EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

herbal acetal
herboxane (Givaudan)

Supplier Sponsors

Fragrance Demo Formulas
Name:2-butyl-4,4,6-trimethyl-1,3-dioxane
CAS Number: 54546-26-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:259-210-8
Nikkaji Web:J266.909I
XlogP3-AA:3.10 (est)
Molecular Weight:186.29474000
Formula:C11 H22 O2
NMR Predictor:Predict (works with chrome or firefox)
Category:fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 96.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.88600 to 8.90000 @ 25.00 °C.
Pounds per Gallon - (est).: 7.372 to 74.057
Refractive Index:1.42700 to 1.43100 @ 20.00 °C.
Boiling Point: 206.00 to 207.00 °C. @ 760.00 mm Hg
Vapor Pressure:0.330000 mmHg @ 25.00 °C. (est)
Flash Point: 166.00 °F. TCC ( 74.44 °C. )
logP (o/w): 3.265 (est)
Soluble in:
 alcohol
 water, 68.81 mg/L @ 25 °C (est)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: herbal
Odor Strength:medium
Substantivity: < 4 hour(s) at 100.00 %
herbal spicy chamomile green basil
Odor Description:at 100.00 %. herbal spice chamomile green basil
Luebke, William tgsc, (1985)
Odor sample from: Naarden International
Flavor Type: herbal
herbal green spicy juniper nutmeg allspice
Taste Description: herbal green spicy juniper nutmeg allspice
Odor and/or flavor descriptions from others (if found).
Givaudan
Herboxane
Odor Description:Fresh, Aromatic, Green
Herboxane is a spicy whilst distinctively herbal particularly basil. Reminiscent of sweet red pepper, Herboxan adds a distinctive freshness to a fragrance.
Vigon International
Herboxane (Valeraldehyde Hexylene Glycol Acetal)
Odor Description:Fresh, Aromatic, Green
Ernesto Ventós
HERBOXANE
Odor Description:HERBAL,SPICE,CHAMOMILE,GREEN BASIL
Tadimety Aromatics
Herbox
Odor Description:Fresh, Aromatic, Green
Moellhausen
HERBOXANE
Odor Description:Fresh, Aromatic, Green
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Augustus Oils
Herboxane
Services
BOC Sciences
For experimental / research use only.
2-Butyl-4,4,6-trimethyl-1,3-dioxane
Diffusions Aromatiques
HERBOLEX (HERBOXANE)
Ernesto Ventós
HERBOXANE
Odor: HERBAL,SPICE,CHAMOMILE,GREEN BASIL
Givaudan
Herboxane
Odor: Fresh, Aromatic, Green
Use: Herboxane is a spicy whilst distinctively herbal particularly basil. Reminiscent of sweet red pepper, Herboxan adds a distinctive freshness to a fragrance.
Indukern F&F
HERBOXANE
Odor: HERBAL, GREEN
Lluch Essence
HERBOXANE
Moellhausen
HERBOXANE 10%DPG
Moellhausen
HERBOXANE
PCW France
Herboxan
Steps to a fragranced product
Penta International
2-BUTYL-4,4,6-TRIMETHYL-1,3-DIOXANE
SRS Aromatics
HERBACETAL
SRS Aromatics
HERBAL ACETAL
Tadimety Aromatics
Herbox
Odor: Fresh, Aromatic, Green
The John D. Walsh Company
Herboxane
Vigon International
Herboxane (Valeraldehyde Hexylene Glycol Acetal)
Odor: Fresh, Aromatic, Green
 
Safety Information:
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 15S, 1992.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 15S, 1992.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
fragrance agents
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for herbal acetal usage levels up to:
  30.0000 % in the fragrance concentrate.
 
