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Category:indirect food additives: adhesives and components of coatings
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless crystalline solid (est) |
| Assay: | 95.00 to 100.00
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 1.30500 @ 25.00 °C.
|
| Melting Point: | 149.60 °C. @ 760.00 mm Hg
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| Boiling Point: | 146.00 °C. @ 760.00 mm Hg (est)
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| Vapor Pressure: | 4.730000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 108.00 °F. TCC ( 42.10 °C. ) (est)
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| logP (o/w): | 0.580 (est) |
| Soluble in: |
| | water, 6.30E+05 mg/L @ 25 °C (exp) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 750 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(10), Pg. 51, 1986.
oral-mouse LD50 500 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(10), Pg. 51, 1986.
intraperitoneal-mouse LD50 > 100 mg/kg
National Technical Information Service. Vol. AD277-689
oral-guinea pig LD50 500 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(10), Pg. 51, 1986.
oral-human TDLo 430 mg/kg
BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"
GASTROINTESTINAL: NAUSEA OR VOMITING
GASTROINTESTINAL: OTHER CHANGES
Deutsches Archiv fuer Klinische Medizin. Vol. 102, Pg. 606, 1911.
intraperitoneal-mouse LD50 500 mg/kg
National Technical Information Service. Vol. AD277-689
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| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
inhalation-mammal (species unspecified) LC > 100 mg/m3
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(10), Pg. 51, 1986.
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Safety in Use Information:
| Category: | | indirect food additives: adhesives and components of coatings |
| Recommendation for ammonium thiocyanate usage levels up to: | | | not for fragrance use.
|
| |
| Recommendation for ammonium thiocyanate flavor usage levels up to: |
| | not for flavor use.
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Safety References:
References:
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Indirect Additives used in Food Contact Substances: | View |
| CHEMBL: | View |
| HMDB (The Human Metabolome Database): | Search |
| Export Tariff Code: | 2838.00.0000 |
| ChemSpider: | View |
| Wikipedia: | View |
Formulations/Preparations:
•grades: technical; cp; 50 to 60 % solution.
•usual grade is 98-99% pure.
•grades or purity: reagent; technical, 50-65% soln in water
•amitrole-t (union carbide); radazone tl was a mixture of amitrole and ammonium thiocyanate
•a technical crystal of 98% minimum assay with approximately 2 wt % maximum of water content is commercially available, as well as a 50-55 wt % aqueous solution. the latter is the predominant product.
•commercial products are 50-60% solution.
•rhodanid
•trans-aid
•usaf ek-p-433
•amthio
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Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | ammonium rhodanate | | | ammonium rhodanide | | | ammonium sulfocyanide | | | ammoniumthiocyanate | | | azanium thiocyanate | | | rhodanine, ammonium salt | | | thiocyanic acid ammonium salt | | | thiocyanic acid, ammonium salt |
Articles:
| PubMed:Assessment of IgG avidity against pertussis toxin and filamentous hemagglutinin via an adapted enzyme-linked immunosorbent assay (ELISA) using ammonium thiocyanate. |
| PubMed:Assembling novel Cd(II) complexes with multidentate nitrogen donor ligands obtained in situ from the system: zerovalent copper, cadmium oxide, 1-hydroxymethyl-3,5-dimethylpyrazole and ammonium thiocyanate. |
| PubMed:Multicomponent reactions of ammonium thiocyanate, acyl chlorides, alkyl bromides, and enaminones: a facile one-pot synthesis of thiophenes. |
| PubMed:Extraction of high-quality epidermal RNA after ammonium thiocyanate-induced dermo-epidermal separation of 4 mm human skin biopsies. |
| PubMed:Amitrole Translocation in Agropyron repens Increased by the Addition of Ammonium Thiocyanate. |
