl cyclogeranate (Firmenich) FR origanum oil FL/FR origanum oil greece FL/FR curled parsley leaf oil FL/FR petitgrain heptane FR pine hexanol FR alpha- pinene FL/FR pinocarveol FL/FR piperitone FL/FR rosemary absolute FL/FR rosemary oil FL/FR rosemary oil africa FL/FR rosemary oil egypt FL/FR rosemary oil morocco FL/FR rosemary oil spain FL/FR rosemary oil tunisia FL/FR sabinene hydrate FL/FR saffron pyranone FR tea leaf absolute FL/FR oswego tea specialty FR terpinolene FL/FR thyme oil wild or creeping FL/FR tricyclodecenyl propionate FR yarrow oil FL/FR mentholic laevo- menthyl acetate FL/FR peppermint cyclohexanone FL/FR minty dextro- dihydrocarvone FL/FR pennyroyal oil FL/FR naphthyl para- methyl anisole FL/FR pine dipentene terpene hydrocarbon byproducts FR pine oil 85 FR spicy 4- carvomenthenol FL/FR beta- caryophyllene FL/FR caryophyllene FL/FR cinnamon acrolein FL/FR cubeb oil CO2 extract (piper cubeba) FL/FR black currant bud absolute FL/FR galangal root oil FL/FR ginger oleoresin africa FL/FR ginger root oil cochin FL/FR 4-iso propyl-2-cyclohexenone FL/FR white sassafras oil FL/FR sugandha kokila berry oil FR laevo- verbenone FL/FR terpenic para- cymene FL/FR gamma- terpinene FL/FR alpha- terpineol FL/FR thujonic armoise oil FR cedarleaf oil terpeneless FR common tansy leaf oil dutch FR woody ketone FL/FR waxy decanal dimethyl acetal FL/FR woody iso bornyl isovalerate FL/FR 2-tert- butyl cyclohexanone FR (+)- camphene FL/FR camphene FL/FR cistus twig/leaf oil FL/FR 6,7- dihydrolinalool FL/FR dragons blood fragrance FR alpha- farnesene FL/FR (E)-beta- farnesene FL/FR hinoki root oil FR juniper berry oil terpenes FR iso longifolene epoxide FR marine formate FR patchouli ethanol FR patchouli hexanol FR polylimonene FL/FR spruce needle oil canada FL/FR For Flavor No flavor group found for these 6- acetoxydihydrotheaspirane FL/FR 3- benzylidene-2-butanone FL/FR dextro,laevo- borneol FL/FR bornyl butyrate FL/FR bornyl isobutyrate FL/FR iso bornyl methyl ether FL/FR beta- bourbonene FL/FR butyrophenone FL/FR delta- cadinene FL alpha- cadinol FL/FR (+)- camphene FL/FR (S)-(-)- citronellal FL/FR (R)-(+)- citronellal FL/FR decanal dimethyl acetal FL/FR 6,7- dihydrolinalool FL/FR dihydroterpinyl acetate FL/FR epoxyoxophorone FL (E)-beta- farnesene FL/FR fenchone FL/FR 2- heptyl cyclopropane carboxylic acid FL ivy carbaldehyde FL/FR 3,5- ivy carbaldehyde FL/FR 3- methyl cyclohexanone FL 1- methyl pyrrole FL 2- methyl-3-butanone FL/FR 3- octyl butyrate FL (Z,Z)- photocitral A FL piperitenone oxide FL polylimonene FL/FR 4-iso propyl-2-cyclohexenone FL/FR white sassafras oil FL/FR (E)-4- undecenal FL laevo- verbenone FL/FR verbenone FL/FR woody ketone FL/FR laurel leaf absolute FL/FR thujyl alcohol FL/FR balsamic balsamic iso bornyl propionate FL/FR camphoreous dextro,laevo-iso borneol FL/FR laevo- borneol FL/FR bornyl acetate FL/FR camphene FL/FR (±)- camphor FL/FR camphor tree bark oil FL/FR fenchol FL/FR (-)-alpha- fenchol FL/FR laevo- fenchone FL/FR 6- hydroxydihydrotheaspirane (mixture of isomers) FL/FR pinocarveol FL/FR rosemary oil tunisia FL/FR citrus bergamot oil italy FL/FR bergamot oil ivory coast FL/FR bergamot oil terpeneless FL/FR cilantro leaf oil FL/FR freesia heptanol FL/FR petitgrain bigarade oil FL/FR alpha- terpineol FL/FR cooling 4- carvomenthenol FL/FR 1,4- cineole FL/FR beta-homo cyclocitral FL/FR dextro- fenchone FL/FR jambu oleoresin FL/FR spike lavender oil FL/FR iso menthol FL sabinene hydrate FL/FR dairy 2- octanone FL/FR floral bois de rose oil peru FL/FR citronellyl acetate FL/FR dihydrolinalool