Recommendation for herbal acetal flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
EPA Substance Registry Services (TSCA):54546-26-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :94569
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
2-butyl-4,4,6-trimethyl-1,3-dioxane
Chemidplus:0054546268
 
References:
 2-butyl-4,4,6-trimethyl-1,3-dioxane
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:54546-26-8
Pubchem (cid):94569
Pubchem (sid):135050670
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
ChemSpider:View
 
Potential Blenders and core components note
For Odor
No odor group found for these
arnica montana flower extract
FL/FR
aldehydic
aldehydic
agrumen nitrile
FR
iso
butyraldehyde
FL/FR
citrus carbaldehyde
FR
nonanal (aldehyde C-9)
FL/FR
amber
angelica root oil
FL/FR
animal
iso
butyl quinoline
FR
anise
sweet
fennel seed oil
FL/FR
anisic
para-
anisaldehyde
FL/FR
ocimum basilicum herb oil
FL/FR
ocimum basilicum leaf oil america
FL/FR
ocimum basilicum leaf oil CO2 extract
FL/FR
balsamic
iso
amyl benzoate
FL/FR
amyris wood oil
FL/FR
artemisia annua herb oil bulgaria
FL/FR
siam
benzoin resinoid
FL/FR
benzyl cinnamate
FL/FR
benzyl salicylate
FL/FR
iso
butyl cinnamate
FL/FR
cinnamyl alcohol
FL/FR
clover nitrile
FR
ethyl cinnamate
FL/FR
fir balsam absolute
FR
fir needle oil siberia
FL/FR
methyl (E)-cinnamate
FL/FR
3-
phenyl propyl alcohol
FL/FR
berry
raspberry ketone methyl ether
FL/FR
caramellic
ethyl maltol
FL/FR
helichrysum italicum flower absolute
FL/FR
strawberry furanone
FL/FR
cheesy
2-
heptanone
FL/FR
chocolate
iso
amyl phenyl acetate
FL/FR
citrus
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
earthy
3-
octen-2-one
FL/FR
fatty
decanol
FL/FR
(E,Z)-2,6-
dodecadienal
FL/FR
perillaldehyde propylene glycol acetal
FL/FR
floral
alpha-
amyl cinnamaldehyde
FL/FR
iso
amyl salicylate
FL/FR
benzyl acetate
FL/FR
bois de rose oil brazil
FL/FR
cassie absolute replacer
FL/FR
cilantro herb oil egypt
FL/FR
citronellol
FL/FR
coriander oil replacer
FR
coriander seed oil
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
beta-
damascenone
FL/FR
9-
decen-1-ol
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinol
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
floral pyranol
FR
gardenia acetal
FR
geraniol
FL/FR
geranium oil africa
FL/FR
geranium oil bourbon
FL/FR
geranium oil china
FL/FR
heliotropyl diethyl acetal
FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hyacinth acetals
FL/FR
hyacinth ether
FR
hydroxycitronellal
FL/FR
(Z)-
jasmone
FL/FR
iso
jasmone
FL/FR
lavender absolute replacer
FR
leerall
FR
lilac absolute
FR
linalool
FL/FR
laevo-
linalool
FL/FR
linalool oxide
FL/FR
methyl dihydrojasmonate
FL/FR
millefleurs fragrance
FR
muguet carboxaldehyde
FR
nerol
FL/FR
nerolidol
FL/FR
nonanol
FL/FR
3-
nonanone
FL/FR
ocean propanal
FL/FR
orris pyridine 25% IPM
FR
peony alcohol
FR
phenethyl acetate
FL/FR
phenethyl alcohol
FL/FR
phenethyl propionate
FL/FR
2-
phenyl propionaldehyde dimethyl acetal
FL/FR
prenyl salicylate
FL/FR
rhodinol
FL/FR
rose absolute
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
rose butanoate
FL/FR
(Z)-
rose oxide
FL/FR
terpinyl isobutyrate
FL/FR
tetrahydrolinalool
FL/FR
violet methyl carbonate
FR
fruity