| PubMed:A one-pot synthesis of functionalized thiazoles from acid chlorides, secondary amines, ethyl bromopyruvate, and ammonium thiocyanate. |
| PubMed:[Simultaneous determination of ammonium thiocyanate and its isomeride by dual wavelength multiplication subtractive spectrophotometry]. |
| PubMed:Herbicide: fatal ammonium thiocyanate and aminotriazole poisoning. |
| PubMed:Formation of proline thiohydantoin with ammonium thiocyanate: progress towards a viable C-terminal amino-acid-sequencing procedure. |
| PubMed:Ammonium thiocyanate for detaching antibodies from histological specimens. |
| PubMed:Synthesis of phospholipids in microstructures, prepared by the interaction of ammonium thiocyanate, minerals, calcium acetate, potassium dihydrogen phosphate, and formaldehyde. |
| PubMed:Ultrasound-assisted thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and DDQ. |
| PubMed:Study of the interactions of sodium thiocyanate, potassium thiocyanate and ammonium thiocyanate in water+N,N-dimethylformamide mixtures by Raman spectroscopy. |
| PubMed:[Effect of ammonium thiocyanate and thiourea on the immune system]. |
| PubMed:[Validation of the tentative safety levels of thiourea and ammonium thiocyanate in the air]. |
| PubMed:Determination of the carboxyl termini of proteins with ammonium thiocyanate and acetic anhydride, with direct identification of the thiohydantoins. |
| PubMed:Spectrophotometric determination of traces of thiourea in ammonium thiocyanate. |
| PubMed:[STUDIES ON METHODS OF STANDARDIZATION OF O.1 N SILVER NITRATE AND O.1 N AMMONIUM THIOCYANATE]. |
| PubMed:The thiocyanate titration of mercury and the standardization of ammonium thiocyanate solution. |
| PubMed:The bacterial purification of gas-works liquors: The biological oxidation of ammonium thiocyanate. |
| PubMed:[Determination of trace iron and cobalt in natoral water by ammonium thiocyanate resin phase-spectrophotometry]. |
| PubMed:[Characteristics of toxicokinetics of ammonium thiocyanate]. |
| PubMed:[Method of determining ammonium thiocyanate]. |
| PubMed:[Data providing a basis for the maximum allowable concentration of ammonium thiocyanate in workplace air]. |
| PubMed:Extraction of vanadium(V) chelates with N-benzohydroxamic acid (BHA) and ammonium thiocyanate and its application in steel and rock analyses. |
| PubMed:[29] Sequential degradation of peptides and proteins from their COOH termini with ammonium thiocyanate and acetic anhydride. |
| PubMed:Sequential degradation of peptides from their carboxyl termini with ammonium thiocyanate and acetic anhydride. |
| PubMed:Lifetime, mobility, and diffusion of photoexcited carriers in ligand-exchanged lead selenide nanocrystal films measured by time-resolved terahertz spectroscopy. |
| PubMed:Impaired haemophilus influenzae type b transplacental antibody transmission and declining antibody avidity through the first year of life represent potential vulnerabilities for HIV-exposed but -uninfected infants. |
| PubMed:Rhenium mixed-ligand complexes with S,N,S-tridentate thiosemicarbazone/thiosemicarbazide ligands. |
| PubMed:Synthesis, characterization, and evaluation of 10-undecenoic acid-based epithio derivatives as multifunctional additives. |
| PubMed:Avidity of IgG antibodies against meningococcal serogroup a polysaccharide and correlations with bactericidal activity in sera from meningitis patients and controls from Ethiopia. |
| PubMed:Air-stable, nanostructured electronic and plasmonic materials from solution-processable, silver nanocrystal building blocks. |
| PubMed:Synthesis, spectroscopic and theoretical studies of ethyl (2E)-3-amino-2-({[(4-benzoyl-1,5-diphenyl-1H-pyrazol-3-yl)carbonyl]amino}carbonothioyl)but-2-enoate butanol solvate. |
| PubMed:High ionicity ionic liquids (HIILs): comparing the effect of ethylsulfonate and ethylsulfate anions. |
| PubMed:Solvent-free synthesis of functionalized thiazoles using multicomponent reaction of isothiocyanates. |
| PubMed:Synthesis and anticancer activity of acyl thioureas bearing pyrazole moiety. |
| PubMed:Chemical Stability of the Lipid Phase in Concentrated Beverage Emulsions Colored with Natural β-Carotene. |
