beta-naphthyl methyl ether
 
Notes:
Flavouring ingredient
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Fragrance Demo Formulas
Name: 2-methoxynaphthalene
CAS Number: 93-04-9Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 202-213-6
FDA UNII:VX2T1Z50C4
Nikkaji Web: J4.667A
Beilstein Number: 1859408
MDL: MFCD00004061
FEMA Number: 4704
CoE Number: 4074
XlogP3: 3.50 (est)
Molecular Weight: 158.19990000
Formula: C11 H10 O
BioActivity Summary: listing
NMR Predictor: Predict (works with chrome or firefox)
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 1257  beta-naphthyl methyl ether
Flavis Number: 04.074 (Old)
DG SANTE Food Flavourings: 04.074  2-methoxynaphthalene
FEMA Number: 4704  beta-naphthyl methyl ether
FDA Mainterm: BETA-NAPHTHYL METHYL ETHER
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Physical Properties:
Appearance: white crystalline flake (est)
Assay: 99.00 to 100.00 % 
Food Chemicals Codex Listed: No
Melting Point: 73.00 to  75.00 °C. @ 760.00 mm Hg
Boiling Point: 274.00 °C. @ 760.00 mm Hg
Congealing Point: 71.50 °C.
Vapor Pressure: 0.010000 mmHg @ 25.00 °C. (est)
Flash Point: 208.00 °F. TCC ( 98.00 °C. )
logP (o/w): 3.470
Shelf Life: 36.00 month(s) or longer if stored properly.
Storage: store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
 alcohol
 water, 75.88 mg/L @ 25 °C (est)
Insoluble in:
 dipropylene glycol
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Organoleptic Properties:
Odor Type: naphthyl
Odor Strength: high ,
recommend smelling in a 1.00 % solution or less
Odor Description:
at 1.00 % in dipropylene glycol. 
sweet naphthyl floral orange blossom acacia neroli
Substantivity: 400 Hour(s)
  
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
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Safety Information:
Most important hazard(s):
Xi N - Irritant, Dangerous for the environment.
  R 36/37/38 - Irritating to eyes, respiratory system, and skin.
R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
Human Experience: 4 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
  oral-rat LD50  > 5000 mg/kg
(Levenstein, 1974h)

oral-mouse LD50  [sex: M,F] 825 mg/kg
(Schafer & Bowles, 1985)

oral-rat LD50  > 5000 mg/kg
Food and Cosmetics Toxicology. Vol. 13, Pg. 885, 1975.

Dermal Toxicity:
  skin-rabbit LD50 > 5000 mg/kg
Food and Cosmetics Toxicology. Vol. 13, Pg. 885, 1975.