allyl amyl glycolate
FR
allyl cyclohexyl propionate
FL/FR
iso
amyl butyrate
FL/FR
benzyl propionate
FL/FR
(E)-beta-
damascone
FL/FR
gamma-
decalactone
FL/FR
1,4-
diethyl-6,8-dioxabicyclo(3.2.1)octane
FR
egletes viscosa flower oil
FR
green acetate
FR
herbanate (Givaudan)
FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
green
holy
basil leaf oil
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
black
currant bud absolute replacer
FL/FR
diphenyl oxide
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl benzoate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl tiglate
FL/FR
melon acetal
FL/FR
melon nonenoate
FL/FR
privet dioxane
FR
2-
propenyl-para-cymene
FR
hay
beeswax absolute
FL/FR
herbal
agate fragrance
FR
anthemis nobilis flower extract
FL/FR
anthemis nobilis flower oil roman
FL/FR
apium graveolens seed oil
FL/FR
sweet
basil absolute
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
carrot seed oil (daucus carota ssp. maximus (desf.) ball)
FR
carum carvi fruit oil
FL/FR
carvacryl methyl ether
FL/FR
celery ketone
FL/FR
chamomile oil morocco
FR
1,4-
cineole
FL/FR
clary sage oil america
FL/FR
clary sage oil france
FL/FR
clary sage oil russia
FL/FR
coriander oleoresin
FL/FR
coriander seed concrete
FR
daucus carota fruit oil
FL/FR
dehydroxylinalool oxide
FL/FR
(E)-2-
dodecenal
FL/FR
elder flower absolute (sambucus canadensis and s. nigra)
FR
florida soap fragrance
FR
geranium cyclohexane
FR
herbal fragrance
FR
herbal specialty
FR
hexyl salicylate
FL/FR
hyssop oil
FL/FR
lavender absolute bulgaria
FL/FR
lavender absolute france
FL/FR
spike
lavender oil
FL/FR
linalyl acetate
FL/FR
linalyl octanoate
FL/FR
marigold absolute (tagetes patula)
FR
matricaria chamomilla flower oil
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
T-
muurolol
FL/FR
3-
nonanol
FL/FR
3-
octanon-1-ol
FL/FR
oregano oil replacer
FR
oregano specialty
FR
origanum oil
FL/FR
curled
parsley leaf oil
FL/FR
curled
parsley seed oil
FL/FR
ravensara aromatica leaf oil
FR
rosmarinus officinalis extract
FL/FR
rosmarinus officinalis tincture
FL/FR
salvia sclarea oil
FL/FR
red
thyme oil india
FL/FR
red
thyme oil replacer
FR
red
thyme oil spain
FL/FR
marine
marine pyridine
FR
minty
betula lenta bark oil america
FL/FR
dextro-
dihydrocarvone
FL/FR
(-)-
menthone
FL/FR
peppermint oil special fractions
FL/FR
mossy
oakmoss absolute
FL/FR
oakmoss distillates
FL/FR
veramoss (IFF)
FR
naphthyl
beta-
naphthyl ethyl ether
FL/FR
powdery
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
spicy
benzyl isoeugenol
FL/FR
iso
butyl angelate
FL/FR
cardamom seed oil CO2 extract
FL/FR
carrot weed oil
FL/FR
carvacryl ethyl ether
FL/FR
cassia bark oil china
FL/FR
clove bud oil
FL/FR
(-)-
cubenol
FL/FR
cuminaldehyde
FL/FR
cuminyl alcohol
FL/FR
black
currant bud absolute
FL/FR
iso
eugenyl acetate
FL/FR
ginger root absolute
FL/FR
hollyberry fragrance
FR
maja fragrance
FR
sweet
marjoram oil replacer
FR
alpha-
methyl cinnamaldehyde
FL/FR
methyl isoeugenol
FL/FR
ocimum gratissimum herb oil india
FR
2-
octanol
FL/FR
origanum majorana oil
FL/FR
origanum majorana oil CO2 extract
FL/FR
outdoors specialty
FR
black
pepper oil
FL/FR
white
pepper oil
FL/FR
black
pepper oil CO2 extract
FL/FR
black
pepper oleoresin