| PubMed:A series of inorganic solid nitrogen sources for the synthesis of metal nitride clusterfullerenes: the dependence of production yield on the oxidation state of nitrogen and counter ion. |
| PubMed:Synthesis, structural and vibrational properties of 1-(adamantane-1-carbonyl)-3-halophenyl thioureas. |
| PubMed:Plant growth regulators enhance gold uptake in Brassica juncea. |
| PubMed:High carrier mobility in single ultrathin colloidal lead selenide nanowire field effect transistors. |
| PubMed:Synthesis and bioactivity of pyrazole acyl thiourea derivatives. |
| PubMed:Phytotoxicity of thiocyanate to rice seedlings. |
| PubMed:A rapid, four-component synthesis of functionalized thiazoles. |
| PubMed:Thiocyanate-capped nanocrystal colloids: vibrational reporter of surface chemistry and solution-based route to enhanced coupling in nanocrystal solids. |
| PubMed:Effects of select anions from the Hofmeister series on the gas-phase conformations of protein ions measured with traveling-wave ion mobility spectrometry/mass spectrometry. |
| PubMed:Microscale chemistry-based design of eco-friendly, reagent-saving and efficient pharmaceutical analysis: a miniaturized Volhard's titration for the assay of sodium chloride. |
| PubMed:In vitro and in vivo antioxidant activities of the aqueous extract of Celosia argentea leaves. |
| PubMed:The beta-core fragment of chorionic gonadotropin is not complexed to macromolecules in amniotic fluid. |
| PubMed:Biochemical identification of pharmacologically and functionally distinct GABA receptors in rat brain. |
| PubMed:Synthesis and anticancer activity evaluation of 4-thiazolidinones containing benzothiazole moiety. |
| PubMed:Synthesis of functionalized 1,2,4-triazole-3-thiones from ammonium isothiocyanate, acid chlorides, and arylhydrazines. |
| PubMed:Long-term conservation of HCV RNA at 4 degrees C using a new RNA stabilizing solution. |
| PubMed:Bioactivity of major components from the seeds of Bunium persicum (Boiss.) Fedtch. |
| PubMed:Cr(III)-Cr(III) interactions in two alkoxo-bridged heterometallic Zn2Cr2 complexes self-assembled from zinc oxide, Reinecke's salt, and diethanolamine. |
| PubMed:Direct synthesis of an heterometallic {Mn(II)3Cr(III)4} wheel by decomposition of Reineckes salt. |
| PubMed:Forensic analysis of explosives using isotope ratio mass spectrometry (IRMS)--part 1: instrument validation of the DELTAplusXP IRMS for bulk nitrogen isotope ratio measurements. |
| PubMed:An extremely rare example of asymmetric tetranuclear core {M(4)(mu(3)-X)(2)(mu-X)(4)} in a novel alkoxo-bridged heterometallic Cr/Cd complex. |
| PubMed:In vitro studies on the antioxidant and protective effect of 2-substituted -8-hydroxyquinoline derivatives against H(2)O(2)-induced oxidative stress in BMSCs. |
| PubMed:HIV-1 infection in Zambian children impairs the development and avidity maturation of measles virus-specific immunoglobulin G after vaccination and infection. |
| PubMed:Comparison of antioxidant and free radical scavenging activities of the essential oils from flowers and fruits of Otostegia persica Boiss. |
| PubMed:Different interaction of estradiol and antiestrogens with the estrogen receptor of rat uterus. |
| PubMed:Spectroscopic study for photocatalytic decomposition of organic compounds on titanium dioxide containing sulfur under visible light irradiation. |
| PubMed:Measurement of relative avidity of antibodies reactive with Porphyromonas (Bacteroides) gingivalis in the sera of subjects having adult periodontitis. |
| PubMed:Affinity chromatography of antibodies directed against soybean lipoxygenase-1 and -2 and an enzyme-linked immunosorbent assay (ELISA) for antibodies and lipoxygenases. |
| PubMed:Purification and characterization of human kidney plasminogen activator dissimilar to urokinase. |
| PubMed:Spectrophotometric determination of molybdenum(VI). |
| PubMed:Synthesis and antitumor activity of some new xanthotoxin derivatives. |
| PubMed:Isolation of the key intermediates in the catalyst-free conversion of oxiranes to thiiranes in water at ambient temperature. |
| PubMed:9-Triptycenecarboxylate-Bridged Diiron(II) Complexes: Capture of the Paddlewheel Geometric Isomer. |