FL/FR geranium oil china FL/FR geranyl tiglate FL/FR linalyl isobutyrate FL/FR fruity 3- benzyl-4-heptanone FL/FR green iso amyl salicylate FL/FR iso cyclocitral (IFF) FL/FR cyclohexyl ethyl acetate FL/FR dextro- dihydrocarvone FL/FR alpha- farnesene FL/FR geranium absolute FL/FR 2,4- ivy carbaldehyde FL/FR 3,6- ivy carbaldehyde FL/FR para- methyl hydratropaldehyde FL/FR (E)- nerolidol FL/FR nerolidol FL/FR ocimene quintoxide FL/FR iso phorone FL herbal cilantro herb oil egypt FL/FR coriander oil fractions FL/FR coriander oleoresin FL/FR hyssop oil FL/FR immortelle flower oil FL/FR laurus nobilis leaf oil FL/FR lavandula angustifolia flower oil FL/FR lavender oil france FL/FR origanum oil FL/FR origanum oil greece FL/FR curled parsley leaf oil FL/FR prenyl salicylate FL/FR rosemary absolute FL/FR rosemary oil FL/FR rosemary oil africa FL/FR rosemary oil egypt FL/FR rosemary oil morocco FL/FR rosemary oil spain FL/FR thyme oil wild or creeping FL/FR yarrow oil FL/FR medicinal dextro- camphor FL/FR mentholic peppermint cyclohexanone FL/FR minty laevo- menthyl acetate FL/FR pennyroyal oil FL/FR piperitone FL/FR naphthyl para- methyl anisole FL/FR spicy caryophyllene FL/FR beta- caryophyllene FL/FR cinnamon acrolein FL/FR cubeb oil CO2 extract (piper cubeba) FL/FR black currant bud absolute FL/FR galangal root oil FL/FR ginger oleoresin africa FL/FR ginger root oil cochin FL/FR tea tea leaf absolute FL/FR terpenic para- cymene FL/FR gamma- terpinene FL/FR woody iso bornyl acetate FL/FR iso bornyl formate FL/FR iso bornyl isovalerate FL/FR cistus twig/leaf oil FL/FR (Z)- jasmone FL/FR alpha- pinene FL/FR spruce needle oil canada FL/FR terpinolene FL/FR   Potential Uses: FR berry FR blueberry FR bois de rose FL/FR camphor tree bark FL champagne FL cola FR fir needle oil replacer FR floral FR geranium FR herbal FR lavender FL/FR marjoram FR mint FR oregano FR rosemary FL tea FR woody   Occurrence (nature, food, other):note   alfalfa Search Trop Picture   apricot fruit Search Trop Picture   blackberry fruit Search PMC Picture   blueberry fruit Search Trop Picture   geranium bourbon Search Trop Picture   grape muscat grape Search PMC Picture   grapefruit Search Trop Picture   lime fruit Search Trop Picture   lime oil distilled mexico @ 0.22% Data GC Search Trop Picture   nectarine Search PMC Picture   wine riesling wine Search Picture   Synonyms:   bois de rose oxide 2- ethenyl tetrahydro-2,6,6-trimethyl-2H-pyran 2- ethenyl-2,6,6-trimethyloxane 2- ethenyl-2,6,6-trimethyltetrahydro-2H-pyran 2- ethenyltetrahydro-2,6,6-trimethyl-2H-pyran   geranic oxide   limetol (Givaudan)   linaloyl oxide 4H- pyran, 2,6,6-trimethyl-2-vinyl- 2H- pyran, 2-ethenyltetrahydro-2,6,6-trimethyl- 2H- pyran, tetrahydro-2,2,6-trimethyl-6-vinyl-   tetrahydro-2,2,6-trimethyl-6-vinyl-2H-pyran (±)- tetrahydro-2,6,6-trimethyl-2-vinyl-2H-pyran   trimethoxy-2-vinyl tetrahydropyran 2,6,6- trimethoxy-2-vinyltetrahydropyran 2,6,6- trimethyl-2-vinyl tetrahydropyran 2,6,6- trimethyl-2-vinyltetrahydropyran 2,2,6- trimethyl-6-ethenyl tetrahydropyran 2,2,6- trimethyl-6-vinyl tetrahydro-2H-pyran 2,2,6- trimethyl-6-vinyl tetrahydropyran 2,2,6- trimethyl-6-vinyl-tetrahydropyran 2,2,6- trimethyl-6-vinyltetrahydropyran 2,6,6- trimethyl-6-vinyltetrahydropyran   Articles:   None found yet. Try the PubMed Search.

Notes: Blends well with wild notes. Flavouring and fragrence ingredient. Present in roselle tea, muscat grapes, lime oil, alfalfa, Riesling wine, grapefruit, yellow passion fruit, apricot, blackberry, blueberry, nectarine, cherimoya, papaya and curuba fruits