FL/FR
pimenta acris leaf oil
FL/FR
saffron oil CO2 extract
FL/FR
annus
wormwood oil vietnam
FL/FR
terpenic
alpha-
terpineol
FL/FR
tonka
tonka bean absolute
FR
vanilla
ethyl vanillin
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
waxy
(Z)-3-
nonen-1-ol
FL/FR
woody
amber carbinol
FR
camphene
FL/FR
camphor tree wood oil
FR
cedarwood oil himalaya
FR
cistus twig/leaf oil
FL/FR
methyl cedryl ketone
FL/FR
patchouli absolute
FR
patchouli ethanone
FR
sandalwood fragrance
FR
sandalwood oil
FL/FR
sandalwood oil replacer
FR
sandalwood specialty
FR
santall
FR
spruce needle oil canada
FL/FR
(±)-
tetrahydronootkatone
FL/FR
tobacarol (IFF)
FR
vetiver oil haiti
FL/FR
woody acetate
FR
(Z)-
woody amylene
FR
For Flavor
No flavor group found for these
arnica montana flower extract
FL/FR
artemisia annua herb oil bulgaria
FL/FR
holy
basil leaf oil
FL/FR
sec-
butyl-3-methyl but-2-ene thioate
FL/FR
carvacryl ethyl ether
FL/FR
carvacryl methyl ether
FL/FR
cassie absolute replacer
FL/FR
methyl (E)-cinnamate
FL/FR
T-
muurolol
FL/FR
3-
nonanol
FL/FR
3-
octanon-1-ol
FL/FR
perillaldehyde propylene glycol acetal
FL/FR
terpinyl isobutyrate
FL/FR
(±)-
tetrahydronootkatone
FL/FR
aldehydic
aldehydic
iso
butyraldehyde
FL/FR
nonanal (aldehyde C-9)
FL/FR
anise
sweet
fennel seed oil
FL/FR
aromatic
hyacinth acetals
FL/FR
balsamic
siam
benzoin resinoid
FL/FR
benzyl salicylate
FL/FR
iso
butyl cinnamate
FL/FR
ethyl cinnamate
FL/FR
fir needle oil siberia
FL/FR
berry
raspberry ketone methyl ether
FL/FR
brown
beeswax absolute
FL/FR
camphoreous
camphene
FL/FR
caramellic
ethyl maltol
FL/FR
strawberry furanone
FL/FR
cheesy
2-
heptanone
FL/FR
citrus
bergamot oil bergaptene reduced italy
FL/FR
bergamot oil turkey
FL/FR
laevo-
linalool
FL/FR
linalool
FL/FR
nerol
FL/FR
alpha-
terpineol
FL/FR
cooling
1,4-
cineole
FL/FR
spike
lavender oil
FL/FR
creamy
para-
anisaldehyde
FL/FR
3-
octen-2-one
FL/FR
gamma-
undecalactone (aldehyde C-14 (so-called))
FL/FR
fatty
(Z)-3-
hexen-1-yl benzoate
FL/FR
floral
iso
amyl phenyl acetate
FL/FR
bois de rose oil brazil
FL/FR
citronellol
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl acetate
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
geraniol
FL/FR
geranium oil africa
FL/FR
geranium oil bourbon
FL/FR
geranium oil china
FL/FR
linalyl acetate
FL/FR
methyl dihydrojasmonate
FL/FR
ocean propanal
FL/FR
phenethyl alcohol
FL/FR
phenethyl propionate
FL/FR
rhodinol
FL/FR
rose absolute
FL/FR
rose absolute (rosa damascena) bulgaria
FL/FR
tetrahydrolinalool
FL/FR
fruity
allyl cyclohexyl propionate
FL/FR
iso
amyl benzoate
FL/FR
para-
anisyl acetate
FL/FR
para-
anisyl alcohol
FL/FR
benzyl acetate
FL/FR
benzyl propionate
FL/FR
black
currant bud absolute replacer
FL/FR
(E)-beta-
damascone
FL/FR
gamma-
decalactone
FL/FR
linalyl octanoate
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
2-
phenyl propionaldehyde dimethyl acetal
FL/FR
rose butanoate
FL/FR
strawberry glycidate 1 (aldehyde C-16 (so-called))
FL/FR
green
iso
amyl salicylate
FL/FR
angelica root oil
FL/FR
iso
butyl angelate
FL/FR
(+)-alpha-
campholenic aldehyde
FL/FR
carrot weed oil
FL/FR
celery ketone
FL/FR
cinnamyl alcohol
FL/FR
cyclamen aldehyde
FL/FR
cyclohexyl ethyl alcohol
FL/FR
dextro-
dihydrocarvone