Inhalation Toxicity:
  Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for beta-naphthyl methyl ether usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 3.50 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.01 (μg/capita/day)
Structure Class: III
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 25
Click here to view publication 25
 average usual ppmaverage maximum ppm
baked goods: 13.0000017.00000
beverages(nonalcoholic): 4.000008.00000
beverages(alcoholic): 0.100000.30000
breakfast cereal: --
cheese: --
chewing gum: 9.0000014.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: 8.0000010.00000
fruit ices: --
gelatins / puddings: 9.0000011.00000
granulated sugar: --
gravies: --
hard candy: 3.000003.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 12.0000014.00000
soups: --
sugar substitutes: --
sweet sauces: --
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 3.0000015.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 2.0000010.00000
Edible ices, including sherbet and sorbet (03.0): 3.0000015.00000
Processed fruit (04.1): 2.0000010.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 10.0000050.00000
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.0000025.00000
Bakery wares (07.0): 10.0000050.00000
Meat and meat products, including poultry and game (08.0): 2.0000010.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.0000010.00000
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.0000025.00000
Foodstuffs intended for particular nutritional uses (13.0): 10.0000050.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 3.0000015.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.0000050.00000
Ready-to-eat savouries (15.0): 15.0000075.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.0000025.00000
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Safety References:
European Food Safety Athority(efsa): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 23 (FGE.23): Aliphatic, alicyclic and aromatic ethers including anisole derivatives From chemical groups 15, 16 and 26 (Commission Regulation (EC) No 1565/2000 of 18 July 2000
View page or View pdf
Flavouring Group Evaluation 59 (FGE.59): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 (2006) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf
Flavouring Group Evaluation 23, Revision 1 (FGE.23Rev1): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 26 and 30[1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010)
View page or View pdf
Scientific Opinion on the safety and efficacy of aromatic ethers including anisole derivatives (chemical group 26) when used as feed additives for all animal species
View page or View pdf
EPI System: View
Env. Mutagen Info. Center: Search
EPA Substance Registry Services (TSCA): 93-04-9
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 7119
National Institute of Allergy and Infectious Diseases: Data
WISER: UN 3082
WGK Germany:2
 2-methoxynaphthalene
Chemidplus: 0000093049
RTECS: QJ9468750 for cas# 93-04-9
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References:
 2-methoxynaphthalene
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 93-04-9
Pubchem (cid): 7119
Pubchem (sid): 134972534
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS): View
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB32861
FooDB: FDB010839
Export Tariff Code: 2909.30.6000
ChemSpider: View
Wikipedia: View
RSC Learn Chemistry: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 robinia pseudoacacia absoluteFR
 satinaldehydeFL/FR
aldehydic
 dodecanal (aldehyde C-12 lauric)FL/FR
2-methyl undecanal (aldehyde C-12 mna)FL/FR
 nonanal (aldehyde C-9)FL/FR
10-undecenal (aldehyde C-11 undecylenic)FL/FR
amber
 ambroxanFL/FR
animal
para-cresyl caprylateFL/FR
 indoleFL/FR
anisic
para-anisaldehydeFL/FR
balsamic
 amyris wood oilFL/FR
siam benzoin resinoidFL/FR
 benzophenoneFR
 benzyl cinnamateFL/FR