| PubMed:Free radical scavenging and lipid peroxidation activity of the Shahani black grape. |
| PubMed:Electrocatalytic behaviour of carbon paste electrode modified with iron(II) phthalocyanine (FePc) nanoparticles towards the detection of amitrole. |
| PubMed:Flow-injection simultaneous determination of iron(III) and copper(II) and of iron(III) and palladium(II) based on photochemical reactions of thiocyanato-complexes. |
| PubMed:Influence of inorganic mobile phase additives on the retention and separation efficiency of selected amino acids in thin-layer chromatography on cellulose layers. |
| PubMed:Criss-cross cycloadditions on ketazines derived from alicyclic ketones. |
| PubMed:Anticancer and anti-inflammatory sulfur-containing semisynthetic derivatives of sarcophine. |
| PubMed:On formation of thiohydantoins from amino acids under acylation conditions. |
| PubMed:Spectrophotometric detection of iodide and chromic (III) in urine after oxidation to iodine and chromate (VI). |
| PubMed:Elevated serum IgG titer and avidity to Actinobacillus actinomycetemcomitans serotype c in Japanese periodontitis patients. |
| PubMed:Synthesis of some new annulated pyrazolo-pyrido (or pyrano) pyrimidine, pyrazolopyridine and pyranopyrazole derivatives. |
| PubMed:Antikinetoplastid activity of 3-aryl-5-thiocyanatomethyl-1,2,4-oxadiazoles. |
| PubMed:Use of a novel elution regimen reveals the dominance of polyreactive antinuclear autoantibodies in lupus kidneys. |
| PubMed:Intensely positively charged perineuronal nets in the adult rat brain as detected by staining with anionic iron colloid. |
| PubMed:Decomposition of alkyl-substituted urea molecules at a hydroxide-bridged dinickel center. |
| PubMed:Synthesis and antimicrobial activity of 4-carbethoxymethyl-2-[(alpha-haloacyl)amino] thiazoles and 5-nonsubstituted/substituted 2-[(4-carbethoxymethylthiazol-2-yl)imino]-4-thiazolidinones. |
| PubMed:Use of diffuse reflectance spectrometry in spot test reactions for quantitative determination of cations in water. |
| PubMed:An improved chemical approach toward the C-terminal sequence analysis of proteins containing all natural amino acids. |
| PubMed:Synthesis and antibacterial activity of 5-aryl-2-[(alpha-chloro-alpha-phenylacetyl/alpha-bromopropionyl)amino]- 1,3,4-oxadiazoles and 2-[(5-aryl-1,3,4-oxadiazol-2-yl)imino]-5-phenyl/methyl-4-thiazolidinone s. |
| PubMed:Chemical carboxy-terminal sequence analysis of peptides using acetyl isothiocyanate. |
| PubMed:Down-regulation of pituitary receptors for luteinizing hormone-releasing hormone (LH-RH) in rats by LH-RH antagonist Cetrorelix. |
| PubMed:The assessment of antibody affinity distribution by thiocyanate elution: a simple dose-response approach. |
| PubMed:Langerhans cells are the major source of mRNA for IL-1 beta and MIP-1 alpha among unstimulated mouse epidermal cells. |
| PubMed:Serum HCG beta-core fragment is masked by associated macromolecules. |
| PubMed:Investigation of penbutolol-iron (III) complex and its spectrophotometric determination in tablets. |
| PubMed:Fractionation of plasma proteins by pseudo-ligand affinity chromatography. Elution from immobilized Brown Fractogel TSK-AF. |
| PubMed:Fine anionic iron colloid and its use in light and electron microscopic detection of cationic sites in the rat kidney. |
| PubMed:Solubilization of quisqualate-sensitive L-[3H]glutamate binding sites from guinea pig brain membranes using a zwitterionic detergent. |
| PubMed:Titrimetric determination of ascorbic acid using chloranil. |
| PubMed:Determination of molybdenum by extraction of its thiocyanate into ethyl methyl ketone. |
| PubMed:Isolation of human glomerular basement membrane antigens by affinity chromatography utilising Goodpasture's kidney antibody eluates. |
| PubMed:Solvent extraction separation of hafnium with 4-methyl-3-pentene-2-one. |
| PubMed:New staining techniques for the Langerhans cell. |
| PubMed:Colorimetric determination of zirconium with 1-(2-pyridylazo)-2-naphthol. |
| PubMed:Synthesis of a sulfur-containing amino acid under simulated prebiotic conditions. |