FL/FR
diphenyl oxide
FL/FR
(E,Z)-2,6-
dodecadienal
FL/FR
helichrysum italicum flower absolute
FL/FR
(Z)-3-
hexen-1-ol
FL/FR
(Z)-3-
hexen-1-yl acetate
FL/FR
(Z)-3-
hexen-1-yl salicylate
FL/FR
(Z)-3-
hexen-1-yl tiglate
FL/FR
hexyl tiglate
FL/FR
iso
jasmone
FL/FR
linalool oxide
FL/FR
melon acetal
FL/FR
melon nonenoate
FL/FR
nerolidol
FL/FR
3-
nonanone
FL/FR
oakmoss absolute
FL/FR
(Z)-
rose oxide
FL/FR
herbal
anthemis nobilis flower extract
FL/FR
anthemis nobilis flower oil roman
FL/FR
apium graveolens seed oil
FL/FR
sweet
basil absolute
FL/FR
carum carvi fruit oil
FL/FR
cilantro herb oil egypt
FL/FR
clary sage oil america
FL/FR
clary sage oil france
FL/FR
clary sage oil russia
FL/FR
coriander oleoresin
FL/FR
coriander seed oil
FL/FR
daucus carota fruit oil
FL/FR
hexyl salicylate
FL/FR
hyssop oil
FL/FR
lavender absolute bulgaria
FL/FR
lavender absolute france
FL/FR
matricaria chamomilla flower oil
FL/FR
ocimum basilicum herb oil
FL/FR
ocimum basilicum leaf oil america
FL/FR
ocimum basilicum leaf oil CO2 extract
FL/FR
origanum majorana oil
FL/FR
origanum majorana oil CO2 extract
FL/FR
origanum oil
FL/FR
curled
parsley leaf oil
FL/FR
curled
parsley seed oil
FL/FR
prenyl salicylate
FL/FR
rosmarinus officinalis extract
FL/FR
rosmarinus officinalis tincture
FL/FR
salvia sclarea oil
FL/FR
red
thyme oil india
FL/FR
red
thyme oil spain
FL/FR
honey
phenethyl acetate
FL/FR
medicinal
dimethyl benzyl carbinol
FL/FR
minty
betula lenta bark oil america
FL/FR
(-)-
menthone
FL/FR
peppermint oil special fractions
FL/FR
mossy
oakmoss distillates
FL/FR
powdery
beta-
naphthyl ethyl ether
FL/FR
spicy
benzyl cinnamate
FL/FR
benzyl isoeugenol
FL/FR
cardamom seed oil CO2 extract
FL/FR
cassia bark oil china
FL/FR
clove bud oil
FL/FR
(-)-
cubenol
FL/FR
cuminaldehyde
FL/FR
cuminyl alcohol
FL/FR
black
currant bud absolute
FL/FR
iso
eugenyl acetate
FL/FR
ginger root absolute
FL/FR
alpha-
methyl cinnamaldehyde
FL/FR
methyl isoeugenol
FL/FR
2-
octanol
FL/FR
white
pepper oil
FL/FR
black
pepper oil
FL/FR
black
pepper oil CO2 extract
FL/FR
black
pepper oleoresin
FL/FR
3-
phenyl propyl alcohol
FL/FR
pimenta acris leaf oil
FL/FR
saffron oil CO2 extract
FL/FR
annus
wormwood oil vietnam
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
vanilla
ethyl vanillin
FL/FR
vanilla bean absolute (vanilla planifolia)
FL/FR
vanillyl acetate
FL/FR
waxy
iso
amyl butyrate
FL/FR
decanol
FL/FR
9-
decen-1-ol
FL/FR
(E)-2-
dodecenal
FL/FR
alpha-
hexyl cinnamaldehyde
FL/FR
hydroxycitronellal
FL/FR
nonanol
FL/FR
(Z)-3-
nonen-1-ol
FL/FR
woody
amyris wood oil
FL/FR
cistus twig/leaf oil
FL/FR
beta-
damascenone
FL/FR
dehydroxylinalool oxide
FL/FR
(Z)-
jasmone
FL/FR
methyl cedryl ketone
FL/FR
sandalwood oil
FL/FR
spruce needle oil canada
FL/FR
vetiver oil haiti
FL/FR
 
Potential Uses:
FRamber
FRbalsam
FRchamomile
FRherbal
FRmusk
FRoriental
FRpine
FRspice
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
2-butyl-4,4,6-trimethyl-1,3-dioxane
1,3-dioxane, 2-butyl-4,4,6-trimethyl-
 herbacetal
 herbal acetal
 herbox (Tadimety)
 herboxane (Givaudan)
2,4-O-pentylidene-2-methyl pentane-2,4-diol
 valeraldehyde hexylene glycol acetal
 valeraldehyde hexyleneglycol acetal
 

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