 benzyl salicylateFL/FR
isobutyl cinnamateFL/FR
 cinnamyl alcoholFL/FR
 clover nitrileFR
 ethyl cinnamateFL/FR
 fir balsam absoluteFR
 methyl cinnamateFL/FR
3-phenyl propyl alcoholFL/FR
berry
 raspberry ketoneFL/FR
 raspberry ketone acetateFL/FR
 raspberry ketone methyl etherFL/FR
caramellic
 ethyl maltolFL/FR
 strawberry furanoneFL/FR
citrus
 bergamot oilFL/FR
 curacao specialtyFR
2-dodecanoneFL/FR
 mandarin oil (citrus reticulata var. ponkan)FL/FR
 mandarin oil italyFL/FR
blood orange oil italyFL/FR
bitter orange peel oil brazilFL/FR
sweet orange peel oil c.p. brazilFL/FR
 petitgrain specialtyFR
 tetrahydromyrcenolFR
fatty
 decanolFL/FR
floral
 acetyl tetralinFR
alpha-amyl cinnamaldehydeFL/FR
isoamyl salicylateFL/FR
 benzyl acetateFL/FR
 benzyl alcoholFL/FR
 bois de rose oil brazilFL/FR
isobutyl salicylateFL/FR
 citronellolFL/FR
 citronellyl anthranilateFL/FR
 coriander seed oilFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
alpha-damasconeFL/FR
2-decanoneFL/FR
(Z)-4-decen-1-yl acetateFL/FR
 dimethyl anthranilateFL/FR
 dimethyl benzyl carbinolFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
 ethyl phenyl acetateFL/FR
 floral pyranolFR
pink frangipani absoluteFR
 geraniolFL/FR
 heliotropinFL/FR
 heliotropyl acetoneFL/FR
 heliotropyl diethyl acetalFR
(Z)-3-hexen-1-yl salicylateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 ho leaf oilFR
 hyacinth etherFR
 hydroxycitronellalFL/FR
 jasmin absolute (from chassis)FL/FR
 leerallFR
 leerall / methyl anthranilate schiff's baseFR
 lilyallFR
laevo-linaloolFL/FR
 linaloolFL/FR
 linalool oxideFL/FR
para-methyl acetophenoneFL/FR
 methyl dihydrojasmonateFL/FR
 muguet carboxaldehydeFR
beta-naphthyl methyl ketoneFL/FR
 nerolFL/FR
 neroli absoluteFL/FR
 neroli extractFL/FR
 neroli oilFL/FR
 neroli oil bigardeFL/FR
 nerolidolFL/FR
 nonanal / methyl anthranilate schiff's baseFR
 nonanolFL/FR
 ocean propanalFL/FR
bitter orangeflower absolute moroccoFL/FR
 orris pyridine 25% IPMFR
 peony alcoholFR
 petitgrain absolute moroccoFL/FR
 petitgrain bigarade oilFL/FR
 petitgrain oil fractionsFR
 petitgrain oil paraguayFL/FR
 petitgrain oil replacerFR
 phenethyl acetateFL/FR
 phenethyl alcoholFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl phenyl acetateFL/FR
 phenethyl propionateFL/FR
 phenethyl salicylateFL/FR
 rhodinolFL/FR
 rose butanoateFL/FR
 surfleurs d'oranger oilFL/FR
 tetrahydrolinaloolFL/FR
 violet methyl carbonateFR
 ylang ylang flower oilFL/FR
 ylang ylang specialtyFR
fruity
isoamyl acetateFL/FR
 benzyl propionateFL/FR
beta-damasconeFL/FR
gamma-decalactoneFL/FR
 methyl anthranilateFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
green
para-dimethyl hydroquinoneFL/FR
 diphenyl oxideFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
(Z)-3-hexen-1-yl propionateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
 phenyl acetaldehyde dimethyl acetalFL/FR
3-phenyl propionaldehydeFL/FR
 violet leaf absoluteFL/FR
hay
 beeswax absoluteFL/FR
 hay absoluteFR
herbal
 clary sage oil franceFL/FR
 lavender absolute bulgariaFL/FR
 linalyl acetateFL/FR
alpha-terpinyl acetateFL/FR
melon
 watermelon ketoneFR
mossy
 oakmoss absoluteFL/FR
 veramoss (IFF)FR
naphthyl
beta-naphthyl ethyl etherFL/FR
2-naphthyl phenyl ketone 
powdery
para-anisyl alcoholFL/FR
spicy
 benzyl isoeugenolFL/FR
 cassia bark oil chinaFL/FR
 clove bud oilFL/FR
 eugenolFL/FR
isoeugenyl acetateFL/FR
alpha-methyl cinnamaldehydeFL/FR
 methyl isoeugenolFL/FR
terpenic
 frankincense oilFL/FR
alpha-terpineolFL/FR
tonka
 coumarinFR
 tonka bean absoluteFR
vanilla
 ethyl vanillinFL/FR
 vanilla bean absolute (vanilla planifolia)FL/FR
 vanillyl acetateFL/FR
waxy
3-decanoneFL/FR
 decyl acetateFL/FR
1-dodecanolFL/FR
 ethyl laurateFL/FR
woody
 amber carbinolFR
 cedarwood oil virginiaFR
 guaiacwood oilFL/FR
 gurjun balsam oilFR
 patchouli ethanoneFR
 santallFR
 tobacarol (IFF)FR
 woody acetateFR
(Z)-woody amyleneFR
 