| PubMed:The use of anion-exchange disks in an optrode coupled to a multi-syringe flow-injection system for the determination and speciation analysis of iron in natural water samples. |
| PubMed:Flow systems exploiting in-line prior assays. |
| PubMed:Specific determination of ferbam residues in fog-water. |
| PubMed:Changes in free-radical scavenging ability of kombucha tea during fermentation. |
| PubMed:Rapid, high-quality and epidermal-specific isolation of RNA from human skin. |
| PubMed:Spectrophotometric method for quantitative determination of iron (III) from iron polymaltose complex in pharmaceutical formulations. |
| PubMed:Alkylthio unit as an alpha-pyrrole protecting group for use in dipyrromethane synthesis. |
| PubMed:Comparison of three ELISA protocols to measure antibody responses elicited against serogroup C meningococcal polysaccharide in mouse, monkey and human sera. |
| PubMed:Intramolecular, reductive cyclization of beta-ketoisothiocyanates promoted by using samarium diiodide. |
| PubMed:A novel one-pot, four component synthesis of some densely functionalized pyrroles. |
| PubMed:Replacement of cyanogen bromide solution PH. EUR. with 1,3-dibromo-5,5-dimethylhydantoin (DBH). Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern, Part 13. |
| PubMed:Phenol-containing macrocyclic diamides as new catalysts in the highly regioselective conversion of epoxides to beta-hydroxy thiocyanates. |
| PubMed:Humoral immune response in early-onset periodontitis: influence of smoking. |
| PubMed:Antioxidant properties of a North American ginseng extract. |
| PubMed:Evaluation of toxin neutralisation in test systems for diphtheria antibody assessment. |
| PubMed:Comparison of physical chemical properties of llama VHH antibody fragments and mouse monoclonal antibodies. |
| PubMed:Seborrhoeic dermatitis is not caused by an altered immune response to Malassezia yeast. |
| PubMed:Spectrophotometric study of diclofenac-Fe(III) complex. |
| PubMed:Investigation of Fe(III) chloride as a colour reagent for the spectrophotometric determination of bumetanide in the pure form and in preparations. |
| PubMed:Purification and photoaffinity labeling of the I-Ak histocompatibility molecule. |
| PubMed:Spectrophotometric determination of oxprenolol hydrochloride as its Fe (III) complex. |
| PubMed:Production, characterization, and utility of monoclonal antibodies which react with a novel chimeric glycoprotein of human respiratory syncytial virus termed FG. |
| PubMed:Low affinity antibody to rubella antigen in patients after rubella infection in utero. |
| PubMed:Ratio of Langerhans cells to Thy-1+ dendritic epidermal cells in murine epidermis influences the intensity of contact hypersensitivity. |
| PubMed:Liquid-liquid extraction separation and sequential determination of plutonium and americium in environmental samples by alpha-spectrometry. |
| PubMed:Biochemical analysis and biological activities of immunoaffinity purified natural murine gamma interferon (MuIFN-gamma). |
| PubMed:Dissimilarities between the uterine estrogen receptor in cytosol of castrated and estradiol-treated rats. |
| PubMed:Glycidyl methacrylate copolymers as suitable supports for immobilizing antigens and antibodies. |
| PubMed:Gas-liquid chromatographic determination of trace amounts of nitrite in egg, egg white, and egg yolk. |
| PubMed:Particle counting immunoassay (PACIA) of ferritin. |
| PubMed:A human choriocarcinoma xenograft in nude mice; a model for the study of antibody localization. |
| PubMed:A technique of silver impregnation for nervous tissues with some thiocyanates. |
| PubMed:Separation of plasminogen activators from human uterine tissue and a comparison with activators from human urine and porcine tissue. |
| PubMed:[On the influence of thiocyanates on the delayed immune response in intact and epinephrectomised guinea pigs (author's transl)]. |
| PubMed:Comparative study of abiogenesis of cysteine and other amino acids catalyzed by various metal ions. |
| PubMed:Ion-exchange behaviour of metals on deae-cellulose in methanol-thiocyanate-hydrochloric acid media. |
| PubMed:Sulphoxides as solvating reagents for the separation of metal ions. |
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3D/inchi