For Flavor
 
No flavor group found for these
3-decanoneFL/FR
(Z)-4-decen-1-yl acetateFL/FR
2-naphthyl phenyl ketone 
 surfleurs d'oranger oilFL/FR
beta-damasconeFL/FR
aldehydic
 nonanal (aldehyde C-9)FL/FR
animal
para-cresyl caprylateFL/FR
 indoleFL/FR
balsamic
siam benzoin resinoidFL/FR
 benzyl salicylateFL/FR
isobutyl cinnamateFL/FR
 ethyl cinnamateFL/FR
berry
 heliotropyl acetoneFL/FR
 raspberry ketoneFL/FR
 raspberry ketone acetateFL/FR
 raspberry ketone methyl etherFL/FR
brown
 beeswax absoluteFL/FR
caramellic
 ethyl maltolFL/FR
 strawberry furanoneFL/FR
cherry
 heliotropinFL/FR
citrus
 bergamot oilFL/FR
laevo-linaloolFL/FR
 linaloolFL/FR
 mandarin oil (citrus reticulata var. ponkan)FL/FR
 mandarin oil italyFL/FR
 nerolFL/FR
blood orange oil italyFL/FR
sweet orange peel oil c.p. brazilFL/FR
 petitgrain bigarade oilFL/FR
alpha-terpineolFL/FR
cooling
isobutyl salicylateFL/FR
creamy
para-anisaldehydeFL/FR
para-methyl acetophenoneFL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
fatty
2-dodecanoneFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
10-undecenal (aldehyde C-11 undecylenic)FL/FR
fermented
2-decanoneFL/FR
floral
 bois de rose oil brazilFL/FR
 citronellolFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
 geraniolFL/FR
 jasmin absolute (from chassis)FL/FR
 linalyl acetateFL/FR
 methyl dihydrojasmonateFL/FR
beta-naphthyl methyl ketoneFL/FR
 neroli absoluteFL/FR
 neroli extractFL/FR
 neroli oilFL/FR
 neroli oil bigardeFL/FR
 ocean propanalFL/FR
bitter orangeflower absolute moroccoFL/FR
 petitgrain absolute moroccoFL/FR
 phenethyl alcoholFL/FR
 phenethyl propionateFL/FR
 rhodinolFL/FR
 satinaldehydeFL/FR
 tetrahydrolinaloolFL/FR
 ylang ylang flower oilFL/FR
fruity
isoamyl acetateFL/FR
para-anisyl alcoholFL/FR
 benzyl acetateFL/FR
 benzyl alcoholFL/FR
 benzyl propionateFL/FR
 citronellyl anthranilateFL/FR
alpha-damasconeFL/FR
gamma-decalactoneFL/FR
 dimethyl anthranilateFL/FR
 methyl anthranilateFL/FR
bitter orange peel oil brazilFL/FR
 rose butanoateFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
green
isoamyl salicylateFL/FR
 cinnamyl alcoholFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
para-dimethyl hydroquinoneFL/FR
 diphenyl oxideFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl propionateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
 linalool oxideFL/FR
 nerolidolFL/FR
 oakmoss absoluteFL/FR
 phenyl acetaldehyde dimethyl acetalFL/FR
3-phenyl propionaldehydeFL/FR
 violet leaf absoluteFL/FR
herbal
 clary sage oil franceFL/FR
 coriander seed oilFL/FR
 lavender absolute bulgariaFL/FR
 petitgrain oil paraguayFL/FR
honey
 ethyl phenyl acetateFL/FR
 phenethyl acetateFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl phenyl acetateFL/FR
medicinal
 dimethyl benzyl carbinolFL/FR
 phenethyl salicylateFL/FR
powdery
beta-naphthyl ethyl etherFL/FR
soapy
 dodecanal (aldehyde C-12 lauric)FL/FR
1-dodecanolFL/FR
spicy
 benzyl cinnamateFL/FR
 benzyl isoeugenolFL/FR
 cassia bark oil chinaFL/FR
 clove bud oilFL/FR
 eugenolFL/FR
isoeugenyl acetateFL/FR
alpha-methyl cinnamaldehydeFL/FR
 methyl cinnamateFL/FR
 methyl isoeugenolFL/FR
3-phenyl propyl alcoholFL/FR
tropical
alpha-amyl cinnamaldehydeFL/FR
vanilla
 ethyl vanillinFL/FR
 vanilla bean absolute (vanilla planifolia)FL/FR
 vanillyl acetateFL/FR
waxy
 decanolFL/FR
 decyl acetateFL/FR
 ethyl laurateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 hydroxycitronellalFL/FR
2-methyl undecanal (aldehyde C-12 mna)FL/FR
 nonanolFL/FR
woody
 ambroxanFL/FR
 amyris wood oilFL/FR
 frankincense oilFL/FR
 guaiacwood oilFL/FR
alpha-terpinyl acetateFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 acaciaFR
 appleFR
 blackberryFR
 bouquetFR
 bubble gumFR
 cherryFR
 cherry blossomFR
 citrusFR
 coffeeFR
 cranberryFR
 dateFR
 fernFR
 fixer 
 floralFR
 gardeniaFR
 gooseberryFR
 grapeFR
 grenadineFL
 honeysuckleFR
 jasminFR
 magnoliaFR
 melonFR
 mulberryFR
 narcissusFR
 neroliFR
 orange blossomFR
 peachFR
 pineappleFR
 plumFR
 rainFR
 raspberryFR
 rose moss roseFR
 spring rainFR
 strawberryFR
 sweet peaFR
 teaFL
 tropicalFL
 vanillaFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
2-methoxy naphthalene
.beta.-methoxynaphthalene
2-methoxynaphthalene
beta-methoxynaphthalene
 methyl 2-naphthyl ether
 methyl beta-naphthyl ether
 methyl naphthalen-2-yl ether
beta-naphthol mether ether
2-naphthol methyl ether
2-naphthyl methyl ether
beta-naphthyl methyl ether
 naphthyl methyl ether 10% BB
beta-napthyl methyl ether
 nerolin yara yara
 neroline yara yara
 yara yara
 yara yara crystals
 yara yara distilled
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